CN1073702A - Glass flake anticorrosion paint and manufacture method thereof - Google Patents
Glass flake anticorrosion paint and manufacture method thereof Download PDFInfo
- Publication number
- CN1073702A CN1073702A CN 91111830 CN91111830A CN1073702A CN 1073702 A CN1073702 A CN 1073702A CN 91111830 CN91111830 CN 91111830 CN 91111830 A CN91111830 A CN 91111830A CN 1073702 A CN1073702 A CN 1073702A
- Authority
- CN
- China
- Prior art keywords
- glass flake
- glass
- resins
- flake
- amine curing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention provides a kind of glass flake anticorrosion paint and manufacture method thereof.It is by Resins, epoxy, solvent, glass flake, titanate coupling agent, and modified amine curing agent is formed.With glass microballon in advance with ferruginous water glass spray, again through broken, spray titanate and glass flake.Its coating has the superior corrosion resistance energy, can be used for heavily corrosion protection field such as sewer line, storage tank.
Description
The present invention relates to a kind of glass flake anticorrosion paint and manufacture method thereof, it belongs to coating and manufacturing field thereof, comprises the protective system and the manufacture method thereof that contain Resins, epoxy, solvent, glass flake, modified amine curing agent.
In the past, metal is low with protective system preservative effect in strong corrosive environment, particularly adopt common protective system and glass reinforced plastic lining, common life-span 2-5 in sewer line, storage tank are anticorrosion.Adopt glass flake anticorrosion paint, promptly in protective system, add corrosion resistant glass flake and obtain effect preferably with the corrosion of resisting surrounding medium, cohesive force between the scale and coating reduces behind the glass flake but add in coating, makes coating be easy to generate layering under external force and chemical corrosion effect.For addressing this problem, adopt silane coupling agent dipping glass flake, for example Japanese publication JP57-179254.Yet this silane coupling agent costs an arm and a leg, and effect is not fine.Mostly existing glass-flake coating is to adopt melten glass to make microballon to form through fragmentation, be difficult for being parallel distribution in spraying, for example Japanese publication JP57-168963.In order to promote being arranged in parallel of glass flake, prolong the curing reaction time and be and be arranged in parallel for example Japanese publication JP56-87474 to increase scale.Prolong set time so undoubtedly, influence production efficiency.In addition, above-mentioned these flake paints are ambient cures, be not easy to solidify at low temperature, and coating performance reduce.
The objective of the invention is to avoid the deficiency of above-mentioned prior art and provide cohesive force between a kind of glass flake and the resin strong, glass flake is easy to a kind of glass flake anticorrosion paint and manufacture method thereof parallel distribution, that erosion resistance is strong, cheap, low-temperature curable.
Purpose of the present invention can reach by following measure.Glass flake anticorrosion paint of the present invention contains Resins, epoxy, solvent, glass flake, modified amine curing agent, it is characterized in that containing titante coupling agent.
Glass flake anticorrosion paint of the present invention, contain the constituent of following proportioning:
100 parts of bisphenol A type epoxy resins
Dimethylbenzene 1-25 part
Glass flake 5-30 part
Titante coupling agent 0.01-10 part
Modified amine curing agent 5-30 part
Flake anticorrosive paint of the present invention, wherein glass flake is to adopt broken by flyash hollow core glass microballon and glass flake that get.
Flake anticorrosive paint of the present invention can contain furfuryl alcohol resin or coal-tar pitch.Each set of dispense is such as following:
100 parts of bisphenol A type epoxy resins
Coal-tar pitch 5-25 part
Dimethylbenzene 1-25 part
Glass flake 5-30 part
Titanic acid ester 0.01-30 part
Modified amine curing agent 5-30 part
Coal-tar pitch in the above-mentioned constituent can be replaced with the furfuryl alcohol resin of equivalent.
The Resins, epoxy that contains among the present invention can adopt bisphenol f type epoxy resin, can improve the antiseptic property of coating.The molecular weight of Bisphenol F type epoxy tree is 390-1400.
Purpose of the present invention can also reach by following measure.A kind of manufacture method that contains the glass flake anticorrosion paint of Resins, epoxy, solvent, glass flake, titante coupling agent, modified amine curing agent of the present invention, it is characterized in that with glass microballon spray contain behind the water glass liquid, drying, broken classification of iron powder again spray titanate class coupling agent, with its gained glass flake with Resins, epoxy, solvent, before spraying workpiece, mix with modified amine curing agent again and spray.
Specify the present invention below.Flake anticorrosive paint of the present invention, wherein Resins, epoxy can be selected bisphenol A type epoxy resin for use, as homemade trade mark E51, E-44, E-42, also can adopt bisphenol f type epoxy resin, as the bisphenol f type epoxy resin of Shanghai resins plants production.
Wherein solvent can be selected commercially available xylene solution for use, also can select the mixed solvent of dimethylbenzene and butanols for use, and usage quantity is by 100 parts of Resins, epoxy (by weight, as follows), and dimethylbenzene is 1-25 part, as is less than 1 part, fully dissolved epoxy; As wasting solvents greater than 25 parts.
Glass flake consumption among the present invention is 5-30 part, and it is not remarkable that consumption is less than 5 parts of anticorrosion effects; The property puddled of coating is bad as greater than 30 parts the time, and antiseptic property lowers.Glass flake among the present invention is to be made by following method: with flyash hollow core glass microballon spray one deck contain the water glass liquid of iron powder, then dry, fragmentation make one side contain the glass flake of irony, again with this scale spray titanate coupling agent, make the circular arc sheet glass flake of mean thickness 5-12 micron, mean particle size 420-520 micron.
Titanate coupling agent consumption among the present invention is 0.01-10 part, the cohesive force during 0.01 part of less than between glass flake and the resin is weak, when surpassing 10 parts, the effect increase not significantly and uneconomical.Titanate coupling agent among the present invention can be selected sec.-propyl three (iso stearate base) titanic acid ester, sec.-propyl three (dioctyl pyrophosphoryl base) titanic acid ester, two (dioctyl pyrophosphoryl base) ethylene titanic acid ester, sec.-propyl two (methacryloyl) Unimac 5680 base titanic acid ester, sec.-propyl three (dioctyl phosphate) titanic acid ester, sec.-propyl three (dodecyl benzenesulfonyl) titanic acid ester for use, single alkoxy type coupling agent be arranged as commercially available NOE-102 type coupling agent, or corrdination type coupling agent such as commercially available NOE-401 type preferably.
Modified amine curing agent of the present invention is to be the modified amine curing agent of the linear phenolic structure of raw material synthetic band oxygen by phenol, formaldehyde, quadrol, dihydroxyphenyl propane, synthetic method identical with common resol synthetic method, (promptly identical with commercially available product T31 modified amine curing agent method for making).Add-on 5-30 part of modified amine curing agent, paint solidification is insufficient when being lower than 5 parts, reduces the anti-corrosion capability of coating as greater than 30 parts the time.Adopt this modified amine curing agent can guarantee that the low temperature at-5 ℃ also can make the coating good solidification.
Glass flake anticorrosion paint of the present invention also can add tinting pigment, antisettling agent (as organic bentonite), stopping composition (as talcum powder) etc.
The Resins, epoxy that contains of the present invention, solvent, glass flake, titanate coupling agent, the manufacture method of the glass flake anticorrosion paint of modified amine curing agent is as follows: at first flyash water float glass process is selected glass microballon, perhaps be blow molded into the glass hollow ball with melten glass, it is made glass microballon or hollow ball outside surface coating one deck iron compound with the water glass liquid spraying that contains iron powder, dry then, broken, classification obtains glass flake, again it is sprayed with titanic acid ester, make the glass flake entire coating that titanate coupling agent be arranged, thereby make this glass flake easy and paint adhesion under the titanate coupling agent effect.In addition, contain the iron powder material, in electrostatic spraying, become positively charged when workpiece because this glass flake is an one side, spraying be coated with on the strip negative electricity time, glass flake is arranged in parallel under the iron powder influence easily.Then with this scale again with Resins, epoxy, solvent, Resins, epoxy can elder generation and solvent, makes so-called A liquid like this, in addition with solidifying agent as B liquid before the spraying workpiece, A liquid is mixed spraying with B liquid, also can adopt methods such as brushing, roller coat, airless spraying.Wherein B liquid adopts modified amine curing agent among the present invention.Both consumptions are 100 weight parts by Resins, epoxy (solid ingredient) generally, and the modified amine curing agent consumption is 5-30 part.
Elaborate below in conjunction with embodiment.
Embodiment 1
A component: weight part
Bisphenol A type epoxy resin (homemade trade mark E-42) 100.0
Dimethylbenzene (commercially available product all can) 25.0
Glass flake (with the water glass liquid spraying that contains iron powder) 25.0
Titanic acid ester (is used to spray above-mentioned glass flake, employing Jinxi chemical industry
Factory produces NOE102 titanic acid ester product) 0.2
Talcum powder (commercially available product all can) 20.0
Antisettling agent (bentonite, commercially available product all can) 2.0
Carbon black 0.2
B component: weight part
(modification of T31 type is produced in second chemical plant, Zhangjiagang to modified amine curing agent
Amine hardener) 30.0
Dehydrated alcohol (commercially available) (also can) 5.0
Above-mentioned A component is puddled evenly, and the B component is puddled evenly, when coating its A component and B component is mixed.Apply, can adopt airless spraying, brushing, roller coat, electrostatic spraying, adopt electrostatic spraying to obtain good result among the present invention.Adopted the rod iron that has eliminated rust of diameter 10mm, long 100mm by the workpiece that sprayed, coating afterwards build, is measured its results of property and is seen Table 1-5 ℃ of ambient cures 14 days greater than 300 microns.
Embodiment 2
A component: weight part
Bisphenol A type epoxy resin (E-42) 100.0
Dimethylbenzene 10.0
Coal-tar pitch (80% solution, commercially available product) 20.0
Glass flake (through containing the water glass liquid spraying of iron powder) 20.0
Titanic acid ester (the NOE102 type is produced in the chemical plant, Jinxi) 0.5
Antisettling agent (bentonite) 2.0
Tinting pigment (carbon black) 5.0
B component: weight part
Modified amine curing agent (the T31 type is produced in second chemical plant, Zhangjiagang) 30.0
Dehydrated alcohol (commercially available) (also can) 5.0
Method for producing paint etc. are identical with embodiment 1.
Embodiment 3
Identical with embodiment 2, but will be wherein coal-tar pitch change the furfuryl alcohol resin of equivalent into.
Embodiment 4
Identical with embodiment 1, but in the A component, also add 20 parts of chromoxide greens, 20 parts of titanium dioxide.
Embodiment 5
Identical with embodiment 1, but wherein powder coal ash glass-microballons changes melten glass blown glass hollow ball into, and other is handled all with embodiment 1.
Comparative example 1
Other is all identical except that the glass flake of embodiment 1 is handled without titanic acid ester.
Comparative example 2
The glass microballon preparation of glass flake in embodiment 1 by the water glass solution spray that need not contain iron powder, all the other are all identical.
Compared with the prior art the present invention has the following advantages:
1, glass flake anticorrosion paint of the present invention can obtain having the corrosion-inhibiting coating of good adhesive property, acid-resisting, salt-resistance, alkali resistance.
2, adopt titanate coupling agent cost low (only be silane coupler price 1/4). And And effective.
3, can adopt electrostatic spraying and obtain the coating that glass flake is parallel distribution. Speed of application is fast, and the coating antiseptic performance is good.
4, can be-5 ℃ low-temperature setting.
5, adopt the very big reduction of powder coal ash glass-microballons cost, and function admirable.
6, glass flake anticorrosion paint of the present invention can be used for oilfield sewage pipeline, storage tank, chemical storage tank, offshore engineering equipment antiseptic project aspect.
Claims (8)
1, a kind of glass flake anticorrosion paint contains Resins, epoxy, solvent, glass flake, modified amine curing agent, it is characterized in that containing titante coupling agent.
2, a kind of glass flake anticorrosion paint as claimed in claim 1 is characterized in that containing the constituent of following proportioning:
100 parts of bisphenol A type epoxy resins (weight part, below all with)
Dimethylbenzene 1-25 part
Glass flake 5-30 part
Titante coupling agent 0.01-10 part
Modified amine curing agent 5-30 part
3, a kind of flake anticorrosive paint as claimed in claim 1 or 2 is characterized in that containing broken by flyash hollow core glass microballon and glass flake that get.
4, a kind of glass flake anticorrosion paint as claimed in claim 1 is characterized in that containing coal-tar pitch or furfuryl alcohol resin.
5, a kind of glass flake anticorrosion paint as claimed in claim 4 is characterized in that containing the constituent of following proportioning:
100 parts of bisphenol A type epoxy resins
Coal-tar pitch 5-25 part
Dimethylbenzene 1-25 part
Glass flake 5-30 part
Titanic acid ester 0.01-10 part
Modified amine curing agent 5-30 part
Coal-tar pitch in the above-mentioned constituent can be replaced with the equivalent furfuryl alcohol resin.
6, a kind of flake anticorrosive paint as claimed in claim 1 is characterized in that Resins, epoxy wherein is bisphenol f type epoxy resin.
7, a kind of glass flake anticorrosion paint as claimed in claim 6 is characterized in that containing the bisphenol f type epoxy resin that molecular weight is 390-1400.
8, a kind of manufacture method that contains the glass flake anticorrosion paint of Resins, epoxy, solvent, glass flake, titanate coupling agent, modified amine curing agent, the water glass liquid, drying fragmentation, classification that it is characterized in that glass microballon spray is contained iron powder again spray titanate class coupling agent, with its gained glass flake with Resins, epoxy, solvent, before spraying workpiece, mix with modified amine curing agent again and spray.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN91111830A CN1035622C (en) | 1991-12-27 | 1991-12-27 | Glass flake anticorrosion paint and its making method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN91111830A CN1035622C (en) | 1991-12-27 | 1991-12-27 | Glass flake anticorrosion paint and its making method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1073702A true CN1073702A (en) | 1993-06-30 |
| CN1035622C CN1035622C (en) | 1997-08-13 |
Family
ID=4910891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN91111830A Expired - Fee Related CN1035622C (en) | 1991-12-27 | 1991-12-27 | Glass flake anticorrosion paint and its making method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1035622C (en) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1083208A3 (en) * | 1998-09-19 | 2001-03-21 | Roland Thom | Anti-corrosion coating for metal masts and a process for restoring metal masts |
| CN1111262C (en) * | 2000-01-01 | 2003-06-11 | 华东理工大学 | Compound steel pipe and pipe elements with liner of glass scales and resin, and making method thereof |
| CN100375765C (en) * | 2006-04-05 | 2008-03-19 | 中国人民解放军国防科学技术大学 | Environment-friendly acid-resistant anticorrosion paint |
| CN100393829C (en) * | 2006-06-01 | 2008-06-11 | 江苏兰陵化工集团有限公司 | Anticorrosive ethenyl ester resin glass flake paint for wet flue desulfating equipment |
| CN100396725C (en) * | 2006-01-13 | 2008-06-25 | 上海昭和高分子有限公司 | Surface treatment method of scale resin with glass scale and prepn process of scale resin |
| CN101007921B (en) * | 2006-01-24 | 2010-05-12 | 中国科学院过程工程研究所 | Anticorrosion paint for chimney of electric plant and its uses |
| CN101875808A (en) * | 2010-05-31 | 2010-11-03 | 刘昆虎 | Epoxy glass flake anticorrosive paint |
| CN101914341A (en) * | 2010-09-02 | 2010-12-15 | 太仓市高分子材料研发中心有限公司 | Light-colored conductive heavy-duty coating and preparation method thereof |
| CN101643615B (en) * | 2008-08-06 | 2011-08-17 | 中国科学院金属研究所 | Polyaniline modified glass flake heavy-duty anti-corrosive coating and preparation method thereof |
| CN101643621B (en) * | 2008-08-06 | 2011-08-24 | 中国科学院金属研究所 | Polyester heavy-duty anticorrosive coating with polyaniline-modified glass flakes, and preparation method thereof |
| CN102190946A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | Acid-resistant corrosion-resistant finish paint for high-temperature-resistant glass flake used by desulfurizer |
| CN102190944A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | High-temperature acid-resistant corrosion-resistant intermediate coating for inner wall of chimney |
| CN102190947A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | High-temperature-resistant glass flake acidproof anticorrosion primer for desulfurizing unit |
| CN102337069A (en) * | 2010-07-21 | 2012-02-01 | 泰安市环境卫生管理处 | Anticorrosive coating of dustbin and preparation method thereof |
| CN102719195A (en) * | 2012-06-12 | 2012-10-10 | 天长市巨龙车船涂料有限公司 | Pipeline coating, application thereof and pipeline coated with same |
| CN102719170A (en) * | 2011-04-25 | 2012-10-10 | 沈阳中科腐蚀控制工程技术中心 | Flake heavy-duty coating for desulfurizing flues and preparation method thereof |
| CN103205187A (en) * | 2012-12-16 | 2013-07-17 | 青岛天人环境股份有限公司 | Anticorrosive coating |
| CN103709895A (en) * | 2013-12-05 | 2014-04-09 | 江苏金波新材料科技有限公司 | Anticorrosive paint used for pipes |
| CN103773168A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Flame-retardant smokeless environmentally-friendly glass reinforced plastic coating material and preparation method thereof |
| CN103773173A (en) * | 2012-10-17 | 2014-05-07 | 中国石油天然气集团公司 | High performance anticorrosive paint for oil field pipes and painting method |
| CN103965746A (en) * | 2014-05-08 | 2014-08-06 | 江苏山力漆业有限公司 | High-temperature acid-resistant interface agent for inner wall of chimney |
| CN104194560A (en) * | 2014-08-15 | 2014-12-10 | 广西梧州龙鱼漆业有限公司 | Epoxy glass-flake antiseptic paint and preparation method thereof |
| CN106634414A (en) * | 2016-11-22 | 2017-05-10 | 天长市金陵电子有限责任公司 | Electrostatic spraying pipe coating with high corrosion resistance |
| CN106811002A (en) * | 2017-01-11 | 2017-06-09 | 合肥英索莱特新材料科技有限公司 | Pipeline anti-corrosive paint |
| CN106833266A (en) * | 2017-01-11 | 2017-06-13 | 合肥英索莱特新材料科技有限公司 | Epoxy coal tar anti-corrosive paint |
| CN109266176A (en) * | 2018-09-21 | 2019-01-25 | 佛山市禅城区诺高环保科技有限公司 | A kind of glass flake anticorrosion paint |
| CN109985792A (en) * | 2018-10-11 | 2019-07-09 | 马付林 | A kind of long range coated lining anti-corrosion method of inner wall of steel pipe |
| CN112724631A (en) * | 2020-12-21 | 2021-04-30 | 上海日之升科技有限公司 | High-shading and high-reflection polycarbonate composite material and preparation method thereof |
| CN115491106A (en) * | 2022-10-12 | 2022-12-20 | 天津华能杨柳青热电有限责任公司 | Epoxy furan glass flake daub and preparation and use methods thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643322B (en) * | 2008-08-06 | 2011-08-03 | 中国科学院金属研究所 | Vinyl ester heavy-duty anticorrosive coating with polyaniline-modified glass flakes, and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57179254A (en) * | 1981-04-27 | 1982-11-04 | Daido Toryo Kk | Method for undercoating of metal surface |
| JPS6044350B2 (en) * | 1982-03-26 | 1985-10-03 | 大日本塗料株式会社 | Anticorrosive coating composition |
| JPH0216614A (en) * | 1988-07-05 | 1990-01-19 | Nec Corp | Established value pre-registration input system for general purpose terminal equipment |
-
1991
- 1991-12-27 CN CN91111830A patent/CN1035622C/en not_active Expired - Fee Related
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1083208A3 (en) * | 1998-09-19 | 2001-03-21 | Roland Thom | Anti-corrosion coating for metal masts and a process for restoring metal masts |
| CN1111262C (en) * | 2000-01-01 | 2003-06-11 | 华东理工大学 | Compound steel pipe and pipe elements with liner of glass scales and resin, and making method thereof |
| CN100396725C (en) * | 2006-01-13 | 2008-06-25 | 上海昭和高分子有限公司 | Surface treatment method of scale resin with glass scale and prepn process of scale resin |
| CN101007921B (en) * | 2006-01-24 | 2010-05-12 | 中国科学院过程工程研究所 | Anticorrosion paint for chimney of electric plant and its uses |
| CN100375765C (en) * | 2006-04-05 | 2008-03-19 | 中国人民解放军国防科学技术大学 | Environment-friendly acid-resistant anticorrosion paint |
| CN100393829C (en) * | 2006-06-01 | 2008-06-11 | 江苏兰陵化工集团有限公司 | Anticorrosive ethenyl ester resin glass flake paint for wet flue desulfating equipment |
| CN101643615B (en) * | 2008-08-06 | 2011-08-17 | 中国科学院金属研究所 | Polyaniline modified glass flake heavy-duty anti-corrosive coating and preparation method thereof |
| CN101643621B (en) * | 2008-08-06 | 2011-08-24 | 中国科学院金属研究所 | Polyester heavy-duty anticorrosive coating with polyaniline-modified glass flakes, and preparation method thereof |
| CN101875808B (en) * | 2010-05-31 | 2012-10-24 | 刘昆虎 | Epoxy glass flake anticorrosive paint |
| CN101875808A (en) * | 2010-05-31 | 2010-11-03 | 刘昆虎 | Epoxy glass flake anticorrosive paint |
| CN102337069A (en) * | 2010-07-21 | 2012-02-01 | 泰安市环境卫生管理处 | Anticorrosive coating of dustbin and preparation method thereof |
| CN101914341A (en) * | 2010-09-02 | 2010-12-15 | 太仓市高分子材料研发中心有限公司 | Light-colored conductive heavy-duty coating and preparation method thereof |
| CN101914341B (en) * | 2010-09-02 | 2012-10-03 | 太仓市开林油漆有限公司 | Light-colored conductive heavy-duty coating and preparation method thereof |
| CN102190946A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | Acid-resistant corrosion-resistant finish paint for high-temperature-resistant glass flake used by desulfurizer |
| CN102190944A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | High-temperature acid-resistant corrosion-resistant intermediate coating for inner wall of chimney |
| CN102190947A (en) * | 2011-03-22 | 2011-09-21 | 无锡市山力高温涂料有限公司 | High-temperature-resistant glass flake acidproof anticorrosion primer for desulfurizing unit |
| CN102190947B (en) * | 2011-03-22 | 2012-10-10 | 江苏山力漆业有限公司 | High-temperature-resistant glass flake acidproof anticorrosion primer for desulfurizing unit |
| CN102190944B (en) * | 2011-03-22 | 2013-03-20 | 无锡市山力高温涂料有限公司 | High-temperature acid-resistant corrosion-resistant intermediate coating for inner wall of chimney |
| CN102719170A (en) * | 2011-04-25 | 2012-10-10 | 沈阳中科腐蚀控制工程技术中心 | Flake heavy-duty coating for desulfurizing flues and preparation method thereof |
| CN102719170B (en) * | 2011-04-25 | 2015-03-18 | 沈阳中科腐蚀控制工程技术中心 | Flake heavy-duty coating for desulfurizing flues and preparation method thereof |
| CN102719195A (en) * | 2012-06-12 | 2012-10-10 | 天长市巨龙车船涂料有限公司 | Pipeline coating, application thereof and pipeline coated with same |
| CN103773173A (en) * | 2012-10-17 | 2014-05-07 | 中国石油天然气集团公司 | High performance anticorrosive paint for oil field pipes and painting method |
| CN103773173B (en) * | 2012-10-17 | 2016-05-11 | 中国石油天然气集团公司 | A kind of oil field tube High Performance Corrosion Protective Coatings and painting method |
| CN103205187A (en) * | 2012-12-16 | 2013-07-17 | 青岛天人环境股份有限公司 | Anticorrosive coating |
| CN103709895B (en) * | 2013-12-05 | 2016-08-17 | 江苏金波新材料科技有限公司 | A kind of anticorrosive paint for tubing |
| CN103709895A (en) * | 2013-12-05 | 2014-04-09 | 江苏金波新材料科技有限公司 | Anticorrosive paint used for pipes |
| CN103773168A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Flame-retardant smokeless environmentally-friendly glass reinforced plastic coating material and preparation method thereof |
| CN103965746A (en) * | 2014-05-08 | 2014-08-06 | 江苏山力漆业有限公司 | High-temperature acid-resistant interface agent for inner wall of chimney |
| CN103965746B (en) * | 2014-05-08 | 2016-06-29 | 江苏山力漆业有限公司 | A kind of acidproof interfacial agents of the high temperature for inner wall of stack |
| CN104194560A (en) * | 2014-08-15 | 2014-12-10 | 广西梧州龙鱼漆业有限公司 | Epoxy glass-flake antiseptic paint and preparation method thereof |
| CN106634414A (en) * | 2016-11-22 | 2017-05-10 | 天长市金陵电子有限责任公司 | Electrostatic spraying pipe coating with high corrosion resistance |
| CN106811002A (en) * | 2017-01-11 | 2017-06-09 | 合肥英索莱特新材料科技有限公司 | Pipeline anti-corrosive paint |
| CN106833266A (en) * | 2017-01-11 | 2017-06-13 | 合肥英索莱特新材料科技有限公司 | Epoxy coal tar anti-corrosive paint |
| CN109266176A (en) * | 2018-09-21 | 2019-01-25 | 佛山市禅城区诺高环保科技有限公司 | A kind of glass flake anticorrosion paint |
| CN109985792A (en) * | 2018-10-11 | 2019-07-09 | 马付林 | A kind of long range coated lining anti-corrosion method of inner wall of steel pipe |
| CN112724631A (en) * | 2020-12-21 | 2021-04-30 | 上海日之升科技有限公司 | High-shading and high-reflection polycarbonate composite material and preparation method thereof |
| CN115491106A (en) * | 2022-10-12 | 2022-12-20 | 天津华能杨柳青热电有限责任公司 | Epoxy furan glass flake daub and preparation and use methods thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1035622C (en) | 1997-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1035622C (en) | Glass flake anticorrosion paint and its making method | |
| CN101555379B (en) | Epoxy nano composite anticorrosion coating for low surface treatment and preparation method thereof | |
| CN109370364B (en) | Nano anticorrosive paint for metal surface in acid-related environment and preparation method thereof | |
| CN114106608B (en) | Low-VOC (volatile organic compound) water-based two-component epoxy zinc-rich coating and preparation method thereof | |
| CN106590356A (en) | Basalt flake anticorrosion paint | |
| CN101591499A (en) | Heavy sizing aqueous heavy anti-corrosion paint and production method | |
| CN103709901B (en) | A kind of Nanometer solvent-free epoxy antirust paint and preparation method thereof | |
| CN1141344C (en) | Priming paint for wet and rusted surface | |
| CN110922855A (en) | Water-based high-temperature-resistant long-acting anticorrosive paint and preparation method thereof | |
| CN102277064A (en) | Epoxy coal pitch anticorrosive paint | |
| CN111004557A (en) | Nano modified epoxy heavy-duty anticorrosive paint | |
| CN114752278B (en) | Solvent-free high-temperature-resistant heavy-duty anticorrosive paint and preparation method thereof | |
| CN109294401A (en) | A kind of watersoluble plumbago alkene zinc-rich paint and preparation method thereof | |
| CN102757724A (en) | Black rust-proof ultraviolet (UV) curing paint for oil steel pipe | |
| CN1318656A (en) | Nanometer treatment method of aluminium shape surface | |
| CN108977003A (en) | Watery anti-corrosion low temperature self-drying paint and anti-flash rusting coating process for ironcasting | |
| CN1329114A (en) | Thick paste air dry water priming paint | |
| CN103725162A (en) | Polypyrrole-bisphenol A epoxy resin composite coating and preparation method thereof | |
| CN1696223A (en) | Drip-dry epoxy presservative strip without solvent | |
| CN1696222A (en) | Epoxy enamel lacquer no need of solvent | |
| CN113861781A (en) | Super quick-drying and rapidly-packaged thick-coating type single-component water-based anticorrosive coating for cast pipe | |
| CN108977004B (en) | Single-component double-curing in-pipeline anti-drag high-adaptability acrylic epoxy coating and preparation method thereof | |
| CN102151651B (en) | Preparation method of surface-coated bar with chloridion erosion resistance | |
| CN1234792C (en) | Nano environmental protection liquid aluminium foil and its preparation method and use method | |
| CN110484072A (en) | A kind of anticorrosive paint and its application method applied in aluminum alloy surface |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |