CN107353532A - A kind of plastic products using Tissuemat E - Google Patents
A kind of plastic products using Tissuemat E Download PDFInfo
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- CN107353532A CN107353532A CN201710545910.1A CN201710545910A CN107353532A CN 107353532 A CN107353532 A CN 107353532A CN 201710545910 A CN201710545910 A CN 201710545910A CN 107353532 A CN107353532 A CN 107353532A
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- tissuemat
- plastic products
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a kind of plastic products using Tissuemat E, its raw material includes by weight：50 60 parts of polyvinyl chloride, 30 40 parts of ethylene-vinyl acetate copolymer, 18 26 parts of polyether-ether-ketone, 24 parts of crosslinking agent, 18 24 parts of vermiculite power, 12 24 parts of lignocellulosic, 8 16 parts of calcined kaolin, 10 16 parts of flyash, 7 11 parts of compatilizer, 24 parts of hyaluronic acid, 35 parts of age resistor.Plastic products proposed by the present invention using Tissuemat E, processing characteristics is excellent, and toughness is fabulous, and hardness is higher, and cost is relatively low.
Description
Technical field
The present invention relates to plastics arts, more particularly to a kind of plastic products using Tissuemat E.
Background technology
Because Tissuemat E has the characteristics of nontoxic, non-corrosiveness, hardness are larger, softening point is high, melting viscosity is low, normal
Temperature is lower to have good moisture resistance, chemical-resistant, electric property and antiwear heat resisting performance, and lubricity, dispersiveness, flowing
Property is good, in plastic industry by extensive use.
Existing Tissuemat E is typically made using the polyethylene of macromolecule by series of process step, and this is made in it
Height, and the molecular weight distribution produced is wider, causes dispersion effect poor, can not meet the requirement of plastic products.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of plastic products using Tissuemat E, added
Work excellent performance, toughness is fabulous, and hardness is higher, and cost is relatively low.
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 50-
60 parts, ethylene-vinyl acetate copolymer 30-40 parts, polyether-ether-ketone 18-26 parts, crosslinking agent 2-4 parts, vermiculite power 18-24 parts, wood
Matter cellulose 12-24 parts, calcined kaolin 8-16 parts, flyash 10-16 parts, compatilizer 7-11 parts, hyaluronic acid 2-4 parts, prevent
Old agent 3-5 parts.
Preferably, age resistor includes by weight：Anti-aging agent RD 1.5-2.5 parts, antioxidant A W 1.5-2.5 parts.
Preferably, compatilizer includes by weight：Pre-process Tissuemat E 6-10 parts, aluminate coupling agent 1.5-2.5 parts.
Preferably, Tissuemat E is pre-processed to prepare using following technique：Under stirring, sequentially added into Tissuemat E
Water, sorbester p17, soybean lecithin, heating stirring, cooling stirring, it is 7.1-7.3 with sodium hydroxide regulation system pH value, obtains pre- place
Manage Tissuemat E.
Preferably, Tissuemat E is pre-processed to prepare using following technique：Under stirring, gather by weight to 30-40 parts
55-65 parts water, 2-4 parts sorbester p17,4-8 part soybean lecithins are sequentially added in ethylene waxes, heating stirring, stirring is cooled to, uses hydrogen
Sodium oxide molybdena regulation system pH value is 7.1-7.3, obtains pre-processing Tissuemat E.
Preferably, Tissuemat E is pre-processed to prepare using following technique：Under stirring, gather by weight to 30-40 parts
55-65 parts water, 2-4 parts sorbester p17,4-8 part soybean lecithins are sequentially added in ethylene waxes, is warming up to 160-170 DEG C of stirring 40-
60min, mixing speed 3400-4000r/min, 75-80 DEG C of stirring 4-8h is cooled to, is with sodium hydroxide regulation system pH value
7.1-7.3, obtain pre-processing Tissuemat E.
The present invention coordinates pretreatment polyethylene using polyvinyl chloride, ethylene-vinyl acetate copolymer, polyether-ether-ketone as major ingredient
Wax acts on, and mutual good dispersion, makes processing characteristics of the present invention excellent, and after crosslinked dose of vulcanization, crosslinking rate is fast, and is not easy
There is incipient scorch, disproportionation and the chain rupture of polymer can be suppressed, toughness is fabulous.
In Tissuemat E is pre-processed, Tissuemat E Low molecular weight polyethylene, by using sorbester p17, soybean phosphorus
It fat high-temperature process, can effectively strengthen emulsifiability, be adjusted using sodium hydroxide to alkalescent, it is possible to increase degree of ionization, and
Particle is small；Pre-process Tissuemat E and polyvinyl chloride, ethylene-vinyl acetate copolymer, polyether-ether-ketone degree of scatter are high, can have
Effect promotes crosslinking agent wherein scattered, and vulcanization effect is fabulous.Pre-process Tissuemat E with aluminate coupling agent to coordinate, Liang Zhebiao
Face com-patibilising effect is good, can reach with vermiculite power, lignocellulosic, calcined kaolin, flyash and combines effect well, to each other
Adhesion is strong, and on the premise of toughness is ensured, hardness is higher, meets the needs of plastic products；It is aided with sodium carboxymethylcellulose again,
Storeroom combination degree and processability are improved, on the premise of hardness is met, toughness further enhances, and can significantly drop
Low cost.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 50
Part, 40 parts of ethylene-vinyl acetate copolymer, 18 parts of polyether-ether-ketone, 4 parts of crosslinking agent, 18 parts of vermiculite power, 24 parts of lignocellulosic,
8 parts of calcined kaolin, 16 parts of flyash, 7 parts of compatilizer, 4 parts of hyaluronic acid, 3 parts of age resistor.
Embodiment 2
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 60
Part, 30 parts of ethylene-vinyl acetate copolymer, 26 parts of polyether-ether-ketone, 2 parts of crosslinking agent, 24 parts of vermiculite power, 12 parts of lignocellulosic,
16 parts of calcined kaolin, 10 parts of flyash, 11 parts of compatilizer, 2 parts of hyaluronic acid, 5 parts of age resistor.
Compatilizer includes by weight：Pre-process 6 parts of Tissuemat E, 2.5 parts of aluminate coupling agent.Age resistor is by weight
Including：1.5 parts of anti-aging agent RD, 2.5 parts of antioxidant A W.
Tissuemat E is pre-processed to prepare using following technique：Under stirring, water, sapn are sequentially added into Tissuemat E
80th, soybean lecithin, heating stirring, cooling stirring, it is 7.1-7.3 with sodium hydroxide regulation system pH value, obtains pre-processing poly- second
Alkene wax.
Embodiment 3
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 52
Part, 38 parts of ethylene-vinyl acetate copolymer, 20 parts of polyether-ether-ketone, 3.5 parts of crosslinking agent, 20 parts of vermiculite power, lignocellulosic 20
Part, 10 parts of calcined kaolin, 14 parts of flyash, 8 parts of compatilizer, 3.5 parts of hyaluronic acid, 3.5 parts of age resistor.
Compatilizer includes by weight：Pre-process 10 parts of Tissuemat E, 1.5 parts of aluminate coupling agent.Age resistor is by weight
Part includes：2.5 parts of anti-aging agent RD, 1.5 parts of antioxidant A W.
Tissuemat E is pre-processed to prepare using following technique：Under stirring, by weight into 35 parts of Tissuemat Es according to
60 parts of water of secondary addition, 3 parts of sorbester p17s, 6 parts of soybean lecithins, heating stirring, are cooled to stirring, with sodium hydroxide regulation system pH value
For 7.1-7.3, obtain pre-processing Tissuemat E.
Embodiment 4
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 58
Part, 32 parts of ethylene-vinyl acetate copolymer, 24 parts of polyether-ether-ketone, 2.5 parts of crosslinking agent, 22 parts of vermiculite power, lignocellulosic 16
Part, 14 parts of calcined kaolin, 12 parts of flyash, 10 parts of compatilizer, 2.5 parts of hyaluronic acid, 4.5 parts of age resistor.
Compatilizer includes by weight：Pre-process 8 parts of Tissuemat E, 2.2 parts of aluminate coupling agent.Age resistor is by weight
Including：1.8 parts of anti-aging agent RD, 2 parts of antioxidant A W.
Tissuemat E is pre-processed to prepare using following technique：Under stirring, by weight into 30 parts of Tissuemat Es according to
65 parts of water of secondary addition, 2 parts of sorbester p17s, 8 parts of soybean lecithins, 160 DEG C of stirrings 60min, mixing speed 3400r/min are warming up to,
80 DEG C of stirring 4h are cooled to, are 7.1-7.3 with sodium hydroxide regulation system pH value, obtain pre-processing Tissuemat E.
Embodiment 5
A kind of plastic products using Tissuemat E proposed by the present invention, its raw material include by weight：Polyvinyl chloride 55
Part, 35 parts of ethylene-vinyl acetate copolymer, 22 parts of polyether-ether-ketone, 3 parts of crosslinking agent, 21 parts of vermiculite power, 18 parts of lignocellulosic,
12 parts of calcined kaolin, 13 parts of flyash, 9 parts of compatilizer, 3 parts of hyaluronic acid, 4 parts of age resistor.
Compatilizer includes by weight：Pre-process 9 parts of Tissuemat E, 2 parts of aluminate coupling agent.Age resistor wraps by weight
Include：2 parts of anti-aging agent RD, 1.8 parts of antioxidant A W.
Tissuemat E is pre-processed to prepare using following technique：Under stirring, by weight into 40 parts of Tissuemat Es according to
55 parts of water of secondary addition, 4 parts of sorbester p17s, 4 parts of soybean lecithins, 170 DEG C of stirrings 40min, mixing speed 4000r/min are warming up to,
75 DEG C of stirring 8h are cooled to, are 7.1-7.3 with sodium hydroxide regulation system pH value, obtain pre-processing Tissuemat E.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of plastic products using Tissuemat E, it is characterised in that its raw material includes by weight：Polyvinyl chloride 50-60
Part, ethylene-vinyl acetate copolymer 30-40 parts, polyether-ether-ketone 18-26 parts, crosslinking agent 2-4 parts, vermiculite power 18-24 parts are wooden
Cellulose 12-24 parts, calcined kaolin 8-16 parts, flyash 10-16 parts, compatilizer 7-11 parts, hyaluronic acid 2-4 parts, prevent old
Agent 3-5 parts.
2. the plastic products of Tissuemat E are used according to claim 1, it is characterised in that age resistor includes by weight：
Anti-aging agent RD 1.5-2.5 parts, antioxidant A W 1.5-2.5 parts.
3. the plastic products according to claim 1 or claim 2 using Tissuemat E, it is characterised in that compatilizer wraps by weight
Include：Pre-process Tissuemat E 6-10 parts, aluminate coupling agent 1.5-2.5 parts.
4. according to any one of the claim 1-3 plastic products using Tissuemat E, it is characterised in that pretreatment polyethylene
Wax is prepared using following technique：Under stirring, water, sorbester p17, soybean lecithin are sequentially added into Tissuemat E, heating is stirred
Mix, cooling stirring, is 7.1-7.3 with sodium hydroxide regulation system pH value, obtains pre-processing Tissuemat E.
5. according to any one of the claim 1-4 plastic products using Tissuemat E, it is characterised in that pretreatment polyethylene
Wax is prepared using following technique：Under stirring, 55-65 parts water, 2- are sequentially added into 30-40 part Tissuemat Es by weight
4 parts of sorbester p17s, 4-8 part soybean lecithins, heating stirring, are cooled to stirring, are 7.1-7.3 with sodium hydroxide regulation system pH value,
Obtain pre-processing Tissuemat E.
6. according to any one of the claim 1-5 plastic products using Tissuemat E, it is characterised in that pretreatment polyethylene
Wax is prepared using following technique：Under stirring, 55-65 parts water, 2- are sequentially added into 30-40 part Tissuemat Es by weight
4 parts of sorbester p17s, 4-8 part soybean lecithins, 160-170 DEG C of stirring 40-60min, mixing speed 3400-4000r/min are warming up to,
75-80 DEG C of stirring 4-8h is cooled to, is 7.1-7.3 with sodium hydroxide regulation system pH value, obtains pre-processing Tissuemat E.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710545910.1A CN107353532A (en) | 2017-07-06 | 2017-07-06 | A kind of plastic products using Tissuemat E |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710545910.1A CN107353532A (en) | 2017-07-06 | 2017-07-06 | A kind of plastic products using Tissuemat E |
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| Publication Number | Publication Date |
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| CN107353532A true CN107353532A (en) | 2017-11-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710545910.1A Withdrawn CN107353532A (en) | 2017-07-06 | 2017-07-06 | A kind of plastic products using Tissuemat E |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317415A (en) * | 2019-08-09 | 2019-10-11 | 青岛创田科技咨询有限公司 | A kind of oxidic polyethylene wax powder and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105037840A (en) * | 2015-06-23 | 2015-11-11 | 中山市鸿程科研技术服务有限公司 | Heatproof and waterproof cable material and preparation method thereof |
| CN105086216A (en) * | 2015-07-27 | 2015-11-25 | 合肥市深朝电子有限公司 | Automobile wiring harness pvc abrasion-resistant flame-retardant sheathing material and preparation method thereof |
| CN106009548A (en) * | 2016-07-28 | 2016-10-12 | 无锡市凯达来塑胶有限公司 | Mildew-proof polyvinyl chloride floor |
-
2017
- 2017-07-06 CN CN201710545910.1A patent/CN107353532A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105037840A (en) * | 2015-06-23 | 2015-11-11 | 中山市鸿程科研技术服务有限公司 | Heatproof and waterproof cable material and preparation method thereof |
| CN105086216A (en) * | 2015-07-27 | 2015-11-25 | 合肥市深朝电子有限公司 | Automobile wiring harness pvc abrasion-resistant flame-retardant sheathing material and preparation method thereof |
| CN106009548A (en) * | 2016-07-28 | 2016-10-12 | 无锡市凯达来塑胶有限公司 | Mildew-proof polyvinyl chloride floor |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317415A (en) * | 2019-08-09 | 2019-10-11 | 青岛创田科技咨询有限公司 | A kind of oxidic polyethylene wax powder and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171117 |
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| WW01 | Invention patent application withdrawn after publication |