CN107349550A - Fire-extinguishing particulate modifying agent - Google Patents
Fire-extinguishing particulate modifying agent Download PDFInfo
- Publication number
- CN107349550A CN107349550A CN201610933313.1A CN201610933313A CN107349550A CN 107349550 A CN107349550 A CN 107349550A CN 201610933313 A CN201610933313 A CN 201610933313A CN 107349550 A CN107349550 A CN 107349550A
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- CN
- China
- Prior art keywords
- fire
- modifying agent
- extinguishing
- extinguishing particulate
- cosolvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0014—Powders; Granules
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/005—Dispersions; Emulsions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Dispersion Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The present invention relates to a kind of fire-extinguishing particulate modifying agent, mainly solves the problems, such as that fire foam can not cover comprehensively in the short time in the prior art or foam is constantly exhausted by oil tank fire burning.Fire-extinguishing particulate is carried out hydrophobic oleophobic surface modification treatment, modifying agent is to contain alkyl or amide groups or sulfoamido cation fluorine carbon surface active agent by the present invention by using a kind of fire-extinguishing particulate modifying agent;Cosolvent is at least one of alcohols, ethers;Activator is sodium hydroxide or potassium hydroxide solution;The weight/mass percentage composition of cation fluorine carbon surface active agent is 5% 25%;Cosolvent weight/mass percentage composition is 15% 25%;Activator weight/mass percentage composition preferably solves above mentioned problem for 10% 30% technical scheme, available in oil tank class fire of putting out a fire to save life and property.
Description
Technical field
The present invention relates to a kind of fire-extinguishing particulate modifying agent.
Background technology
Tank fire is put out mainly using serial fire foam at present, has been played in storage tank fire extinguishing procedure huge
Effect, but fire foam ability of anti-burning is poor, anti-resume combustion ability is relatively low.For large oil tank fire, fire it is lasting when
Between may be up to a few hours even several days;Multi-injection foam is needed, if foam supply capacity is insufficient, it is impossible to which formation is effectively covered
Lid, the then foam that early stage sprays can constantly rupture, and make the intensity of a fire out of hand, again resume combustion.Therefore, for oil tank class fire, need
New extinguishing chemical is continually developed, existing defect is overcome, meets extinguishment requirement.
Most of inorganic light weight particles are a kind of cellular, porous and surface open-celled structure, high silicon content (general >
70%) mineral matter, has that nontoxic, tasteless, nonflammable, unit weight is small, thermal conductivity factor is small, chemical stability is good, sound insulation, source are wide
The features such as general, often it is widely used in as insulation material on building.But light granules have very strong adsorptivity, easily
Moisture around absorbing, and it is relatively low with the cohesive force of organic matter, and its intensity is relatively low, and it is broken in work progress.
In order to reduce the adsorption rate of light granules, increase its intensity, CN105645803A has invented a kind of aeroge expansion
The preparation method of perlite, using waterglass as presoma, using expanded perlite as carrier, utilize sol-gel process and vacuum pressure
Power impregnate full-cell process, by vacuum drying process by hydrophobic type aeroge fill or outsourcing be wrapped in expanded perlite it is compound and
Into particle diameter is more than 0.05mm.The expanded perlite of the patent simply wraps up hydrophobic group to its appearance, and the production technology of use is only
Its intensity is the increase in, and is unable to oleophobic, it is difficult to for putting out oil tank class fire.
CN103550898A is related to a kind of modified expanded glass bead extinguishing chemical, including 65~94.5 parts of expansion vitrification is micro-
Pearl, 0.5~5 part of macromolecule wax, amino resins, organo-silicon coupling agent, organic silicon surfactant, fluorine-containing surfactant
In a kind of or their mixture, 5~30 parts of anion surfactant, cationic surfactant, nonionic table
A kind of or their mixture in the activating agent of face.The extinguishing chemical sprawls rapid, suspending stabilized, accumulation covering on pasta,
With fire resistanttime it is long the advantages of.Classes of compounds is simply added in expanded and vitrified small ball by the patent respectively or all, shape
Into a kind of extinguishing chemical, if being added thereto one kind, single hydrophobic or oleophobic can only be also played, it is impossible to hydrophobic oleophobic is fully achieved
Property;If all adding, each compound can not dissolve each other completely, can produce layering and separate out, and to going out, oil tank fire is unfavorable, and cost is high.
CN201110172399 is related to a kind of oil product extinguishment hollow glass micropearl three-phase froth and preparation method thereof, and this three
The component of phase foam is matched by following percentage by weight:8-15% general proteins fire foam and 3-10% hollow glass
Microballon, surplus are water.Hollow glass micropearl used is hated oil processing through fluorine containing silane coupling agent and obtained.The three-phase bubble of the invention
Foam in pasta by that can form form compact and stable solid overlayer during flame thermal radiation, its anti-burning and anti-resume combustion performance are better than common
Protein foam extinguishing agent, and stability significantly improves.The three-phase froth that the patent is related to, can partly it defoam in actual applications,
Hollow glass micropearl addition is bigger, and brokenly bubble rate is higher, influences extinguishing effect.
The content of the invention
The technical problems to be solved by the invention be in the prior art fire foam can not be covered comprehensively in the short time or
The problem of foam is constantly exhausted by oil tank fire burning, there is provided a kind of new fire-extinguishing particulate modifying agent, fire-extinguishing particulate modifying agent tool
Have and prevent oil gas volatilization, prevent fire spreading, the advantages of oil reservoir and water layer surface can be floated over for a long time.
To solve the above problems, the technical solution adopted by the present invention is as follows:A kind of fire-extinguishing particulate modifying agent, by fire-extinguishing particulate
Hydrophobic oleophobic surface modification treatment is carried out, modifying agent is to contain alkyl or amide groups or sulfoamido cation fluorine carbon surface active
Agent;Cosolvent is at least one of alcohols, ethers;Activator is sodium hydroxide or potassium hydroxide solution;Cation fluorine carbon table
The weight/mass percentage composition of face activating agent is 5%-25%;Cosolvent weight/mass percentage composition is 15%-25%;Activator quality percentage
Content is 10%-30%.
In above-mentioned technical proposal, it is preferable that cation fluorine carbon surface active agent is fluorine-containing alkylamine quaternary amines salt, perfluoroalkyl
One kind in amidoquat salt, perfluorinated octyl sulfuryl amine quaternary ammonium salt, fluorine-containing alkyl sulfonic acid ester quat, fluoroalkyl amine salt.
In above-mentioned technical proposal, it is preferable that alcohols is isopropanol or ethanol, and ethers is ethylene glycol monobutyl ether or diethylene glycol
Butyl ether.
In above-mentioned technical proposal, it is preferable that the mass ratio of modifying agent and inorganic solid particles material is 3~1:1.
The invention provides it is a kind of can swim in for a long time on fuel level, the light inorganic for the modification that complete oleophobic is hydrophobic
Matter fire-extinguishing particulate.Because fluorocarbon surfactant has lipophobic hydrophobic in itself so that modified lightweight fire-extinguishing particulate is same
With lipophobic hydrophobic.Therefore, when during the fire-extinguishing particulate being in oily or in water, the surface of " clean " can be formed.When fire extinguishing is fought
During bucket, the fire-extinguishing particulate of injection it is shallow fall on pasta without being infected with oil and water, form one layer of solid overlayer, prevent oil gas
Volatilization, controls burning away for flame, serves the effect of fire extinguishing, solving fire foam can not cover comprehensively in the short time
The problem that lid or foam are constantly exhausted by oil tank fire burning.The fire-extinguishing particulate raw material is easy to get, and it is convenient to prepare, simple to operate, is easy to
Cleaning, achieves preferable technique effect.
Below by embodiment, the invention will be further elaborated, but is not limited only to the present embodiment.
Embodiment
Embodiment 1:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Expanded perlite 50%
Modifying agent fluoroalkyl amine quaternary ammonium salt 5%
Cosolvent isopropanol 15%
Activator sodium hydroxide solution 30%
(2) preparation method:
30% sodium hydroxide solution is added in jacketed reactor, temperature control is at 65 DEG C, then under stirring
50% expanded perlite is added, stirring 45min is activated;Material after activation is all imported in centrifuge and filters 10min,
Material in centrifuge is washed with deionized to pH<9;Filter residue is poured into another solid-liquid mixing kettle, added under agitation
5% fluoroalkyl amine quaternary ammonium salt and 15% isopropanol, 60min is stirred, in the process, bottom material is released, passes through charge door
Add in solid-liquid mixing kettle, it is so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then the water for adding 50% enters to material
Row cleaning dries, and finally imports in microwave oven (electric heating, steam heating, drying also can) material of drying, is dried at 105 DEG C
It is dry, obtain a kind of fire-extinguishing particulate.
Embodiment 2:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Expanded vermiculite 50%
Modifying agent perfluoroalkyl amidoquat salt 25%
Cosolvent ethanol 15%
Activator potassium hydroxide solution 10%
(2) preparation method:
10% potassium hydroxide solution is added in jacketed reactor, temperature control is at 55 DEG C, then under stirring
50% expanded vermiculite is added, stirring 50min is activated;Material after activation is all imported in centrifuge and filters 10min, is used
Material in deionized water washing centrifuge is to pH<9;Filter residue is poured into another solid-liquid mixing kettle, added under agitation
25% perfluoroalkyl amidoquat salt and 15% ethanol, 60min is stirred, in the process, bottom material is released, passes through charging
Mouth is added in solid-liquid mixing kettle, so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then the water of addition 50% is to material
Cleaning drying is carried out, finally the material of drying is imported in microwave oven (electric heating, steam heating, drying also can) and dried, obtains one
The kind fire-extinguishing particulate.
Embodiment 3:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Hollow glass microbead 50%
Modifying agent perfluorinated octyl sulfuryl amine quaternary ammonium salt 15%
Cosolvent isopropanol 15%
Activator sodium hydroxide solution 20%
(2) preparation method:
20% sodium hydroxide solution is added in jacketed reactor, temperature control is at 75 DEG C, then under stirring
50% hollow glass microbead is added, stirring 60min is activated;Material after activation is all imported in centrifuge and filtered
15min, material in centrifuge is washed with deionized to pH<9;Filter residue is poured into another solid-liquid mixing kettle, stirred
15% perfluorinated octyl sulfuryl amine quaternary ammonium salt of lower addition and 15% isopropanol, 60min is stirred, in the process, bottom material is put
Go out, added to by charge door in solid-liquid mixing kettle, it is so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then add
50% water carries out cleaning drying to material, and the material of drying finally is imported into microwave oven, and (electric heating, steam heating, drying are also
Can) in dry, obtain a kind of fire-extinguishing particulate.
Embodiment 4:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Floating bead 50%
The fluorine-containing alkyl sulfonic acid ester quat 15% of modifying agent
Cosolvent ethanol 15%
Activator potassium hydroxide solution 20%
(2) preparation method:
20% potassium hydroxide solution is added in jacketed reactor, temperature control is at 60 DEG C, then under stirring
50% floating bead is added, stirring 45min is activated;Material after activation is all imported in centrifuges and filters 15min, spend from
Material in sub- water washing centrifuge is to pH<9;Filter residue is poured into another solid-liquid mixing kettle, 15% is added under agitation and contains
Fluoroalkyl sulfonic acids ester quat and 15% ethanol, stir 45min, in the process, bottom material released, by charge door plus
It is so repeatedly 3~5 times, irregular to prevent bottom material stirring into solid-liquid mixing kettle.Then the water of addition 50% is carried out to material
Cleaning dries, and finally imports in microwave oven (electric heating, steam heating, drying also can) material of drying and dries, obtains a kind of institute
State fire-extinguishing particulate.
Embodiment 5:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Hollow glass microbead 25%
Modifying agent perfluorinated octyl sulfuryl amine quaternary ammonium salt 20%
Cosolvent isopropanol 25%
Activator sodium hydroxide solution 30%
(2) preparation method:
30% sodium hydroxide solution is added in jacketed reactor, temperature control is at 55 DEG C, then under stirring
25% hollow glass microbead is added, stirring 50min is activated;Material after activation is all imported in centrifuge and filtered
15min, material in centrifuge is washed with deionized to pH<9;Filter residue is poured into another solid-liquid mixing kettle, stirred
20% perfluorinated octyl sulfuryl amine quaternary ammonium salt of lower addition and 25% isopropanol, 50min is stirred, in the process, bottom material is put
Go out, added to by charge door in solid-liquid mixing kettle, it is so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then add
50% water carries out cleaning drying to material, and the material of drying finally is imported into microwave oven, and (electric heating, steam heating, drying are also
Can) in dry, obtain a kind of fire-extinguishing particulate.
Embodiment 6:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Expanded perlite 25%
Modifying agent fluoroalkyl amine quaternary ammonium salt 25%
Cosolvent isopropanol 20%
Activator sodium hydroxide solution 30%
(2) preparation method:
30% sodium hydroxide solution is added in jacketed reactor, temperature control is at 65 DEG C, then under stirring
25% expanded perlite is added, stirring 45min is activated;Material after activation is all imported in centrifuge and filters 10min,
Material in centrifuge is washed with deionized to pH<9;Filter residue is poured into another solid-liquid mixing kettle, added under agitation
25% fluoroalkyl amine quaternary ammonium salt and 20% isopropanol, 60min is stirred, in the process, bottom material is released, passes through charge door
Add in solid-liquid mixing kettle, it is so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then the water for adding 50% enters to material
Row cleaning dries, and finally imports in microwave oven (electric heating, steam heating, drying also can) material of drying, is dried at 105 DEG C
It is dry, obtain a kind of fire-extinguishing particulate.
Embodiment 7:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Expanded vermiculite 35%
Modifying agent perfluoroalkyl amidoquat salt 20%
Cosolvent ethanol 15%
Activator potassium hydroxide solution 30%
(2) preparation method:
30% potassium hydroxide solution is added in jacketed reactor, temperature control is at 65 DEG C, then under stirring
35% expanded vermiculite is added, stirring 45min is activated;Material after activation is all imported in centrifuge and filters 15min, is used
Material in deionized water washing centrifuge is to pH<9;Filter residue is poured into another solid-liquid mixing kettle, added under agitation
20% perfluoroalkyl amidoquat salt and 15% ethanol, 45min is stirred, in the process, bottom material is released, passes through charging
Mouth is added in solid-liquid mixing kettle, so repeatedly 3~5 times, irregular to prevent bottom material stirring.Then the water of addition 50% is to material
Cleaning drying is carried out, finally the material of drying is imported in microwave oven (electric heating, steam heating, drying also can) and dried, obtains one
The kind fire-extinguishing particulate.
Embodiment 8:
(1) percent mass ratio of raw material needed for fire-extinguishing particulate:
Floating bead 35%
The fluorine-containing alkyl sulfonic acid ester quat 15% of modifying agent
Cosolvent ethanol 25%
Activator potassium hydroxide solution 25%
(2) preparation method:
25% potassium hydroxide solution is added in jacketed reactor, temperature control is at 60 DEG C, then under stirring
35% floating bead is added, stirring 45min is activated;Material after activation is all imported in centrifuges and filters 15min, spend from
Material in sub- water washing centrifuge is to pH<9;Filter residue is poured into another solid-liquid mixing kettle, 15% is added under agitation and contains
Fluoroalkyl sulfonic acids ester quat and 25% ethanol, stir 45min, in the process, bottom material released, by charge door plus
It is so repeatedly 3~5 times, irregular to prevent bottom material stirring into solid-liquid mixing kettle.Then the water of addition 50% is carried out to material
Cleaning dries, and finally imports in microwave oven (electric heating, steam heating, drying also can) material of drying and dries, obtains a kind of institute
State fire-extinguishing particulate.
Claims (4)
1. a kind of fire-extinguishing particulate modifying agent, fire-extinguishing particulate is subjected to hydrophobic oleophobic surface modification treatment, modifying agent is to contain alkyl
Or amide groups or sulfoamido cation fluorine carbon surface active agent;Cosolvent is at least one of alcohols, ethers;Activator is
Sodium hydroxide or potassium hydroxide solution;The weight/mass percentage composition of cation fluorine carbon surface active agent is 5%-25%;Cosolvent matter
Amount percentage composition is 15%-25%;Activator weight/mass percentage composition is 10%-30%.
2. fire-extinguishing particulate modifying agent according to claim 1, it is characterised in that described cation fluorine carbon surface active agent is
Fluorine-containing alkylamine quaternary amines salt, perfluoroalkyl amidoquat salt, perfluorinated octyl sulfuryl amine quaternary ammonium salt, fluorine-containing alkyl sulfonic ester quaternary ammonium
One kind in salt, fluoroalkyl amine salt.
3. fire-extinguishing particulate modifying agent according to claim 1, it is characterised in that cosolvent is alcohols, including isopropanol or second
Alcohol, ethers are ethylene glycol monobutyl ether or butyl.
4. fire-extinguishing particulate modifying agent according to claim 1, it is characterised in that the mass ratio of modifying agent and solid inorganic material
For 3~1:1.
Priority Applications (1)
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CN201610933313.1A CN107349550A (en) | 2016-10-25 | 2016-10-25 | Fire-extinguishing particulate modifying agent |
Applications Claiming Priority (1)
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CN201610933313.1A CN107349550A (en) | 2016-10-25 | 2016-10-25 | Fire-extinguishing particulate modifying agent |
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CN107349550A true CN107349550A (en) | 2017-11-17 |
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CN201610933313.1A Pending CN107349550A (en) | 2016-10-25 | 2016-10-25 | Fire-extinguishing particulate modifying agent |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108671447A (en) * | 2018-05-15 | 2018-10-19 | 朱琳 | A kind of mixed type extinguishing fluid for fire fighting truck |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103550898A (en) * | 2013-10-17 | 2014-02-05 | 中国人民武装警察部队学院 | Modified expanded and vitrified microbead fire extinguishing agent and preparation method thereof |
CN105344056A (en) * | 2015-11-04 | 2016-02-24 | 中国人民武装警察部队学院 | Novel aqueous film forming anti-burning type foam extinguishing agent and preparing method thereof |
-
2016
- 2016-10-25 CN CN201610933313.1A patent/CN107349550A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103550898A (en) * | 2013-10-17 | 2014-02-05 | 中国人民武装警察部队学院 | Modified expanded and vitrified microbead fire extinguishing agent and preparation method thereof |
CN105344056A (en) * | 2015-11-04 | 2016-02-24 | 中国人民武装警察部队学院 | Novel aqueous film forming anti-burning type foam extinguishing agent and preparing method thereof |
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刘程等: "《表面活性剂应用手册》", 31 August 1995, 化学工业出版社 * |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108671447A (en) * | 2018-05-15 | 2018-10-19 | 朱琳 | A kind of mixed type extinguishing fluid for fire fighting truck |
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