CN107333467A - Transparent or semitransparent skin cleansing compositions - Google Patents

Transparent or semitransparent skin cleansing compositions Download PDF

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Publication number
CN107333467A
CN107333467A CN201480084471.3A CN201480084471A CN107333467A CN 107333467 A CN107333467 A CN 107333467A CN 201480084471 A CN201480084471 A CN 201480084471A CN 107333467 A CN107333467 A CN 107333467A
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composition
weight
ion source
potassium ion
soap
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CN201480084471.3A
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CN107333467B (en
Inventor
王勇
Y·陈
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LOreal SA
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LOreal SA
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

Composition is related to the translucent or transparent composition for cleaning keratin material, and it includes (i) at least one soda soap (ii) at least one both sexes comprising glycine betaine or at least one potassium ion source of zwitterionic surfactant (iii) and (iV) water.

Description

Transparent or semitransparent skin cleansing compositions
The present invention relates to a kind of cosmetic composition of the cleaning keratin material based on soda soap.More specifically, this hair It is bright to be related to a kind of translucent or transparent cosmetic composition of the cleaning keratin material based on soda soap.
Cosmetic composition comprising soap base material is well known in the art.It is used to clean keratin material using soap base material Cosmetic composition is widely used, particularly for cleaning skin.
Solid, transparent soap composition are well-known in prior art state.They generally by tallow or/or Coconut and/or castor oil plant aliphatic acid and the soap of transparent agent are formed in the case of with or without alcohol, described transparent Reagent is preferably selected from polyalcohol, for example sugar, glycerine or glycol such as propane diols, ethylene glycol or the mixture of the latter.
Application EP-A 0336803 describe it is a kind of with improved foaming capacity based on containing at least one 1,2- alkane The solid transparent soap composition of the tallow fatty acid soap of glycol.The transparent agent used in the composition is selected from C2-C6It is polynary Alcohol, for example, more specifically, glycerine, propane diols and D-sorbite or possible urea, and their mixture.
United States Patent (USP) No.4165293 describes one kind and contains soda soap, anion or amphoteric surfactant and C2-6Glycol Solid transparent soap.Generally, this solid composite includes anion or amphoteric surfactant, such as second of lauryl sulfate three Alcohol amine salt, lauryl sulfate diethanolamine salt, lauryl betaine, coco dimethyl betaines, laurylamino-propionic acid and bay Dipropionic acid sodium.
One of solid soap has the disadvantage be applied to keratin material such as skin, is difficult to before particularly in face Mixed with water (or with hydration simultaneously).This causes foaming capacity poor, for example foam volume.For consumers, solid composite Attraction may also be less than the attraction of other forms.Sensation on skin, the particularly sensation in face are not made us It is satisfied.
Liquid soap for personal hygiene commercially occurred already.These soaps are typically fatty acid soaps, sodium, potassium, smart ammonia Acid, methyl amimoacetic acid or amine.They have the advantages that and health more more convenient than solid soap.But they are not fully satisfactory.For The gratifying outward appearance of realization, i.e., transparent or semitransparent outward appearance is used as the triethanolamine and fat of principal surfactant Acid has been used to conventional liq soap.However, due to there is triethanolamine, turning yellow when composition is stored after manufacture, this is unstable Fixed sign, and cause outward appearance unsatisfactory.Further, it is difficult to realize desired aspect.In general, such group The aspect of compound is typically the yellow working fluid with very low viscosity.In addition, amino acid such as arginine, methyl amimoacetic acid, paddy ammonia Acid, glycine etc. are applied in combination with the conventional surfactants for cleaning products.Expect to glue however, being still difficult to obtain to have Degree and satisfactory outward appearance are without the cleaning products of any color change unsatisfactory.
Another prior art of delivering clean composition is to introduce anion or amphoteric surfactant such as sulphur Hydrochlorate, glycine betaine or derivatives thereof are used as principal surfactant.But there is shortcoming.When in the absence of polymer, these combinations Thing has low viscosity, and this causes the inconvenience applied on skin.In addition, they are not easy to be flush with water.
Finally, soap sodium is widely used as main surfactant in soap bar formula, but due to its solubility in water It is low, it is difficult to for the cleaning products of non-solid, or, in other words, with expectation in terms of liquid or gelation cleaning production Product, especially as main surfactant.In addition, the soap bar of the sodium containing soap is typically opaque solid bar, and be difficult to Water is mixed.
All above-mentioned prior arts all have the shortcomings that the cosmetic property or outward appearance that influence composition.
Accordingly, it would be desirable to a kind of product for overcoming above mentioned problem.
It is an object of the invention to provide be easily controlled aspect Cleasing compositions, i.e., with expectation in terms of cleaning combination Thing.The present invention also aims to provide a kind of translucent or transparent composition, particularly a kind of Cleasing compositions.
It is an object of the invention to provide a kind of Cleasing compositions easily mixed with water, and therefore allow good foaming The amount of characteristic, particularly foam.
The present invention also aims to provide to show good stability in storage simultaneously with good sanitary characteristics Cleasing compositions.
The present invention also aims to provide a kind of sensation (such as hydration sense after applying with good skin It is feel, opposite with compacting or drying sensation) and good flushing characteristics Cleasing compositions.
Above-mentioned technical problem is by present invention solution.
The inventors have discovered that (i) at least one soda soap, (ii) at least one both sexes comprising glycine betaine or both sexes from Sub- surfactant, (iii) at least one potassium ion source and (iv) water combination allow prepare have expectation in terms of and with The transparent or semitransparent cleaning products of good stability during storage.
More specifically, it has been found by the present inventors that certain weight ratio comprising glycine betaine (particularly alkyl betaine) Both sexes or zwitterionic surfactant can provide the sodium containing soap with transparent or semitransparent cleaning products with potassium ion source Composition, in terms of it has expectation and with extraordinary and water homogenisation ability.The weight ratio is expressed as existing in composition The both sexes comprising glycine betaine, particularly alkyl betaine or zwitterionic surfactant weight divided by the weight of potassium ion source Amount.
More specifically, this composition is easily mixed with water, and is easily flush with water.
" in terms of expectation " or " easily controllable aspect " are intended to indicate that the present invention allows outward appearance and viscosity by transparent or semi-transparent The dynamic fluid composition of free flow is controlled to transparent or semitransparent gel." gel " refers to the sufficiently high composition of viscosity so that Composition will not flow immediately under its own weight at 25 DEG C and under atmospheric pressure (about 101325Pa).This composition can To be shaped according to expectation aspect.The viscosity of composition is especially through the both sexes comprising glycine betaine or zwitterionic surfactant Amount is adjusted with the amount of potassium ion source.
The product of this form is appreciated by consumer, and makes product attractive.
Transparent and translucent soap has aesthetic appeal to consumer, and associated with purity, thus with " nature " phase Association.The transparent essential distinction between translucent soap is relevant with the relative mass of optical transport." transparent " is understood to light Transport property is without perceptible scattering so that being placed on the object behind transparent soap bar is fully visible and can hold Change places it is identified out.
Composition is preferably transparent or semitransparent.
Term " transparent or semitransparent ", which is understood to mean that to have at 25 DEG C, is less than 400NTU (nephelometric turbidity unit), And the composition of the turbidity preferably at 25 DEG C less than 250NTU, is measured with the 2100AN nephelometers machine from HACH, Sample cell wherein for turbidity test is made up of quartz glass.
It is highly preferred that according to the present invention, the composition has the turbidity less than or equal to 200NTU.
The cosmetic composition of the present invention comprising (i) at least one soda soap (ii) at least one both sexes comprising glycine betaine or Zwitterionic surfactant, (iii) at least one potassium ion source and (iv) water.
According to the present invention, the cosmetic composition includes at least one soda soap.
Soda soap can the form of known soap base (soap noodle) be added in the composition of the present invention.Soap base is usual It is made up of vegetable oil (such as palm oil, coconut oil or olive oil) and/or animal tallow (tallow).These are " to be saponified ", usually using sodium hydroxide to form the salt of aliphatic acid.Soap base constitutes the very basic form of soap.Soap base is maximum to be come Source is Malaysia and Indonesia (essentially from palm oil).Other countries of origin include India, Brazil, southern Europe, China and The Middle East.
As soap, obtained especially as the soap of soap base from fatty bronsted lowry acids and bases bronsted lowry.Advantageously, aliphatic acid is included With 10 to 22 carbon atoms, and the saturation or undersaturated straight or branched alkyl chain of preferably 10 to 20 carbon atoms.Therefore, In one embodiment, soda soap is C10-C20The sodium salt of soap or its mixture.Soap for the present invention is this area It is known, typically fatty acid soaps of tallow and/or coconut oil and/or castor oil plant.These soaps are preferably selected from sodium salt, special It is not C10-C20Sodium salt, the C of aliphatic acid10-C14The sodium salt and its mixture of aliphatic acid.
In one embodiment, the aliphatic acid of soda soap is natural origin, i.e., extracted from plant.In an embodiment party In case, the aliphatic acid of soda soap is palm oil.
According to an embodiment, soda soap be selected from animal resin acid sodium, sodium palmitate, coconut oil sodium, palm kernel acid sodium and its Any mixture.In a preferred embodiment, the aliphatic acid of soda soap is sodium palmitate, palm kernel acid sodium or its mixing Thing.It is highly preferred that soda soap is the mixture of sodium palmitate and palm kernel acid sodium.This mixture is for example by KLK OLEO with commodity NameSale.
According to a preferred embodiment, relative to the gross weight of the composition, soda soap is using scope as 1 to 20 weight % is measured, preferably 1 to 15 weight %, even more preferably 2 to 10 weight % amount are present.
The cosmetic composition of the present invention includes at least one both sexes or zwitterionic surfactant.
The both sexes including glycine betaine that can be used or the example of zwitterionic surfactant include alkyl betaine, N- Alkyl amido betaine and its derivative, sulfobetaines (sultaine) and its any mixture.In an embodiment In, both sexes or zwitterionic surfactant comprising glycine betaine are selected from (C8-C20) alkyl betaine, sulfobetaines (sulfobetaine)、(C8-C20) alkyl acyl ammonia (C1-C6) alkyl betaine or (C8-C20) alkylamide (C1-C6) alkyl sulphur Base glycine betaine and its any mixture.
It can be mentioned that alkyl betaine example include coco betaine, such as by Cognis companies with titleBy Clariant companies with title GenagenThe product of sale；Lauryl betaine, for example By Huntsman companies with titleThe product of BB/LS sale；Oxyethylation (10EO) lauryl betaine, for example By Shin Nihon Rica companies with title Lauryl Ether (10OE)The product of sale；Oxyethylation (10EO) stearyl betaine, such as by Shin Nihon Rica companies with title Stearyl Ether (10OE) The product of sale.Preferably, in the present invention use by HUNTSMAN companies with titleThe bay of BB/LS sale Base glycine betaine.Lauryl betaine, which can be used as, contains lauryl dimethyl amine glycine betaine (INCI titles：Lauryl betaine The aqueous solution of (and) sodium chloride) is found.
It is preferred that using in the present invention by CLARIANT companies with title GenagenThe coco betaine of sale.
For example, it can be mentioned that N- alkyl acyl ammonia glycine betaine and its derivative in be, for example, Cocoamidopropyl betaine, By Sanyo companies with title Lebon 2000By Albright＆Wilson companies with title EmpigenOr by COGNIS companies are with titlePK 45 is sold；Lauroylamidopropyl betaine, by Witco companies with title RewotericSale.It is preferred that using in the present invention by COGNIS with titlePK45 is sold Cocoamidopropyl betaine.
It can be mentioned that sulfobetaines be with title Crosultaine by Croda companiesThe cocoyl of sale- Amido propyl hydroxyl sulfo betaine.
Advantageously, the composition does not include the anion surfactant of containing sulfate.It is this in Cleasing compositions Sulfate surfactant is typically sodium laureth sulfate, and it is preferably avoided in the present compositions.
According to one embodiment of the invention, relative to the gross weight of the composition, the composition comprising 0.1 to 20 weight %, preferably 0.5 to 15 weight %, even more preferably 0.5 to 10 weight the % a kind of both sexes or two for including glycine betaine Property ionic surface active agent.
The composition of the present invention includes at least one potassium ion source.The potassium ion source can provide potassium ion in water.
It can be mentioned that potassium hydroxide, sylvite or its mixture.
For potassium hydroxide, it can be mentioned that the potassium hydroxide sold by CHT South Africa companies, it contains in water There is 50% potassium hydroxide.
Sylvite can be organic or inorganic.The gegenion of sylvite is not limited.
According to a preferred embodiment, the gross weight meter with the weight of potassium ion source relative to the composition, potassium Ion gun is using scope as 1 to 20%, and preferably 2 to 20%, even more preferably 3 to 18% amount is present.
According to a specific embodiment, the composition includes the both sexes comprising glycine betaine or amphion surface-active Agent (if there is several both sexes comprising glycine betaine or zwitterionic surfactant, its total amount) is with potassium ion source (if deposited In several potassium ion sources, its total amount) weight than scope be 1/10 to 20/1, preferably 1/5 to 10/1, more particularly 1/2 to 5/1.Such as " 1/10 " refers to the nonionic surfactant comprising glycine betaine of 1 part of total amount and the sylvite of 10 parts of total amounts, described Part is expressed as parts by weight.
In a specific embodiment, both sexes or zwitterionic surfactant and potassium ion source comprising glycine betaine Between above-mentioned ratio be about 1/2.
According to a specific embodiment, the composition includes at least one aliphatic acid.
The example of aliphatic acid is those with 4 to 30 carbon atoms.
The aliphatic acid can be selected from laurate, palmitic acid, stearic acid, oleic acid, linoleic acid, myristic acid and its mix Compound, preferably laurate, myristic acid and its mixture.
In one embodiment, composition of the invention includes laurate.
In one embodiment, composition of the invention can include at least one aliphatic acid, such as, such as C10-C20 Aliphatic acid, relative to the gross weight of the composition, preferably described composition includes 1 to 20 weight %, preferably 1 to 15 weight Measure %, even more preferably 5 to 10 weight the % aliphatic acid.
The composition of the present invention can include one or more buffers.These reagents are known in the art.At one In embodiment, the buffer is selected from weak organic acid, such as, such as polybasic carboxylic acid.
In a specific embodiment, the buffer is citric acid.
Relative to the gross weight of the composition, the scope of the amount of buffer can be preferably 0.1 to 20 weight %, more excellent Select 1 to 10 weight %, even more preferably 2 to 8 weight %.
In one embodiment, the pH scopes of the composition are 5 to 11, preferably 6 to 11, more preferably 8 to 10.
In known manner, composition of the invention can also contain assistant common in cosmetics and/or dermatology Agent, such as preservative, antioxidant, complexing agent, pH adjusting agent (acid or alkalescence), spices, filler, bactericide, odor adsorption Agent, film forming polymer, surfactant (such as anion, both sexes, cation or nonionic surfactant) in addition；Oily example Such as silicone oil or fluorocarbon oil, thickener and/or gelling agent, active component and plant extracts.
Term " silicone oil " refers to the oil comprising carbon atom and at least one silicon atom in its structure.
Term " fluorocarbon oil " refers to the be based partially on hydrocarbon and/or oil based on siloxanes comprising carbon atom and fluorine atom.
Much less, those skilled in the art will carefully select this or these optional other compounds and/or its amount, So that not negatively affected according to the property of the composition of the present invention by the addition contemplated or substantially.
The composition of the present invention can include one or more water-soluble alcoholic solvents.In one embodiment, alcohol Solvent is selected from C1-C5Alcohol, including ethanol, propyl alcohol, isopropanol and its mixture.
In a specific embodiment, the alcohol is ethanol.
The scope of the amount of water-soluble alcoholic solvent can be 0.05 to 10 weight relative to the gross weight of the composition Measure %, more preferably preferably 0.1 to 10 weight %, 0.5 to 3 weight %.
Present invention additionally comprises water, preferably deionized water.Relative to the gross weight of the composition, water content may range from 20 to 70 weight %, preferably 30 to 60 weight %, more preferably 40 to 55 weight %.
Advantageously, the composition can be the form of lotion, creme or gel, and preferably described composition is aqueous solidifying Glue.
Term " aqueous gel " refers to the composition of the continuous aqueous phase containing the viscoplasticity block formed by colloidal suspension liquid.
The present invention composition viscosity can by any method known to those skilled in the art, in particular according to Lower conventional method is measured.Therefore, it is possible to use being equipped with the viscosimeters of Rheomat 180 with the 200rpm ingots rotated at 25 DEG C Under measure.Those skilled in the art can select to be used to measure based on their general knowledge from ingot M1, M2, M3 and M4 The ingot of viscosity, so as to perform measurement.
Using being equipped with the 200rpm ingot M2 rotated ProRheo R180 viscosimeters from Prorheo companies, The viscosity of the lotion according to the present invention is measured at 25 DEG C, its value is generally 20UD to 80UD (deviation metric).
Measured according to the viscosity of aqueous gel of the present invention at 25 DEG C, using from Prorheo companies be equipped with The ingot M3 or M4 of 200rpm rotations ProRheo R180 viscosimeters, its value is usually 20UD to 80UD (deviation metric).
It is highly preferred that according to an embodiment, the viscosity of composition of the invention uses ingot by ProRheo at 25 DEG C The viscosity of M4 measurements is 30UD.
Term " fluid " is the composition for referring to flow under its own weight, the combination with alleged solid or gel Thing is relative.
According to an aspect of the present invention, it has been found by the present inventors that rheology need not be added in the present compositions Modifying agent, polymer and/or thickener.There is no rheology modifier, polymer or thickener, the composition keeps stable.
In one embodiment, composition of the invention do not include rheology modifier, and/or not comprising polymer and/ Or not comprising thickener.
More specifically, in one embodiment, the composition does not include carbomer and/or polysiloxanes or its derivative Thing, such as dimethyl silicone polymer.
In one embodiment, relative to the gross weight of the composition, composition of the invention is included by weight (i) at least one both sexes comprising glycine betaine of 2 to 10% at least one soda soap (ii) 0.5 to 15% or amphion surface At least one potassium ion source and (iv) water of activating agent (iii) 3 to 18%.
In a specific embodiment, the composition scope is 1/5 to 10/1, preferably 1/2 to 5/1 bag The ratio of both sexes or zwitterionic surfactant and potassium ion source containing glycine betaine.
In one embodiment, the mixture of composition of the invention comprising (i) sodium palmitate and palm kernel acid sodium, and (ii) lauryl betaine.
It is highly preferred that relative to the gross weight of the composition, the composition includes 1 to 20 weight %, preferably 1 to 15 Weight %, even more preferably 3 to 10 weight % sodium palmitate and palm kernel acid sodium mixture, and 1 to 40 weight %, preferably 10 to 40 weight %, even more preferably 10 to 30 weight % lauryl betaine.
In a specific embodiment, the mixing of composition of the invention comprising (i) sodium palmitate and palm kernel acid sodium Thing, (ii) lauryl betaine and (iii) potassium hydroxide.
It is highly preferred that relative to the gross weight of the composition, the composition includes (i) 1 to 20 weight %, preferably 1 To 15 weight %, even more preferably 3 to 10 weight % sodium palmitate and palm kernel acid sodium mixture, (ii) 1 to 40 weight Measure %, preferably 10 to 40 weight %, even more preferably 10 to 30 weight % lauryl betaine, and (iii) 1 to 20 weight Measure %, preferably 3 to 20 weight %, even more preferably 5 to 18 weight % potassium hydroxide.
In a specific embodiment, the mixing of composition of the invention comprising (i) sodium palmitate and palm kernel acid sodium Thing, (ii) lauryl betaine, (iii) potassium hydroxide and at least one aliphatic acid.
It is highly preferred that relative to the gross weight of the composition, the composition includes (i) 1 to 20 weight %, preferably 1 To 15 weight %, even more preferably 3 to 10 weight % sodium palmitate and palm kernel acid sodium mixture, (ii) 1 to 40 weight Measure %, preferably 10 to 40 weight %, even more preferably 10 to 30 weight % lauryl betaine, and (iii) 1 to 20 weight Measure %, preferably 3 to 20 weight %, even more preferably 5 to 18 weight % potassium hydroxide, and 1 to 20 weight %, preferably 1 to 15 Weight %, even more preferably 5 to 10 weight % aliphatic acid.
In a specific embodiment, the mixing of composition of the invention comprising (i) sodium palmitate and palm kernel acid sodium Thing, (ii) lauryl betaine, (iii) potassium hydroxide, at least one aliphatic acid, at least one chelating agent, at least one spices, At least one preservative, at least one alcohol, at least one two alcohol and water.
Advantageously, composition of the invention is cosmetic composition or the acceptable composition of cosmetics.
Term " cosmetic composition " is interpreted as to be administered to including skin, face, lip, nail, hair and scalp Human keratin material non-toxic composite.
Especially, cosmetic composition of the invention is used to clean keratin material.The invention further relates to according to the present invention Composition purposes in itself, or it is for cleaning keratin material, particularly skin, especially from the change of facial skin Purposes in cosmetic product.
The present invention relates to a kind of non-therapeutic beauty method for being used to clean human keratin material, it is included in the keratin On the surface of material apply the present invention at least one composition, and for example with water by the present invention composition rinse out, with from Human keratin material removes the composition.
The composition of the present invention is also used as bath products, as bath product, as cleaning products such as shampoo with Hand-washing article, or for cleaning face.
The invention further relates to the non-therapeutic beauty method for cleaning human keratin material, including by least one layer of basis The composition of the present invention is administered to keratin material.
The invention further relates to a kind of beauty method for being used to clean human keratin material, methods described includes will be according to this hair Bright composition is administered on human keratin material.
The invention further relates to a kind of beauty method for cleaning human keratin materials, including by least one layer according to the present invention's Composition is administered to keratin material.
Term " keratin material " refers to skin (skin around body, face and eyes), hair, eyelashes, eyebrow, body Hair, nail, lip or mucous membrane, particularly skin.
The following examples are intended to indicate that according to the compositions and methods of the invention, but are not limited in any way The scope of the present invention.
All parts and percentages in embodiment are provided on the basis of weight, unless otherwise stated, all survey Amount is obtained at about 25 DEG C.
Embodiment
Embodiment 1- according to the present invention composition composition
Manufacturing process：
1. phase B is pre-mixed until uniform；
2. phase A is added in main still, phase B is then added.It is heated to 75 DEG C, stirring to formation transparent aquagel or flexibility Gel；
3. phase C is added in the mixture obtained above, and it is cooled to 40 DEG C；
4. preservative phase D is added in the mixture obtained above；
5. phase E is added in mixture and 30 DEG C are cooled to.
The machine used：The homogenizer VMI of i-Tech companies sale.
As a result：
The aspect of composition 1 be at 25 DEG C with 30UD viscosity stabilization aqueous gel, using be equipped with The ingot M4 of the 200rpm rotations viscosimeters of Rheomat 180 (from 2 months), and viscosity is easily controlled with composition regulation.
, can be by decreasing or increasing lauryl betaine and potassium hydroxide in view of the preferred ratio between two kinds of compositions Amount carry out the viscosity of regulation composition 1, such preferred ratio between lauryl betaine and potassium hydroxide is about 1/2.Plus The amount for entering lauryl betaine and potassium hydroxide is higher, and viscosity is higher.
It is transparent according to the composition 1 of the present invention, turbidity is 20NTU when being measured with Hach 2100AN nephelometers.
It is clean composition according to the composition 1 of the present invention, it is aqueous gel.
After composition 1, the cosmetic property of composition 1 is evaluated by 15 well-trained group members.
Therefore, assessment is followed the steps below：
1. composition 1 is mixed with water to form foam in palm；
2. composition, foam 1 is applied in face；
3. the wheel of face 40 and 60 wheels are massaged respectively with composition, foam 1；
4. rinse face with water；
5. drying face with towel, wait 2 minutes at room temperature.
Finally, group member is directed to provides fraction 1-3 with properties, and：
1：Difference, outside the present invention；
2：Acceptable, good property；
3：It is outstanding, extraordinary property.
As a result it is as follows：
Attribute Fraction
Outward appearance 3
Easily mixed with water 2
Easily rinse out 3
Hydration sensation after rinsing out 3
The amount of foam when being mixed on hand with water 3
According to the above results, composition 1 has extraordinary cosmetic property, that is to say, that according to the combination of the present invention Thing 1 has very gratifying outward appearance, easily mixes and is flush with water with water.In addition, having when mixed with water good Gas release, and provide in face hydration sensation.

Claims (15)

1. cosmetic composition, includes (i) at least one soda soap (ii) at least one both sexes comprising glycine betaine or amphion Surfactant (iii) at least one potassium ion source and (iv) water.
2. composition according to claim 1, wherein the soda soap is C10-C20The sodium salt of soap or its mixture.
3. according to the composition of claim 1 or 2, wherein, relative to the gross weight of the composition, the soda soap using scope as 1 to 20 weight %, preferably 1 to 15 weight %, even more preferably 2 to 10 weight % amount are present.
4. according to the composition of any one of claims 1 to 3, wherein, relative to the gross weight of the composition, the combination Thing includes 0.1 to 20 weight %, and preferably 0.5 to 15 weight %, even more preferably 0.5 to 10 weight % at least one include sweet tea The both sexes of dish alkali or zwitterionic surfactant.
5. according to the composition of any one of Claims 1-4, wherein, with the weight of potassium ion source relative to the composition Gross weight meter, the potassium ion source is using scope as 1 to 20%, and preferably 2 to 20%, even more preferably 3 to 18% amount is present.
6. according to the composition of any one of claim 1 to 5, wherein the composition scope is 1/10 to 20/1, it is excellent Select 1/5 to 10/1 both sexes comprising glycine betaine or the weight ratio of zwitterionic surfactant and potassium ion source.
7. according to the composition of any one of claim 1 to 6, wherein the composition scope includes for 1/2 to 5/1 The nonionic surfactant of glycine betaine and the weight ratio of potassium ion source.
8. according to the composition of any one of claim 1 to 7, wherein the composition is also comprising at least one aliphatic acid.
9. according to the composition of any one of claim 1 to 8, wherein the cosmetic composition is used to clean keratin material Material.
10. according to the composition of any one of claim 1 to 9, wherein the composition is transparent or semitransparent composition.
11. according to the composition of any one of claim 1 to 10, wherein the composition is gel.
12. according to the cosmetic composition of any one of claim 1 to 11, it is included by weight relative to the composition Gross weight, at least one both sexes comprising glycine betaine or two of (i) 2 to 10% at least one soda soap (ii) 0.5 to 15% Property ionic surface active agent, (iii) 3 to 18% at least one potassium ion source and (iv) water.
13. composition according to claim 12, wherein the composition scope is 1/5 to 10/1, preferably 1/2 to 5/ The ratio of 1 both sexes comprising glycine betaine or zwitterionic surfactant and potassium ion source.
14. a kind of beauty method for being used to clean human keratin material, methods described includes according in claim 1 to 13 to appoint The composition of one is administered on human keratin material.
15. the method for claim 14, wherein methods described include to be rushed according to the composition of any one of claim 1 to 13 Wash off to remove the composition from human keratin material.
CN201480084471.3A 2014-12-26 2014-12-26 Transparent or translucent skin cleansing compositions Active CN107333467B (en)

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Publication number Priority date Publication date Assignee Title
CN109640933A (en) * 2016-06-30 2019-04-16 罗地亚经营管理公司 Both sexes acetate and beet alkali surface activator containing potassium

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CN1362505A (en) * 2000-12-25 2002-08-07 资生堂贺妮健工业株式会社 Transparent bar-type soap composition
CN1524515A (en) * 2003-09-17 2004-09-01 李慧娟 Natural plant distillate bath lotion
CN1679498A (en) * 2005-01-26 2005-10-12 王瑞琴 Prescription of skin-cleaning cosmetics containing pot marigold oil and production thereof
CN1784207A (en) * 2003-05-07 2006-06-07 味之素株式会社 Cleansing composition
US20080009429A1 (en) * 2006-07-06 2008-01-10 Clariant International Ltd. Cosmetic or dermatological cleansing compositions comprising secondary alkanesulfonates

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1362505A (en) * 2000-12-25 2002-08-07 资生堂贺妮健工业株式会社 Transparent bar-type soap composition
CN1784207A (en) * 2003-05-07 2006-06-07 味之素株式会社 Cleansing composition
CN1524515A (en) * 2003-09-17 2004-09-01 李慧娟 Natural plant distillate bath lotion
CN1679498A (en) * 2005-01-26 2005-10-12 王瑞琴 Prescription of skin-cleaning cosmetics containing pot marigold oil and production thereof
US20080009429A1 (en) * 2006-07-06 2008-01-10 Clariant International Ltd. Cosmetic or dermatological cleansing compositions comprising secondary alkanesulfonates

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