CN107364926A - A kind of ultrasonic wave depth algae-removing device and method - Google Patents
A kind of ultrasonic wave depth algae-removing device and method Download PDFInfo
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- CN107364926A CN107364926A CN201710604482.5A CN201710604482A CN107364926A CN 107364926 A CN107364926 A CN 107364926A CN 201710604482 A CN201710604482 A CN 201710604482A CN 107364926 A CN107364926 A CN 107364926A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
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- Hydrology & Water Resources (AREA)
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Abstract
The invention discloses it is a kind of including be sequentially connected flotation tank, except algae pipeline and the device in several heavy algae ponds being connected in parallel, wherein, it is described except algae pipeline is internally provided with ultrasonic probe;The bottom in each heavy algae pond is provided with scraper, ash pit and water discharging valve, in flotation tank and except being provided with inlet valve between algae pipeline and except algae pipeline and each between heavy algae pond.Present invention further proposes the method carried out using said apparatus except algae.Apparatus of the present invention carry out advanced treating to the water sample after Bubble-floating Method processing, and the purpose for efficiently going in water removal to remain algae can be reached, and reach with water requirement, and the harmful material such as Algae toxins is discharged except during algae frustule will not rupture, whole device realizes Automated condtrol by programmable logic controller (PLC) (PLC);Pipeline internal ultrasonic ripple probe laying mode be advantageous to probe maintained and safeguarded, the more hommization of the management to whole device.
Description
Technical field
The invention belongs to water-treatment technology field, more particularly to a kind of ultrasonic wave depth algae-removing device and method.
Background technology
It is one of main water environmental problems that China faces that large area microcystis waterbloom, which breaks out,.Microcystis waterbloom not only influences
Water landscape, heavy damage is produced to water area ecological environment, it is also possible to produce Algae toxins;If it occurs in water head site water body,
Water factory's operation and drinking water safety may be seriously endangered.
At present, both at home and abroad common algae-removing method include Physical (machinery drag for algae method, manually salvage, the method for dredging changes water law
Deng, these methods, not only cost is high but also efficiency is low), chemical method (mainly add the chemical agents such as sodium hypochlorite, copper sulphate with
And flocculant, this method easily cause the death and cracking of frustule so that intracellular organic matter discharges, and causes secondary pollution) and
Bioanalysis (mainly launches predator, this method can not quickly remove algae and efficiency is low).And for waterworks
For, if containing substantial amounts of algae in raw water, above-mentioned three kinds of methods are not used to the processing to algae in raw water.It is near several
Year, air flotation technology is applied in terms of the efficient algae removal of waterworks.The air production entered during air supporting in water
Raw microbubble is attached to formation gas algae mixture on algae, due to the imbalance of density between gas algae mixture and liquid, produces
Buoyancy, separation of solid and liquid is realized so as to reach a kind of purpose (air floatation alga removings of Guangdong Liansu Scientific And Technical Industry Co., Ltd of removal algae
Aeration oxygen replenishing shower nozzle:China, ZL201220367431.8 [P] .2013-03-20.).Traditional air flotation technology is that China is currently wide
A kind of general method for being applied to algae in processing raw water of waterworks, but by traditional air-float technology equipment limit, air supporting process
In caused bubble diameter larger (80-100 μm) cause on the premise of not dosing coagulant remove algae effect (Ye Jian
A kind of micro- air floatation alga removing devices and its algae-removing method for small water of peak:China, ZL201310299604.6 [P]
.2013-09-25.), if dosing coagulant is possible to that water quality security can be caused.Therefore need to find it is a kind of to air supporting after
Water sample carries out the method for advanced treating, while to reach high clearance and can prevent frustule rupture release harmful substance
(cell inclusion etc.) and cause water quality security, so as to preferably meeting water demand.
The content of the invention
To solve technical problem present in prior art, the present invention proposes a kind of ultrasonic wave depth algae-removing device and side
Method, advanced treating is carried out to the water sample after Bubble-floating Method processing, and the purpose for efficiently going in water removal to remain algae can be reached, and reached
Required with water.
Technical scheme:To realize above-mentioned technical purpose, ultrasonic wave depth algae-removing device of the invention, it is characterised in that bag
Include be sequentially connected flotation tank, except algae pipeline and several heavy algae ponds being connected in parallel, wherein, it is described except being set inside algae pipeline
It is equipped with ultrasonic probe;The bottom in each heavy algae pond is provided with scraper, ash pit and water discharging valve, in flotation tank and removes algae pipe
Inlet valve is provided between road and except algae pipeline and each between heavy algae pond.Whole device passes through Programmable logical controller
Device (PLC) realizes Automated condtrol.
Preferably, described remove has been equidistantly positioned four ultrasonic probes, upside two, downside two inside algae pipeline.
Enter Line Continuity, homogeneity processing to raw water containing algae except the design of algae pipeline can guarantee that.
It is further preferred that the parameter of ultrasonic probe is arranged to:Supersonic frequency is 30~35kHz, and ultrasound intensity is
0.0206~0.0353W/mL, ultrasonic time are 5~10s.
Wherein, designed except the length of algae pipeline according to processing time and flow velocity so that under certain water sample flow velocity, protect
Card water sample can handle 5-10s in pipeline.
Preferably, heavy algae bottom of pond portion is connected with skew wall, and skew wall inclination angle is 45 °~75 °.
Present invention further proposes the method carried out using above-mentioned ultrasonic wave depth algae-removing device except algae, its feature exists
In comprising the following steps:
Water sample after air supporting is introduced except algae pipeline is ultrasonically treated, the water sample after processing enters first heavy algae pond,
Heavy algae pond orlop is ash pit, and the depth of water reaches set depth (in general Practical Project, as long as ensureing that the water in heavy algae pond does not overflow
Go out, a water level sensor can be installed above heavy algae pond) after, inlet valve is closed, and second heavy algae pond starts to intake,
Then carry out successively, after the sedimentation time of algae in first heavy algae pond the optimal sedimentation time is reached, open the draining in heavy algae pond
Valve, when the first heavy algae pool inner water can not discharge, open ash pit row algae, while the scraper of both sides is by the remaining algae of side wall
Strike off, subsequent first heavy algae pond starts to intake again, and remaining heavy algae pond is intake by this, arranges algae successively.
Preferably, the parameter of ultrasonic probe is arranged to:Supersonic frequency is 30~35kHz, ultrasound intensity is 0.0206~
0.0353W/mL, ultrasonic time are 5~10s.
Beneficial effect is:Compared with prior art, the invention has the advantages that:
1st, the device carries out advanced treating to the water sample after Bubble-floating Method processing, and can reach and efficiently go in water removal to remain algae
Purpose, and reach with water requirement;
2nd, the device each several part cost is not very high, and whole device can realize Automated condtrol, except during algae not
Frustule can be made to rupture and discharge the harmful material such as Algae toxins;
3rd, the laying mode of the ultrasonic probe to sink in algae pond can carry out homogeneous, continuous processing to raw water containing algae;It is and favourable
In being maintained it and safeguarded, the management more hommization of whole device.
Brief description of the drawings
Fig. 1 is influence of the ultrasonic time to chlorophyll clearance;
Fig. 2 is influence of the ultrasonic time to the rate of settling;
Fig. 3 is influence of the ultrasonic time to frustule rupture rate;
Fig. 4 is influence of the ultrasonic time to algae clearance;
Fig. 5 is ultrasonic wave depth algae-removing device structural representation
Fig. 6 is to remove algae pipeline internal structure schematic diagram, wherein, 1- flotation tanks, 2- inlet valves, 3- water pumps, 4- flowmeters,
5- ultrasonic probes, 6- remove algae pipeline, 7- aqueducts, 8- scrapers, 9- ash pits, 10- water discharging valves, and 11- sinks algae pond.
Embodiment
The present invention proposes a kind of ultrasonic wave depth algae-removing device, as shown in figures 5 and 6, including the air supporting being sequentially connected
Pond 1, except algae pipeline 6 and several heavy algae ponds 11 being connected in parallel, wherein, it is described to be visited except algae pipeline is internally provided with ultrasonic wave
First 5;The bottom in each heavy algae pond 11 is provided with scraper 8, ash pit 9 and water discharging valve 10, flotation tank with except algae pipeline it
Between and except algae pipeline and each between heavy algae pond be provided with inlet valve 2.Water in flotation tank 1 is delivered to by water pump 3 to be removed
Algae pipeline 6, and by being arranged at water pump 3 and except the flowmeter 4 between algae pipeline 6 determines flow.Except algae pipeline 6 passes through water-supply-pipe
Road 7 is connected with each heavy algae pond 11 respectively.Except being equidistantly positioned four ultrasonic probes inside algae pipeline, upside two, under
Side two.Enter Line Continuity, homogeneity processing to raw water containing algae except the design of algae pipeline can guarantee that.Whole device passes through programmable
Logic controller (PLC) realizes Automated condtrol.
In use, the water sample after air supporting is introduced except algae pipeline is ultrasonically treated, the water sample after processing enters first
Individual heavy algae pond, heavy algae pond orlop are ash pit, and the depth of water reaches set depth (in general Practical Project, as long as ensureing heavy algae pond
In water do not spill over, a water level sensor can be installed above the heavy algae pond) after, inlet valve is closed, second heavy algae
Pond starts to intake, and then carries out successively, and after the sedimentation time of algae in first heavy algae pond the optimal sedimentation time is reached, it is heavy to open
The water discharging valve in algae pond, when the first heavy algae pool inner water can not discharge, open ash pit row algae, while the scraper of both sides is by side
The remaining algae of wall is struck off, and subsequent first heavy algae pond starts to intake again, and remaining heavy algae pond is intake by this, arranged successively
Algae.
Below by specific embodiment, the present invention is further described.
Embodiment 1
The wawter bloom Microcystis aeruginosa (more than 90% phytoplankton is microcystis kutz) gathered using summer Lake Taihu, by 0.45
The suspension that Taihu Lake raw water after μm membrane filtration is configured to low algae cell density (OD680 0.2) again is experiment algae kind, and
Laboratory carries out removing algae effect experiment.
(1) take the above-mentioned algae suspensions of 200mL to be placed in 400mL beakers, be ultrasonically treated 5,10,30,60 and 300s, ultrasound intensity
0.0353W/mL is set to, supersonic frequency is set to 35kHz, and temperature maintains 25 DEG C, sets blank control group in addition.Then by algae sample
Uniformly go in four colorimetric cylinders, be placed in quiescent culture in bio-incubator.Culture light intensity is 30 μm of ol (photons) m-2s-1,
Temperature is 25 DEG C, Light To Dark Ratio 12h:12h.Each of the above processing setting three is parallel, and averages.Take respectively at each ultrasound
Algae suspension after the foster 20s of reason tissue culture determines its Chlorophyll-a Content;The sample for wherein cultivating 0s takes 50mL to be shaken up after supersound process
Algae solution determines in time;And remaining algae sample takes layering to determine, that is, upper strata 45mL algaes suspension is taken as suspension or floating frustule leaf
Green plain a contents, bottom 5mL algae solutions are as sedimentation frustule Chlorophyll-a Content.Calculate Chlorophyll-a Content vertical distribution ratio.It is super
The equal quiescent culture 20s of each group after sonication, the rate of settling according to colorimetric cylinder length computation each group frustule is (under being equivalent at the uniform velocity
It is heavy).
(2) take the above-mentioned algae suspensions of 50mL to be placed in colorimetric cylinder to be ultrasonically treated, sonication treatment time is arranged to 5,30 and
300s, ultrasound intensity, which is set, includes 0.0206,0.0353,0.0433W/mL, supersonic frequency is set to 35kHz, and temperature maintains 25
DEG C, blank control group is set in addition, and every group three are parallel.The equal quiescent culture 20s of each group after supersound process, then take bottom 5mL algaes
Liquid, measure OD680 (characterizes frustule concentration), and calculates clearance (=(the raw water OD680- supernatants of algae in water sample
OD680)/raw water OD680).Upper strata 45mL algae suspensions are taken, the OD440 of supernatant is determined after centrifugation, and pass through blood counting chamber pair
Wherein complete cell is counted, and (by contrasting 35kHz, 0.0353W/mL is ultrasonically treated lower supernatant OD440 measure knot
The count results of fruit and blood counting chamber find that OD440 can characterize the rupture event of frustule well, are specifically shown in Table 1).
The frustule rupture rate of two kinds of evaluation indexes under 1 different sonication treatment times of table
As shown in figure 1, in experimentation, most frustules of control group are floated or are suspended in water column;Ultrasound
The algae suspension of processing is after 20s quiescent cultures, and water column Determination of Chlorophyll clearance changes with the change of processing time, wherein at 5s
The clearance of reason group is maximum (88%);And the algae rate of settling now is 0.52cm s-1 (Fig. 2), actual heavy algae can be drawn accordingly
The Best Times that algae settles in pond are (heavy algae tank depth (H) × 103/0.52) s, so as to calculate the heavy algae pond number that should be designed
Amount.In summary, the algae that this device can be effectively gone in water removal, and optimal ultrasound parameter is:Supersonic frequency is 35kHz, is surpassed
Sound intensity is 0.0353W/mL, ultrasonic time 5s.This is visible, proposed by the invention that original tap water is carried out with ultrasonic wave
The method of advanced treating, it is simple to operate, it is easy to accomplish, the purpose for efficiently removing algae in raw water can be reached, can preferably be expired
The water demand of sufficient waterworks.
From the figure 3, it may be seen that with the increase of ultrasound intensity and the extension of ultrasonic time, frustule rupture rate increases therewith
Greatly, but there is not the phenomenon ruptured in ultrasonic 5s, frustule under ultrasound intensity 0.0206,0.0353W/mL.Three kinds of ultrasounds are strong
Under degree during processing 5s, the clearance of algae is maximum, and the clearance under wherein 0.0353W/mL processing has reached 88%, but with processing
The extension of time, removal efficiency show the trend (Fig. 4) reduced.Consider the rupture event of frustule and the removal of algae
Effect, it has been found that it both can guarantee that frustule will not rupture and discharge intracellular inclusion when 5s is ultrasonically treated under 0.0353W/mL,
And can efficiently removes the algae in raw water simultaneously.
The existing document except algae aspect have much on ultrasound condition optimization, effect optimization, but do not account for into
Row practical application, also there is the invention of the technology except algae, but these inventions often do not reach good treatment effect, and do not examine
Consider to apply and raw water containing algae is carried out on further treatment technique in waterworks;The present invention is best except algae effect by selecting
Ultrasound condition, devise it is a kind of it is new remove algae pipeline, it can reach homogeneity, continuity processing to raw water containing algae, and can protect
Card frustule will not rupture and discharge noxious material (such as Algae toxins), while on the basis of high removal efficiency is reached, obtain
The optimal sedimentation time, so as to devising above-mentioned ultrasonic wave depth algae-removing device.
Claims (7)
- A kind of 1. ultrasonic wave depth algae-removing device, it is characterised in that including be sequentially connected flotation tank, except algae pipeline and several The heavy algae pond being connected in parallel, wherein, it is described except algae pipeline is internally provided with ultrasonic probe;The bottom in each heavy algae pond is set There are scraper, ash pit and water discharging valve, in flotation tank and except between algae pipeline and except between algae pipeline and each heavy algae pond It is provided with inlet valve.
- 2. ultrasonic wave depth algae-removing device according to claim 1, it is characterised in that described except equidistant inside algae pipeline It is provided with four ultrasonic probes, upside two, downside two.
- 3. ultrasonic wave depth algae-removing device according to claim 2, it is characterised in that the parameter of ultrasonic probe is arranged to: Supersonic frequency is 30~35kHz, and ultrasound intensity is 0.0206~0.0353W/mL, and ultrasonic time is 5~10s.
- 4. ultrasonic wave depth algae-removing device according to claim 1, it is characterised in that except the length of algae pipeline is according to processing Time and flow velocity design so that under certain water sample flow velocity, ensure that water sample can handle 5-10s in pipeline.
- 5. ultrasonic wave depth algae-removing device according to claim 1, it is characterised in that heavy algae bottom of pond portion is connected with skew wall, Skew wall inclination angle is 45 °~75 °.
- 6. a kind of ultrasonic wave depth algae-removing device using described in claim 1 carries out the method except algae, it is characterised in that including Following steps:Water sample after air supporting is introduced except algae pipeline is ultrasonically treated, the water sample after processing enters first heavy algae pond, heavy algae Pond orlop is ash pit, and after the depth of water reaches set depth, inlet valve is closed, and second heavy algae pond start to intake, then according to Secondary progress, after the sedimentation time of algae in first heavy algae pond the optimal sedimentation time is reached, the water discharging valve in heavy algae pond is opened, when When first heavy algae pool inner water can not discharge, ash pit row algae is opened, while the scraper of both sides strikes off the remaining algae of side wall, with First heavy algae pond starts to intake again afterwards, and remaining heavy algae pond is intake by this, arranges algae successively.
- 7. according to the method for claim 6, it is characterised in that the parameter of ultrasonic probe is arranged to:Supersonic frequency be 30~ 35kHz, ultrasound intensity are 0.0206~0.0353W/mL, and ultrasonic time is 5~10s.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109853496A (en) * | 2019-04-02 | 2019-06-07 | 生态环境部南京环境科学研究所 | A kind of quick disposal plant of float-type full-automation cyanobacteria |
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CN101712498A (en) * | 2009-11-06 | 2010-05-26 | 东南大学 | Ultrasonic algae removing method used for getting water from water head site |
CN202214239U (en) * | 2011-08-24 | 2012-05-09 | 同济大学 | Ultrasonic strengthened floating device for removing algae and algal toxin |
KR101184174B1 (en) * | 2012-03-16 | 2012-09-18 | 최중철 | Air floatation type algae removing apparatus |
CN104211242A (en) * | 2014-09-25 | 2014-12-17 | 上海市政工程设计研究总院(集团)有限公司 | Ultrasonic air floatation integrated water treatment device and treatment process thereof |
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2017
- 2017-07-21 CN CN201710604482.5A patent/CN107364926A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101712498A (en) * | 2009-11-06 | 2010-05-26 | 东南大学 | Ultrasonic algae removing method used for getting water from water head site |
CN202214239U (en) * | 2011-08-24 | 2012-05-09 | 同济大学 | Ultrasonic strengthened floating device for removing algae and algal toxin |
KR101184174B1 (en) * | 2012-03-16 | 2012-09-18 | 최중철 | Air floatation type algae removing apparatus |
CN104211242A (en) * | 2014-09-25 | 2014-12-17 | 上海市政工程设计研究总院(集团)有限公司 | Ultrasonic air floatation integrated water treatment device and treatment process thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109853496A (en) * | 2019-04-02 | 2019-06-07 | 生态环境部南京环境科学研究所 | A kind of quick disposal plant of float-type full-automation cyanobacteria |
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Application publication date: 20171121 |