CN107345283A - A kind of diamond particles enhancing aluminium base braking wearing composite material and preparation method - Google Patents

A kind of diamond particles enhancing aluminium base braking wearing composite material and preparation method Download PDF

Info

Publication number
CN107345283A
CN107345283A CN201710042309.0A CN201710042309A CN107345283A CN 107345283 A CN107345283 A CN 107345283A CN 201710042309 A CN201710042309 A CN 201710042309A CN 107345283 A CN107345283 A CN 107345283A
Authority
CN
China
Prior art keywords
diamond particles
preparation
alloy
wear parts
composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710042309.0A
Other languages
Chinese (zh)
Other versions
CN107345283B (en
Inventor
张洋
陈蕴博
刘玉里
刘晓萍
左玲立
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Longji Machinery Co ltd
Beijing National Innovation Institute of Lightweight Ltd
Original Assignee
SHANDONG LONGJI MACHINERY CO Ltd
Advanced Manufacture Technology Center China Academy of Machinery Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG LONGJI MACHINERY CO Ltd, Advanced Manufacture Technology Center China Academy of Machinery Science and Technology filed Critical SHANDONG LONGJI MACHINERY CO Ltd
Priority to CN201710042309.0A priority Critical patent/CN107345283B/en
Publication of CN107345283A publication Critical patent/CN107345283A/en
Application granted granted Critical
Publication of CN107345283B publication Critical patent/CN107345283B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D23/00Casting processes not provided for in groups B22D1/00 - B22D21/00
    • B22D23/04Casting by dipping
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1005Pretreatment of the non-metallic additives
    • C22C1/101Pretreatment of the non-metallic additives by coating
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • C22C1/1073Infiltration or casting under mechanical pressure, e.g. squeeze casting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium

Abstract

The present invention is a kind of diamond particles enhancing aluminium base braking high-abrasive material and preparation method, belongs to high-abrasive material field.It is characterized in that 5 15 μm of diamond particles that surface is modified are placed in shaping dies after being mixed with Al Cu alloy powders, after vacuumizing, utilize gases at high pressure, under 750 950 DEG C and 0.1 2.0 MPa of forming temperature and pressure condition, fast driving Al Si alloy melts infiltration shapes, after the min of heat-insulation pressure keeping 5 30, acquisition enhancing phase volume fraction is 5 25% composites with applied to braking wear parts;By this method, composite two-phase interface and tissue topography can realize accuracy controlling and significantly optimization, and ensure strengthens phase diamond particles excellent properties under actual damped condition can stablize and fully play.The present invention prepares composite, compared to brake component tradition ferrous materials, while friction and wear characteristic optimizes, density is substantially reduced, thermal conductivity is realized and significantly lifted, so as to meet that transportation equipment develops the brand-new requirement brought to brake material and part to more high speed, light weight, safety, comfortable direction.

Description

A kind of diamond particles enhancing aluminium base braking wearing composite material and preparation method
Technical field
The invention belongs to high-abrasive material field, in particular, provides a kind of braking wear parts diamond particles enhancing aluminium Based composites and preparation method thereof.
Background technology
It is a key areas for belonging to high-abrasive material to brake high-abrasive material, and current main application concentrates on manufacture traffic The brake component of transportation equipment(Such as brake disc, brake drum), they are to ensure that equipment is steadily reliably braked by high-speed motion state Critical function part, therefore high-performance braking high-abrasive material and concerned brake part turn into hoisting device security, comfortableness, The key technology of high-performance.
Traditional braking part is mainly the ferrous materials such as cast iron, cast steel or forged steel with material, and with High Speed Railway Trains Transportation equipment for representative is continuous and promptly develops to high speed, lightweight and energy-saving direction, to braking wear-resisting material Material proposes harsher requirement, and in addition to more excellent friction and wear characteristic, the lifting to two aspect performance requirements is the most Highlight:It is to improve heat conductivility first, so as to quickly distribute caused heat transfer in braking procedure, to ensure to brake System is operated in preferable temperature range, avoids brake fade;Secondly density is reduced, to serve the overall loss of weight of equipment, is reduced Specific energy consumption.And traditional steel brake material thermal conductivity is low(~45 W/mK), density is big(~7.8 g/cm3), it has been difficult to meet The growth requirement of equipment upgrading innovation.
Metallic aluminium density is low(~2.7 g/cm3), thermal conductivity height(~230 W/mK), as matrix, with appropriate enhancing Composite is mutually prepared as, the friction and wear characteristic of Single Phase Metal while above-mentioned advantage is kept, can be significantly improved, therefore Aluminum matrix composite turns into the important candidate materials of Novel brake part.Currently, the enhancing phase of wear-resisting aluminum matrix composite is braked Mainly with carbide(Such as SiC), oxide(Such as Al2O3), boride(TiB2)Based on particle(The effect of wear parameters and heat treatment on two body abrasive wear of Al–SiC–Gr hybrid composites, Tribology International, 2016, 96: 184-190; Abrasive wear behaviour of SiCp/Al alloy composite in comparison with ausferritic ductile iron, Wear, 2011, 271(11-12): 2766-2774;A kind of brake disc is closed with additional SiC particles reinforced sial The preparation method of auri composite, 201310008715.7;The brake disc aluminum-base composite of carborundum-zirconia particles enhancing The preparation method of material, 201310008726.5), but because the assertive evidence thermal conductivity of above-mentioned ceramic particle is relatively low, so as to limit The lifting upper limit of composite heat dispersion, it is even more important that the enhancing ceramic phase particle being widely used at present generally is presented For irregular polygon geometric shape, after being prepared into composite, there can be larger stress concentration in a large amount of wedge angle interface locations, So that enhancing phase particle is more easy to occur broken and peeled off, cause the anti-wear performance of integral material to reduce, while coefficient of friction fluctuates Amplitude is big;Although the more excellent enhancing phase particle of geometric shape can be obtained using composite shaped in situ technology (Mechanical properties and tribological behavior of aluminum matrix composites reinforced with in-situ AlB2 particles, Tribology International, 2016, 98: 41-47; The effect of reinforcement ratio on the wear behaviour of AlB2 flake reinforced metal matrix composites, ActaPhysicaPolonica A, 2014, 125(2): 590-592;The method that original position prepares TiB2 reinforced aluminum matrix composites, 201210289172.6), but due to original The limitation of position enhancing phase size and volume fraction, the braking anti-wear performance of composite are unsatisfactory.
Diamond has excellent combination property, and thermal conductivity can reach 1800 W/mK, and microhardness is higher than 50 GPa, The g/cm of density 3.523, after being prepared as composite, on the basis of low-density and optimization friction and wear behavior is kept, Ke Yijin One step improves heat conductivility, in addition, single crystal grain has well-regulated tetrakaidecahedron form, coordinates rational Interface Control, can be with Significantly optimization two-phase interface tissue and stress state, so as to improve using process in which materials composite construction stability, therefore are new Generation aluminium base brakes the preferable reinforcement of wearing composite material.On the other hand, as diamond particles production technology is constantly ripe The price reduction brought, and raw material market advantage of the China as diamond particles producing country the biggest in the world so that Buddha's warrior attendant The extensive use of stone particle is possibly realized and therefore obtains increasing concern.
But at present, using diamond particles reinforced aluminum matrix composites as braking the related work of high-abrasive material and part still It is rarely reported, is applying for a patent " a kind of method for preparing brake rim aluminum matrix composite, 201410305219.2 " middle selections Various reinforced phase, including alumina fibre, flake graphite and a small amount of diamond particle.Although relate to the use of diamond as increasing Qiang Xiang, but do not clearly state and illustrate its central role and the feature realized;What is more important, for diamond The problem as a key problem of Reinforcements for Metal Matrix Composites, i.e. the two-phase interface optimization of diamond and aluminum substrate, Solution is not provided with, and due to the diamond particle surfaces chemical characteristic that special crystal structure determines, it is formed with aluminium During composite, it is difficult to obtain preferable two and be combined and interface topography, this can result in uses in composite, especially It is in the braking procedure dominated with tangential force, and diamond particles easily depart from metallic matrix and can not play the design of enhancing phase Function, ultimately cause braking ability and decline even brake fade, this just greatly constrains the practical application of associated materials.
The content of the invention
It is an object of the invention to provide one kind braking wear-resisting diamond particles reinforced aluminum matrix composites and its preparation side Method, in the application being modified by diamond particle surfaces and high pressure air pressure infiltration shapes, realize two-phase interface optimising and adjustment and material On the basis of expecting that forming quality improves, diamond excellent properties can be with more efficient to integral material transmission, so as to obtain high fever The Novel brake high-abrasive material and part of conductance, low-density and preferable friction and wear characteristic, led with solving tradition with ferrous materials The big key issue of heat differential, density, meet the growth requirement that transportation equipment lowers consumption at a high speed.
A kind of diamond particles enhancing aluminium base braking wearing composite material and preparation method, it is characterized in that from particle size range The high heat conduction high rigidity diamond particles for being 5-15 μm are as enhancing phase, by being mixed with Al alloy powder, control diamond body Fraction is 5-25%, and forming pressure is supplied using inert gas argon air lift, and combination is simultaneously realized in driving aluminium alloy melt filling gap, It is final to obtain composite or accordingly brake wear parts;Specific molding condition is to place the graphite jig for filling mixed-powder In former, after vacuum is less than 0.1 Pa, at 250 DEG C to the min of unitary mould the pre-heat treatment 20, then aluminium is closed Gold is heated to 750-950 DEG C, and in the case where argon gas quickly provides 0.1-2.0 MPa pressure conditions, infiltration shapes, heat-insulation pressure keeping 5-30 After min, furnace cooling, demoulding sampling.
Surface metalation pretreatment wherein is carried out to diamond particles, diamond particles are pressed with 25-75 μm of Titanium powder Mol ratio(40:1-10:1)Uniformly mixed, provide salt bath environment using villaumite, be incubated under the conditions of 800-900 DEG C 15-90 min, the water-soluble dechlorination salt of deionization after furnace cooling, by sub-sieve, obtain surface modified diamond particle;Mixing It it is 25 μm with Al alloy powder granularity, main alloy element copper content is 1-3 wt.%, main alloy element in infiltration aluminium alloy Silicone content is 7-12 wt.%.
The positive effect of the present invention is embodied in:
1. mutually obtain aluminum matrix composite as enhancing by using diamond particles, and traditional braking is wear-resisting uses ferrous materials Compare, on the basis of optimizing friction and wear characteristic and obtaining low-density, the thermal conductivity of material is improved significantly, and is meeting While lightweight requirements, it can more efficiently realize that the transmission of braking heat is shifted to improve the safety and stability of braking procedure Property, so as to adapt to the new demand that transportation equipment develops to high speed and energy-saving.
2. pair tetrakaidecahedron diamond particles carry out surface modification treatment, itself and aluminum substrate two-phase knot can be effectively improved Merge optimization interfacial stress state, ensure that diamond particles strengthen filling for the excellent properties such as mutually wear-resisting, high heat conduction in braking procedure Distribution is waved;Meanwhile filled and shaped using isotropism drive of high-pressure gas metal bath, it can effectively reduce forming pressure and liquid Flow disturbance, so as to eliminate defect and promote to be densified, further improve microstructure of composite and stability.
3. can with it is convenient realize to enhancing phase volume fraction and matrix composition adjustment, reinforcing material performance designability, Air pressure infiltration technique coordinates reasonable mold design simultaneously, can complete the local strengthening and near-net forming of Irregular Shaped Parts.
Brief description of the drawings
Fig. 1 is process flow diagram.
Fig. 2 strengthens aluminium base braking wearing composite material typical organization pattern SEM photograph to prepare diamond particles.
Fig. 3 is diamond particles and aluminum substrate two-phase interface microstructure TEM photos.
Specific embodiment
Embodiment 1:
" shape for hat " passenger car brake disc component of diamond particles reinforced aluminum matrix composites.
15 μm of diamond particles of selection and 50 μm of titanium valves press mol ratio 20:1 is sufficiently mixed with villaumite, is then existed 30 min are incubated under the conditions of 800 DEG C of salt baths, obtain surface metalation diamond particles;By obtained Ti-coated diamond particle and 25 μm Al-2 wt.%Cu alloy powders by volume 3:1 under protective atmosphere mechanical mixture, by mixed-powder be filled in graphite mill In tool and ultrasonic jolt ramming;Unitary mould is positioned in building mortion, is heated after vacuum is less than 0.1 Pa, in 850 DEG C of conditions Lower Fast Filling argon pressurization is to 0.8 MPa, and driving Al-7 wt.%Si alloys infiltration shapes, after the min of heat-insulation pressure keeping 10, with stove Cool down and be stripped processing, obtain the composite brake disk blank of near-net forming.Disc material is better than in friction and wear characteristic It is density stabilized in about 2.9 g/cm on the basis of traditional cast iron material3, room temperature thermal conductivity is more than 200 W/mK, shows excellent Combination property.

Claims (4)

1. one kind braking wear parts diamond particles reinforced aluminum matrix composites and preparation method, it is characterized in that from granularity The high heat conduction high rigidity diamond particles that scope is 5-15 μm are as enhancing phase, by being mixed with Al alloy powder, control enhancing Phase volume fraction is 5-25%, supplies forming pressure using inert gas argon air lift, knot is simultaneously realized in driving aluminium alloy melt filling gap Close, it is final to obtain composite and accordingly brake wear parts.
2. wear parts diamond particles reinforced aluminum matrix composites and preparation method thereof are braked described in foundation claim 1, It is characterized in that to carrying out surface metalation pretreatment using diamond particles, diamond particles are pressed with 25-75 μm of Titanium powder Mol ratio(40:1-10:1)Uniformly mixed, provide salt bath environment using villaumite, be incubated under the conditions of 800-900 DEG C 15-90 min, the water-soluble dechlorination salt of deionization after furnace cooling, by sub-sieve, obtain surface modified diamond particle.
3. wear parts diamond particles reinforced aluminum matrix composites and preparation method thereof are braked described in foundation claim 1, It is characterized in that mixing Al alloy powder granularity is 25 μm, main alloy element copper content is 1-3 wt.%, is led in infiltration aluminium alloy It is 7-12 wt.% to want alloy silicon content.
4. wear parts diamond particles reinforced aluminum matrix composites and preparation method thereof are braked described in foundation claim 1, It is characterized in that the graphite jig for filling mixed-powder is positioned in former, it is right first after vacuum is less than 0.1 Pa Aluminium alloy is then heated to 750-950 DEG C, quickly carried in gases at high pressure in 250 DEG C of min of the pre-heat treatment 20 by unitary mould Shaped for infiltration under the conditions of 0.1-2.0 MPa, after heat-insulation pressure keeping 5-30 min, furnace cooling, demoulding sampling.
CN201710042309.0A 2017-01-20 2017-01-20 Diamond particle reinforced aluminum-based brake wear-resistant composite material and preparation method thereof Expired - Fee Related CN107345283B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710042309.0A CN107345283B (en) 2017-01-20 2017-01-20 Diamond particle reinforced aluminum-based brake wear-resistant composite material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710042309.0A CN107345283B (en) 2017-01-20 2017-01-20 Diamond particle reinforced aluminum-based brake wear-resistant composite material and preparation method thereof

Publications (2)

Publication Number Publication Date
CN107345283A true CN107345283A (en) 2017-11-14
CN107345283B CN107345283B (en) 2020-03-17

Family

ID=60253477

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710042309.0A Expired - Fee Related CN107345283B (en) 2017-01-20 2017-01-20 Diamond particle reinforced aluminum-based brake wear-resistant composite material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107345283B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110117731A (en) * 2019-05-17 2019-08-13 北京科技大学 A kind of preparation method of superelevation thermal conductivity diamond particles reinforced aluminum matrix composites
CN113481403A (en) * 2021-06-22 2021-10-08 安徽省新方尊自动化科技有限公司 High-strength wear-resistant foamed aluminum composite material and preparation method thereof
CN113667879A (en) * 2021-07-29 2021-11-19 山东大学 Light high-modulus aluminum-based composite material and preparation method thereof
CN114411010A (en) * 2021-12-21 2022-04-29 山东昌润钻石股份有限公司 Preparation method of diamond reinforced aluminum-based high-thermal-conductivity composite material
CN114985707A (en) * 2022-05-30 2022-09-02 长飞光纤光缆股份有限公司 Preparation method of aluminum-clad metal-based diamond composite material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0821072A1 (en) * 1996-07-23 1998-01-28 Akihisa Inoue Highly wear-resistant aluminium-based composite alloy and wear-resistant parts
CN101538661A (en) * 2009-05-06 2009-09-23 北京科技大学 Method for preparing high thermal conductive diamond/Al composite material
CN104313385A (en) * 2014-11-21 2015-01-28 哈尔滨工业大学 Ultrahigh heat-conduction diamond/aluminum composite material and preparation method of ultrahigh heat-conduction diamond/aluminum composite material
CN104651658A (en) * 2015-03-17 2015-05-27 北京科技大学 Preparation method of novel copper-based composite material having high thermal conductivity
CN105921753A (en) * 2016-05-06 2016-09-07 西安工业大学 Method for preparing near-net-shape parts with complex shapes from diamond-copper composite material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0821072A1 (en) * 1996-07-23 1998-01-28 Akihisa Inoue Highly wear-resistant aluminium-based composite alloy and wear-resistant parts
CN101538661A (en) * 2009-05-06 2009-09-23 北京科技大学 Method for preparing high thermal conductive diamond/Al composite material
CN104313385A (en) * 2014-11-21 2015-01-28 哈尔滨工业大学 Ultrahigh heat-conduction diamond/aluminum composite material and preparation method of ultrahigh heat-conduction diamond/aluminum composite material
CN104651658A (en) * 2015-03-17 2015-05-27 北京科技大学 Preparation method of novel copper-based composite material having high thermal conductivity
CN105921753A (en) * 2016-05-06 2016-09-07 西安工业大学 Method for preparing near-net-shape parts with complex shapes from diamond-copper composite material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张洋等: ""气体压力熔渗制备电子封装用金刚石/铝复合材料的研究"", 《人工晶体学报》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110117731A (en) * 2019-05-17 2019-08-13 北京科技大学 A kind of preparation method of superelevation thermal conductivity diamond particles reinforced aluminum matrix composites
CN113481403A (en) * 2021-06-22 2021-10-08 安徽省新方尊自动化科技有限公司 High-strength wear-resistant foamed aluminum composite material and preparation method thereof
CN113667879A (en) * 2021-07-29 2021-11-19 山东大学 Light high-modulus aluminum-based composite material and preparation method thereof
CN114411010A (en) * 2021-12-21 2022-04-29 山东昌润钻石股份有限公司 Preparation method of diamond reinforced aluminum-based high-thermal-conductivity composite material
CN114985707A (en) * 2022-05-30 2022-09-02 长飞光纤光缆股份有限公司 Preparation method of aluminum-clad metal-based diamond composite material
CN114985707B (en) * 2022-05-30 2024-01-23 长飞光纤光缆股份有限公司 Preparation method of aluminum-clad Jin Shuji diamond composite material

Also Published As

Publication number Publication date
CN107345283B (en) 2020-03-17

Similar Documents

Publication Publication Date Title
CN107345283A (en) A kind of diamond particles enhancing aluminium base braking wearing composite material and preparation method
CN103939509B (en) A kind of Al/Sic and Cu/Sic composite materials friction pair for rail vehicle and preparation method thereof
CN104235237B (en) Brake disc made of carborundum foamed ceramics/aluminum alloy composite materials and production method of road vehicle brake disc
CN102676883B (en) Silicon carbide reinforced aluminum-based composite material and preparation method thereof
CN108359825B (en) A kind of preparation method of ceramics-graphene enhancing Cu-base composites
Kang et al. Effect of molybdenum carbide intermediate layers on thermal properties of copper–diamond composites
CN109321767B (en) Method for preparing hybrid particle reinforced aluminum matrix composite material by composite reinforcement method
CN105798311B (en) A kind of preparation method of high heat conduction ferrous based powder metallurgical brake block for high-speed train
Akhlaghi et al. Effect of the SiC content on the tribological properties of hybrid Al/Gr/SiC composites processed by in situ powder metallurgy (IPM) method
CN107460391B (en) A kind of gradient hard alloy cutter material and its fast preparation method adding graphene
CN109280795A (en) One kind, which receives micron SiC particle, enhances wear-resisting aluminum matrix composite and preparation method thereof
Zhou et al. Improvement of thermal conductivity of diamond/Al composites by optimization of liquid-solid separation process
CN104525949A (en) High abrasion-resisting copper-based friction composite material and preparing method thereof
CN109504869A (en) A kind of metal-base nanometer composite material and preparation method thereof with bionical multilevel structure
Zhao et al. Microstructure and mechanical properties of ZrCW matrix composite prepared by reactive infiltration at 1300° C
CN113817933B (en) Ceramic reinforced titanium-based composite material, preparation method and application thereof
CN102676956B (en) Method for preparing iron-based surface composite material by virtue of in-situ synthesis
CN111690840A (en) Amorphous phase silicate particle and SiC particle reinforced aluminum matrix composite material and preparation
CN103725909B (en) The forging of a kind of powder LP-mode is for the method for aluminium alloy
CN109663900A (en) A kind of steel-based composite plate hammer and preparation method thereof
CN109439950A (en) A kind of base steel composite hammer head and preparation method thereof
CN105385902B (en) A kind of AlN and AlB2Particle enhanced aluminum-based composite material and preparation method thereof
CN102029369A (en) Method for preparing SiC particle-aluminum alloy composite material cylinder liner
Wang et al. Pulse electric current sintering of 3D interpenetrating SiC/Al composites
CN113582697A (en) Gradient layer shape B4C-TiB2Al composite material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 100083 No. 18 clear road, Haidian District, Beijing

Co-patentee after: SHANDONG LONGJI MACHINERY Co.,Ltd.

Patentee after: BEIJING NATIONAL INNOVATION INSTITUTE OF LIGHTWEIGHT Ltd.

Address before: 100083 No. 18 clear road, Haidian District, Beijing

Co-patentee before: SHANDONG LONGJI MACHINERY Co.,Ltd.

Patentee before: Advanced Manufacture Technology Center, China Academy of Machinery Science & Technology

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20200317