CN107325484A - A kind of enhanced power gold utensil material of weather-resistance flame-retardant and preparation method thereof - Google Patents

A kind of enhanced power gold utensil material of weather-resistance flame-retardant and preparation method thereof Download PDF

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Publication number
CN107325484A
CN107325484A CN201710537429.8A CN201710537429A CN107325484A CN 107325484 A CN107325484 A CN 107325484A CN 201710537429 A CN201710537429 A CN 201710537429A CN 107325484 A CN107325484 A CN 107325484A
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Prior art keywords
parts
weather
gold utensil
enhanced power
resistance flame
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Inventor
杨自芬
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Hefei Zhuo Zhuo Electric Power Co Ltd
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Hefei Zhuo Zhuo Electric Power Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of enhanced power gold utensil material of weather-resistance flame-retardant, belong to electric armour clamp technical field, include the raw material of following parts by weight:55 65 parts of Lauxite, 20 25 parts of acrylic resin, 79 parts of epoxidized methyl acetorieinoleate, 12 18 parts of nitrile rubber, 14 16 parts of fluorubber, 12 14 parts of carbon fiber, 13 15 parts of steel fibre, 79 parts of glass fibre, 35 parts of aluminium hydroxide, 26 parts of silicon nitride, 57 parts of white fused alumina micro mist, 10 12 parts of epoxidized soybean oil, 17 21 parts of plasticizer, 12 parts of antioxidant, 35 parts of lubricant;The invention also discloses a kind of preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant;The present invention is prepared simply, with preferably toughness, weatherability, anti-flammability and wearability.

Description

A kind of enhanced power gold utensil material of weather-resistance flame-retardant and preparation method thereof
Technical field
The present invention relates to electric armour clamp technical field, specifically, a kind of enhanced power gold of weather-resistance flame-retardant relate to Has material and preparation method thereof.
Background technology
Gold utensil is that power transmission line is widely used iron or aluminum metal-ware, is referred to as gold utensil.Most of gold utensil is in operation Middle to need to bear larger pulling force, what is had will also be while ensure that electrically aspect contact is good.But gold utensil uses metal material cost Height, and insulating properties is poor, so, for the purpose of energy-saving and emission-reduction, develop new easy processing, recyclable plastics electric armour clamp material Material has important practical significance.
In Publication No. CN106543716A patent document, a kind of high purity carbon fiberreinforced PA66/PP electric power is disclosed Gold utensil material, and its preparation technology, it is characterised in that with PA66, carbon fiber, glass fibre, polypropylene, melamine cyanurate Salt, Firebrake ZB, hypo-aluminum orthophosphate, bamboo charcoal, silicon rubber, aqueous polyurethane, maleic anhydride inoculated polypropylene, bovine serum albumin(BSA) are molten Liquid, crystal whisker of hexa potassium titanate, graphene oxide, multi-walled carbon nanotube, epoxy resin, hollow glass micropearl, the fourth of phthalic acid two Ester, dimethicone, polyamide, maleic anhydride grafting POE etc. are raw material.The invention is using Firebrake ZB to melamine cyanurate Salt is coated, and obtains composite flame-retardant agent;With bovine serum albumin(BSA) modified glass-fiber surface, oxygen is prepared using electrostatic absorption principle The glass fiber compound material of graphite cladding;Fibre reinforced PA66 has excellent mechanical property, self lubricity and conduction Performance;Obtain a kind of high purity carbon fiberreinforced PA66/PP electric armour clamps material.
The weather-resistance flame-retardant performance of above-mentioned high purity carbon fiberreinforced PA66/PP electric armour clamps material is not enough, however it remains lifting Space.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of enhanced power of weather-resistance flame-retardant Gold utensil material and preparation method thereof, is prepared simply, with preferably toughness, weatherability, anti-flammability and wearability.
A kind of enhanced power gold utensil material for weather-resistance flame-retardant that the present invention is provided, includes the raw material of following parts by weight:
55-65 parts of Lauxite, 20-25 parts of acrylic resin, 7-9 parts of epoxidized methyl acetorieinoleate, nitrile rubber 12-18 parts, 14-16 parts of fluorubber, 12-14 parts of carbon fiber, 13-15 parts of steel fibre, 7-9 parts of glass fibre, aluminium hydroxide 3-5 Part, 2-6 parts of silicon nitride, 5-7 parts of white fused alumina micro mist, 10-12 parts of epoxidized soybean oil, 17-21 parts of plasticizer, 1-2 parts of antioxidant, profit 3-5 parts of lubrication prescription.
Preferably, the length of glass fibre, steel fibre and carbon fiber is 1-2mm, diameter is 0.5-1mm.
Preferably, the mesh number of aluminium hydroxide is 200 mesh, the mesh number of silicon nitride is 300 mesh, and white fused alumina micro mist is 400 mesh.
Preferably, plasticizer is triethyl citrate, ATBC, tributyl 2-acetylcitrate, citric acid three Monooctyl ester, ATOC, citric acid tri-n-hexyl ester, one or two or more kinds of mixing of ATHC Thing.
Preferably, antioxidant is the mixture of Hinered phenols antioxidant and auxiliary antioxidant, weight ratio between the two For 3:1;Hinered phenols antioxidant is 2,6- three-level butyl -4- methylphenols, double thioether, one kind of tetrapentaerythritol ester or two kinds Mixture above, auxiliary antioxidant is double Lauryl Alcohol esters, double ten four carbon alcohols esters and one kind of double octadecanol esters or two kinds Mixture above.
Preferably, lubricant is silicone oil, white oil, stearic acid, butyl stearate, oleamide, ethylene bis stearamide One or two or more kinds of mixtures.
Present invention also offers a kind of preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant, including following step Suddenly:
(1) various raw materials, are weighed by above-mentioned parts by weight;
(2), by Lauxite, acrylic resin, epoxidized methyl acetorieinoleate, carbon fiber, steel fibre, glass fibers Dimension, aluminium hydroxide, silicon nitride, white fused alumina micro mist, epoxidized soybean oil, plasticizer and lubricant are added in high-speed mixer, are mixed 4-6min is closed, mixture is obtained, mixture is then put into extruding pelletization in double screw extruder, pellet is obtained;
(3), the pellet and nitrile rubber in step (2), fluorubber are mixed, put into banbury, banburying 15- After 20min, antioxidant, then banburying 20min are added;
(4) carried out after the compound that banburying is obtained, is transported into double screw extruder extrusion processing, extrusion on vulcanizer Vulcanization, is dried after vulcanization.
Wherein,
The temperature of double screw extruder in step (4) is:180 DEG C of first paragraph, 200 DEG C of second segment, the 3rd section 230 DEG C.
The mixing velocity of high-speed mixer in step (2) is 400r/min.
A kind of enhanced power gold utensil material of weather-resistance flame-retardant and preparation method thereof of the present invention, prepare it is simple, with compared with Good ground toughness, weatherability, anti-flammability and wearability, specifically have the beneficial effect that:
(1), Lauxite causes plastics to have preferably resistance to acids and bases, insulating properties, wearability;Epoxy acetylricinoleate oleic acid Methyl esters can increase the plasticity of material;Nitrile rubber oil resistant, ageing-resistant performance are good, also with water resistance, air-tightness and excellent viscous Performance is tied, the weatherability of material can be greatly improved;It is fluorubber high temperature resistant, oil resistant, resistant to chemical etching, further improve the resistance to of material Hou Xing;
(2), steel fibre can greatly improve the physical strength of material;Glass fibre can improve the impact strength of material and tough Property, also improve temperature capacity;Carbon fiber have good good electrical and thermal conductivity performance, electromagnetic wave shielding, high temperature resistant, it is corrosion-resistant, Intensity is high, can greatly enhance the performance of material;
(3), the addition of aluminium hydroxide, silicon nitride and white fused alumina micro mist can improve the fire resistance of material, can also improve material The anti-wear performance and physical strength of material;
(4), plasticizer can improve the plasticity of material, the physical strength of reinforcement material;Antioxidant can improve the durable of material Property.
(5), the mixing of various raw materials correspondence ratio of the invention cause material that there is intensity height, it is good wearability, acid and alkali-resistance, resistance to Time, high temperature resistant, it is fire-retardant the features such as;And preparation method is simple, it can stablize, effectively prepare gold utensil material.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1
A kind of enhanced power gold utensil material of weather-resistance flame-retardant of the present embodiment, includes the raw material of following parts by weight:
55 parts of Lauxite, 20 parts of acrylic resin, 7 parts of epoxidized methyl acetorieinoleate, 12 parts of nitrile rubber, fluorine rubber 14 parts of glue, 12 parts of carbon fiber, 13 parts of steel fibre, 7 parts of glass fibre, 3 parts of aluminium hydroxide, 2 parts of silicon nitride, 5 parts of white fused alumina micro mist, 10 parts of epoxidized soybean oil, 17 parts of plasticizer, 1 part of antioxidant, 3 parts of lubricant.
In the present embodiment, the length of glass fibre, steel fibre and carbon fiber is 1mm, and diameter is 0.5mm.
In the present embodiment, the mesh number of aluminium hydroxide is 200 mesh, and the mesh number of silicon nitride is 300 mesh, and white fused alumina micro mist is 400 Mesh.
In the present embodiment, plasticizer is triethyl citrate, ATBC, tributyl 2-acetylcitrate, citric acid Three monooctyl esters, ATOC, citric acid tri-n-hexyl ester, the mixture of ATHC.
In the present embodiment, antioxidant is the mixture of Hinered phenols antioxidant and auxiliary antioxidant, weight between the two Than for 3:1;Hinered phenols antioxidant is 2,6- three-level butyl -4- methylphenols, double thioether, the mixture of tetrapentaerythritol ester, Auxiliary antioxidant is the mixture of double Lauryl Alcohol esters, double ten four carbon alcohols esters and double octadecanol esters.
In the present embodiment, lubricant is silicone oil, white oil, stearic acid, butyl stearate, oleamide, ethylene bis stearamide Mixture.
The present embodiment additionally provides a kind of preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant, including following step Suddenly:
(1) various raw materials, are weighed by above-mentioned parts by weight;
(2), by Lauxite, acrylic resin, epoxidized methyl acetorieinoleate, carbon fiber, steel fibre, glass fibers Dimension, aluminium hydroxide, silicon nitride, white fused alumina micro mist, epoxidized soybean oil, plasticizer and lubricant are added in high-speed mixer, are mixed 4min is closed, mixture is obtained, mixture is then put into extruding pelletization in double screw extruder, pellet is obtained;
(3), the pellet and nitrile rubber in step (2), fluorubber are mixed, put into banbury, banburying 15min Afterwards, antioxidant, then banburying 20min are added;
(4) carried out after the compound that banburying is obtained, is transported into double screw extruder extrusion processing, extrusion on vulcanizer Vulcanization, is dried after vulcanization.
Wherein,
The temperature of double screw extruder in step (4) is:180 DEG C of first paragraph, 200 DEG C of second segment, the 3rd section 230 DEG C.
The mixing velocity of high-speed mixer in step (2) is 400r/min.
Embodiment 2
A kind of enhanced power gold utensil material of weather-resistance flame-retardant of the present embodiment, includes the raw material of following parts by weight:
60 parts of Lauxite, 23 parts of acrylic resin, 8 parts of epoxidized methyl acetorieinoleate, 15 parts of nitrile rubber, fluorine rubber 15 parts of glue, 13 parts of carbon fiber, 14 parts of steel fibre, 8 parts of glass fibre, 4 parts of aluminium hydroxide, 4 parts of silicon nitride, 6 parts of white fused alumina micro mist, 13 parts of epoxidized soybean oil, 19 parts of plasticizer, 1.5 parts of antioxidant, 4 parts of lubricant.
In the present embodiment, the length of glass fibre, steel fibre and carbon fiber is 1.5mm, and diameter is 0.8mm.
In the present embodiment, the mesh number of aluminium hydroxide is 200 mesh, and the mesh number of silicon nitride is 300 mesh, and white fused alumina micro mist is 400 Mesh.
In the present embodiment, plasticizer is triethyl citrate, ATBC, tributyl 2-acetylcitrate, citric acid Three monooctyl esters, ATOC, citric acid tri-n-hexyl ester, the mixture of ATHC.
In the present embodiment, antioxidant is the mixture of Hinered phenols antioxidant and auxiliary antioxidant, weight between the two Than for 3:1;Hinered phenols antioxidant is 2,6- three-level butyl -4- methylphenols, double thioether, the mixture of tetrapentaerythritol ester, Auxiliary antioxidant is the mixture of double Lauryl Alcohol esters, double ten four carbon alcohols esters and double octadecanol esters.
In the present embodiment, lubricant is silicone oil, white oil, stearic acid, butyl stearate, oleamide, ethylene bis stearamide Mixture.
The present embodiment additionally provides a kind of preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant, including following step Suddenly:
(1) various raw materials, are weighed by above-mentioned parts by weight;
(2), by Lauxite, acrylic resin, epoxidized methyl acetorieinoleate, carbon fiber, steel fibre, glass fibers Dimension, aluminium hydroxide, silicon nitride, white fused alumina micro mist, epoxidized soybean oil, plasticizer and lubricant are added in high-speed mixer, are mixed 5min is closed, mixture is obtained, mixture is then put into extruding pelletization in double screw extruder, pellet is obtained;
(3), the pellet and nitrile rubber in step (2), fluorubber are mixed, put into banbury, banburying 18min Afterwards, antioxidant, then banburying 20min are added;
(4) carried out after the compound that banburying is obtained, is transported into double screw extruder extrusion processing, extrusion on vulcanizer Vulcanization, is dried after vulcanization.
Wherein,
The temperature of double screw extruder in step (4) is:180 DEG C of first paragraph, 200 DEG C of second segment, the 3rd section 230 DEG C.
The mixing velocity of high-speed mixer in step (2) is 400r/min.
Embodiment 3
A kind of enhanced power gold utensil material of weather-resistance flame-retardant of the present embodiment, includes the raw material of following parts by weight:
65 parts of Lauxite, 25 parts of acrylic resin, 9 parts of epoxidized methyl acetorieinoleate, 18 parts of nitrile rubber, fluorine rubber 16 parts of glue, 14 parts of carbon fiber, 15 parts of steel fibre, 9 parts of glass fibre, 5 parts of aluminium hydroxide, 6 parts of silicon nitride, 7 parts of white fused alumina micro mist, 12 parts of epoxidized soybean oil, 21 parts of plasticizer, 2 parts of antioxidant, 5 parts of lubricant.
In the present embodiment, the length of glass fibre, steel fibre and carbon fiber is 2mm, and diameter is 1mm.
In the present embodiment, the mesh number of aluminium hydroxide is 200 mesh, and the mesh number of silicon nitride is 300 mesh, and white fused alumina micro mist is 400 Mesh.
In the present embodiment, plasticizer is triethyl citrate, ATBC, tributyl 2-acetylcitrate, citric acid Three monooctyl esters, ATOC, citric acid tri-n-hexyl ester, the mixture of ATHC.
In the present embodiment, antioxidant is the mixture of Hinered phenols antioxidant and auxiliary antioxidant, weight between the two Than for 3:1;Hinered phenols antioxidant is 2,6- three-level butyl -4- methylphenols, double thioether, the mixture of tetrapentaerythritol ester, Auxiliary antioxidant is the mixture of double Lauryl Alcohol esters, double ten four carbon alcohols esters and double octadecanol esters.
In the present embodiment, lubricant is silicone oil, white oil, stearic acid, butyl stearate, oleamide, ethylene bis stearamide Mixture.
The present embodiment additionally provides a kind of preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant, including following step Suddenly:
(1) various raw materials, are weighed by above-mentioned parts by weight;
(2), by Lauxite, acrylic resin, epoxidized methyl acetorieinoleate, carbon fiber, steel fibre, glass fibers Dimension, aluminium hydroxide, silicon nitride, white fused alumina micro mist, epoxidized soybean oil, plasticizer and lubricant are added in high-speed mixer, are mixed 6min is closed, mixture is obtained, mixture is then put into extruding pelletization in double screw extruder, pellet is obtained;
(3), the pellet and nitrile rubber in step (2), fluorubber are mixed, put into banbury, banburying 20min Afterwards, antioxidant, then banburying 20min are added;
(4) carried out after the compound that banburying is obtained, is transported into double screw extruder extrusion processing, extrusion on vulcanizer Vulcanization, is dried after vulcanization.
Wherein,
The temperature of double screw extruder in step (4) is:180 DEG C of first paragraph, 200 DEG C of second segment, the 3rd section 230 DEG C.
The mixing velocity of high-speed mixer in step (2) is 400r/min.
Embodiment 1-3 testing result is as follows:
Embodiment 1 Embodiment 2 Embodiment 3
Fracture strength, MPa 212 214 214
Elongation at break, % 2.8 2.8 2.9
Impact strength, J/mm2 23.7 23.8 23.9
Bending strength, MPa 140.5 140.8 141.0
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (9)

1. a kind of enhanced power gold utensil material of weather-resistance flame-retardant, it is characterised in that:Include the raw material of following parts by weight:
55-65 parts of Lauxite, 20-25 parts of acrylic resin, 7-9 parts of epoxidized methyl acetorieinoleate, nitrile rubber 12-18 Part, 14-16 parts of fluorubber, 12-14 parts of carbon fiber, 13-15 parts of steel fibre, 7-9 parts of glass fibre, 3-5 parts of aluminium hydroxide, nitridation 2-6 parts of silicon, 5-7 parts of white fused alumina micro mist, 10-12 parts of epoxidized soybean oil, 17-21 parts of plasticizer, 1-2 parts of antioxidant, lubricant 3-5 Part.
2. the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1, it is characterised in that:Glass fibre, steel The length of fiber and carbon fiber is 1-2mm, and diameter is 0.5-1mm.
3. the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1, it is characterised in that:The mesh of aluminium hydroxide Number is 200 mesh, and the mesh number of silicon nitride is 300 mesh, and white fused alumina micro mist is 400 mesh.
4. the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1, it is characterised in that:Plasticizer is lemon Triethylenetetraminehexaacetic acid ester, ATBC, tributyl 2-acetylcitrate, trioctyl lemon acid, ATOC, citric acid three One or two or more kinds of mixtures of just own ester, ATHC.
5. the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1, it is characterised in that:Antioxidant is to be obstructed The mixture of phenolic antioxidant and auxiliary antioxidant, weight ratio between the two is 3:1;Hinered phenols antioxidant is 2,6- three-levels Butyl -4- methylphenols, double thioether, one or two or more kinds of mixtures of tetrapentaerythritol ester, auxiliary antioxidant are double ten One or two or more kinds of mixtures of two carbon alcohol esters, double ten four carbon alcohols esters and double octadecanol esters.
6. the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1, it is characterised in that:Lubricant is silicon Oil, white oil, stearic acid, butyl stearate, oleamide, one or two or more kinds of mixtures of ethylene bis stearamide.
7. a kind of preparation side of the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 1-6 any one Method, it is characterised in that:Comprise the following steps:
(1) various raw materials, are weighed by above-mentioned parts by weight;
(2), by Lauxite, acrylic resin, epoxidized methyl acetorieinoleate, carbon fiber, steel fibre, glass fibre, hydrogen Aluminum oxide, silicon nitride, white fused alumina micro mist, epoxidized soybean oil, plasticizer and lubricant are added in high-speed mixer, mix 4- 6min, obtains mixture, and mixture then is put into extruding pelletization in double screw extruder, pellet is obtained;
(3), the pellet and nitrile rubber in step (2), fluorubber are mixed, put into banbury, after banburying 15-20min, Add antioxidant, then banburying 20min;
(4) sulphur is carried out on vulcanizer after the compound that banburying is obtained, is transported into double screw extruder extrusion processing, extrusion Change, dried after vulcanization.
8. the preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 7, it is characterised in that:Step Suddenly the temperature of the double screw extruder in (4) is:180 DEG C of first paragraph, 200 DEG C of second segment, the 3rd section 230 DEG C.
9. the preparation method of the enhanced power gold utensil material of weather-resistance flame-retardant according to claim 7, it is characterised in that:Step Suddenly the mixing velocity of the high-speed mixer in (2) is 400r/min.
CN201710537429.8A 2017-07-04 2017-07-04 A kind of enhanced power gold utensil material of weather-resistance flame-retardant and preparation method thereof Withdrawn CN107325484A (en)

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Publication number Priority date Publication date Assignee Title
CN111978813A (en) * 2020-08-07 2020-11-24 红旗集团电力金具有限公司 High-strength strain clamp and processing technology thereof
CN112080068A (en) * 2020-08-29 2020-12-15 盐城工学院 Flame-retardant composite material for new energy automobile interior and preparation method thereof

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Application publication date: 20171107