CN107353681A - A kind of flame resistant glass coating and preparation method thereof - Google Patents
A kind of flame resistant glass coating and preparation method thereof Download PDFInfo
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- CN107353681A CN107353681A CN201710396826.8A CN201710396826A CN107353681A CN 107353681 A CN107353681 A CN 107353681A CN 201710396826 A CN201710396826 A CN 201710396826A CN 107353681 A CN107353681 A CN 107353681A
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- flame resistant
- resistant glass
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- glass coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of flame resistant glass coating and preparation method thereof, coating includes following component：Hollow glass microbead, glass fibre, calcium oxide, methyl methacrylate, titanium dioxide, maleic acid resin, propylene glycol methyl ether acetate, antioxidant, curing agent, solvent.Preparation method obtains mixture one for hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent；Methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one again, heats up and adds curing agent, stirring obtains mixture two；Finally antioxidant is added in mixture two, is stirred, obtains flame resistant glass coating.Fireproof coating provided by the invention has good adhesion property, water resistance and fire resistance.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of flame resistant glass coating and preparation method thereof.
Background technology
Fireproof coating is coated on flammable substrates surface, can reduce by the combustibility of painting material surface, block the fast of fire
Speed sprawling, or coated on structural material surface, for improving the fire endurance of component；Fireproof coating is typically by base-material, scattered
Medium, fire retardant, filler, auxiliary agent (plasticizer, stabilizer, waterproofing agent, anti-blushing agent etc.) composition, its fire-retardant principle is generally divided into swollen
The swollen class of type and non-expansion type two, Non-expansive fireproof paint are to lean on the high fire retardant or noninflammability of its own to reach fire-retardant fireproof
Purpose, the flameproof effect for wanting to have reached must apply very thick, and addition largely largely has containing the fire retardants such as halogen, nitrogen, phosphorus, generation
Poisonous gas, expanding fire-proof paint are exactly that film expanded by heating forms cellular charring layer, flame heat regulating is isolated and is subtracted
Less or slow down transmission to ground, while coating decomposites non-flammable compressive gas in high temperature, completely cuts off and dilutes air, in addition coating
In fire prevention, a series of physical that occurs and chemical reaction absorb amount of heat so as to play fire-retardant and delay flame spread, climing
Prolong, the time of fire extinguishing is provided for people.The fireproof coating that glass uses not only requires good fire prevention in use
Performance, while should also have good water proofing property, otherwise it can influence attractive in appearance.
The content of the invention
It is an object of the invention in order to overcome above the deficiencies in the prior art and provide a kind of flame resistant glass coating and its
Preparation method, while improve the water-fast and fire resistance of coating.
Technical scheme is as follows：
A kind of flame resistant glass coating, including following component in parts by weight：Hollow glass microbead 2-6 parts, glass fibre
1-3 parts, calcium oxide 1-2 parts, methyl methacrylate 5-10 parts, titanium dioxide 2-3 parts, maleic acid resin 3-6 parts, propylene glycol monomethyl ether
Acetate 4-7 parts, antioxidant 1-2 parts, curing agent 1-3 parts, solvent 30-40 parts.
Further, described flame resistant glass coating, antioxidant are antioxidant 1010.
Further, described flame resistant glass coating, curing agent are ethylenediamine.
Further, described flame resistant glass coating, solvent are ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature simultaneously adds curing agent, stirs 30-40 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Further, the preparation method of described flame resistant glass coating, the temperature to heat up in step 2 are 50-60 DEG C.
Fireproof coating provided by the invention has good adhesion property, water resistance and fire resistance, wherein water resistance
More than 170h is reached without corrugation, adhesive force has reached 1 grade, and fire resistance has reached more than 176min.
Embodiment：
Embodiment 1
A kind of flame resistant glass coating, including following component in parts by weight：2 parts of hollow glass microbead, glass fibre 1
Part, 1 part of calcium oxide, 5 parts of methyl methacrylate, 2 parts of titanium dioxide, 3 parts of maleic acid resin, 4 parts of propylene glycol methyl ether acetate, resist
1 part of oxygen agent, 1 part of curing agent, 30 parts of solvent.
Above antioxidant is antioxidant 1010, and curing agent is ethylenediamine, and solvent is ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature is to 50 DEG C and adds curing agent, stirs 30 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Embodiment 2
A kind of flame resistant glass coating, including following component in parts by weight：3 parts of hollow glass microbead, glass fibre 2
Part, 1 part of calcium oxide, 6 parts of methyl methacrylate, 2 parts of titanium dioxide, 4 parts of maleic acid resin, 5 parts of propylene glycol methyl ether acetate, resist
1 part of oxygen agent, 1 part of curing agent, 32 parts of solvent.
Above antioxidant is antioxidant 1010, and curing agent is ethylenediamine, and solvent is ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature is to 52 DEG C and adds curing agent, stirs 35 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Embodiment 3
A kind of flame resistant glass coating, including following component in parts by weight：4 parts of hollow glass microbead, glass fibre 2
Part, 2 parts of calcium oxide, 7 parts of methyl methacrylate, 2 parts of titanium dioxide, 5 parts of maleic acid resin, 6 parts of propylene glycol methyl ether acetate, resist
1 part of oxygen agent, 2 parts of curing agent, 36 parts of solvent.
Above antioxidant is antioxidant 1010, and curing agent is ethylenediamine, and solvent is ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature is to 57 DEG C and adds curing agent, stirs 35 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Embodiment 4
A kind of flame resistant glass coating, including following component in parts by weight：5 parts of hollow glass microbead, glass fibre 2
Part, 2 parts of calcium oxide, 8 parts of methyl methacrylate, 3 parts of titanium dioxide, 6 parts of maleic acid resin, 6 parts of propylene glycol methyl ether acetate, resist
2 parts of oxygen agent, 2 parts of curing agent, 39 parts of solvent.
Above antioxidant is antioxidant 1010, and curing agent is ethylenediamine, and solvent is ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature is to 57 DEG C and adds curing agent, stirs 40 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Embodiment 5
A kind of flame resistant glass coating, including following component in parts by weight：6 parts of hollow glass microbead, glass fibre 3
Part, 2 parts of calcium oxide, 10 parts of methyl methacrylate, 3 parts of titanium dioxide, 6 parts of maleic acid resin, 7 parts of propylene glycol methyl ether acetate,
2 parts of antioxidant, 3 parts of curing agent, 40 parts of solvent.
Above antioxidant is antioxidant 1010, and curing agent is ethylenediamine, and solvent is ethanol.
The preparation method of above-described flame resistant glass coating, comprises the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, risen
Temperature is to 60 DEG C and adds curing agent, stirs 40 minutes, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
Performance test is carried out to the flame resistant glass coating that above example provides, it is as a result as follows：
| Test event | It is completely dried the time | Water resistance | Adhesive force | Fire resistance |
| Reference standard | GB/T1728-89 | GB/T1733-93 | GB/T1720-89 | GB14907-2002 |
| Embodiment 1 | 46min | More than 170h is without corrugation | 1 grade | 176min |
| Embodiment 2 | 44min | More than 170h is without corrugation | 1 grade | 182min |
| Embodiment 3 | 43min | More than 170h is without corrugation | 1 grade | 185min |
| Embodiment 4 | 45min | More than 170h is without corrugation | 1 grade | 183min |
| Embodiment 5 | 44min | More than 170h is without corrugation | 1 grade | 181min |
Above as can be seen that fireproof coating provided by the invention has good adhesion property, water resistance and fire resisting
Property, wherein water resistance have reached more than 170h without corrugation, and adhesive force has reached 1 grade, and fire resistance has reached more than 176min.
Claims (6)
1. a kind of flame resistant glass coating, it is characterised in that including following component in parts by weight：Hollow glass microbead 2-6 parts,
Glass fibre 1-3 parts, calcium oxide 1-2 parts, methyl methacrylate 5-10 parts, titanium dioxide 2-3 parts, maleic acid resin 3-6 parts, third
Glycol methyl ether acetate 4-7 parts, antioxidant 1-2 parts, curing agent 1-3 parts, solvent 30-40 parts.
2. flame resistant glass coating according to claim 1, it is characterised in that antioxidant is antioxidant 264.
3. flame resistant glass coating according to claim 1, it is characterised in that curing agent is ethylenediamine.
4. flame resistant glass coating according to claim 1, it is characterised in that solvent is ethanol.
5. the preparation method of the flame resistant glass coating described in claim 1, it is characterised in that comprise the following steps：
Step 1, hollow glass microbead, glass fibre, calcium oxide, divided titanium dioxide are scattered in solvent, obtain mixture one；
Step 2, methyl methacrylate, maleic acid resin, propylene glycol methyl ether acetate are added in mixture one, heating is simultaneously
Curing agent is added, 30-40 minutes is stirred, obtains mixture two；
Step 3, antioxidant is added in mixture two, be stirred, obtain flame resistant glass coating.
6. the preparation method of flame resistant glass coating according to claim 5, it is characterised in that the temperature to be heated up in step 2
For 50-60 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396826.8A CN107353681A (en) | 2017-05-31 | 2017-05-31 | A kind of flame resistant glass coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396826.8A CN107353681A (en) | 2017-05-31 | 2017-05-31 | A kind of flame resistant glass coating and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107353681A true CN107353681A (en) | 2017-11-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710396826.8A Pending CN107353681A (en) | 2017-05-31 | 2017-05-31 | A kind of flame resistant glass coating and preparation method thereof |
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| CN (1) | CN107353681A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371476A (en) * | 2014-11-14 | 2015-02-25 | 无锡中洁能源技术有限公司 | Flame-retardant and moisture-proof coating for solar cells and preparation method of coating |
-
2017
- 2017-05-31 CN CN201710396826.8A patent/CN107353681A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371476A (en) * | 2014-11-14 | 2015-02-25 | 无锡中洁能源技术有限公司 | Flame-retardant and moisture-proof coating for solar cells and preparation method of coating |
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Application publication date: 20171117 |
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