CN107325646A - Colorful high elastic antibacterial environment protection wax crayon - Google Patents
Colorful high elastic antibacterial environment protection wax crayon Download PDFInfo
- Publication number
- CN107325646A CN107325646A CN201710686806.4A CN201710686806A CN107325646A CN 107325646 A CN107325646 A CN 107325646A CN 201710686806 A CN201710686806 A CN 201710686806A CN 107325646 A CN107325646 A CN 107325646A
- Authority
- CN
- China
- Prior art keywords
- environment protection
- wax crayon
- high elastic
- chinese medical
- antibacterial environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The present invention relates to a kind of colorful high elastic antibacterial environment protection wax crayon, the composition weight proportion of material used：High molecular polymer 35 ~ 45%, emulsifying wax 5 ~ 10%, white or colorless solid powder 25 ~ 35%, Chinese medical extract 5 ~ 10%, developer 7 ~ 14%, assistant toner 1 ~ 10%, stearic acid 1 ~ 10%, adhesive 1 ~ 10%.The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanilla, and tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2~1.5：0.8~1.2：1~1.5：1.7~1.9：0.7~0.9.Make wax crayon that there is good elasticity by adding thermoplastic macromolecule material, so as to be difficult to be bent over, make wax crayon that there are antibacterial functions by adding Chinese medical extract；The constituent of whole wax crayon is nontoxic, and suitable child uses.
Description
Technical field
The present invention relates to a kind of chemical material technical field, more particularly to a kind of colorful high elastic antibacterial environment protection wax crayon.
Background technology
Wax crayon be it is a kind of write calligraphy and painting instrument, it by pigment be dispersed in solid or（With）In liquid medium, by means of being situated between
It is attached on the surface of solid material to the effect of matter and uniform and delicate, there can be tens of kinds of colors；But wax crayon does not have permeability, it is
It is fixed on by adhesive force on picture；Produced by wax crayon is mainly what children used, thus its topmost defect is raw material
The carcinogens such as aromatic hydrocarbon are exceeded, to the healthy harmful of child；Simultaneously present wax crayon is in use once curved
Qu Zehui is broken off, and is unfavorable for child and is used；In order to overcome drawbacks described above, in the market is proposed some water soluble crayons, such as
Chinese invention patent document（Application number：200910189491.8）Wax crayon can be washed it is main by paraffin, water solubility by disclosing one kind
Wax, inserts, colouring agent composition, the composition and mass percent of the of the invention primary raw material for washing wax crayon are：Paraffin 51.5-
79.5%, water soluble wax 10-20%, inserts 10-30%, colouring agent 0.2-1.5%.But the wax crayon of the technical scheme is easy to be rolled over
It is disconnected.
Accordingly, it would be desirable to which developing one kind is not easily broken colorful high elastic antibacterial environment protection wax crayon, suitable child uses.
The content of the invention
The technical problem to be solved in the present invention is to provide one kind and is not easily broken colorful high elastic antibacterial environment protection wax crayon.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is：The colorful high elastic antibacterial environment protection wax crayon
Component is by weight proportion：High molecular polymer 35 ~ 45%, emulsifying wax 5 ~ 10%, white or colorless solid powder 25 ~ 35%, Chinese medicine
Extract 5 ~ 10%, developer 7 ~ 14%, assistant toner 1 ~ 10%, stearic acid 1 ~ 10%, adhesive 1 ~ 10%.
Using above-mentioned technical proposal, by the synergy of various components, make obtained wax crayon that there are antibacterial functions, and not
Easily it is bent over；Make wax crayon flexible by adding thermoplastic macromolecule material, so as to be difficult to be bent over, carried by adding Chinese medicine
Thing is taken to make wax crayon that there are antibacterial functions；The constituent of whole wax crayon is nontoxic, and suitable child uses.
Further improvement is that, the Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and perfume (or spice)
Orchid, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2~1.5：0.8~1.2：1~1.5：
1.7~1.9：0.7~0.9.
Further improvement is that, the concentration of the Chinese medical extract is 0.72g/ml.
The technical problem to be solved in the present invention is to provide a kind of preparation side for being not easily broken colorful high elastic antibacterial environment protection wax crayon
Method.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is：The colorful high elastic antibacterial environment protection wax crayon
Preparation method, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；
（5）It is added into extruding machine to be molded, forms cylindrical product；Cut on demand again after cooling, that is, obtain colored height
Play antibacterial environment protection wax crayon.
Using above-mentioned technical proposal, high molecular polymer and other materials one can be made by magnetic stirring apparatus heating stirring
Rise and melt and uniformly mix, adding macromolecule polymer material can make obtained wax crayon have flexible characteristic, so that
Obtained wax crayon is not easily broken, by extruding machine, can quickly cool and solidify shaping.
Preferred scheme is, the composition weight proportion of the material used in it：High molecular polymer 35 ~ 45%, emulsifying wax 5 ~ 10%,
White or colorless solid powder 25 ~ 35%, Chinese medical extract 5 ~ 10%, developer 7 ~ 14%, assistant toner 1 ~ 10%, stearic acid 1 ~ 10%,
Adhesive 1 ~ 10%.
Preferred scheme is that the Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanilla,
Tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2~1.5：0.8~1.2：1~1.5：1.7~
1.9：0.7 ~ 0.9, using again distill obtaining traditional Chinese medicine extraction after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C
Thing.
Preferred scheme is, the step（2）The temperature setting of middle magnetic stirring apparatus is at 80 ~ 90 DEG C, and the rotating speed of stirring is 200
~ 400r/min, mixing time is 2 ~ 10h；The step（3）The temperature of middle magnetic stirring apparatus is 90 ~ 160 DEG C, the rotating speed of stirring
For 200 ~ 500r/min, the time of stirring is 4 ~ 12h；The step（4）In magnetic stirring apparatus temperature setting 80 ~ 150
DEG C, the rotating speed of stirring is 200 ~ 350r/min, and the time of stirring is 5 ~ 15h；The step（5）In shaping temperature for 100 ~
140℃。
Preferred scheme is that the high molecular polymer is makrolon, polyethylene, polypropylene, polyolefin, polyester, polychlorostyrene
One or more mixing in ethene and rubber.
Preferred scheme is that described adhesive is modified rosin；The developer is metal salt or organic toner or inorganic face
Material；The assistant toner is sodium nitrate or the sour potassium of pin.
Preferred scheme is that the white or colorless solid are talcum powder, kaolin, calcium carbonate, white carbon, titanium dioxide, glass
Any one or two or more mixtures of glass powder, lignocellulose.
Preferred scheme is, described organic toner for the fine arts are red or lithol rubine or permanent bordeaux FGR or Fast Yellow 10G or
Permanent yellow 5GX or forever solid orange or phthalocyanine green or phthalocyanine blue or permanent violet or fluorescent red or lucifer yellow or fluorescent be blue or fluorescent is green or
Fluorescent is pink or fluorescent is purple.
Preferred scheme is that the inorganic pigment is titanium dioxide or carbon black or iron oxide red or pearl essence or medium chrome yellow or noctilucence
Powder.
Compared with prior art, the invention has the advantages that：The colorful high elastic antibacterial environment protection wax crayon of the present invention
Preparation method has good stability and practicality, favorable repeatability, and used material is nontoxic environmentally friendly material
Acted synergistically between material, each material component, so that prepared flexible wax crayon had not only realized flexible characteristic but also ring
Suitable child is protected to use.
Embodiment
In order to deepen the understanding of the present invention, the present invention is described in further detail below in conjunction with embodiment, the reality
Apply example to be only used for explaining the present invention, protection scope of the present invention is not constituted and limited.
Embodiment 1：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer
35%, emulsifying wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5% glues
Mixture 5%；High molecular polymer is polyethylene；Described adhesive is modified rosin；The developer is inorganic pigment；The nothing
Machine pigment is any one in titanium dioxide, carbon black, medium chrome yellow, iron oxide red, pearl essence, luminescent powder；The assistant toner is nitre
Sour sodium；The white or colorless solid are calcium carbonate；The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, open country
Chrysanthemum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：0.8：1：1.7：
0.7。
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 2：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 45%, breast
Change wax 10%, white or colorless solid powder 25%, Chinese medical extract 5%, developer 7%, assistant toner 2%, stearic acid 3%, adhesive
3%；High molecular polymer is polyethylene；Described adhesive is modified rosin；The developer is inorganic pigment；The inorganic face
Expect for any one in titanium dioxide, carbon black, medium chrome yellow, iron oxide red, pearl essence, luminescent powder；The assistant toner is nitric acid
Sodium；The white or colorless solid are calcium carbonate；The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, mother chrysanthemum
Flower and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.5：1：1：1.9：0.9.
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 200r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 400r/min, and the time of stirring is 8h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 300r/min, and the time of stirring is 7h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 3：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 40%, breast
Change wax 8%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 11%, assistant toner 1%, stearic acid 2%, adhesive
3%.High molecular polymer is polyethylene；Described adhesive is modified rosin；The developer is inorganic pigment；The inorganic face
Expect for any one in titanium dioxide, carbon black, medium chrome yellow, iron oxide red, pearl essence, luminescent powder；The assistant toner is nitric acid
Sodium；The white or colorless solid are calcium carbonate.The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, mother chrysanthemum
Flower and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1： 1.5：1.2：1.5：
1.8：0.8.
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 300r/min, and mixing time is 8h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 500r/min, and the time of stirring is 4h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 350r/min, and the time of stirring is 5h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 4：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is polypropylene；Described adhesive is modified rosin；The developer is metal salt；Metal salt be mantoquita,
Molysite；The assistant toner is the sour potassium of pin；The white or colorless solid are talcum powder；The Chinese medical extract include tripterygium wilfordii,
Radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight
Than for 1：1.2：0.8：1：1.7：0.7.
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 5：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is that polyolefin described adhesive is modified rosin；The developer is organic toner；The assistant toner is
Sodium nitrate；The white or colorless solid are kaolin；Described organic toner is the red fine arts, lithol rubine, permanent bordeaux
FGR, permanent yellow 5GX, forever Fast Yellow 10G, solid orange, phthalocyanine blue, phthalocyanine green, permanent violet, fluorescent red, lucifer yellow, fluorescent
Blue, fluorescent is green, fluorescent is pink or fluorescent it is purple in any one；The Chinese medical extract include tripterygium wilfordii, radix glycyrrhizae, honeysuckle,
Lilac daphne, chrysanthemum indicum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：
0.8：1：1.7：0.7.
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 6：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is makrolon；Described adhesive is modified rosin；The developer is inorganic pigment；It is described to help color
Agent is the sour potassium of pin；The white or colorless solid are white carbon；The inorganic pigment is titanium dioxide, carbon black, medium chrome yellow, oxidation
Any one in iron oxide red, pearl essence, luminescent powder；The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, mother chrysanthemum
Flower and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：0.8：1：1.7：
0.7。
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 7：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is polyester；Described adhesive is modified rosin；The developer is inorganic pigment；The assistant toner is
Sodium nitrate；The white or colorless solid are lignocellulose；The inorganic pigment is titanium dioxide, carbon black, medium chrome yellow, oxygen
Change any one in iron oxide red, pearl essence, luminescent powder；The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, open country
Chrysanthemum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：0.8：1：1.7：
0.7。
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 8：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is polyvinyl chloride；Described adhesive is modified rosin；The developer is inorganic pigment；It is described to help color
Agent is the sour potassium of pin；The white or colorless solid are titanium dioxide；The inorganic pigment is titanium dioxide, carbon black, medium chrome yellow, oxidation
Any one in iron oxide red, pearl essence, luminescent powder；The Chinese medical extract includes tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, mother chrysanthemum
Flower and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：0.8：1：1.7：
0.7。
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
Embodiment 9：The composition weight proportion of material used in the colorful high elastic antibacterial environment protection wax crayon：High molecular polymer 35%, breast
Change wax 5%, white or colorless solid powder 30%, Chinese medical extract 5%, developer 8%, assistant toner 7%, stearic acid 5%, adhesive
5%；High molecular polymer is rubber；Described adhesive is modified rosin；The developer is inorganic pigment；The assistant toner is
Sodium nitrate or the sour potassium of pin；The white or colorless solid are glass dust；The inorganic pigment be titanium dioxide, carbon black, medium chrome yellow,
Any one in iron oxide red, pearl essence, luminescent powder；The Chinese medical extract include tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne,
Chrysanthemum indicum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic weight ratio are 1：1.2：0.8：1：
1.7：0.7.
The preparation method of the colorful high elastic antibacterial environment protection wax crayon, comprises the following steps：
（1）Raw material are weighed by component ratio, and white or colorless solid powder are mixed with stearic acid and grind uniform, are treated
With；
（2）Emulsifying wax is put into beaker, emulsifying wax is melted using magnetic stirring apparatus heating stirring, until emulsifying wax melts completely
Change；The temperature setting of magnetic stirring apparatus is at 80 DEG C, and the rotating speed of stirring is 400r/min, and mixing time is 5h；
（3）High molecular polymer is added into the emulsifying wax melted, continues to stir, until being completely melt；Magnetic stirring apparatus
Temperature is 95 DEG C, and the rotating speed of stirring is 300r/min, and the time of stirring is 12h；
（4）To step（3）Middle addition step（1）In powder, Chinese medical extract, developer and adhesive, continue stir, until
It is completely dissolved in after homogeneous milkiness shape, assistant toner is added while stirring, until develops the color and stirring completely；Magnetic stirring apparatus
Temperature setting at 150 DEG C, the rotating speed of stirring is 200r/min, and the time of stirring is 10h；The concentration of the Chinese medical extract is
0.72g/ml；Using again distill obtaining Chinese medical extract after above-mentioned Chinese medicine mixing and water adding is decocted 2 hours at 100 DEG C；
（5）It is added into extruding machine to be molded, forms the cylindrical product of certain specification size；Obtained after cooling, cutting
Colorful high elastic antibacterial environment protection wax crayon；The temperature of shaping is 120 DEG C.
For the ordinary skill in the art, simply the present invention is exemplarily described for specific embodiment, it is clear that
The present invention, which is implemented, to be not subject to the restrictions described above, as long as employing inventive concept and technical scheme of the present invention progress
The improvement of various unsubstantialities, or it is not improved by the present invention design and technical scheme directly apply to other occasions,
Within protection scope of the present invention.
Claims (8)
1. a kind of colorful high elastic antibacterial environment protection wax crayon, it is characterised in that the composition weight proportion of material used：High molecular polymerization
Thing 35 ~ 45%, emulsifying wax 5 ~ 10%, white or colorless solid powder 25 ~ 35%, Chinese medical extract 5 ~ 10%, developer 7 ~ 14%, are helped
Toner 1 ~ 10%, stearic acid 1 ~ 10%, adhesive 1 ~ 10%.
2. colorful high elastic antibacterial environment protection wax crayon according to claim 1, it is characterised in that the Chinese medical extract includes thunder
Public rattan, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanilla, tripterygium wilfordii, radix glycyrrhizae, honeysuckle, lilac daphne, chrysanthemum indicum and vanillic
Weight ratio is 1：1.2~1.5：0.8~1.2：1~1.5：1.7~1.9：0.7~0.9.
3. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that the concentration of the Chinese medical extract
For 0.72g/ml.
4. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that the high molecular polymer is poly-
One or more mixing in carbonic ester, polyethylene, polypropylene, polyolefin, polyester, polyvinyl chloride and rubber.
5. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that described adhesive is modified pine
It is fragrant；The developer is metal salt or organic toner or inorganic pigment；The assistant toner is sodium nitrate or the sour potassium of pin.
6. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that the white or colorless solid are
Talcum powder, kaolin, calcium carbonate, white carbon, titanium dioxide, glass dust, lignocellulose any one or it is two or more
Mixture.
7. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that described organic toner is the fine arts
Red or lithol rubine or permanent bordeaux FGR or Fast Yellow 10G or permanent yellow 5GX or forever solid orange or phthalocyanine green or phthalocyanine blue or forever
Gu purple or fluorescent red or lucifer yellow or fluorescent are blue or fluorescent is green or fluorescent is pink or fluorescent is purple.
8. colorful high elastic antibacterial environment protection wax crayon according to claim 2, it is characterised in that the inorganic pigment is titanium dioxide
Or carbon black or iron oxide red or pearl essence or medium chrome yellow or luminescent powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710686806.4A CN107325646A (en) | 2017-08-11 | 2017-08-11 | Colorful high elastic antibacterial environment protection wax crayon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710686806.4A CN107325646A (en) | 2017-08-11 | 2017-08-11 | Colorful high elastic antibacterial environment protection wax crayon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107325646A true CN107325646A (en) | 2017-11-07 |
Family
ID=60225710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710686806.4A Pending CN107325646A (en) | 2017-08-11 | 2017-08-11 | Colorful high elastic antibacterial environment protection wax crayon |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107325646A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533005A (en) * | 2010-12-30 | 2012-07-04 | 刘颖 | Colorful high-elastoplastic pen and making method thereof |
| CN102558969A (en) * | 2012-01-06 | 2012-07-11 | 深圳云之彩美术工艺用品有限公司 | Low volatile organic compound (VOC) green crayon |
| CN104292985A (en) * | 2014-09-18 | 2015-01-21 | 中山市品汇创新专利技术开发有限公司 | Negative ion lavender-scented crayons |
| CN104908510A (en) * | 2015-06-24 | 2015-09-16 | 江苏海事职业技术学院 | Environment-friendly crayon |
| CN106833134A (en) * | 2015-12-04 | 2017-06-13 | 青岛宏致复合织造有限公司 | A kind of antibacterial wax crayon of environment-friendly degradable |
-
2017
- 2017-08-11 CN CN201710686806.4A patent/CN107325646A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533005A (en) * | 2010-12-30 | 2012-07-04 | 刘颖 | Colorful high-elastoplastic pen and making method thereof |
| CN102558969A (en) * | 2012-01-06 | 2012-07-11 | 深圳云之彩美术工艺用品有限公司 | Low volatile organic compound (VOC) green crayon |
| CN104292985A (en) * | 2014-09-18 | 2015-01-21 | 中山市品汇创新专利技术开发有限公司 | Negative ion lavender-scented crayons |
| CN104908510A (en) * | 2015-06-24 | 2015-09-16 | 江苏海事职业技术学院 | Environment-friendly crayon |
| CN106833134A (en) * | 2015-12-04 | 2017-06-13 | 青岛宏致复合织造有限公司 | A kind of antibacterial wax crayon of environment-friendly degradable |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5008719B2 (en) | Aqueous pigment formulation | |
| CN100575434C (en) | Composite printing ink of plastic intaglio printing | |
| CN101240099A (en) | Resin clay composition | |
| CN107523141A (en) | A kind of preparation method of high-elastic environmentally friendly wax crayon | |
| CN109504182A (en) | A kind of UV cure offset printing color shifting ink and its preparation method and application | |
| CN101831218B (en) | Environment-friendly dustless biochemical chalk and making method thereof | |
| KR20180063630A (en) | Capsule for play | |
| US3853797A (en) | Polyvinyl acetate /dextrin/ c to c polyhydric alcohols material for novelty items and arts and crafts applications | |
| CN107325646A (en) | Colorful high elastic antibacterial environment protection wax crayon | |
| KR20080009376A (en) | Thermochromic polymer clay and method for manufacturing thereof | |
| CN107384028A (en) | A kind of preparation method of antibacterial environment protection wax crayon | |
| JP5091436B2 (en) | crayon | |
| CN108102266A (en) | A kind of ultralight clay and preparation method thereof | |
| CN103692818A (en) | Food-grade scrawling chalk and preparation method thereof | |
| CN102002284B (en) | Photosensitized oxidation delible ink composite | |
| CN106007476A (en) | Antibacterial air-breathable sand composition and preparation method thereof | |
| CN106833134A (en) | A kind of antibacterial wax crayon of environment-friendly degradable | |
| TW202033683A (en) | Method for manufacturing environmentally friendly water-based ink wherein the water-based ink is mainly printed on PET, CPP or OPP plastic films used in food or sanitary product packaging | |
| CN110494298A (en) | Erasing tool | |
| CN1392203B (en) | Engraved intaglo printing pearlite ink and producing technology | |
| CN108219595A (en) | A kind of polyvinyl chloride environmental protection mill base | |
| CN103666027A (en) | Blended waterborne photocurable resin material and preparation method thereof | |
| CN110016253A (en) | A kind of PE//compound PE novel gravure composite inks for plastics and preparation method thereof | |
| CN102807788A (en) | High-adhesion ink | |
| JPH0433970A (en) | Solid painting material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171107 |
|
| RJ01 | Rejection of invention patent application after publication |