CN108165157A - A kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process - Google Patents
A kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process Download PDFInfo
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- CN108165157A CN108165157A CN201810114862.5A CN201810114862A CN108165157A CN 108165157 A CN108165157 A CN 108165157A CN 201810114862 A CN201810114862 A CN 201810114862A CN 108165157 A CN108165157 A CN 108165157A
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- coating
- retardant
- insulating flame
- expansion heat
- water expansion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water expansion heat-insulating flame-retardants to press down cigarette coating and its coating process, including following component by weight percentage：Modified polyurethane emulsion 25%~40%, dispersant 1%~10%, hollow glass powder 5%~15%, halogen-free expansion fire retardant 20%~35%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.The present invention overcomes shortcoming and defect in the prior art, for wood product surface processing, improves the adhesive force and impact resistance of woodwork paint film, it is heat-insulated, fire-retardant, smoke suppressing effect is good, in a pipeline using the woodwork with fire protecting performance, it is suitble to quick production, greatly improves efficiency.
Description
Technical field
The present invention relates to a kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process, belong to Building technology neck
Domain.
Background technology
At present, the use of coating and interfacing relationship are close, and coating is a kind of multicomponent system --- and resin (base-material), face are filled out
Material, solvent, auxiliary agent.There are there are certain interfaces between many interfaces, particularly color stuffing and resin, solvent inside system；
Coating is a kind of semi-finished product simultaneously, it is necessary to the effects that coated in workpiece, product, structure, protection, decoration, function could be provided,
There are certain interface state also certain requirement will necessarily be proposed for coating use.In addition, in coating after construction, there are one
Dry, cured process, wherein must consider contact of the film (wet) between surface and air, it is good to guarantee to provide
Appearance of film, prevent the appearance of surface defect.
Woodwork because of the inflammable characteristic of its low ignition point, easily causes fire in itself.To avoid this disadvantage, use at present
Method mainly fire-retardant liquid medicine or application anti-flaming dope are added into timber.To avoid this disadvantage, the method used at present
Fire-retardant liquid medicine or application anti-flaming dope are mainly added into timber.However, existing anti-flaming dope can not carry out wooden product
Effective thermal insulation protection does not have Smoke prevention effect or even some fire proofings that can discharge halogen-containing toxic gas when decomposing yet.
Meanwhile existing anti-flaming dope, it can not also meet the production requirement on assembly line.For ensure and improve paint film adhesive force and
Impact resistance, realizes the production requirement for woodwork of preventing fires on assembly line, and woodwork is made to have heat-insulated and Smoke prevention effect, it is necessary to
The prior art is improved.
Invention content
It is an object of the invention to overcome shortcoming and defect in the prior art, in order to achieve the above objectives, this hair
First technical solution of bright use be：A kind of water expansion heat-insulating flame-retardant presses down cigarette coating, including following component by weight hundred
Divide ratio：Modified polyurethane emulsion 25%~40%, dispersant 1%~10%, hollow glass powder 5%~15%, halogen-free expansible
Fire retardant 20%~35%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
Preferably technical solution is：A kind of water expansion heat-insulating flame-retardant presses down cigarette coating, including following component by weight hundred
Divide ratio：Modified polyurethane emulsion 25%~35%, dispersant 1%~10%, hollow glass powder 5%~15%, halogen-free expansible
Fire retardant 25%~35%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
Preferably technical solution is：A kind of water expansion heat-insulating flame-retardant presses down cigarette coating, including following component by weight hundred
Divide ratio：Modified polyurethane emulsion 30%~40%, dispersant 1%~10%, hollow glass powder 5%~15%, halogen-free expansible
Fire retardant 20%~30%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
Preferably technical solution is：A kind of water expansion heat-insulating flame-retardant presses down cigarette coating, including following component by weight hundred
Divide ratio：Modified polyurethane emulsion 30%~35%, dispersant 1%~10%, hollow glass powder 7%~12%, halogen-free expansible
Fire retardant 25%~30%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
Preferably technical solution is：The halogen-free expansion fire retardant includes following component by weight percentage：Tricresyl phosphate
Toluene ester 10%~20%, phosphoric acid tri-isopropyl benzene ester 10%~20%, cresyl diphenyl phosphate 10%~40%, aluminium oxide
15%~50%, zinc borate 15%~50%
Preferably technical solution is：The paint spraying is on woodwork substrate surface.
Second technical solution that the present invention uses be：A kind of application side of water expansion heat-insulating flame-retardant suppression cigarette coating
Method includes the following steps：
The first step：Coating is coated on wood product surface；
Second step：Cured using air-heater；
Third walks：Ultraviolet-curing paint is coated with its surface, then cures；
4th step：Direct finished product packing on assembly line.
Preferably technical solution is：Coating method in the first step is roller coating, electrostatic spraying, airless spraying, showering,
Dip-coating, spin coating or pumping painting.
Preferably technical solution is：The dispersant be BYK-192, byk companies chemical products.
Preferably technical solution is：The antifoaming agent be byk-022, byk companies chemical products.
Since above-mentioned technical proposal is used, the present invention has following advantages：
(1) adhesive force and impact resistance of woodwork paint film are improved using polyaminoester emulsion in coating；
(2) woodwork with fire protecting performance is used on assembly line, is suitble to quick production, greatly improves efficiency；
(3) when fire occurs, good heat-insulation effect can be delayed or prevent the intensity of a fire from spreading.400 DEG C of Coated Surface Temperature with
Under, hollow glass can obstruct heat transfer, prevent steam or other substances in timber from raising a dust and coating is caused to burst apart, so as to avoid inside
Timber contacts heat source.When Coated Surface Temperature is more than 400 DEG C, coating starts to liquefy, and constantly expands, and forms thicker heat-insulated guarantor
Sheath；
(4) it is conducted using toughness thermal insulation layer and the expanding layer being continuously generated come trap heat, not using halogen material
Volatilization absorbing and cooling temperature fire prevention principle, avoids the generation of toxic gas and cigarette, prevents having smoke suppressing effect while fire spreading,
Preferably escape condition is obtained for personnel in the scene of a fire.
Specific embodiment
It is described below to disclose the present invention so that those skilled in the art can realize the present invention.It is excellent in being described below
Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious deformations.
Forming the various raw materials of the present invention can directly buy or the means system by the prior art from the market
It is standby.Further detailed description is done to the present invention in conjunction with specific embodiment.
Embodiment 1：The present invention provides a kind of water expansion heat-insulating flame-retardant suppression cigarette coating, including following component, by weight
Content matches, and refers to table 1：
Table 1
| Component | Content (Wt./%) |
| Modified polyurethane emulsion | 25~40 |
| Dispersant | 1~10 |
| Hollow glass powder | 5~15 |
| Halogen-free expansion fire retardant | 20~35 |
| Antifoaming agent | 0.01~1 |
| Pure water | 0.1~30 |
Dispersant in said components is BYK-192 (byk companies chemical products)；Antifoaming agent is byk-022 (byk companies
Chemical products).
Wherein halogen-free expansion fire retardant includes following component, and content by weight matches, and refers to table 2：
Table 2
| Component | Content (Wt./%) |
| Tricresyl phosphate | 15 |
| Phosphoric acid tri-isopropyl benzene ester | 15 |
| Cresyl diphenyl phosphate | 15 |
| Aluminium oxide | 30 |
| Zinc borate | 25 |
Formula in above-described embodiment, specific preparation method are：
In the modified polyurethane emulsion of certain mass percent, the dispersant of certain mass percent is added in, is being stirred
Under state, hollow glass powder, halogen-free expansion fire retardant, the antifoaming agent of certain mass percent are added in, after stirring evenly, is added
Enter the water of certain mass percent, adjust to appropriate viscosity, so as to which water expansion heat-insulating flame-retardant suppression cigarette coating be made.
Embodiment 2：The present invention provides a kind of water expansion heat-insulating flame-retardant suppression cigarette coating, including following component, by weight
Content matches, and refers to table 3：
Table 3
| Component | Content (Wt./%) |
| Modified polyurethane emulsion | 25~35 |
| Dispersant | 1~10 |
| Hollow glass powder | 5~15 |
| Halogen-free expansion fire retardant | 25~35 |
| Antifoaming agent | 0.01~1 |
| Pure water | 0.1~30 |
Dispersant in said components is BYK-192 (byk companies chemical products)；Antifoaming agent is byk-022 (byk companies
Chemical products).
Wherein halogen-free expansion fire retardant includes following component, and content by weight matches, and refers to table 4：
Table 4
| Component | Content (Wt./%) |
| Tricresyl phosphate | 10 |
| Phosphoric acid tri-isopropyl benzene ester | 10 |
| Cresyl diphenyl phosphate | 10 |
| Aluminium oxide | 50 |
| Zinc borate | 20 |
Formula in above-described embodiment, specific preparation method are：
In the modified polyurethane emulsion of certain mass percent, the dispersant of certain mass percent is added in, is being stirred
Under state, hollow glass powder, halogen-free expansion fire retardant, the antifoaming agent of certain mass percent are added in, after stirring evenly, is added
Enter the water of certain mass percent, adjust to appropriate viscosity, so as to which water expansion heat-insulating flame-retardant suppression cigarette coating be made.
Embodiment 3：The present invention provides a kind of water expansion heat-insulating flame-retardant suppression cigarette coating, including following component, by weight
Content matches, and refers to table 5：
Table 5
| Component | Content (Wt./%) |
| Modified polyurethane emulsion | 30~40 |
| Dispersant | 1~10 |
| Hollow glass powder | 5~15 |
| Halogen-free expansion fire retardant | 20~30 |
| Antifoaming agent | 0.01~1 |
| Pure water | 0.1~30 |
Dispersant in said components is BYK-192 (byk companies chemical products)；Antifoaming agent is byk-022 (byk companies
Chemical products).
Wherein halogen-free expansion fire retardant includes following component, and content by weight matches, and refers to table 6：
Table 6
| Component | Content (Wt./%) |
| Tricresyl phosphate | 20 |
| Phosphoric acid tri-isopropyl benzene ester | 20 |
| Cresyl diphenyl phosphate | 20 |
| Aluminium oxide | 20 |
| Zinc borate | 20 |
Formula in above-described embodiment, specific preparation method are：
In the modified polyurethane emulsion of certain mass percent, the dispersant of certain mass percent is added in, is being stirred
Under state, hollow glass powder, halogen-free expansion fire retardant, the antifoaming agent of certain mass percent are added in, after stirring evenly, is added
Enter the water of certain mass percent, adjust to appropriate viscosity, so as to which water expansion heat-insulating flame-retardant suppression cigarette coating be made.
Embodiment 4：The present invention provides a kind of water expansion heat-insulating flame-retardant suppression cigarette coating, including following component, by weight
Content matches, and refers to table 7：
Table 7
| Component | Content (Wt./%) |
| Modified polyurethane emulsion | 30~35 |
| Dispersant | 1~10 |
| Hollow glass powder | 7~12 |
| Halogen-free expansion fire retardant | 25~30 |
| Antifoaming agent | 0.01~1 |
| Pure water | 0.1~30 |
Dispersant in said components is BYK-192 (byk companies chemical products)；Antifoaming agent is byk-022 (byk companies
Chemical products).
Wherein halogen-free expansion fire retardant includes following component, and content by weight matches, and refers to table 8：
Table 8
| Component | Content (Wt./%) |
| Tricresyl phosphate | 20 |
| Phosphoric acid tri-isopropyl benzene ester | 20 |
| Cresyl diphenyl phosphate | 20 |
| Aluminium oxide | 20 |
| Zinc borate | 20 |
Formula in above-described embodiment, specific preparation method are：
In the modified polyurethane emulsion of certain mass percent, the dispersant of certain mass percent is added in, is being stirred
Under state, hollow glass powder, halogen-free expansion fire retardant, the antifoaming agent of certain mass percent are added in, after stirring evenly, is added
Enter the water of certain mass percent, adjust to appropriate viscosity, so as to which water expansion heat-insulating flame-retardant suppression cigarette coating be made.
Analysis is tested for the property to embodiment 1 to 4, test result is shown in Table 9：
Table 9
A kind of coating process of above-mentioned water expansion heat-insulating flame-retardant suppression cigarette coating：
The first step：Coating is coated on wood product surface；
Second step：Cured using air-heater；
Third walks：Ultraviolet-curing paint is coated with its surface, then cures；
4th step：Direct finished product packing on assembly line, obtains the woodwork with flameproof effect.
Roller coating, spraying (electrostatic spraying), airless spraying, showering, dip-coating, rotation may be used in coating method in the first step
The modes such as painting, pumping painting.
The coating that embodiment is prepared has the following advantages that：
(1) adhesive force and impact resistance of woodwork paint film are improved using polyaminoester emulsion in coating；
(2) woodwork with fire protecting performance is used on assembly line, is suitble to quick production, greatly improves efficiency；
(3) when fire occurs, good heat-insulation effect can be delayed or prevent the intensity of a fire from spreading.400 DEG C of Coated Surface Temperature with
Under, hollow glass can obstruct heat transfer, prevent steam or other substances in timber from raising a dust and coating is caused to burst apart, so as to avoid inside
Timber contacts heat source.When Coated Surface Temperature is more than 400 DEG C, coating starts to liquefy, and constantly expands, and forms thicker heat-insulated guarantor
Sheath；
(4) it is conducted using toughness thermal insulation layer and the expanding layer being continuously generated come trap heat, not using halogen material
Volatilization absorbing and cooling temperature fire prevention principle, avoids the generation of toxic gas and cigarette, prevents having smoke suppressing effect while fire spreading,
Preferably escape condition is obtained for personnel in the scene of a fire.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all according to the present invention
The equivalent change or modification that Spirit Essence is made, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of water expansion heat-insulating flame-retardant presses down cigarette coating, which is characterized in that including following component by weight percentage：It is modified
Polyaminoester emulsion 25%~40%, dispersant 1%~10%, hollow glass powder 5%~15%, halogen-free expansion fire retardant 20%
~35%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
2. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to claim 1, which is characterized in that including such as the following group
Divide by weight percentage：Modified polyurethane emulsion 25%~35%, dispersant 1%~10%, hollow glass powder 5%~15%,
Halogen-free expansion fire retardant 25%~35%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
3. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to claim 1, which is characterized in that including such as the following group
Divide by weight percentage：Modified polyurethane emulsion 30%~40%, dispersant 1%~10%, hollow glass powder 5%~15%,
Halogen-free expansion fire retardant 20%~30%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
4. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to claim 1, which is characterized in that including such as the following group
Divide by weight percentage：Modified polyurethane emulsion 30%~35%, dispersant 1%~10%, hollow glass powder 7%~12%,
Halogen-free expansion fire retardant 25%~30%, antifoaming agent 0.01%~1%, pure water 0.1%~30%.
5. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to Claims 1 to 4 any claim, feature
It is, the halogen-free expansion fire retardant includes following component by weight percentage：Tricresyl phosphate 10%~20%, phosphoric acid
Tri-isopropyl benzene ester 10%~20%, cresyl diphenyl phosphate 10%~40%, aluminium oxide 15%~50%, zinc borate 15%
~50%.
6. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to claim 5, which is characterized in that the coating applies
On woodwork substrate surface.
7. a kind of a kind of painting of water expansion heat-insulating flame-retardant suppression cigarette coating as described in Claims 1 to 4 any claim
Dress method, which is characterized in that the coating process includes the following steps：
The first step：Coating is coated on wood product surface；
Second step：Cured using air-heater；
Third walks：Ultraviolet-curing paint is coated with its surface, then cures；
4th step：Direct finished product packing on assembly line.
8. a kind of coating process of water expansion heat-insulating flame-retardant suppression cigarette coating according to claim 7, which is characterized in that
Coating method in the first step is roller coating, electrostatic spraying, airless spraying, showering, dip-coating, spin coating or pumping painting.
9. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to Claims 1 to 4 any claim, feature
Be, the dispersant be BYK-192, byk companies chemical products.
10. a kind of water expansion heat-insulating flame-retardant suppression cigarette coating according to Claims 1 to 4 any claim, special
Sign is, the antifoaming agent is byk-022, byk companies chemical products.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810114862.5A CN108165157A (en) | 2018-02-02 | 2018-02-02 | A kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810114862.5A CN108165157A (en) | 2018-02-02 | 2018-02-02 | A kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process |
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| CN108165157A true CN108165157A (en) | 2018-06-15 |
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ID=62512961
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|---|---|---|---|
| CN201810114862.5A Pending CN108165157A (en) | 2018-02-02 | 2018-02-02 | A kind of water expansion heat-insulating flame-retardant suppression cigarette coating and its coating process |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110591424A (en) * | 2019-10-29 | 2019-12-20 | 中国民航大学 | Preparation method of aluminum phosphate gum base halogen-free high-expansion flame-retardant heat-insulating fireproof coating |
| CN111117438A (en) * | 2019-12-28 | 2020-05-08 | 江阴市玲珑高分子材料有限公司 | Insulating flame-retardant coating |
| CN112646472A (en) * | 2020-12-18 | 2021-04-13 | 东周化学工业（昆山）有限公司 | Flame-retardant water-based paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881550A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof |
| CN107501868A (en) * | 2017-09-30 | 2017-12-22 | 四会市启德信息咨询服务有限公司 | A kind of halogen-free expansion type flame-proof cable cover(ing) |
-
2018
- 2018-02-02 CN CN201810114862.5A patent/CN108165157A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881550A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof |
| CN107501868A (en) * | 2017-09-30 | 2017-12-22 | 四会市启德信息咨询服务有限公司 | A kind of halogen-free expansion type flame-proof cable cover(ing) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110591424A (en) * | 2019-10-29 | 2019-12-20 | 中国民航大学 | Preparation method of aluminum phosphate gum base halogen-free high-expansion flame-retardant heat-insulating fireproof coating |
| CN110591424B (en) * | 2019-10-29 | 2021-07-06 | 中国民航大学 | Preparation method of aluminum phosphate gum base halogen-free high-expansion flame-retardant heat-insulating fireproof coating |
| CN111117438A (en) * | 2019-12-28 | 2020-05-08 | 江阴市玲珑高分子材料有限公司 | Insulating flame-retardant coating |
| CN112646472A (en) * | 2020-12-18 | 2021-04-13 | 东周化学工业（昆山）有限公司 | Flame-retardant water-based paint and preparation method thereof |
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Application publication date: 20180615 |