CN107318842A - A kind of rice seed treating agent - Google Patents

A kind of rice seed treating agent Download PDF

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Publication number
CN107318842A
CN107318842A CN201710352834.2A CN201710352834A CN107318842A CN 107318842 A CN107318842 A CN 107318842A CN 201710352834 A CN201710352834 A CN 201710352834A CN 107318842 A CN107318842 A CN 107318842A
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CN
China
Prior art keywords
rice
treating agent
agent
rice seed
seed treating
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CN201710352834.2A
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Chinese (zh)
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CN107318842B (en
Inventor
吴仁海
鲁传涛
苏旺苍
徐洪乐
薛飞
魏红梅
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Institute of Plant Protection of Henan Academy of Agricultural Sciences
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Institute of Plant Protection of Henan Academy of Agricultural Sciences
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring

Abstract

A kind of rice seed treating agent, it is made up of active ingredient and auxiliary agent, the quality of the active ingredient accounts for the 5~85% of rice seed treating agent gross mass, the active ingredient is Shuan Ben oxazoles formic acid and gibberellin, and the auxiliary agent is the three kinds or more in surfactant, solvent, suspending agent and antifreezing agent.A kind of rice seed treating agent that the present invention is provided, Rice seeds treated, the drug resistance of the herbicides such as rice seedling Dui fenoxaprops can be improved, herbicide is improved to the selectivity between the malignant weeds such as paddy rice and Weedy Rice, ensure rice seedling rate, influence when reduction Shuan Ben oxazole formic acid is individually handled to Germination Percentage of Rice.

Description

A kind of rice seed treating agent
Technical field
The present invention relates to technical field of pesticide, and in particular to a kind of rice seed treating agent.
Background technology
Paddy rice is one of main cereal crops in the world, and paddy field weed is serious, and wherein grassy weed preventing and treating is difficult, water Rice field is efficient, safety, selective good gramineous weed weedicide have wide market prospects and commercial value.
Fenoxaprop is higher to grassy weed preventive effect, but poor to Security of rice for the rice seedling phase, Easily there is poisoning when the rice seedlings such as seedling field or direct sowing rice field are more immature.
Isoxadifen ethyl ester, English name:Isoxadifen-ethyl, No. CAS:163520-33-0, molecular formula: C18H17NO3, chemical name:4,5- dihydro -5,5- diphenyl -1,2- azoles -3- carboxylic acid, ethyl esters, are a kind of safeners, are usually used in carrying Drug resistance of the high corn to herbicide.Safener has stronger selectivity, and using effect has very big difference in Different Crop.
Shuan Ben oxazole formic acid, English name:Isoxadifen (free acid), No. CAS:209866-92-2, molecular formula: C16H13NO3, chemical name:4,5- dihydro -5,5- diphenyl -1,2- azoles -3- formic acid, also known as Shuan Ben oxazole formic acid, Shuan Ben oxazoles Sour (free acid), is isoxadifen ethyl ester hydrolysate, also available for safener.
Gibberellin is a plant growth regulators, has promotion seed breaking dormancy, promotes the effect such as plant growth.
Rice safety agent isoxadifen ethyl ester is used in after seedling, the drug resistance of paddy rice Dui fenoxaprops can be improved, But the drug resistance of Dui fenoxaprops also rises after such as Weedy Rice weeds touch-safe agent;Use rice safety agent Shuan Ben Evil Azoles acetoacetic ester handles seed, the weeds touch-safe agent such as Weedy Rice can be avoided, however, during isoxadifen ethyl ester seed treatment not Easily absorb, it is impossible to effectively protect paddy rice from poisoning.It can be played a protective role during Shuan Ben oxazole formic acid seed treatments, but to paddy rice Emergence rate has suppression.
The content of the invention
It is an object of the invention to provide a kind of resistance for ensureing rice seedling rate and improving rice seedlings Dui fenoxaprops The rice seed treating agent of property.
A kind of rice seed treating agent, is made up of active ingredient and auxiliary agent, and the quality of the active ingredient accounts for rice paddy seed The 5~85% of inorganic agent gross mass, the active ingredient is Shuan Ben oxazoles formic acid and gibberellin, and the auxiliary agent is surface-active Three kinds or more in agent, solvent, suspending agent and antifreezing agent.
Further, the quality of the active ingredient accounts for the 5~40% of rice seed treating agent gross mass.
Further, the quality of the Shuan Ben oxazole formic acid accounts for the 0.5~80% of rice seed treating agent gross mass, red mould The quality of element accounts for the 0.01~5% of rice seed treating agent gross mass.
Further, the surfactant is Tween 80, naphthalenesulfonate formaldehyde condensation compound and lignin and its sulfonate The one or more of derivative.
Further, the suspending agent is gelatin, xanthans, polyvinyl alcohol, sodium carboxymethylcellulose, natural gum, magnesium silicate Aluminium, bentonitic one or more.
Further, the solvent is alcohols and/or water.
Further, the antifreezing agent is ethylene glycol or glycerine.
Further, the formulation of the rice seed treating agent is aqueous suspension agent or aqueous suspension seed coat agent.
Further, when the formulation of the rice seed treating agent is aqueous suspension seed coat agent, rice seed treating agent is also Including warning colorant, the warning colorant is rose-red colorant.
Beneficial effects of the present invention are:
1st, after the rice seed treating agent Rice seeds treated that the present invention is provided, rice seedling Dui fenoxaprops etc. can be improved The drug resistance of herbicide, rice inhibiting rate is less than 10%.
2nd, after the rice seed treating agent Rice seeds treated that the present invention is provided, herbicide is improved to paddy rice and Weedy Rice etc. Selectivity between malignant weed.
3rd, active ingredient of the present invention is Shuan Ben oxazoles formic acid and gibberellin, can ensure rice seedling rate, reduces Shuan Ben oxazoles To the influence of Germination Percentage of Rice when formic acid is individually handled.
Embodiment
With reference to embodiment, the invention will be further described:
Embodiment 1
A kind of rice seed treating agent, formulation is aqueous suspension seed coat agent, by mass percentage, and Shuan Ben oxazoles formic acid is 10%, Gibberellin is 0.06%, and Tween 80 is 2%, and aluminium-magnesium silicate is 2%, and sodium carboxymethylcellulose is 0.2%, and xanthans is 0.05%, propane diols is 10%, and rose-red colorant is 2%, and water is 73.69%.Above-mentioned raw material are agitated, shear, sand is ground, mistake The step of seed coat agent is routinely prepared in filter etc. is processed into rice seed treating agent.
Embodiment 2
A kind of rice seed treating agent, formulation is aqueous suspension seed coat agent, by mass percentage, and Shuan Ben oxazoles formic acid is 20%, Gibberellin is 0.1%, and Tween 80 is 2%, and aluminium-magnesium silicate is 2%, and polyvinyl alcohol is 0.5%, and xanthans is 0.05%, propane diols For 10%, rose-red colorant is 2%, and water is 63.35%.Above-mentioned raw material are agitated, shearing, husky mill, filtering etc. are routinely matched somebody with somebody The step of seed coat agent processed, is processed into rice seed treating agent.
Embodiment 3
A kind of rice seed treating agent, formulation is aqueous suspension seed coat agent, by mass percentage, and Shuan Ben oxazoles formic acid is 40%, Gibberellin is 0.5%, and Tween 80 is 2%, and aluminium-magnesium silicate is 2%, and sodium carboxymethylcellulose is 0.2%, and xanthans is 0.05%, Propane diols is 10%, and rose-red colorant is 2%, and water is 43.25%.Above-mentioned raw material are agitated, shearing, husky mill, filtering etc. are pressed The step of seed coat agent is formulated conventionally is processed into rice seed treating agent.
Embodiment 4
A kind of rice seed treating agent, formulation is aqueous suspension agent, by mass percentage, and Shuan Ben oxazoles formic acid is 5%, gibberellin For 0.01%, Tween 80 is 2%, and aluminium-magnesium silicate is 2%, and sodium lignin sulfonate is 1%, and natural gum is 2%, and propane diols is 10%, Water is 77.99%.The step of above-mentioned raw material are agitated, aqueous suspension agent is routinely prepared in shearing, husky mill, filtering etc. is processed into water Rice inorganic agent.
Embodiment 5
A kind of rice seed treating agent, formulation is aqueous suspension agent, by mass percentage, and Shuan Ben oxazoles formic acid is 10%, red mould Element is 0.2%, and Tween 80 is 2%, and bentonite is 2%, and sodium lignin sulfonate is 1%, and sodium carboxymethylcellulose is 0.2%, third Triol is 8%, and water is 76.6%.Above-mentioned raw material are agitated, the step of aqueous suspension agent is routinely prepared in shearing, husky mill, filtering etc. Suddenly it is processed into rice seed treating agent.
Embodiment 6
A kind of rice seed treating agent, formulation is aqueous suspension agent, by mass percentage, and Shuan Ben oxazoles formic acid is 50%, red mould Element is 0.5%, and Tween 80 is 2%, and aluminium-magnesium silicate is 2%, and naphthalenesulfonate formaldehyde condensation compound is 1%, and sodium carboxymethylcellulose is 0.2%, ethylene glycol is 10%, and water is 34.3%.Above-mentioned raw material are agitated, shearing, husky mill, filtering etc. are routinely prepared water and hanged The step of floating agent, is processed into rice seed treating agent.
Embodiment 7 is to Security of rice indoor measurement
Method:Indoor pot experiment method.Air-dried, sieving field soil is taken, basin is filled;Indoor pot experiment sets 9 groups:
1st group:The rice seed treating agent 20g of embodiment 1 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
2nd group:The rice seed treating agent 10g of embodiment 2 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
3rd group:The rice seed treating agent 10g of embodiment 3 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
4th group:The rice seed treating agent 40g of embodiment 4 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
5th group:The rice seed treating agent 20g of embodiment 5 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
6th group:The rice seed treating agent 10g of embodiment 6 is weighed, 80g is added water to, adds and is stirred in 1kg rice paddy seeds;
7th group:2g bis- Ben oxazole formic acid is weighed, is dissolved in 20g ethyl acetate, is slowly dropped under stirring in seed;
8th group (blank control 1):80g water is weighed, adds and is stirred in 1kg rice paddy seeds;
9th group (blank control 2):80g water is weighed, adds and is stirred in 1kg rice paddy seeds;
Above-mentioned 9 groups of treated rice paddy seeds are sown into soil after drying in the shade, and 10, culture to the heart stage of 1 leaf 1, the 1st group are sowed per basin Fenoxaprop 0.2g/L is sprayed to the 8th group, 30kg/ mus of spouting liquid, the 9th group is set to not spray fenoxaprop pair According to each processing is repeated 3 times.15d investigates paddy rice fresh weight after medicine, calculates fresh weight inhibition and remission rate.
It the results are shown in Table 1.The rice seedling phase sprays 6g/ mus of fenoxaprop, produces serious poisoning, and growth stops, lobus cardiacus Withered, fresh weight inhibition is up to 77.55%.1st group to the 6th group is carried out at seed using the rice seed treating agent of embodiment 1~6 Reason can significantly improve the resistance of rice seedling Dui fenoxaprops, and rice inhibiting rate is less than 10%.And the 7th group is to be used alone Shuan Ben oxazoles formic acid has suppression to rice seedlings growth, and rice growth is not so good as the 1st group to the 6th group.
Alleviation protecting effect of the different rice seed treating agents of table 1 to Shui Dao fenoxaprop poisoning.
Group Paddy rice fresh weight (g/ basins) Fresh weight inhibition (%) Remission rate (%)
1st group 1.6804 9.22 88.11
2nd group 1.7281 6.64 91.43
3rd group 1.7146 7.37 90.49
4th group 1.7037 7.96 89.73
5th group 1.6946 8.45 89.10
6th group 1.7547 5.21 93.29
7th group 1.1272 39.11 49.58
8th group 0.4155 77.55
9th group 1.8511
The field plot trial of embodiment 8
Experiment is carried out in Henan Yuanyang, field prepartion of land, and fertility is suitable, and soil moisture is moderate.During preparing soil in rice field, uniformly it is sprinkled into Weeds rice, 1kg/ mus of application rate harrows even rear sowing cultivated rice.Cultivate before seed rice sowing, the rice seed treating agent of embodiment 6 Soaked seed, it is specific as follows:Weigh the rice seed treating agent of embodiment 6, with clear water dilute 100 times, 25 DEG C, by seed:Paddy rice Seed treatment ratio is 1:3 pairs of rice paddy seeds are soaked seed, and are stirred once per 6h, are pulled out and dry after 48h, and seeder carries out drought It is live, 8kg/ mus of application rate.After planting sprayed water with fine-spraying belt, keep ground moistening and without ponding.After planting 15d, the leaf of rice seedlings 3 1 heart stage, sprayed 2g/ mus of 6g/ mus+penoxsuam of fenoxaprop, and spray amount is 30kg/ mus, each 18 squares of plot area Rice, each processing is repeated 3 times, and indwelling check plot, and check plot does not spray fenoxaprop and penoxsuam.
7d, 14d, 21d after medicine, investigate each processing cultivated rice and its inter-row weed rice poisoning index.Before dispenser and after medicine 21d, 5 points of samplings of cell, investigates fresh weight.
Table 2 estimates cultivated rice poisoning class criteria
Table 3 estimates Weedy Rice poisoning class criteria
Poisoning rank Growth inhibition ratio (%)
0 0
1 1~15
2 16~25
3 26~35
4 36~45
5 46~55
6 56~65
7 66~75
8 76~85
9 86~100
The rice seed treating agent of table 4 seed soaking Dui fenoxaprops and the selective visual observation of penoxsuam
21d fresh weight measurement results after the medicine of table 5
From table 2- tables 5,7d, 14d, 21d after fenoxaprop and penoxsuam is sprayed are estimated miscellaneous to cultivated rice machine The poisoning rank of careless rice, as a result shows, 7d after medicine, 5 grades of Weedy Rice poisoning rank, growth inhibition;14d after medicine, Weedy Rice evil level Other 7 grades, lobus cardiacus is withered, stops growing;21d after medicine, Weedy Rice 8 grades of rank of evil is gradually withered.21d determines fresh weight, weeds after medicine Rice fresh weight inhibition is up to 76.88%, and cultivated rice suppresses to be only 6.71%.Result above shows, by entering to cultivation rice The processing of row rice seed treating agent, can improve selectivity of the fenoxaprop to cultivated rice and Weedy Rice.
Embodiment described above, simply presently preferred embodiments of the present invention, not limits the scope of the present invention, therefore All equivalent change or modifications done according to technical scheme described in the scope of the claims of the present invention, all should be included in the present patent application patent model In enclosing.

Claims (9)

1. a kind of rice seed treating agent, it is characterised in that rice seed treating agent is made up of active ingredient and auxiliary agent, described to have The quality of effect composition accounts for the 5~85% of rice seed treating agent gross mass, and the active ingredient is Shuan Ben oxazoles formic acid and red mould Element, the auxiliary agent is the three kinds or more in surfactant, solvent, suspending agent and antifreezing agent.
2. a kind of rice seed treating agent according to claim 1, it is characterised in that the quality of the active ingredient accounts for water The 5~40% of rice inorganic agent gross mass.
3. a kind of rice seed treating agent according to claim 1, it is characterised in that the quality of the Shuan Ben oxazole formic acid Account for the 0.5~80% of rice seed treating agent gross mass, the quality of gibberellin account for rice seed treating agent gross mass 0.01~ 5%.
4. a kind of rice seed treating agent according to claim 1, it is characterised in that the surfactant is tween 80th, the one or more of naphthalenesulfonate formaldehyde condensation compound and lignin and its sulfonate derivatives.
5. a kind of rice seed treating agent according to claim 1, it is characterised in that the suspending agent is gelatin, xanthan Glue, polyvinyl alcohol, sodium carboxymethylcellulose, natural gum, aluminium-magnesium silicate, bentonitic one or more.
6. a kind of rice seed treating agent according to claim 1, it is characterised in that the solvent is alcohols and/or water.
7. a kind of rice seed treating agent according to claim 1, it is characterised in that the antifreezing agent is ethylene glycol or third Triol.
8. a kind of rice seed treating agent according to claim 1, it is characterised in that the agent of the rice seed treating agent Type is aqueous suspension agent or aqueous suspension seed coat agent.
9. a kind of rice seed treating agent according to claim 8, it is characterised in that when the rice seed treating agent When formulation is aqueous suspension seed coat agent, rice seed treating agent also includes warning colorant, and the warning colorant is rose-red colorant.
CN201710352834.2A 2017-05-18 2017-05-18 A kind of rice seed treating agent Active CN107318842B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113099920A (en) * 2021-04-06 2021-07-13 江苏沿海地区农业科学研究所新洋试验站(盐城市新洋农业试验站) Artificial weedy rice removing method

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