CN105037840A - Heatproof and waterproof cable material and preparation method thereof - Google Patents
Heatproof and waterproof cable material and preparation method thereof Download PDFInfo
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- CN105037840A CN105037840A CN201510346127.3A CN201510346127A CN105037840A CN 105037840 A CN105037840 A CN 105037840A CN 201510346127 A CN201510346127 A CN 201510346127A CN 105037840 A CN105037840 A CN 105037840A
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Abstract
The invention discloses a heatproof and waterproof cable material which comprises the following raw materials in parts by weight: 6-8 parts of mica powder, 4-6 parts of polyphenyl ether, 3-5 parts of polyetheretherketone, 3-6 parts of microcrystalline wax, 4-6 parts of activated calcium carbonate, 2-5 parts of polyphenyl ether, 4-5 parts of nano titanium dioxide, 2-5 parts of antimonous oxide, 1-2 parts of vanadium phosphate, 50-60 parts of isoprene rubber, 2-3 parts of tricresyl phosphate, 3-4 parts of ethylene-vinyl acetate copolymer, 10-15 parts of diphenyl isopropylphenyl phosphate, 5-10 parts of polyvinyl chloride, 3-5 parts of tert-butylperoxy isopropyl carbonate, 4-5 parts of tetramethyl thiuram tetrasulfide and 8-12 parts of an auxiliary. The heatproof and waterproof cable material is very high in corrosion resistance, creep resistance, heat resistance and water resistance.
Description
Technical field
The present invention relates to cable material technical field, particularly relate to water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant and preparation method thereof.
Background technology
The quality of polyvinyl chloride cable material and PVC cable material quality is fundamentally to be filled a prescription by PVC cable material and selected raw material decides.Along with the various auxiliary agent of PVC and the continuous renewal of weighting material and development, also the formula of PVC cable material is made constantly to improve and improve, the block-water performance of the cable that existing market uses is weak, long term operation is in water surrounding, easily cause cable transmission electric power and communication to can not get ensureing, under the prerequisite not affecting its serviceability, thus need the water resistance improving whole cable.Traditional cable jacket material tensile strength and shock strength, erosion resistance, creep resistance, wear resistance Shortcomings situation.
Summary of the invention
Object of the present invention will provide water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant and preparation method thereof exactly, is solved that prior art heat impedance is poor, water tolerance is bad and the technical problem of wear resistance Shortcomings by the present invention.
To achieve these goals, the present invention adopts following technical scheme:
The water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant, be made up of following raw material, mica powder 6-8 part, polyphenylene oxide 4-6 part, polyether-ether-ketone 3-5 part, microcrystalline wax 3-6 part, activated Calcium carbonate 4-6 part, polyphenylene oxide 2-5 part, nano titanium oxide 4-5 part, antimonous oxide 2-5 part, vanadium phosphate 1-2 part, polyisoprene rubber 50-60 part, Tritolyl Phosphate 2-3 part, ethylene-vinyl acetate copolymer 3-4 part, p isopropylbenzoic acid base benzene diphenyl ester 10-15 part, polyvinyl chloride 5-10 part, tert-butylperoxy isopropyl carbonate 3-5 part, tetramethylthiuram tetrasulfide 4-5 part, auxiliary agent 8-12 part;
Wherein, the polymerization degree of described polyvinyl chloride is 800-1000; Consisting of of described auxiliary agent: graphite 2-4 part, borax 2-4 part, diatom ooze 25-35 part, Zinic stearas 6-10 part, Vaseline 5-6 part, Vanay 4-6 part, polyhexamethylene guanidine 3-4 part.
Preferred version of the present invention is: mica powder 8 parts, polyphenylene oxide 6 parts, polyether-ether-ketone 5 parts, microcrystalline wax 6 parts, activated Calcium carbonate 6 parts, polyphenylene oxide 5 parts, nano titanium oxide 5 parts, antimonous oxide 5 parts, vanadium phosphate 2 parts, polyisoprene rubber 60 parts, Tritolyl Phosphate 3 parts, ethylene-vinyl acetate copolymer 4 parts, p isopropylbenzoic acid base benzene diphenyl ester 15 parts, polyvinyl chloride 10 parts, tert-butylperoxy isopropyl carbonate 5 parts, tetramethylthiuram tetrasulfide 5 parts, auxiliary agent 12 parts;
Wherein, the polymerization degree of described polyvinyl chloride is 1000; Consisting of of described auxiliary agent: 4 parts, graphite, borax 4 parts, diatom ooze 35 parts, Zinic stearas 10 parts, 6 parts, Vaseline, Vanay 6 parts, polyhexamethylene guanidine 4 parts;
A preparation method for CABLE MATERIALS that heat resistanceheat resistant is water-fast, comprises the following steps:
Step 1): in proportion ball grinder is put in the mixing of graphite, borax, diatom ooze, Zinic stearas, Vaseline, Vanay and polyhexamethylene guanidine, Ball-milling Time is 4-6 hour, ball milling temperature is room temperature, drum's speed of rotation 600 revs/min, and the particle diameter being milled to raw material is 500 orders;
Step 2): polyphenylene oxide, polyether-ether-ketone, microcrystalline wax, activated Calcium carbonate, polyphenylene oxide, nano titanium oxide, antimonous oxide, vanadium phosphate filler are added water, PH to 4-5 is regulated with the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 70-80 DEG C, 1500-2000rpm speed lapping 10-15min, then neutrality is neutralized to the sodium hydroxide solution that concentration is 10-15%, leave standstill 20-30min, filter, dry filter residue;
Step 3): mica powder, polyisoprene rubber, Tritolyl Phosphate, ethylene-vinyl acetate copolymer, p isopropylbenzoic acid base benzene diphenyl ester, polyvinyl chloride, tert-butylperoxy isopropyl carbonate, tetramethylthiuram tetrasulfide and auxiliary agent are stirred, mix after together drop into twin screw extruder and carry out melt blending, then extruding pelletization, naturally cool to room temperature, can obtain;
Stirring velocity 400-500 in wherein said step 3) turns/min.
The invention has the beneficial effects as follows:
The present invention processes auxiliary agent separately and prepares burden, by adding graphite, borax and diatom ooze can the water tolerance of improving product, the present invention can increase the thermostability of product by the tert-butylperoxy isopropyl carbonate added, the interpolation of polyhexamethylene guanidine can increase the biocidal property of CABLE MATERIALS product, greatly strengthens the use value of final CABLE MATERIALS finished product.
Embodiment
Be described principle of the present invention and feature below, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
The water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant, is made up of following raw material: mica powder 8 parts, polyphenylene oxide 6 parts, polyether-ether-ketone 5 parts, microcrystalline wax 6 parts, activated Calcium carbonate 6 parts, polyphenylene oxide 5 parts, nano titanium oxide 5 parts, antimonous oxide 5 parts, vanadium phosphate 2 parts, polyisoprene rubber 60 parts, Tritolyl Phosphate 3 parts, ethylene-vinyl acetate copolymer 4 parts, p isopropylbenzoic acid base benzene diphenyl ester 15 parts, polyvinyl chloride 10 parts, tert-butylperoxy isopropyl carbonate 5 parts, tetramethylthiuram tetrasulfide 5 parts, auxiliary agent 12 parts;
Wherein, the polymerization degree of described polyvinyl chloride is 1000; Consisting of of described auxiliary agent: 4 parts, graphite, borax 4 parts, diatom ooze 35 parts, Zinic stearas 10 parts, 6 parts, Vaseline, Vanay 6 parts, polyhexamethylene guanidine 4 parts;
A preparation method for CABLE MATERIALS that heat resistanceheat resistant is water-fast, comprises the following steps:
Step 1): in proportion ball grinder is put in the mixing of graphite, borax, diatom ooze, Zinic stearas, Vaseline, Vanay and polyhexamethylene guanidine, Ball-milling Time is 6 hours, ball milling temperature is room temperature, drum's speed of rotation 600 revs/min, and the particle diameter being milled to raw material is 500 orders;
Step 2): polyphenylene oxide, polyether-ether-ketone, microcrystalline wax, activated Calcium carbonate, polyphenylene oxide, nano titanium oxide, antimonous oxide, vanadium phosphate filler are added water, PH to 5 is regulated with the hydrochloric acid soln that concentration is 20%, heating in water bath to 80 DEG C, 2000rpm speed lapping 15min, then neutrality is neutralized to the sodium hydroxide solution that concentration is 15%, leave standstill 30min, filter, dry filter residue;
Step 3): mica powder, polyisoprene rubber, Tritolyl Phosphate, ethylene-vinyl acetate copolymer, p isopropylbenzoic acid base benzene diphenyl ester, polyvinyl chloride, tert-butylperoxy isopropyl carbonate, tetramethylthiuram tetrasulfide and auxiliary agent are stirred, mix after together drop into twin screw extruder and carry out melt blending, then extruding pelletization, naturally cool to room temperature, can obtain;
Stirring velocity 500 turns/min in wherein said step 3);
Embodiment 2:
The water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant, be made up of following raw material, mica powder 6 parts, polyphenylene oxide 4 parts, polyether-ether-ketone 3 parts, microcrystalline wax 3 parts, activated Calcium carbonate 4 parts, polyphenylene oxide 2 parts, nano titanium oxide 4 parts, antimonous oxide 2 parts, vanadium phosphate 1 part, polyisoprene rubber 50 parts, Tritolyl Phosphate 2 parts, ethylene-vinyl acetate copolymer 3 parts, p isopropylbenzoic acid base benzene diphenyl ester 10 parts, polyvinyl chloride 5 parts, tert-butylperoxy isopropyl carbonate 3 parts, tetramethylthiuram tetrasulfide 4 parts, auxiliary agent 8 parts;
Wherein, the polymerization degree of described polyvinyl chloride is 800; Consisting of of described auxiliary agent: 2 parts, graphite, borax 2 parts, diatom ooze 25 parts, Zinic stearas 6 parts, 5 parts, Vaseline, Vanay 4 parts, polyhexamethylene guanidine 3 parts;
A preparation method for CABLE MATERIALS that heat resistanceheat resistant is water-fast, comprises the following steps:
Step 1): in proportion ball grinder is put in the mixing of graphite, borax, diatom ooze, Zinic stearas, Vaseline, Vanay and polyhexamethylene guanidine, Ball-milling Time is 4 hours, ball milling temperature is room temperature, drum's speed of rotation 600 revs/min, and the particle diameter being milled to raw material is 500 orders;
Step 2): polyphenylene oxide, polyether-ether-ketone, microcrystalline wax, activated Calcium carbonate, polyphenylene oxide, nano titanium oxide, antimonous oxide, vanadium phosphate filler are added water, PH to 4 is regulated with the hydrochloric acid soln that concentration is 15%, heating in water bath is to 70-DEG C, 1500rpm speed lapping 10min, then neutrality is neutralized to the sodium hydroxide solution that concentration is 10%, leave standstill 20min, filter, dry filter residue;
Step 3): mica powder, polyisoprene rubber, Tritolyl Phosphate, ethylene-vinyl acetate copolymer, p isopropylbenzoic acid base benzene diphenyl ester, polyvinyl chloride, tert-butylperoxy isopropyl carbonate, tetramethylthiuram tetrasulfide and auxiliary agent are stirred, mix after together drop into twin screw extruder and carry out melt blending, then extruding pelletization, naturally cool to room temperature, can obtain;
Stirring velocity 400 turns/min in wherein said step 3);
Embodiment 3:
The water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant, be made up of following raw material, mica powder 7 parts, polyphenylene oxide 5 parts, polyether-ether-ketone 4 parts, microcrystalline wax 5 parts, activated Calcium carbonate 5 parts, polyphenylene oxide 3 parts, nano titanium oxide 4 parts, antimonous oxide 3 parts, vanadium phosphate 1 part, polyisoprene rubber 55 parts, Tritolyl Phosphate 2 parts, ethylene-vinyl acetate copolymer 3 parts, p isopropylbenzoic acid base benzene diphenyl ester 12 parts, polyvinyl chloride 6 parts, tert-butylperoxy isopropyl carbonate 4 parts, tetramethylthiuram tetrasulfide 4 parts, auxiliary agent 10 parts;
Wherein, the polymerization degree of described polyvinyl chloride is 900; Consisting of of described auxiliary agent: 3 parts, graphite, borax 3 parts, diatom ooze 30 parts, Zinic stearas 8 parts, 5 parts, Vaseline, Vanay 5 parts, polyhexamethylene guanidine 3 parts;
A preparation method for CABLE MATERIALS that heat resistanceheat resistant is water-fast, comprises the following steps:
Step 1): in proportion ball grinder is put in the mixing of graphite, borax, diatom ooze, Zinic stearas, Vaseline, Vanay and polyhexamethylene guanidine, Ball-milling Time is 5 hours, ball milling temperature is room temperature, drum's speed of rotation 600 revs/min, and the particle diameter being milled to raw material is 500 orders;
Step 2): polyphenylene oxide, polyether-ether-ketone, microcrystalline wax, activated Calcium carbonate, polyphenylene oxide, nano titanium oxide, antimonous oxide, vanadium phosphate filler are added water, PH to 4 is regulated with the hydrochloric acid soln that concentration is 15%, heating in water bath to 70 DEG C, 1500rpm speed lapping 10min, then neutrality is neutralized to the sodium hydroxide solution that concentration is 10%, leave standstill 25min, filter, dry filter residue;
Step 3): mica powder, polyisoprene rubber, Tritolyl Phosphate, ethylene-vinyl acetate copolymer, p isopropylbenzoic acid base benzene diphenyl ester, polyvinyl chloride, tert-butylperoxy isopropyl carbonate, tetramethylthiuram tetrasulfide and auxiliary agent are stirred, mix after together drop into twin screw extruder and carry out melt blending, then extruding pelletization, naturally cool to room temperature, can obtain;
Stirring velocity 450 turns/min in wherein said step 3);
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. the water-fast CABLE MATERIALS of heat resistanceheat resistant, it is characterized in that, be made up of following raw material, mica powder 6-8 part, polyphenylene oxide 4-6 part, polyether-ether-ketone 3-5 part, microcrystalline wax 3-6 part, activated Calcium carbonate 4-6 part, polyphenylene oxide 2-5 part, nano titanium oxide 4-5 part, antimonous oxide 2-5 part, vanadium phosphate 1-2 part, polyisoprene rubber 50-60 part, Tritolyl Phosphate 2-3 part, ethylene-vinyl acetate copolymer 3-4 part, p isopropylbenzoic acid base benzene diphenyl ester 10-15 part, polyvinyl chloride 5-10 part, tert-butylperoxy isopropyl carbonate 3-5 part, tetramethylthiuram tetrasulfide 4-5 part, auxiliary agent 8-12 part.
2. the water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant according to claim 1, is characterized in that, the polymerization degree of described polyvinyl chloride is 800-1000.
3. the water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant according to claim 1, it is characterized in that, consisting of of described auxiliary agent: graphite 2-4 part, borax 2-4 part, diatom ooze 25-35 part, Zinic stearas 6-10 part, Vaseline 5-6 part, Vanay 4-6 part, polyhexamethylene guanidine 3-4 part.
4. the preparation method of the water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant as claimed in claim 1, is characterized in that, comprise the following steps:
Step 1): in proportion ball grinder is put in the mixing of graphite, borax, diatom ooze, Zinic stearas, Vaseline, Vanay and polyhexamethylene guanidine, Ball-milling Time is 4-6 hour, ball milling temperature is room temperature, drum's speed of rotation 600 revs/min, and the particle diameter being milled to raw material is 500 orders;
Step 2): polyphenylene oxide, polyether-ether-ketone, microcrystalline wax, activated Calcium carbonate, polyphenylene oxide, nano titanium oxide, antimonous oxide, vanadium phosphate filler are added water, PH to 4-5 is regulated with the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 70-80 DEG C, 1500-2000rpm speed lapping 10-15min, then neutrality is neutralized to the sodium hydroxide solution that concentration is 10-15%, leave standstill 20-30min, filter, dry filter residue;
Step 3): mica powder, polyisoprene rubber, Tritolyl Phosphate, ethylene-vinyl acetate copolymer, p isopropylbenzoic acid base benzene diphenyl ester, polyvinyl chloride, tert-butylperoxy isopropyl carbonate, tetramethylthiuram tetrasulfide and auxiliary agent are stirred, mix after together drop into twin screw extruder and carry out melt blending, then extruding pelletization, naturally cool to room temperature, can obtain.
5. the preparation method of the water-fast CABLE MATERIALS of a kind of heat resistanceheat resistant according to claim 4, it is characterized in that, the stirring velocity 400-500 in described step 3) turns/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510346127.3A CN105037840A (en) | 2015-06-23 | 2015-06-23 | Heatproof and waterproof cable material and preparation method thereof |
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| CN201510346127.3A CN105037840A (en) | 2015-06-23 | 2015-06-23 | Heatproof and waterproof cable material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105461999A (en) * | 2015-12-11 | 2016-04-06 | 中冠电缆有限公司 | Modified particle for electric wire and cable sheath material of locomotive and preparation method thereof |
| CN107353532A (en) * | 2017-07-06 | 2017-11-17 | 无为华兴高分子材料有限公司 | A kind of plastic products using Tissuemat E |
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| JP2001236833A (en) * | 2000-02-22 | 2001-08-31 | Yazaki Corp | Incombustible cable |
| CN102977610A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Cross-linked low-smoke and zero-halogen flame retardant cable material for locomotive vehicles, and its preparation method |
| CN104371155A (en) * | 2014-10-30 | 2015-02-25 | 安徽电信器材贸易工业有限责任公司 | Heat-resisting anti-ageing cable material and preparation method thereof |
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2015
- 2015-06-23 CN CN201510346127.3A patent/CN105037840A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001236833A (en) * | 2000-02-22 | 2001-08-31 | Yazaki Corp | Incombustible cable |
| CN102977610A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Cross-linked low-smoke and zero-halogen flame retardant cable material for locomotive vehicles, and its preparation method |
| CN104371155A (en) * | 2014-10-30 | 2015-02-25 | 安徽电信器材贸易工业有限责任公司 | Heat-resisting anti-ageing cable material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105461999A (en) * | 2015-12-11 | 2016-04-06 | 中冠电缆有限公司 | Modified particle for electric wire and cable sheath material of locomotive and preparation method thereof |
| CN107353532A (en) * | 2017-07-06 | 2017-11-17 | 无为华兴高分子材料有限公司 | A kind of plastic products using Tissuemat E |
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