CN107349899A - A kind of diatom nanometer ore deposit crystalline substance particle containing anion and preparation method thereof - Google Patents

A kind of diatom nanometer ore deposit crystalline substance particle containing anion and preparation method thereof Download PDF

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CN107349899A
CN107349899A CN201710622970.9A CN201710622970A CN107349899A CN 107349899 A CN107349899 A CN 107349899A CN 201710622970 A CN201710622970 A CN 201710622970A CN 107349899 A CN107349899 A CN 107349899A
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文卓齐
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    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
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    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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Abstract

The invention discloses a kind of diatom nanometer ore deposit crystalline substance particle containing anion and preparation method thereof, the brilliant raw material for purifying particle, including following parts by weight of this nanometer of ore deposit:50 70 parts of sepiolite, 0.1 0.5 parts of negative ion powder, 5 10 parts of attapulgite, 10 20 parts of activated carbon, 5 10 parts of diatomite, 10 15 parts of kaolin, 35 parts of manganese oxide.Mixed after sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are weighed by weight, add the proper amount of sodium carbonate aqueous solution and be granulated into pellet;Dry by primary again, activate and produce.The brilliant purification particle of nanometer ore deposit produced by the present invention not only can be with pernicious gases such as formaldehyde adsorption, benzene, TVOC, and can play a part of decomposing and remove and discharge anion.The present invention is bonded using mineral materials such as sepiolite and attapulgites, it is ensured that the pure natural property of product, preparation process is simple, technical maturity, suitable for industrialized production.

Description

A kind of diatom nanometer ore deposit crystalline substance particle containing anion and preparation method thereof
Technical field
The present invention relates to environment-friendly materials technical field, specifically a kind of diatom nanometer ore deposit crystalline substance particle containing anion and its Preparation method.
Background technology
With the rapid raising of our people's living standard, modern to quality of life and the pursuit more and more higher of health, Result be living space increase, finishing it is more and more luxurious, tight.But due to the hygienic quality mark of China's building and ornament materials Standard, the supervision of product quality and management etc. management are not in place, cause substantial amounts of finishing material inferior to be flooded with building materials market. Investigation shows, indoors in environmental contaminants, four classes such as formaldehyde, ammonia, benzene (being thing) and radioactive substance are generally existings, harm Most serious, it has also become cause the maximum of occupant's health to endanger source.
Natural purification product is based on activated carbon, bamboo charcoal in the market, but this two classes product only has simple thing Manage adsorption function, can not play a part of removing formaldehyde, the harmful substance such as benzene, be adsorbed onto it is a certain amount of in the case of suction occurs Attached individual saturation, or even under given conditions it is also possible to discharging again.Although also there is photocatalyst activity charcoal in the market, system It is easily saturated during standby complex process use.
The content of the invention
It is stronger it is an object of the invention to provide a kind of adsorption capacity at the same can play decompose remove formaldehyde containing negative Brilliant purification particle of the nanometer ore deposit of ion powder and preparation method thereof, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of brilliant purification particle of the nanometer ore deposit containing negative ion powder, include the raw material of following parts by weight:Sepiolite 50-70 Part, negative ion powder 0.1-0.5 parts, attapulgite 5-10 parts, activated carbon 10-20 parts, diatomite 5-10 parts, kaolin 10-15 parts, Manganese oxide 3-5 parts.
As the further scheme of the present invention:The brilliant purification particle of nanometer ore deposit containing negative ion powder, including it is following heavy Measure the raw material of part:Sepiolite 55-65 parts, negative ion powder 0.2-0.4 parts, attapulgite 6.5-8.5 parts, activated carbon 12.5-17.5 Part, diatomite 6.5-8.5 parts, kaolin 11-14 parts, manganese oxide 3-5 parts.
As further scheme of the invention:The brilliant purification particle of nanometer ore deposit containing negative ion powder, including it is following The raw material of parts by weight:60 parts of sepiolite, 0.3 part of negative ion powder, 7.5 parts of attapulgite, 15 parts of activated carbon, 7.5 parts of diatomite, height Ridge soil 12.5 parts, 4 parts of manganese oxide.
As further scheme of the invention:The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, The grain graininess of kaolin and manganese oxide is respectively less than 200 mesh.
As further scheme of the invention:The sepiolite active principle content > 90%.
Another object of the present invention is to provide a kind of preparation method of the brilliant purification particle of nanometer ore deposit containing negative ion powder, including Following steps:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed respectively and are less than The sieve of 200 mesh, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into low temperature drying stove and carries out primary dry 1-2 hours, drying temperature is 170-270 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 580-750 DEG C of activation temperature, constant temperature produces a nanometer ore deposit in 1 hour Crystalline substance purification particle.
As further scheme of the invention:In step (4), drying temperature is 200-240 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention is using sepiolite as main raw material(s) and adds the brilliant purification particle of nanometer ore deposit of negative ion powder, is made by enrichment The fine pore size that hole technology is formed is advantageously in the attachment and suction of the deleterious moleculars such as formaldehyde, benzene, at the same time, the present invention The brilliant purification particle of nanometer ore deposit be polar substances, compared to nonpolar activated carbon, PARA FORMALDEHYDE PRILLS(91,95) isopolarity molecule has stronger suction Attached effect.
In addition, making activity and the thermal conductivity increase of product after addition negative ion powder, the time of particle drying greatly shortens, saved About cost, addition negative ion powder makes nanometer ore deposit is brilliant to have more stable molecular structure, by days such as sepiolite, diatomite, kaolin Right raw material is organically combined with manganese oxide, not only can be with pernicious gases such as formaldehyde adsorption, benzene, TVOC, and can play decomposition Remove and discharge the effect of anion.The present invention is bonded using mineral materials such as sepiolite and attapulgites, it is ensured that The pure natural property of product, preparation method step is simple, technical maturity, suitable for industrialized production.
Brief description of the drawings
Fig. 1 is the flow chart of the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of brilliant original for purifying particle, including following parts by weight of the nanometer ore deposit containing negative ion powder Material:50 parts of sepiolite, 0.1 part of negative ion powder, 5 parts of attapulgite, 10 parts of activated carbon, 5 parts of diatomite, 10 parts of kaolin, oxidation 3 parts of manganese.
The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are equal For 250 mesh.The sepiolite active principle content > 90%.
Referring to Fig. 1, the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder, including following step Suddenly:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed into 250 mesh respectively Sieve, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into progress primary in low temperature drying stove to dry 1 hour, drying temperature is 170 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 580 DEG C of activation temperature, constant temperature produces for 1 hour.
Embodiment 2
In the embodiment of the present invention, a kind of brilliant original for purifying particle, including following parts by weight of the nanometer ore deposit containing negative ion powder Material:55 parts of sepiolite, 0.2 part of negative ion powder, 6.5 parts of attapulgite, 12.5 parts of activated carbon, 6.5 parts of diatomite, kaolin 11 Part, 3 parts of manganese oxide.
The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are equal For 300 mesh.The sepiolite active principle content > 90%.
Referring to Fig. 1, the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder, including following step Suddenly:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed into 300 mesh respectively Sieve, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into progress primary in low temperature drying stove to dry 1 hour, drying temperature is 200 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 630 DEG C of activation temperature, constant temperature produces for 1 hour.
Embodiment 3
In the embodiment of the present invention, a kind of brilliant original for purifying particle, including following parts by weight of the nanometer ore deposit containing negative ion powder Material:60 parts of sepiolite, 0.3 part of negative ion powder, 7.5 parts of attapulgite, 15 parts of activated carbon, 7.5 parts of diatomite, kaolin 12.5 Part, 4 parts of manganese oxide.
The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are equal For 350 mesh.The sepiolite active principle content > 90%.
Referring to Fig. 1, the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder, including following step Suddenly:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed into 350 mesh respectively Sieve, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into progress primary in low temperature drying stove to dry 1.5 hours, drying temperature is 220 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 690 DEG C of activation temperature, constant temperature produces for 1 hour.
Embodiment 4
In the embodiment of the present invention, a kind of brilliant original for purifying particle, including following parts by weight of the nanometer ore deposit containing negative ion powder Material:65 parts of sepiolite, 0.4 part of negative ion powder, 8.5 parts of attapulgite, 17.5 parts of activated carbon, 8.5 parts of diatomite, kaolin 14 Part, 5 parts of manganese oxide.
The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are equal For 400 mesh.The sepiolite active principle content > 90%.
Referring to Fig. 1, the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder, including following step Suddenly:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed into 400 mesh respectively Sieve, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into progress primary in low temperature drying stove to dry 1.5 hours, drying temperature is 240 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 730 DEG C of activation temperature, constant temperature produces for 1 hour.
Embodiment 5
In the embodiment of the present invention, a kind of brilliant original for purifying particle, including following parts by weight of the nanometer ore deposit containing negative ion powder Material:70 parts of sepiolite, 0.5 part of negative ion powder, 10 parts of attapulgite, 20 parts of activated carbon, 10 parts of diatomite, 15 parts of kaolin, oxygen Change 5 parts of manganese.
The sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are equal For 450 mesh.The sepiolite active principle content > 90%.
Referring to Fig. 1, the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder, including following step Suddenly:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed into 450 mesh respectively Sieve, it is standby;
(2) sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are pressed Parts by weight mix after weighing, and stir, and obtain mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into progress primary in low temperature drying stove to dry 2 hours, drying temperature is 260 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 780 DEG C of activation temperature, constant temperature produces for 1 hour.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (7)

1. a kind of brilliant purification particle of the nanometer ore deposit containing negative ion powder, it is characterised in that include the raw material of following parts by weight:Hai Pao Stone 50-70 parts, negative ion powder 0.1-0.5 parts, attapulgite 5-10 parts, activated carbon 10-20 parts, diatomite 5-10 parts, kaolin 10-15 parts, manganese oxide 3-5 parts.
2. the brilliant purification particle of the nanometer ore deposit containing negative ion powder according to claim 1, it is characterised in that including following heavy Measure the raw material of part:Sepiolite 55-65 parts, negative ion powder 0.2-0.4 parts, attapulgite 6.5-8.5 parts, activated carbon 12.5-17.5 Part, diatomite 6.5-8.5 parts, kaolin 11-14 parts, manganese oxide 3-5 parts.
3. the brilliant purification particle of the nanometer ore deposit containing negative ion powder according to claim 1, it is characterised in that including following heavy Measure the raw material of part:60 parts of sepiolite, 0.3 part of negative ion powder, 7.5 parts of attapulgite, 15 parts of activated carbon, 7.5 parts of diatomite, kaolinite Native 12.5 parts, 4 parts of manganese oxide.
4. according to any brilliant purification particles of the described nanometer ore deposit containing negative ion powder of claim 1-3, it is characterised in that described Sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, the grain graininess of kaolin and manganese oxide are respectively less than 200 mesh.
5. according to any brilliant purification particles of the described nanometer ore deposit containing negative ion powder of claim 1-3, it is characterised in that described Sepiolite active principle content > 90%.
6. a kind of preparation method of the brilliant purification particle of nanometer ore deposit containing negative ion powder as described in claim 1-5 is any, its It is characterised by, comprises the following steps:
(1) sepiolite, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide are crossed respectively and is less than 200 mesh Sieve, it is standby;
(2) by the sepiolite after sieving, negative ion powder, attapulgite, activated carbon, diatomite, kaolin and manganese oxide by weight Part mixes after weighing, and stirs, obtains mixed powder;
(3) the proper amount of sodium carbonate aqueous solution is added in the mixed powder to stir, then carry out being granulated into pellet;
(4) pellet is put into low temperature drying stove and carries out primary dry 1-2 hours, drying temperature is 170-270 DEG C;
(5) pellet is put into high-temperature activation stove again and activated, 580-750 DEG C of activation temperature, it is brilliant net that constant temperature produces nanometer ore deposit for 1 hour Change particle.
7. the preparation method of the brilliant purification particle of the nanometer ore deposit containing negative ion powder according to claim 6, it is characterised in that In step (4), drying temperature is 200-240 DEG C.
CN201710622970.9A 2017-07-27 2017-07-27 A kind of diatom nanometer ore deposit crystalline substance particle containing anion and preparation method thereof Pending CN107349899A (en)

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CN107961674A (en) * 2017-12-26 2018-04-27 郑州紫加黑环保科技有限公司 Polluted gas purification particle and preparation method thereof
CN107986530A (en) * 2017-12-14 2018-05-04 厦门市浩铂科技股份有限公司 A kind of composite Nano ore deposit crystalline substance energy filter core and preparation method thereof
CN108126513A (en) * 2017-11-30 2018-06-08 安徽宏远职业卫生技术服务有限公司 It is a kind of to be used to absorb absorbent of pernicious gas and preparation method thereof in air
CN109092053A (en) * 2018-08-27 2018-12-28 青岛宜家阳光环保技术有限公司 A kind of NEW TYPE OF COMPOSITE air purifying particles and preparation method thereof containing cold catalyst
CN109550385A (en) * 2018-11-30 2019-04-02 广东美沃布朗科技有限公司 A kind of new function filtrate and preparation method thereof of oxygenation and releasable negative oxygen ion
CN111841489A (en) * 2020-07-31 2020-10-30 上海斯米克健康环境技术有限公司 Light high-strength anion purification ball and manufacturing method thereof
CN114345309A (en) * 2022-01-24 2022-04-15 西南石油大学 Benzene and benzene series adsorbent and preparation method thereof
CN115073065A (en) * 2022-06-23 2022-09-20 中国冶金地质总局矿产资源研究院 Formaldehyde purification material based on natural mineral composition and preparation method thereof
CN115212840A (en) * 2022-06-23 2022-10-21 中国冶金地质总局矿产资源研究院 Method for preparing formaldehyde purification material by comprehensively utilizing refractory smelting associated iron-manganese ore

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CN111841489A (en) * 2020-07-31 2020-10-30 上海斯米克健康环境技术有限公司 Light high-strength anion purification ball and manufacturing method thereof
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