CN107313061A - One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling - Google Patents
One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling Download PDFInfo
- Publication number
- CN107313061A CN107313061A CN201710576249.0A CN201710576249A CN107313061A CN 107313061 A CN107313061 A CN 107313061A CN 201710576249 A CN201710576249 A CN 201710576249A CN 107313061 A CN107313061 A CN 107313061A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- parts
- acid
- friendly cleaning
- neutral environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
Abstract
The present invention relates to cleaning agent technical field, a kind of neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling and preparation method thereof is specifically disclosed.6~10 parts of the cleaning agent citric acid, 2~5 parts of malic acid, 8~10 parts of ultra-pure water, 1~2 part of sodium gluconate, 5~10 parts of sodium citrate.The neutral environment-friendly cleaning agent of the present invention, all neutral environment-friendly materials of raw material used, smell is light, not phosphorous, without halogen, without flash-point, non-corrosiveness.The cleaning agent of the present invention is good, non-ignitable not quick-fried, strong using safety, cleaning force without influence, material compatibility on zero device of cleaning, not only but also environment will not be had any impact, also harmless to human body.
Description
Technical field
The present invention relates to cleaning agent technical field, specifically disclose it is a kind of substitute the neutral environment-friendly cleaning agent of chlorohydric acid pickling and its
Preparation method.
Background technology
The common dirt that steel product surface is commonly present has caused oxide skin in hot-working and heat treatment process, does not protect
Used under the conditions of shield and storage process in the iron rust that produces, in order to protect steel product and mineral oil, lubrication in surface smear
Oil, vegetable and animals oils etc..The presence of these dirts can influence acid pickling and rust removing and phosphatization quality, influence coating drying property and
Reduce the adhesive force of coating.Therefore equipment must carry out surface clean before, and otherwise the product quality that processed can be made
Into influence.
The cleaning performance of existing steel surface cleaning articles for use is not very good, is produced especially for steel surface
Oxidation film layer etc. be difficult to clean.In traditional handicraft, carried out when encountering oxide layer or rusty stain with hydrochloric acid or sulfuric acid at cleaning
Reason, causes substantial amounts of strongly acid wastewater, what is had stealthily drains, causes Heavy environmental pollution and environmental disruption, some big valencys of cost
Money establishes water treatment system, causes great economy to bear to operator.Simultaneously common cleaning agent is generally phosphorous, and phosphorus containg substances
It is not degradable, also easily cause environmental pollution.The neutral environment-friendly cleaning agent product using environment-friendly materials is developed, meets country right
In enterprise development to walk environment-friendly and green, the development model of environmental protection and energy saving requirement, meet the state of environmental protection and sustainable development
Family's strategy, with important practical significance.
The content of the invention
All it is to use strong acid treatment for traditional handicraft cleaning oxide layer in background technology and rusty stain, at produced waste water
Manage cost very high, inconvenient operation, it is dangerous big, the problem of also do not save not environmentally, salt is substituted the invention provides one kind
Pickling neutrality environment-friendly cleaning agent and preparation method thereof.
To achieve the above object, the neutral environmental protection of chlorohydric acid pickling is substituted clearly there is provided one kind as one aspect of the present invention
Lotion：One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, it is characterised in that including：Citric acid, malic acid, sodium gluconate,
Sodium citrate and ultra-pure water；Described citric acid, malic acid, sodium gluconate, the weight proportion of sodium citrate and ultra-pure water are
6~10 parts of citric acid, 2~5 parts of malic acid, 1~2 part of sodium gluconate, 5~10 parts of sodium citrate, 8~10 parts of ultra-pure water.
It is preferred that, described neutral environment-friendly cleaning agent can also add 0.2 part of essence.
It is preferred that, described neutral environment-friendly cleaning agent can also add 1~6 part of glycolic.
It is preferred that, described neutral environment-friendly cleaning agent can also add 0.2 part of potassium silicate.
It is preferred that, the pH value of the cleaning agent is 5~7.
As another aspect of the present invention, there is provided a kind of making side for substituting the neutral environment-friendly cleaning agent of chlorohydric acid pickling
Method, this method at least comprises the following steps：
S1, weigh A group raw materials：6~10 parts of citric acid, 2~5 parts of malic acid, 8~10 parts of ultra-pure water, by citric acid, apple
Acid is poured into ultra-pure water respectively, is stirred；
S2, weigh B group raw materials：1~2 part of sodium gluconate, is added slowly to stir in A group raw materials；
S3, weigh C group raw materials：5~10 parts of sodium citrate；
S4, B group, C group raw materials are sufficiently mixed, and ph value of mixture is adjusted using C group raw materials so that mixed liquor
PH value reaches 5~7；
S5, by above-mentioned mixed liquor continue stir 20 minutes, packaging to be cooled.
It is preferred that, a kind of preparation method of the neutral environment-friendly cleaning agent of described replacement chlorohydric acid pickling can also include following
Step：After B groups, the mixing of C groups raw materials, continuously added in mixed liquor 0.2 part essence, 1~6 part of glycolic, 0.2 part
One or more in potassium silicate.
Compared with prior art, the beneficial effects of the invention are as follows：(1) present invention is with citric acid, malic acid, gluconic acid
Sodium, sodium citrate are raw material, while producing synergy with other components so that cleaning performance is more prominent.It is anti-by neutralizing
Neutral environment-friendly cleaning agent should be made, with steel material surface oxide layer and rusty stain function is removed, hydrochloric acid cleaning performance can be reached,
Surface rusty stain and oxide skin can be removed completely.(2) all environment-friendly materials of raw material of the present invention, pollution-free, complete
Complete alternative traditional chlorohydric acid pickling ferrous materials technique, the contaminated wastewater environmental problem produced by solving in traditional handicraft.(3)
The cleaning agent security performance of the present invention is high, operating personnel is safe from harm, will not burn body, be conducive to safe construction.
Brief description of the drawings
Fig. 1 is a kind of Making programme schematic diagram of the neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling of the present invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Referring to Fig. 1, the present invention provides a kind of technical scheme：One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, and it is special
Levy and be, including：Citric acid, malic acid, sodium gluconate, sodium citrate and ultra-pure water；Described citric acid, malic acid, Portugal
The weight proportion of grape sodium saccharate, sodium citrate and ultra-pure water is 6~10 parts of citric acid, 2~5 parts of malic acid, ultra-pure water 8~10
Part, 1~2 part of sodium gluconate, 5~10 parts of sodium citrate.
It is preferred that, described neutral environment-friendly cleaning agent can also add 0.2 part of essence.
It is preferred that, described neutral environment-friendly cleaning agent can also add 1~6 part of malic acid.
It is preferred that, described neutral environment-friendly cleaning agent can also add 2 parts of ethanol.
It is preferred that, the pH value of the cleaning agent is 5~7.
As another aspect of the present invention, there is provided a kind of making side for substituting the neutral environment-friendly cleaning agent of chlorohydric acid pickling
Method, this method at least comprises the following steps：
S1, weigh A group raw materials：6~10 parts of citric acid, 2~5 parts of malic acid, 8~10 parts of ultra-pure water, by citric acid, apple
Acid is poured into ultra-pure water respectively, is stirred；
S2, weigh B group raw materials：1~2 part of sodium gluconate, is added slowly to stir in A group raw materials；
S3, weigh C group raw materials：5~10 parts of sodium citrate, is adjusted PH to 5~7；
S4, A groups, B groups, C group raw materials be sufficiently mixed, and ph value of mixture is adjusted using C group raw materials so that be mixed
The pH value for closing liquid reaches 5~7；
S5, by above-mentioned mixed liquor continue stir 20 minutes, packaging to be cooled.
It is preferred that, a kind of preparation method of the neutral environment-friendly cleaning agent of described replacement chlorohydric acid pickling can also include following
Step：In essence, 1~6 part of malic acid, 2 parts of ethanol that 0.2 part is continuously added in A groups, B groups, the mixed liquor of C group raw materials
One or more.
Embodiment 1
One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, it is characterised in that be made up of following weight percent composition：Lemon
Lemon acid, malic acid, sodium gluconate, the weight proportion of sodium citrate and ultra-pure water are 6 parts of citric acid, 2 parts of malic acid, glucose
Sour 2 parts of sodium, 5 parts of sodium citrate, 10 parts of ultra-pure water.A kind of preparation method for substituting the neutral environment-friendly cleaning agent of chlorohydric acid pickling, the party
Method comprises the following steps：Weigh A group raw materials：6 parts of citric acid, 2 parts of malic acid, 8 parts of ultra-pure water distinguishes citric acid, malic acid
Pour into ultra-pure water, stir；Weigh B group raw materials：2 parts of sodium gluconate, is added slowly to stir equal in A group raw materials
It is even；Weigh C group raw materials：5 parts of sodium citrate；B groups, C group raw materials are sufficiently mixed, and ph value of mixture entered using C group raw materials
Row regulation so that the pH value of mixed liquor reaches 5~7；Continuously add 0.2 part of essence；Above-mentioned mixed liquor is continued to stir 20 points
Clock, treats cold and packs the making for completing the cleaning agent of the present invention.
Embodiment 2
One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, it is characterised in that be made up of following weight percent composition：Lemon
Lemon acid, malic acid, sodium gluconate, the weight proportion of sodium citrate and ultra-pure water are 10 parts of citric acid, 5 parts of malic acid, grape
1 part of sodium saccharate, 5 parts of sodium citrate, 8 parts of ultra-pure water.
A kind of preparation method for substituting the neutral environment-friendly cleaning agent of chlorohydric acid pickling, this method comprises the following steps：Weigh A groups former
Material：Citric acid, malic acid are poured into ultra-pure water, stirred by 10 parts of citric acid, 5 parts of malic acid, 8 parts of ultra-pure water respectively；Claim
Take B group raw materials：1 part of sodium gluconate, is added slowly to stir in A group raw materials；Weigh C group raw materials：Sodium citrate 5
Part；B groups, C group raw materials are sufficiently mixed, and ph value of mixture are adjusted using C group raw materials so that the pH value of mixed liquor reaches
To 5~7；Continuously add 0.2 part of essence, 1 part of malic acid, 2 parts of ethanol；Above-mentioned mixed liquor is continued to stir 20 minutes,
Treat cold and pack the making for completing the cleaning agent of the present invention.
Embodiment 3
One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, it is characterised in that be made up of following weight percent composition：Lemon
Lemon acid, malic acid, sodium gluconate, the weight proportion of sodium citrate and ultra-pure water are 6 parts of citric acid, 5 parts of malic acid, glucose
Sour 1 part of sodium, 10 parts of sodium citrate, 10 parts of ultra-pure water.
A kind of preparation method for substituting the neutral environment-friendly cleaning agent of chlorohydric acid pickling, this method comprises the following steps：Weigh A groups former
Material：Citric acid, malic acid are poured into ultra-pure water, stirred by 6 parts of citric acid, 5 parts of malic acid, 10 parts of ultra-pure water respectively；Claim
Take B group raw materials：1 part of sodium gluconate, is added slowly to stir in A group raw materials；Weigh C group raw materials：Sodium citrate 10
Part；B groups, C group raw materials are sufficiently mixed, and ph value of mixture are adjusted using C group raw materials so that the pH value of mixed liquor reaches
To 5~7；Continuously add 6 parts of malic acid, the one or more in 2 parts of ethanol；Above-mentioned mixed liquor is continued to stir 20 points
Clock, treats cold and packs the making for completing the cleaning agent of the present invention.
A kind of application method of the neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling of the present invention is：Take neutral environment-friendly cleaning agent by
6 parts as stoste and clean water 4 parts mix, obtain tank liquor, the PH numerical value of tank liquor is 5~7；The material of cleaning needed for being put into groove
Material, and tank liquor need to will be warming up to 75~85 DEG C by firing equipment, it is different according to material surface conditions, cleaning material is soaked
10~40 minutes.During immersion, timing detects the soda acid numerical value of tank liquor, and cleaning agent is added in time.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. one kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling, it is characterised in that including：Citric acid, malic acid, gluconic acid
Sodium, sodium citrate and ultra-pure water.
2. a kind of neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling according to claim 1, it is characterised in that described lemon
Acid, malic acid, sodium gluconate, the weight proportion of sodium citrate and ultra-pure water are 6~10 parts of citric acid, 2~5 parts of malic acid,
1~2 part of sodium gluconate, 5~10 parts of sodium citrate, 8~10 parts of ultra-pure water.
3. a kind of neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling according to claim 1, it is characterised in that described neutrality
Environment-friendly cleaning agent can also add 0.2 part of essence.
4. a kind of neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling according to claim 1, it is characterised in that described neutrality
Environment-friendly cleaning agent can also add 1-6 parts of glycolic.
5. a kind of neutral environment-friendly cleaning agent of replacement chlorohydric acid pickling according to claim 1, it is characterised in that described neutrality
Environment-friendly cleaning agent can also add 0.2 part of potassium silicate.
6. according to a kind of any described neutral environment-friendly cleaning agents of replacement chlorohydric acid pickling of claim 1-5, it is characterised in that：It is described
The pH value of cleaning agent is 5~7.
7. according to a kind of preparation method of the neutral environment-friendly cleaning agent of any described replacement chlorohydric acid picklings of claim 1-6, it is special
Levy and be, at least comprise the following steps：
S1, weigh A group raw materials：6~10 parts of citric acid, 2~5 parts of malic acid, 8~10 parts of ultra-pure water, by citric acid, malic acid point
Do not pour into ultra-pure water, stir；
S2, weigh B group raw materials：1~2 part of sodium gluconate, is added slowly to stir in A group raw materials；
S3, weigh C group raw materials：5~10 parts of sodium citrate, is adjusted PH to 5~7；
S4, B group, C group raw materials are sufficiently mixed, and ph value of mixture is adjusted using C group raw materials so that the pH value of mixed liquor
Reach 5~7；
S5, by above-mentioned mixed liquor continue stir 20 minutes, pack after cooling.
8. according to a kind of preparation method of the neutral environment-friendly cleaning agent of any described replacement chlorohydric acid picklings of claim 1-7, it is special
Levy and be, can also comprise the following steps：B groups, C groups raw material mixing after, continuously added in mixed liquor 0.2 part essence, 1~
One or more in 6 parts of glycolic, 0.2 part of potassium silicate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710576249.0A CN107313061A (en) | 2017-07-14 | 2017-07-14 | One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710576249.0A CN107313061A (en) | 2017-07-14 | 2017-07-14 | One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107313061A true CN107313061A (en) | 2017-11-03 |
Family
ID=60178663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710576249.0A Pending CN107313061A (en) | 2017-07-14 | 2017-07-14 | One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107313061A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109136946A (en) * | 2018-09-04 | 2019-01-04 | 张光德 | A kind of Deruster for metal of food-grade environmental protection organic acid and preparation method thereof, application method |
| CN111235619A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN114058452A (en) * | 2021-11-16 | 2022-02-18 | 青岛双瑞海洋环境工程股份有限公司 | Cleaning agent for electrolytic cell and cleaning method for electrolytic cell |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103046061A (en) * | 2012-12-22 | 2013-04-17 | 黄山金瑞泰科技有限公司 | Cleaning agent for development equipment and use method thereof |
| CN104164310A (en) * | 2014-07-31 | 2014-11-26 | 青岛华承天机械制造有限公司 | Fragrant high-efficiency detergent |
| CN105063643A (en) * | 2015-09-11 | 2015-11-18 | 烟台市誉大清洗有限公司 | Neutral environment-friendly deruster and preparation method thereof |
| CN105441961A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Metal cleaning agent |
| CN105441962A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Water-based metal cleaning agent |
-
2017
- 2017-07-14 CN CN201710576249.0A patent/CN107313061A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103046061A (en) * | 2012-12-22 | 2013-04-17 | 黄山金瑞泰科技有限公司 | Cleaning agent for development equipment and use method thereof |
| CN104164310A (en) * | 2014-07-31 | 2014-11-26 | 青岛华承天机械制造有限公司 | Fragrant high-efficiency detergent |
| CN105063643A (en) * | 2015-09-11 | 2015-11-18 | 烟台市誉大清洗有限公司 | Neutral environment-friendly deruster and preparation method thereof |
| CN105441961A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Metal cleaning agent |
| CN105441962A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Water-based metal cleaning agent |
Non-Patent Citations (2)
| Title |
|---|
| 张英: "《精品化学品配方大全下》", 31 May 2001, 北京：化学工业出版社 * |
| 路甬祥: "《中国传统工艺全集-文物修复和辨伪》", 30 September 2007, 郑州：大象出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109136946A (en) * | 2018-09-04 | 2019-01-04 | 张光德 | A kind of Deruster for metal of food-grade environmental protection organic acid and preparation method thereof, application method |
| CN111235619A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN111235619B (en) * | 2020-01-15 | 2022-05-31 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN114058452A (en) * | 2021-11-16 | 2022-02-18 | 青岛双瑞海洋环境工程股份有限公司 | Cleaning agent for electrolytic cell and cleaning method for electrolytic cell |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107313061A (en) | One kind substitutes the neutral environment-friendly cleaning agent of chlorohydric acid pickling | |
| CN102995036B (en) | Metal surface cleaning solution | |
| CN100420773C (en) | Multifunctional high-efficient metal anti-rusting liquid for removing oil | |
| CN102653868A (en) | Novel stainless steel acid-washing passivation liquid | |
| CN103046036A (en) | Metal derusting and antirusting agent and preparation method of metal derusting and antirusting agent | |
| JP3858047B1 (en) | Rust removal / rust inhibitor and rust removal method using the same | |
| CN101265583A (en) | Cleaning medicine and method for cleaning metallic surface using same | |
| CN101962779A (en) | Acidic cleaner for removing oxide scale and oily carbon deposition mixing layer on surface of aluminum | |
| CN106917095A (en) | A kind of acid-washing stainless steel passivation cream and preparation method thereof | |
| CN101113305B (en) | Nonferrous metal material surface cleaning rubbing paste and method for making same | |
| CN106011877B (en) | A kind of non-phosphate environment-friendly type metal surface degreasing agent and preparation method thereof | |
| CN101994126A (en) | Environmentally friendly multifunctional metal cleaning agent | |
| CN102936539A (en) | Environment-friendly wax removing and oil removing cleaning agent | |
| CN112745983A (en) | Phosphorus-free alkaline water-based spray cleaning antirust agent and preparation method thereof | |
| CN102634420B (en) | A kind of concentrated clothes detergent and preparation method thereof | |
| CN102031531A (en) | Sewage disposal and rust removal agent for metal surface | |
| CN104005033A (en) | Anti-corrosion rust remover and preparation method thereof | |
| CN106591855A (en) | Metal surface cleaning agent and preparation method thereof | |
| CN106011893B (en) | A kind of environment-friendly type iron castings surface treating agent and its processing method | |
| CN102061464B (en) | Novel environmentally-friendly passivating agent | |
| CN109082672A (en) | Can derust the environmentally friendly steel surface cleaning agent to descale | |
| CN104451756A (en) | High-cleanliness rust-proof cleaning fluid as well as preparation method and application thereof | |
| CN102978597A (en) | Spraying type comprehensive phosphate treating agent for cold-rolled sheet workpiece spraying coating and preparation method of spraying type comprehensive phosphate treating agent | |
| CN101240421A (en) | Passivator | |
| CN103667632A (en) | Medium for carrying out medium-frequency hardening on surface of medium-carbon alloy steel workpiece and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171103 |
|
| RJ01 | Rejection of invention patent application after publication |