CN107353945B - High energy alcohol vaporising fuel and its production method - Google Patents
High energy alcohol vaporising fuel and its production method Download PDFInfo
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- CN107353945B CN107353945B CN201710609679.8A CN201710609679A CN107353945B CN 107353945 B CN107353945 B CN 107353945B CN 201710609679 A CN201710609679 A CN 201710609679A CN 107353945 B CN107353945 B CN 107353945B
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- high energy
- additive
- vaporising fuel
- production method
- energy alcohol
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/04—Catalyst added to fuel stream to improve a reaction
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/24—Mixing, stirring of fuel components
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a kind of high energy alcohol vaporising fuel and its production methods, are related to technical field of new energy production, and the component including calculating by weight is as follows: C5-C6 hydrocarbon mixture: 20 parts, alcohols: and 70~75 parts, 1# additive: 1 part, 4~9 parts of 2# additive；The alcohols includes any one of methanol, propyl alcohol, butanol；The 1# additive includes sodium xylene sulfonate and fatty acid sorbitan；The 2# additive includes ether, butanone, morpholine, ferric sulfate, ammonium persulfate, triethyl phosphate, hydroxyammonium nitrate.It is an advantage of the current invention that the high energy alcohol vaporising fuel of synthesis has reconciliation rational technology, non-volatile, stable product quality, the storage period is long, the advantage for sufficiently environmental protection of burning.
Description
Technical field
The present invention relates to technical field of new energy production, more particularly, to a kind of high energy alcohol vaporising fuel and its producer
Method.
Background technique
Due to generating a large amount of exhaust gas after traditional fuel burning, including carbon dioxide, sulfur dioxide, carbon monoxide and
Various nitrogen oxides etc., cause air pollution to aggravate increasingly, and a large amount of carbon drop emission reduction has been done since the 21th century certainly by country
Work, the main energy is also mainly following several classes: coal, diesel oil, gasoline, natural gas, liquefied gas etc. at this stage, above all of
Fuel releases a large amount of sulphur, nitrogen oxides, carbon dioxide etc. in combustion；And high energy alcohol vaporising fuel mainly substitutes
The fuel such as coal, diesel oil, natural gas, liquefied gas provide for family's kitchen range, hotel's kitchen range, various boilers and take heat energy, burned
The discharge such as sulphur, nitrogen oxides, carbon dioxide is reduced in journey.But high energy alcohol vaporising fuel production technology also falls behind relatively at present,
The degree of automation is low, and production efficiency is low, causes production cost higher.
Summary of the invention
In order to solve the above-mentioned technical problem the present invention, provides a kind of high energy alcohol vaporising fuel, mainly substitution coal, diesel oil,
The fuel such as natural gas, liquefied gas provide for family's kitchen range, hotel's kitchen range, various boilers and take heat energy, reduce in combustion
40% or more the discharge such as sulphur, nitrogen oxides, carbon dioxide, in this product using the high carbohydrate content substance of hydro carbons and alcohols (including
The macromolecules such as methanol, propyl alcohol, butanol alcohols), then after being mixed with additive, be mixed 2 hours or more.
To achieve the goals above, the present invention adopts the following technical scheme: a kind of high energy alcohol vaporising fuel, including by weight
The component that part calculates is as follows:
C5-C6 hydrocarbon mixture: 20 parts, alcohols: 70~75 parts, 1# additive: 1 part, 4~9 parts of 2# additive；
The alcohols includes any one of methanol, propyl alcohol, butanol；
The 1# additive includes sodium xylene sulfonate and fatty acid sorbitan；
The 2# additive includes ether, butanone, morpholine, ferric sulfate, ammonium persulfate, triethyl phosphate, hydroxyammonium nitrate.
Preferably, the weight ratio of sodium xylene sulfonate and fatty acid sorbitan is 1:1 in the 1# additive.
Preferably, the ether, butanone, morpholine, ferric sulfate, ammonium persulfate, triethyl phosphate, hydroxyammonium nitrate weight ratio
For 3:2:1:1:1:1:1.
A kind of production method of above-mentioned high energy alcohol vaporising fuel, includes the following steps:
Step a: it is mixed after closed container is added with the 1# additive in the C5-C6 hydrocarbon mixture；
Step b: it recycles the volatilization gas in closed container and is condensed, obtain condensed fluid；
Step c: continue to stir and be added in closed container the alcohols；
Step d: condensed fluid and the 2# additive obtained in step b is added and stirs；
Step e: it stands.
Preferably, it is 40 DEG C that temperature, which is mixed, in the step a.
Preferably, the temperature stood in the step e is maintained at 30 DEG C.
Preferably, the mixing time of the step a is 20 minutes.
Preferably, the mixing time of the step c is 15 minutes.
Preferably, the mixing time of the d is 25 minutes.
Preferably, the time of repose of the step e is 2 hours.
It is an advantage of the current invention that the high energy alcohol vaporising fuel of synthesis has reconciliation rational technology, non-volatile, product quality
Stablize, meet high-temperature gasification burning, the storage period is long, sufficiently environmental protection of burning；The combustion such as coal, diesel oil, natural gas, liquefied gas can be substituted
Material, provides for family's kitchen range, hotel's kitchen range, various boilers and takes heat energy, reduces sulphur, nitrogen oxides, dioxy in combustion
Change 40% or more the discharge such as carbon.This fuel applications is in heating equipments such as hotel, family Cooking stove set boiler combustors, in combustion
Due to the catalytic action by additive, the low boiling point of liquid fuel is reduced, liquid fuel the pyrolytic conversion by flame at
For gasification, and combustion, there is burning sufficiently, adequately solving to burn in traditional liquid burning combustion process insufficient is discharged into air
Middle generation peculiar smell, and cause the harm to human body
Detailed description of the invention
Fig. 1 is the structural schematic diagram of process units in the present invention.
Specific embodiment
The invention will be further described with embodiment with reference to the accompanying drawing.
As shown in Figure 1, a kind of high energy alcohol vaporising fuel attemperation apparatus, including additive fill pipeline 8, hydrocarbon mixture filler pipe
Road 7, blending tank 1, condensate tank(trap) 2 and accumulator tank 3；The top of blending tank 1 is provided with feed inlet 19 and volatile matter recovery port 18, mixing
The bottom of tank 1 is provided with discharge port 16 and slag-drip opening 17；Additive fills pipeline 8 and is connected to charging with hydrocarbon mixture filling pipeline 7
Mouth 19；It is connected between volatile matter recovery port 18 and accumulator tank 3 by condenser pipe 23, condenser pipe 23 is interior by condensate tank(trap) 2
Portion, it is coil pipe that condenser pipe 23, which is located at the part inside condensate tank(trap) 2,；Accumulator tank 3 is provided with inlet 31 and liquid outlet 32, out liquid
32 pipeline connection feed inlets 19 of mouth；Blending tank 1 is internally provided with agitating shaft 14, and stirring blade 13 is provided on agitating shaft 14,
Agitating shaft 14 can be driven by motor 12 to be rotated；Electric hot plate 15 is provided on the tube wall 10 of blending tank 1.It was provided at feed inlet 19
Contaminant filter in hydrocarbon mixture, additive to ensure the quality of product, can be reduced deslagging, guarantee blending tank by strainer 11
Cleaning inside.Discharge port valve 55 and slag-drip opening valve 54 are separately installed at discharge port 16 and slag-drip opening 17.Additive filling
Additive filling valve 51 is installed on pipeline 8, hydrocarbon mixture filling valve 52, liquid outlet are installed on hydrocarbon mixture filling pipeline 7
Withdrawal liquid pipeline 34 is installed at 32, withdrawal liquid filling valve 53, additive filling are installed on withdrawal liquid pipeline 34
Pipeline 8, hydrocarbon mixture filling pipeline 7 are crossed after being connected to withdrawal liquid pipeline 34 through 6 pipeline connections of explosion-proof pump to feed inlet 19.
Motor 12 uses fire-proof motor, can increase the security performance of equipment.Water inlet 21 and water outlet 22 are provided on condensate tank(trap) 2,
Pipeline is connected to the condensation-water drain 41 and condensing water inlet 42 of condensed water compressor 4 respectively.
Production method one: process units is added blending tank, will mix as shown in Figure 1, using 20 parts of C5-C6 hydrocarbon mixture
Tank is heated to 40 DEG C, and 1 part of 1# additive is added in blending tank, and stirring after twenty minutes, stands, closes in whipping process
Cover, the volatilization gas in tank is by flowing into accumulator tank after the coil condensation in condensate tank(trap), and temperature is about 5 DEG C in condensate tank(trap)；Again
75 parts of addition alcohols (require to distinguish according to calorific value, 6000 kilocalorie of calorific value/kilogram within can be used methanol, calorific value 8000 is big
Card/kilogram fuel can be used propyl alcohol, calorific value require 9500 kilocalories/kilogram or more use butanol) Bian Tianjia, side stirring stirs
Speed is mixed less than 20 turns per minute, mixing speed is improved after addition to 40~45 turns per minute, after stirring 15 minutes, is added
The liquid of recycling in accumulator tank is added 4 parts of 2# additive immediately, reaches 30 right sides of turning left in revolving speed and is slowly added into, filling finishes
It improves mixing speed immediately afterwards, while opening condensate recycling device, the mixing of high energy alcohol vaporising fuel is obtained after stirring 25 minutes
Liquid, static 2 hours, quiescing process controlled temperature at 30 DEG C or so always, checked whether fuel combination is layered after twenty minutes, if
There is precipitating, checks and so (slight precipitating allows) go out canned bucket afterwards without layering and precipitating.This product in use, does not have to transformation
Kitchen range can be used directly, and stove core temperature is more than 85 DEG C of automatic gasifying burnings, this burning addition reduces volatile additives, and fuel is not easy
Explosion ratio is formed in air, and this fuel is dissolved in water, once fire burning occurs, can be extinguished with one times of water dilution.
Following table is embodiment one using the fuel of different alcohols and the related data of liquefied gas Experimental Comparison:
Show from above aobvious it can be seen that using nitrogen oxides, particulate matter, sulfur dioxide rear after fuel combustion of the invention etc.
Pollutant, which is substantially reduced, much illustrates the excellent of kitchen range fuel of the invention more traditional kitchen range fuel (liquefied gas) in environmental protection
Gesture is clearly.
Production method two: the difference of this method and method one is that alcohols is 70 parts, and 2# additive is 9 parts.
1# additive: this additive includes: sodium xylene sulfonate and fatty acid sorbitan, is added after mixing by weight 1:1
It is added in C5-C6 hydrocarbon mixture to play and reduces hydrocarbon mixture viscosity, homogenizing and dispersion effect raising, increase the active work of molecular surface
With.
2# additive: main function is the syncretizing effect for increasing hydrocarbon mixture and alcohols material, reduces volatilization, reduces fuel and steams
Air pressure, wherein ingredient is ether (as drop boiling point), butanone (for reducing vapour pressure), morpholine (for adjusting vapour pressure), sulphur
Sour iron (as deodorant), ammonium persulfate (as deodorizer), triethyl phosphate (for reducing volatilization), hydroxyammonium nitrate (are used for
Volatilize fire-retardant), the weight ratio of mentioned component is 3:2:1:1:1:1:1.
Number in specification of the invention is parts by weight.
Above-mentioned, although the foregoing specific embodiments of the present invention is described with reference to the accompanying drawings, not protects model to the present invention
The limitation enclosed, for some technology contents well known to those of ordinary skill in the art, details are not described herein again, fields technology
Personnel should be understood that based on the technical solutions of the present invention those skilled in the art do not need to make the creative labor i.e.
The various modifications or changes that can be made are still within protection scope of the present invention.
Claims (10)
1. a kind of high energy alcohol vaporising fuel, which is characterized in that the component including calculating by weight is as follows:
C5-C6 hydrocarbon mixture: 20 parts, alcohols: 70~75 parts, 1# additive: 1 part, 4~9 parts of 2# additive；
The alcohols includes any one of methanol, propyl alcohol, butanol；
The 1# additive includes sodium xylene sulfonate and fatty acid sorbitan；
The 2# additive includes ether, butanone, morpholine, ferric sulfate, ammonium persulfate, triethyl phosphate, hydroxyammonium nitrate.
2. high energy alcohol vaporising fuel according to claim 1, which is characterized in that xylene monosulfonic acid in the 1# additive
The weight ratio of sodium and fatty acid sorbitan is 1:1.
3. high energy alcohol vaporising fuel according to claim 1, which is characterized in that the ether, butanone, morpholine, sulfuric acid
Iron, ammonium persulfate, triethyl phosphate, hydroxyammonium nitrate weight ratio are 3:2:1:1:1:1:1.
4. a kind of production method of high energy alcohol vaporising fuel as claimed in any one of claims 1 to 3, which is characterized in that including
Following steps:
Step a: it is mixed after closed container is added with the 1# additive in the C5-C6 hydrocarbon mixture；
Step b: it recycles the volatilization gas in closed container and is condensed, obtain condensed fluid；
Step c: continue to stir and be added in closed container the alcohols；
Step d: condensed fluid and the 2# additive obtained in step b is added and stirs；
Step e: it stands.
5. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that the step a mixing
Whipping temp is 40 DEG C.
6. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that quiet in the step e
The temperature set is maintained at 30 DEG C.
7. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that the step a's stirs
Mixing the time is 20 minutes.
8. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that the step c's stirs
Mixing the time is 15 minutes.
9. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that when the stirring of the d
Between be 25 minutes.
10. the production method of high energy alcohol vaporising fuel according to claim 4, which is characterized in that the step e's is quiet
Setting the time is 2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710609679.8A CN107353945B (en) | 2017-07-25 | 2017-07-25 | High energy alcohol vaporising fuel and its production method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710609679.8A CN107353945B (en) | 2017-07-25 | 2017-07-25 | High energy alcohol vaporising fuel and its production method |
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| Publication Number | Publication Date |
|---|---|
| CN107353945A CN107353945A (en) | 2017-11-17 |
| CN107353945B true CN107353945B (en) | 2019-04-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710609679.8A Active CN107353945B (en) | 2017-07-25 | 2017-07-25 | High energy alcohol vaporising fuel and its production method |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110684566A (en) * | 2018-07-04 | 2020-01-14 | 白凤臣 | Low-carbon environment-friendly methanol gasoline |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1032026A (en) * | 1987-09-12 | 1989-03-29 | 成都新型燃料工业有限公司 | Civil liquid fuel |
| CN101063056A (en) * | 2006-04-28 | 2007-10-31 | 上海中茂新能源应用有限公司 | Vehicular light hydrocarbon fuel composition |
| CN101747954A (en) * | 2010-01-20 | 2010-06-23 | 杜维生 | Alcohol group H2O methanol compound gasoline |
| CN103540367A (en) * | 2013-11-07 | 2014-01-29 | 济南开发区星火科学技术研究院 | Furnace liquid fuel |
-
2017
- 2017-07-25 CN CN201710609679.8A patent/CN107353945B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1032026A (en) * | 1987-09-12 | 1989-03-29 | 成都新型燃料工业有限公司 | Civil liquid fuel |
| CN101063056A (en) * | 2006-04-28 | 2007-10-31 | 上海中茂新能源应用有限公司 | Vehicular light hydrocarbon fuel composition |
| CN101747954A (en) * | 2010-01-20 | 2010-06-23 | 杜维生 | Alcohol group H2O methanol compound gasoline |
| CN103540367A (en) * | 2013-11-07 | 2014-01-29 | 济南开发区星火科学技术研究院 | Furnace liquid fuel |
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| Publication number | Publication date |
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| CN107353945A (en) | 2017-11-17 |
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