CN107354726A - 抗静电涤纶纤维改性剂 - Google Patents
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Abstract
一种抗静电涤纶纤维改性剂及其制备方法,所述改性剂由以下重量份的原料组成:交联剂0.2‑0.6份,正丁醇5‑8份,乙二酸四乙酸二钠0.4‑0.8份,乳化剂0.6‑1.2份,无水乙醇3‑5份,石英粉1.2‑1.6份,表面改性剂1.3‑1.5份,双氰胺0.3‑0.7份,抗静电剂1‑3份,去离子水5‑10份。本发明通过结合两种抗静电方法,使得涤纶纤维获得很好的抗静电性能,可适用于各种纤维制品,能够长时间保持抗静电性能;本发明所提供的改性剂制备方法,步骤简单,制得的改性剂均匀性好。
Description
技术领域
本发明涉及纤维技术领域,具体涉及一种抗静电涤纶纤维改性剂及其制备方法。
背景技术
涤纶是合成纤维中的一个重要品种,是我国聚酯纤维的商品名称。它是以精对苯二甲酸(PTA)或对苯二甲酸二甲酯(DMT)和乙二醇(EG)为原料经酯化或酯交换和缩聚反应而制得的成纤高聚物——聚对苯二甲酸乙二醇酯 (PET),经纺丝和后处理制成的纤维。
涤纶纤维制成的织物具有较高的强度与弹性恢复能力。坚牢耐用,免熨烫,易洗快干,但吸湿性差,穿着有闷热感,易产生静电而吸尘沾污,耐酸碱性、耐光的性能好,不怕霉菌、虫蛀。
发明内容
本发明所要解决的技术问题是提供一种抗静电涤纶纤维改性剂及其制备方法。
本发明所要解决的技术问题采用以下的技术方案来实现:
一种抗静电涤纶纤维改性剂,所述改性剂由以下重量份的原料组成:
交联剂0.2-0.6份,正丁醇5-8份,乙二酸四乙酸二钠0.4-0.8份,乳化剂 0.6-1.2份,无水乙醇3-5份,石英粉1.2-1.6份,表面改性剂1.3-1.5份,双氰胺0.3-0.7份,抗静电剂1-3份,去离子水5-10份。
优选的,所述改性剂由以下重量份的原料组成:
交联剂0.4份,正丁醇6.5份,分散剂0.6份,乳化剂0.9份,无水乙醇4份,石英粉1.4份,表面改性剂1.4份,双氰胺0.5份,添加剂2份,去离子水7.5份。
所述交联剂为正硅酸四乙酯或正硅酸四乙酯、二月桂酸二丁基锡混合物。
所述乳化剂为季铵酸钠。
所述表面改性剂选自脂肪醇聚乙烯醚硫酸钠、十二烷基硫酸铵或脂肪醇聚乙烯醚硫酸铵的一种或几种。
所述抗静电剂为脂肪醇聚醚酰胺。
一种抗静电涤纶纤维改性剂制备方法,包括以下步骤:
(1)分别称取交联剂,乙二酸四乙酸二钠,乳化剂,石英粉,双氰胺,抗静电剂,去离子水,混合均匀后进行微波处理,得混合液;
(2)将步骤(1)所得混合液与正丁醇、无水乙醇混合加入反应釜中,进行酯交换制备相应的多元醇酯混合物;
(3)将表面改性剂和步骤(2)所得混合物加入调和釜中,混合后进行脉冲调和,并进行静态混合,然后同步搅拌1小时;
(4)调和搅拌完成后,取出,进行检验分析,得所述涤纶纤维改性剂。
所述步骤(1)中微波处理时微波功率为300-350W,微波频率为50kHz,间隔5min微波处理一次,每次处理10min,重复4-5次。
所述步骤(2)中进行酯交换时连续搅拌保持温度大于80℃,压力为1-2 个大气压。
本发明的有益效果为:本发明通过表面改性剂结合交联剂、正丁醇、乙二酸四乙酸二钠等组分对涤纶纤维表面进行改性处理,在纤维中有表面迁移的倾向,可补充纤维表面受损的抗静电层,是一种半永久性的抗静电方法;抗静电剂、乳化剂等与纤维以共混或共聚的形式存在,在纤维内部形成亲水的“导电通道”,是一种永久性的抗静电方法;本发明通过结合两种抗静电方法,使得涤纶纤维获得很好的抗静电性能,可适用于各种纤维制品,能够长时间保持抗静电性能;本发明所提供的改性剂制备方法,步骤简单,制得的改性剂均匀性好。
具体实施方式
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解,下面结合实施例,进一步阐述本发明。
实施例1
一种抗静电涤纶纤维改性剂,所述改性剂由以下重量份的原料组成:
交联剂0.2份,正丁醇5份,乙二酸四乙酸二钠0.4份,乳化剂0.6份,无水乙醇3份,石英粉1.2份,表面改性剂1.3份,双氰胺0.3份,抗静电剂1份,去离子水5份。
所述交联剂为正硅酸四乙酯或正硅酸四乙酯、二月桂酸二丁基锡混合物。
所述乳化剂为季铵酸钠。
所述表面改性剂选自脂肪醇聚乙烯醚硫酸钠、十二烷基硫酸铵或脂肪醇聚乙烯醚硫酸铵的一种或几种。
所述抗静电剂为脂肪醇聚醚酰胺。
一种抗静电涤纶纤维改性剂制备方法,包括以下步骤:
(1)分别称取交联剂,乙二酸四乙酸二钠,乳化剂,石英粉,双氰胺,抗静电剂,去离子水,混合均匀后进行微波处理,得混合液,微波处理时微波功率为300-350W,微波频率为50kHz,间隔5min微波处理一次,每次处理 10min,重复4-5次;
(2)将步骤(1)所得混合液与正丁醇、无水乙醇混合加入反应釜中,进行酯交换制备相应的多元醇酯混合物,酯交换时连续搅拌保持温度大于 80℃,压力为1-2个大气压;
(3)将表面改性剂和步骤(2)所得混合物加入调和釜中,混合后进行脉冲调和,并进行静态混合,然后同步搅拌1小时;
(4)调和搅拌完成后,取出,进行检验分析,得所述涤纶纤维改性剂。
实施例2
一种抗静电涤纶纤维改性剂,所述改性剂由以下重量份的原料组成:
交联剂0.4份,正丁醇6.5份,分散剂0.6份,乳化剂0.9份,无水乙醇4份,石英粉1.4份,表面改性剂1.4份,双氰胺0.5份,添加剂2份,去离子水7.5份。
所述交联剂为正硅酸四乙酯或正硅酸四乙酯、二月桂酸二丁基锡混合物。
所述乳化剂为季铵酸钠。
所述表面改性剂选自脂肪醇聚乙烯醚硫酸钠、十二烷基硫酸铵或脂肪醇聚乙烯醚硫酸铵的一种或几种。
所述抗静电剂为脂肪醇聚醚酰胺。
一种抗静电涤纶纤维改性剂制备方法,包括以下步骤:
(1)分别称取交联剂,乙二酸四乙酸二钠,乳化剂,石英粉,双氰胺,抗静电剂,去离子水,混合均匀后进行微波处理,得混合液,微波处理时微波功率为300-350W,微波频率为50kHz,间隔5min微波处理一次,每次处理 10min,重复4-5次;
(2)将步骤(1)所得混合液与正丁醇、无水乙醇混合加入反应釜中,进行酯交换制备相应的多元醇酯混合物,酯交换时连续搅拌保持温度大于 80℃,压力为1-2个大气压;
(3)将表面改性剂和步骤(2)所得混合物加入调和釜中,混合后进行脉冲调和,并进行静态混合,然后同步搅拌1小时;
(4)调和搅拌完成后,取出,进行检验分析,得所述涤纶纤维改性剂。
实施例3
一种抗静电涤纶纤维改性剂,所述改性剂由以下重量份的原料组成:
交联剂0.6份,正丁醇8份,乙二酸四乙酸二钠0.8份,乳化剂1.2份,无水乙醇5份,石英粉1.6份,表面改性剂1.5份,双氰胺0.7份,抗静电剂3份,去离子水10份。
所述交联剂为正硅酸四乙酯或正硅酸四乙酯、二月桂酸二丁基锡混合物。
所述乳化剂为季铵酸钠。
所述表面改性剂选自脂肪醇聚乙烯醚硫酸钠、十二烷基硫酸铵或脂肪醇聚乙烯醚硫酸铵的一种或几种。
所述抗静电剂为脂肪醇聚醚酰胺。
一种抗静电涤纶纤维改性剂制备方法,包括以下步骤:
(1)分别称取交联剂,乙二酸四乙酸二钠,乳化剂,石英粉,双氰胺,抗静电剂,去离子水,混合均匀后进行微波处理,得混合液,微波处理时微波功率为300-350W,微波频率为50kHz,间隔5min微波处理一次,每次处理 10min,重复4-5次;
(2)将步骤(1)所得混合液与正丁醇、无水乙醇混合加入反应釜中,进行酯交换制备相应的多元醇酯混合物,酯交换时连续搅拌保持温度大于 80℃,压力为1-2个大气压;
(3)将表面改性剂和步骤(2)所得混合物加入调和釜中,混合后进行脉冲调和,并进行静态混合,然后同步搅拌1小时;
(4)调和搅拌完成后,取出,进行检验分析,得所述涤纶纤维改性剂。
将经过实施例1-3处理得到的涤纶纤维进行抗静电测试并与对比例1(普通涤纶纤维)进行对比,检测数据如下:
实施例1 | 实施例2 | 实施例3 | 对比例1 | |
抗静电能力(Ω·CM) | 18 | 20 | 17 | 13 |
以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的仅为本发明的优选例,并不用来限制本发明,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (10)
1.一种抗静电涤纶纤维改性剂,其特征在于,所述改性剂由以下重量份的原料组成:
交联剂0.2-0.6份,正丁醇5-8份,乙二酸四乙酸二钠0.4-0.8份,乳化剂0.6-1.2份,无水乙醇3-5份,石英粉1.2-1.6份,表面改性剂1.3-1.5份,双氰胺0.3-0.7份,抗静电剂1-3份,去离子水5-10份。
2.如权利要求1所述的抗静电涤纶纤维改性剂,其特征在于,所述改性剂由以下重量份的原料组成:
交联剂0.4份,正丁醇6.5份,分散剂0.6份,乳化剂0.9份,无水乙醇4份,石英粉1.4份,表面改性剂1.4份,双氰胺0.5份,添加剂2份,去离子水7.5份。
3.如权利要求1所述的抗静电涤纶纤维改性剂,其特征在于,所述交联剂为正硅酸四乙酯或正硅酸四乙酯、二月桂酸二丁基锡混合物。
4.如权利要求1所述的抗静电涤纶纤维改性剂,其特征在于,所述乳化剂为季铵酸钠。
5.如权利要求1所述的抗静电涤纶纤维改性剂,其特征在于,所述表面改性剂选自脂肪醇聚乙烯醚硫酸钠、十二烷基硫酸铵或脂肪醇聚乙烯醚硫酸铵的一种或几种。
6.如权利要求1所述的抗静电涤纶纤维改性剂,其特征在于,所述抗静电剂为脂肪醇聚醚酰胺。
7.一种抗静电涤纶纤维改性剂制备方法,其特征在于,包括以下步骤:
(1)分别称取交联剂,乙二酸四乙酸二钠,乳化剂,石英粉,双氰胺,抗静电剂,去离子水,混合均匀后进行微波处理,得混合液;
(2)将步骤(1)所得混合液与正丁醇、无水乙醇混合加入反应釜中,进行酯交换制备相应的多元醇酯混合物;
(3)将表面改性剂和步骤(2)所得混合物加入调和釜中,混合后进行脉冲调和,并进行静态混合,然后同步搅拌1小时;
(4)调和搅拌完成后,取出,进行检验分析,得所述涤纶纤维改性剂。
8.如权利要求7所述的抗静电涤纶纤维改性剂制备方法,其特征在于,所述步骤(1)中微波处理时微波功率为300-350W,微波频率为50kHz。
9.如权利要求8所述的抗静电涤纶纤维改性剂制备方法,其特征在于,间隔5min微波处理一次,每次处理10min,重复4-5次。
10.如权利要求7所述的抗静电涤纶纤维改性剂制备方法,其特征在于,所述步骤(2)中进行酯交换时连续搅拌保持温度大于80℃,压力为1-2个大气压。
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