CN107353710A - A kind of Antiforge fluorescent ink composition - Google Patents
A kind of Antiforge fluorescent ink composition Download PDFInfo
- Publication number
- CN107353710A CN107353710A CN201710718143.XA CN201710718143A CN107353710A CN 107353710 A CN107353710 A CN 107353710A CN 201710718143 A CN201710718143 A CN 201710718143A CN 107353710 A CN107353710 A CN 107353710A
- Authority
- CN
- China
- Prior art keywords
- ink composition
- copper
- fluorescent ink
- resin
- clad plate
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of Antiforge fluorescent ink composition, include the material composition of following mass percent：Fluorescent material 0.1 10%；Resin 5 30%；Auxiliary agent 0.1 6%；Solvent 60 90%.It is false proof that the present invention is used for copper-clad plate, the anti-fake mark printed on reinforcing material, colourless stealth, antifalse effect is good, heat endurance is good, resistance to copper-clad plate spare resin, after reinforcing material infiltrates resin and is hot pressed into copper-clad plate with copper foil, remain able to send brilliant green fluorescence under uviol lamp, the evidence of certified products, safeguard rights and interests can be recognized as producer, the ability that fake products dispute is evaded by producer is improved, reduces the right-safeguarding loss of producer, self-control fluorescent material improves the difficulty that the Antiforge fluorescent ink is forged.
Description
Technical field
The present invention relates to anti-forgery ink field, particularly a kind of Antiforge fluorescent ink composition.
Background technology
Copper-clad plate, also known as copper-clad laminate.It is that reinforcing material is made by wood pulp paper or glass-fiber-fabric etc., soaks with resin, one side
A kind of or two-sided coated with copper foil, the product formed through hot pressing.Copper-clad plate is the basic material of electronics industry, is mainly used in processing system
Make printed circuit board（PCB）, it is widely used in the electronic products such as television set, radio, computer, computer, mobile communication.With collection
Into the invention and application of circuit, the miniaturization of electronic product and high performance, further promoted copper-clad plate technology and produce into
One step develops, and the production scale of copper-clad plate rapidly expands.During this, counterfeit and shoddy goods are also developed rapidly, high
The copper-clad plate manufacturer of quality inevitably runs into the impact of mountain vallage product, anti-from anti-forgery ink printing in copper-clad plate
Puppet mark is that copper-clad plate manufacturer defends the rights and interests of itself, a solution of the rights and interests of protection client.Hitherto reported
Anti-forgery ink is various in style, is mainly used in money, ticket and product packaging etc., might not be used directly for covering copper
Plate is false proof.
The special structure of copper-clad plate and preparation technology require that anti-forgery ink can be printed on its reinforcing material, and are increasing
For strong material infiltration resin with copper foil after being hot pressed into copper-clad plate, printed anti-fake mark keeps original anti-counterfeiting characteristic.Therefore market
On also lack one kind and can be infiltrated in reinforcing material after resin and copper foil be hot pressed into copper-clad plate, remain able to providing anti-counterfeiting characteristic
Ink composite.
The content of the invention
In order to overcome the disadvantages mentioned above of prior art, it is an object of the invention to provide for copper-clad plate to be false proof, false proof effect
A kind of good Antiforge fluorescent ink composition of fruit.
The technical solution adopted for the present invention to solve the technical problems is：A kind of Antiforge fluorescent ink composition, wherein, bag
Include the material composition of following mass percent：
Fluorescent material 0.1-10%；
Resin 5-30%；
Auxiliary agent 0.1-6%；
Solvent 60-90%；
As a further improvement on the present invention：The fluorescent material is anti-in a solvent by rare earth terbium salt, alkali and monocyclic organic carboxyl acid
It should make by oneself.
As a further improvement on the present invention：The rare earth terbium salt is perchlorate, nitrate, villaumite, carbonate and sulphur
One of which or any combination in hydrochlorate；
The alkali is calcium hydroxide, sodium hydroxide, potassium hydroxide, triethylamine, one of which or any combination in ammoniacal liquor；
The monocyclic organic carboxyl acid is benzoic acid, benzoic acid derivative, picolinic acid, pyridine carboxylic acid derivatives, imidazolyl carboxylic acid, miaow
One of which or any combination in triazole carboxylic acid's derivative.
As a further improvement on the present invention：The resin is one or both of polyamide and polyurethane resin
Compound, the polyamide is polyvinylpyrrolidone, and the polyurethane resin is waterborne polyurethane resin.
As a further improvement on the present invention：The auxiliary agent is the one of which of attachment fastness reinforcing agent and filler, described
Attachment fastness reinforcing agent is that one or both of erucyl amide and caprolactam are compound；The filler is silica and carbonic acid
One or both of calcium is compound.
As a further improvement on the present invention：The solvent be deionized water, ethanol, isopropanol, in n-butanol wherein
A kind of or any combination, the ethanol, isopropanol and n-butanol are pure to analyze.
A kind of application of Antiforge fluorescent ink composition fake marker on copper-clad plate reinforcing material.
As a further improvement on the present invention：The anti-forgery ink composition reinforcing material infiltrate resin and with copper foil heat
After being pressed into copper-clad plate, bright green fluorescence still can be presented under uviol lamp.
As a further improvement on the present invention：The reinforcing material is wood pulp paper or glass-fiber-fabric, and the infiltration resin is ring
Oxygen tree fat.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is false proof for copper-clad plate, and the anti-fake mark printed on reinforcing material, colourless stealth, antifalse effect is good, and heat is steady
It is qualitative good, resistance to copper-clad plate spare resin, after reinforcing material infiltrates resin and is hot pressed into copper-clad plate with copper foil, remain able to
Brilliant green fluorescence is sent under uviol lamp, the evidence of certified products, safeguard rights and interests can be recognized as producer, raising producer evades fake products and entangled
Confused ability, reduces the right-safeguarding loss of producer, and self-control fluorescent material improves the difficulty that the Antiforge fluorescent ink is forged.
Embodiment
The present invention is further described for current embodiment：
Case study on implementation 1：
A kind of Antiforge fluorescent ink composition, wherein, include the material composition of following mass percent：
Fluorescent material 2%, polyamide 4%, polyurethane resin 2%, erucyl amide 0.2%, caprolactam 0.5%, calcium carbonate
1.8%, deionized water 84%, ethanol 5.5%；
The fluorescent material is reacted self-control in deionized water and ethanol by perchlorate, calcium hydroxide and benzoic acid and obtained；
The anti-fake mark that the gained Antiforge fluorescent ink composition of case study on implementation 1 prints on copper-clad plate reinforcing material, in strengthening material
After material infiltrates resin and is hot pressed into copper-clad plate with copper foil, bright green fluorescence still can be presented under uviol lamp.
Case study on implementation 2：
A kind of Antiforge fluorescent ink composition, wherein, include the material composition of following mass percent：
Fluorescent material 4%, polyamide 12%, polyurethane resin 2%, erucyl amide 0.2%, caprolactam 0.8%, calcium carbonate 2%,
Deionized water 76%, ethanol 3%.
Case study on implementation 3：
A kind of Antiforge fluorescent ink composition, wherein, include the material composition of following mass percent：
Fluorescent material 8%, polyvinylpyrrolidone 22%, caprolactam 1.5%, calcium carbonate 1%, silica 1 %, deionized water
63%, ethanol 2.5%, isopropanol 1%.
Case study on implementation 4：
A kind of Antiforge fluorescent ink composition, wherein, include the material composition of following mass percent：
Fluorescent material 10%, polyvinylpyrrolidone 26%, erucyl amide 0.5%, caprolactam 1.5%, silica 2%, deionization
Water 58%, ethanol 1%, isopropanol 1%.
In summary, after one of ordinary skill in the art reads file of the present invention, technique according to the invention scheme and
Technical concept makes other various corresponding conversion schemes without creative mental labour, belongs to the model that the present invention is protected
Enclose.
Claims (9)
1. a kind of Antiforge fluorescent ink composition, it is characterized in that, include the material composition of following mass percent：
Fluorescent material 0.1-10%；
Resin 5-30%；
Auxiliary agent 0.1-6%；
Solvent 60-90%.
2. a kind of Antiforge fluorescent ink composition according to claim 1, it is characterized in that：The fluorescent material is by rare earth terbium
Salt, alkali and monocyclic organic carboxyl acid react self-control in a solvent.
3. a kind of Antiforge fluorescent ink composition according to claim 2, it is characterized in that：
The rare earth terbium salt is the one of which or any combination in perchlorate, nitrate, villaumite, carbonate and sulfate；
The alkali is calcium hydroxide, sodium hydroxide, potassium hydroxide, triethylamine, one of which or any combination in ammoniacal liquor；
The monocyclic organic carboxyl acid is benzoic acid, benzoic acid derivative, picolinic acid, pyridine carboxylic acid derivatives, imidazolyl carboxylic acid, miaow
One of which or any combination in triazole carboxylic acid's derivative.
4. a kind of Antiforge fluorescent ink composition according to claim 1, it is characterized in that：The resin is polyamide
Compound with one or both of polyurethane resin, the polyamide is polyvinylpyrrolidone, the polyurethane resin
For waterborne polyurethane resin.
5. a kind of Antiforge fluorescent ink composition according to claim 1, it is characterized in that：The auxiliary agent increases for attachment fastness
Strong agent and the one of which of filler, the attachment fastness reinforcing agent are multiple for one or both of erucyl amide and caprolactam
Close；The filler is that one or both of silica and calcium carbonate are compound.
6. a kind of Antiforge fluorescent ink composition according to claim 1 or 2, it is characterized in that：The solvent is deionization
One of which or any combination in water, ethanol, isopropanol, n-butanol, the ethanol, isopropanol and n-butanol are pure to analyze.
A kind of 7. application of Antiforge fluorescent ink composition fake marker on copper-clad plate reinforcing material.
A kind of 8. Antiforge fluorescent ink composition fake marker on copper-clad plate reinforcing material according to claim 7
Application, it is characterized in that：The anti-forgery ink composition is after reinforcing material infiltrates resin and is hot pressed into copper-clad plate with copper foil, still
Bright green fluorescence can so be presented under uviol lamp.
A kind of 9. Antiforge fluorescent ink composition fake marker on copper-clad plate reinforcing material according to claim 8
Application, it is characterized in that：The reinforcing material is wood pulp paper or glass-fiber-fabric, and the infiltration resin is epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710718143.XA CN107353710B (en) | 2017-08-21 | 2017-08-21 | Fluorescent anti-counterfeiting ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710718143.XA CN107353710B (en) | 2017-08-21 | 2017-08-21 | Fluorescent anti-counterfeiting ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107353710A true CN107353710A (en) | 2017-11-17 |
| CN107353710B CN107353710B (en) | 2020-11-06 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710718143.XA Active CN107353710B (en) | 2017-08-21 | 2017-08-21 | Fluorescent anti-counterfeiting ink composition |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108642860A (en) * | 2018-04-26 | 2018-10-12 | 深圳市裕同包装科技股份有限公司 | A kind of environment-friendly biomass base rare earth down-conversion fluorescent fiber and preparation method |
| CN109385142A (en) * | 2018-09-29 | 2019-02-26 | 广东轻工职业技术学院 | A kind of fluorescent ink and preparation method thereof and discrimination method |
| CN109711511A (en) * | 2018-01-02 | 2019-05-03 | 海南亚元防伪技术研究所（普通合伙） | Transfinite ink dot method for anti-counterfeit and printed article |
| CN110105812A (en) * | 2018-10-24 | 2019-08-09 | 重庆理工大学 | A kind of no ink ink-jet ink and its preparation method and application |
| CN111192515A (en) * | 2019-12-19 | 2020-05-22 | 北京化工大学 | Preparation and application methods of temperature-sensitive irreversible intelligent fluorescent anti-counterfeiting composite coating material |
| CN113698815A (en) * | 2021-07-28 | 2021-11-26 | 东莞市美盈森环保科技有限公司 | Fluorescent anti-counterfeiting printing ink, preparation method and printing method |
| CN114752256A (en) * | 2022-04-25 | 2022-07-15 | 安徽大学 | MOG fluorescent ink and preparation method thereof, and information encryption and anti-counterfeiting application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104760437A (en) * | 2014-01-06 | 2015-07-08 | 泸州金鑫印务有限公司 | Invisible ultraviolet fluorescent falsification-preventing low-temperature bright hot-stamping paper and printing method thereof |
| CN106752378A (en) * | 2015-10-01 | 2017-05-31 | 惠州市随和科技有限公司 | A kind of fluorescent ink and preparation method thereof |
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2017
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Patent Citations (2)
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| CN104760437A (en) * | 2014-01-06 | 2015-07-08 | 泸州金鑫印务有限公司 | Invisible ultraviolet fluorescent falsification-preventing low-temperature bright hot-stamping paper and printing method thereof |
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Non-Patent Citations (2)
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109711511A (en) * | 2018-01-02 | 2019-05-03 | 海南亚元防伪技术研究所（普通合伙） | Transfinite ink dot method for anti-counterfeit and printed article |
| CN108642860A (en) * | 2018-04-26 | 2018-10-12 | 深圳市裕同包装科技股份有限公司 | A kind of environment-friendly biomass base rare earth down-conversion fluorescent fiber and preparation method |
| CN108642860B (en) * | 2018-04-26 | 2021-08-27 | 深圳市裕同包装科技股份有限公司 | Environment-friendly biomass-based rare earth down-conversion fluorescent fiber and preparation method thereof |
| CN109385142A (en) * | 2018-09-29 | 2019-02-26 | 广东轻工职业技术学院 | A kind of fluorescent ink and preparation method thereof and discrimination method |
| CN109385142B (en) * | 2018-09-29 | 2021-12-14 | 广东轻工职业技术学院 | Fluorescent ink and preparation method and identification method thereof |
| CN110105812A (en) * | 2018-10-24 | 2019-08-09 | 重庆理工大学 | A kind of no ink ink-jet ink and its preparation method and application |
| CN111192515A (en) * | 2019-12-19 | 2020-05-22 | 北京化工大学 | Preparation and application methods of temperature-sensitive irreversible intelligent fluorescent anti-counterfeiting composite coating material |
| CN113698815A (en) * | 2021-07-28 | 2021-11-26 | 东莞市美盈森环保科技有限公司 | Fluorescent anti-counterfeiting printing ink, preparation method and printing method |
| CN114752256A (en) * | 2022-04-25 | 2022-07-15 | 安徽大学 | MOG fluorescent ink and preparation method thereof, and information encryption and anti-counterfeiting application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107353710B (en) | 2020-11-06 |
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