CN107310001A - A kind of bamboo slab rubber and preparation method thereof - Google Patents
A kind of bamboo slab rubber and preparation method thereof Download PDFInfo
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- CN107310001A CN107310001A CN201710509447.5A CN201710509447A CN107310001A CN 107310001 A CN107310001 A CN 107310001A CN 201710509447 A CN201710509447 A CN 201710509447A CN 107310001 A CN107310001 A CN 107310001A
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- weaving
- strips used
- phenolic resin
- slab rubber
- impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K9/00—Chemical or physical treatment of reed, straw, or similar material
- B27K9/002—Cane, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/02—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/002—Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of bamboo slab rubber and preparation method thereof, belong to building material field.The present invention is matched by weight, progress takes raw material, then by after the stirring mixing of phenolic resin 2124, polyvinyl alcohol, NPE and diluent, obtain phenolic resin adhesive, filter cake is placed in impregnation in phenolic resin adhesive again, and is dried to obtain the thin bamboo strips used for weaving after impregnation, compacting obtains blank in being put into using steam as the hot press of thermal source, cooling, obtains bamboo slab rubber.The beneficial effects of the invention are as follows：Bamboo slab rubber of the present invention is difficult buckling deformation and degumming after having preferable bonding strength, use, is worthy to be popularized and uses.
Description
Technical field
The present invention relates to a kind of bamboo slab rubber and preparation method thereof, belong to building material field.
Background technology
Bamboo slab rubber, be with bamboo wood material make main frame and casting resin through high pressure into base sheet material, because bamboo slab rubber hardness is high,
Anti- folding, compression strength are big, acid and alkali-resistance and be widely used in false work mould, railway carriage casing, big machinery packaging, mine door etc. are more
Individual field.Again because bamboo is easy culture, grow into forest fast forest, can just cut down within 3 to five years, can replace timber, therefore, forestry
The wood-based plate using bamboo as main rapidoprint is greatly developed in portion's policy support, substituted for wood type sheet material in many places
Use.Current production method of bamboo plywood is more, a kind of bamboo slab rubber as disclosed in Chinese Patent Application No. CN200610121114.7
And its manufacture method, its step is selects the second layer and third layer thin bamboo strips used for weaving of more than 4 years mao bamboons and weaves into bamboo curtain splint, the painting on bamboo curtain splint
Dry to water content 13%, be first cold-pressed after assembly to 180MPa and then release after glue, then be warming up to after 150 DEG C of insulation 45min, it is whole
Reason surrounding is formed.The and for example production method of fly wood made from bamboo mat and hard sundry wood disclosed in Chinese Patent Application No. CN93118042.2, its
Bamboo is first processed into bamboo mat, hardwood is processed into plank block, phenolic resin glue is then applied on bamboo mat again, will after drying
It is hot-forming that bamboo mat is sticked on plank two sides.Prior art is typically that mao bamboon first is processed into bamboo mat or bamboo curtain splint, bamboo mat or bamboo curtain warp element
Drying-impregnation-dries again-and assembly-hot-press solidifying is into plate.But the bonding strength for the bamboo slab rubber that these methods are produced is poor, makes
With rear easy buckling deformation and degumming.Therefore, developing a kind of good bamboo slab rubber of bonding strength has necessary meaning.
The content of the invention
The technical problems to be solved by the invention：It is poor for traditional bamboo slab rubber bonding strength, easy buckling deformation after use
And there is provided a kind of bamboo slab rubber and preparation method thereof the drawbacks of degumming.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of bamboo slab rubber, includes the raw material of following parts by weight：
40~50 parts of phenolic resin 2124,3~5 parts of polyvinyl alcohol, 1~3 part of NPE, 20~30 parts of diluents
With 180~200 parts of filter cakes；
Described filter cake is obtained by following steps：
（1）It is with biogas slurry to soak 5~8 after the thin bamboo strips used for weaving that 10~20mm, thickness are 1.0~1.5mm that 1~2kg bamboos are split into width
My god, after immersion terminates, thin bamboo strips used for weaving is taken out and dried, obtain pre-processing thin bamboo strips used for weaving；
（2）It is 25% salpeter solution and 400~500mL mass that 200~300g is pre-processed into thin bamboo strips used for weaving, 150~200mL mass fractions
Fraction is 50% sulfuric acid solution, is filtered after reacting 3~4h at 80~90 DEG C, obtains filter residue, after filter residue is washed with water, washed
Net filter residue；
（3）After clean filter residue, 400~500mL epoxychloropropane and 10~15g hydroquinones are mixed, 1~3g catalysis is added
Agent, and filtered after 110~120 DEG C of 3~4h of reaction, obtain filter cake.
Described diluent is one or both of glycerine, ethylene glycol.
Described catalyst is in triethyl benzyl ammonia chloride, tetrabutylammonium chloride, DTAC
It is one or more of.
The preparation method of described bamboo slab rubber, specific preparation process is：
（1）Match by weight, progress takes raw material；
（2）After the stirring mixing of phenolic resin 2124, polyvinyl alcohol, NPE and diluent, phenolic aldehyde tree is obtained
Fat adhesive, phenolic resin adhesive is poured into cement dipping machine, and filter cake is placed in phenolic resin adhesive, in 4~5MPa
1~2h of lower impregnation, by the filtration cakes torrefaction after impregnation, obtains the thin bamboo strips used for weaving after impregnation；
（3）During thin bamboo strips used for weaving after impregnation is put into using steam as the hot press of thermal source, it is 75~85 DEG C to control press temperature, and pressure is
3~4MPa, suppresses 20~30min, obtains blank, blank is cooled down, obtain bamboo slab rubber.
The present invention is compared with other method, and advantageous effects are：
The present invention is first handled thin bamboo strips used for weaving with biogas slurry, through the microbial action in biogas slurry thin bamboo strips used for weaving surface can be made to form bumps not
Flat hollow, increases the physical interface that thin bamboo strips used for weaving is bonded with adhesive, is that follow-up impregnation raising adhesion strength creates conditions, then use
Mixed acid is handled thin bamboo strips used for weaving, and the free oxygen atom that mixed acid is discharged in processing procedure is combined with the carbon atom on thin bamboo strips used for weaving
Formation-C=O, and then hydroxyl, carboxyl are combined to form with the hydrogen ion in water, hydroxide ion, so as to form hydroxyl on thin bamboo strips used for weaving surface
Base and carboxyl, using carboxyl and epichlorohydrin reaction, to thin bamboo strips used for weaving surface grafting epoxide group, epoxide group is conducive to adhesive
Sprawling and permeate on thin bamboo strips used for weaving surface, and the phenolic resin in adhesive is crosslinked reaction with epoxide group, so as to strengthen
Interfacial structure, further improves the bonding strength of bamboo slab rubber.
Embodiment
It is the thin bamboo strips used for weaving that 10~20mm, thickness are 1.0~1.5mm to take 1~2kg bamboos to be split into width with knife, by thin bamboo strips used for weaving natural pond
Immersion is steeped 5~8 days, and after immersion terminates, thin bamboo strips used for weaving is taken out, is placed in baking oven, after 105~115 DEG C of dry 40~50min
It is warming up to 150~160 DEG C to continue to dry 30~40min, then naturally cools to room temperature, obtains pre-processing thin bamboo strips used for weaving, take 200~300g
Pretreatment thin bamboo strips used for weaving, 150~200mL mass fractions are 25% salpeter solution and 400~500mL mass fractions are that 50% sulfuric acid solution adds
Enter into the three-necked flask with thermometer and reflux, three-necked flask is placed in water-bath, it is 80 to control bath temperature
~90 DEG C, filter after 3~4h of stirring reaction, obtain filter residue, filter residue is washed with water to cleaning solution pH after 5.8~6.0, to obtain
Filter residue is cleaned, clean filter residue, 400~500mL epoxychloropropane and 10~15g hydroquinones are added to thermometer and returned
In the three-necked flask for flowing device, three-necked flask is placed in oil bath pan, it is 110~120 DEG C to control oil bath temperature, stirring mixing 3
After~5min, then into three-necked flask 1~3g catalyst is added, filter after 3~4h of stirring reaction, obtain filter cake, finally by weight
Number meter is measured, 40~50 parts of phenolic resin 2124,3~5 parts of polyvinyl alcohol, 1~3 part of NPE, 20~30 are taken
Part diluent and 180~200 parts of filter cakes, phenolic resin 2124, polyvinyl alcohol, NPE and diluent are added
Into beaker, stirring 15~20min of mixing obtains phenolic resin adhesive, phenolic resin adhesive is poured into cement dipping machine, and
Filter cake is placed in phenolic resin adhesive, 1~2h of impregnation under 4~5MPa, by the filter cake natural air drying 40 after impregnation~
Moved into after 50min in baking oven, 3~4h is dried at 105~110 DEG C, the thin bamboo strips used for weaving after impregnation is obtained, the thin bamboo strips used for weaving after impregnation is placed in
In using steam as the hot press of thermal source, it is 75~85 DEG C to control press temperature, and pressure is 3~4MPa, suppresses 20~30min, obtains
To blank, blank is naturally cooled into room temperature, bamboo slab rubber is obtained.Described catalyst is triethyl benzyl ammonia chloride, the tetrabutyl
One or more in ammonium chloride, DTAC.Described diluent is one kind in glycerine, ethylene glycol
Or two kinds.
Example 1
It is the thin bamboo strips used for weaving that 10mm, thickness are 1.0mm to take 1kg bamboos to be split into width with knife, and thin bamboo strips used for weaving is soaked 5 days with biogas slurry, waits to soak
After end, thin bamboo strips used for weaving is taken out, is placed in baking oven, 150 DEG C are warming up to after 105 DEG C of dry 40min and continues to dry 30min, then
Naturally cool to room temperature, obtain pre-process thin bamboo strips used for weaving, take 200g pre-process thin bamboo strips used for weaving, 150mL mass fractions be 25% salpeter solution and
400mL mass fractions are that 50% sulfuric acid solution is added in the three-necked flask with thermometer and reflux, and three-necked flask is put
In water-bath, it is filtering after 80 DEG C, stirring reaction 3h to control bath temperature, obtains filter residue, filter residue is washed with water into washing
Liquid pH be 5.8 after, obtain clean filter residue, by clean filter residue, 400mL epoxychloropropane and 10g hydroquinones be added to temperature
In the three-necked flask of degree meter and reflux, three-necked flask is placed in oil bath pan, it is 110 DEG C to control oil bath temperature, and stirring is mixed
Close after 3min, then filtering after 1g catalyst, stirring reaction 3h is added into three-necked flask, obtain filter cake, by weight finally
Meter, takes 40 parts of phenolic resin 2124,3 parts of polyvinyl alcohol, 1 part of NPE, 20 parts of diluents and 180 parts of filter cakes,
Phenolic resin 2124, polyvinyl alcohol, NPE and diluent are added in beaker, stirring mixing 15min is obtained
To phenolic resin adhesive, phenolic resin adhesive is poured into cement dipping machine, and filter cake is placed in phenolic resin adhesive,
Impregnation 1h under 4MPa, will move into baking oven after the filter cake natural air drying 40min after impregnation, 3h is dried at 105 DEG C, impregnation is obtained
Thin bamboo strips used for weaving afterwards, during the thin bamboo strips used for weaving after impregnation is placed in using steam as the hot press of thermal source, it is 75 DEG C to control press temperature, and pressure is
3MPa, suppresses 20min, obtains blank, blank is naturally cooled into room temperature, obtain bamboo slab rubber.Described catalyst is triethyl group
Benzyl ammonium chloride.Described diluent is glycerine.
Example 2
It is the thin bamboo strips used for weaving that 15mm, thickness are 1.3mm to take 2kg bamboos to be split into width with knife, and thin bamboo strips used for weaving is soaked 7 days with biogas slurry, waits to soak
After end, thin bamboo strips used for weaving is taken out, is placed in baking oven, 155 DEG C are warming up to after 110 DEG C of dry 45min and continues to dry 35min, then
Naturally cool to room temperature, obtain pre-process thin bamboo strips used for weaving, take 250g pre-process thin bamboo strips used for weaving, 180mL mass fractions be 25% salpeter solution and
450mL mass fractions are that 50% sulfuric acid solution is added in the three-necked flask with thermometer and reflux, and three-necked flask is put
In water-bath, it is filtering after 85 DEG C, stirring reaction 4h to control bath temperature, obtains filter residue, filter residue is washed with water into washing
Liquid pH be 5.9 after, obtain clean filter residue, by clean filter residue, 450mL epoxychloropropane and 13g hydroquinones be added to temperature
In the three-necked flask of degree meter and reflux, three-necked flask is placed in oil bath pan, it is 115 DEG C to control oil bath temperature, and stirring is mixed
Close after 4min, then filtering after 2g catalyst, stirring reaction 4h is added into three-necked flask, obtain filter cake, by weight finally
Meter, takes 45 parts of phenolic resin 2124,4 parts of polyvinyl alcohol, 2 parts of NPEs, 25 parts of diluents and 190 parts of filter cakes,
Phenolic resin 2124, polyvinyl alcohol, NPE and diluent are added in beaker, stirring mixing 18min is obtained
To phenolic resin adhesive, phenolic resin adhesive is poured into cement dipping machine, and filter cake is placed in phenolic resin adhesive,
Impregnation 2h under 5MPa, will move into baking oven after the filter cake natural air drying 45min after impregnation, 4h is dried at 108 DEG C, impregnation is obtained
Thin bamboo strips used for weaving afterwards, during the thin bamboo strips used for weaving after impregnation is placed in using steam as the hot press of thermal source, it is 80 DEG C to control press temperature, and pressure is
4MPa, suppresses 25min, obtains blank, blank is naturally cooled into room temperature, obtain bamboo slab rubber.Described catalyst is the tetrabutyl
Ammonium chloride.Described diluent is ethylene glycol.
Example 3
It is the thin bamboo strips used for weaving that 20mm, thickness are 1.5mm to take 2kg bamboos to be split into width with knife, and thin bamboo strips used for weaving is soaked 8 days with biogas slurry, waits to soak
After end, thin bamboo strips used for weaving is taken out, is placed in baking oven, 160 DEG C are warming up to after 115 DEG C of dry 50min and continues to dry 40min, then
Naturally cool to room temperature, obtain pre-process thin bamboo strips used for weaving, take 300g pre-process thin bamboo strips used for weaving, 200mL mass fractions be 25% salpeter solution and
500mL mass fractions are that 50% sulfuric acid solution is added in the three-necked flask with thermometer and reflux, and three-necked flask is put
In water-bath, it is filtering after 90 DEG C, stirring reaction 4h to control bath temperature, obtains filter residue, filter residue is washed with water into washing
Liquid pH be 6.0 after, obtain clean filter residue, by clean filter residue, 500mL epoxychloropropane and 15g hydroquinones be added to temperature
In the three-necked flask of degree meter and reflux, three-necked flask is placed in oil bath pan, it is 120 DEG C to control oil bath temperature, and stirring is mixed
Close after 5min, then filtering after 3g catalyst, stirring reaction 4h is added into three-necked flask, obtain filter cake, by weight finally
Meter, takes 50 parts of phenolic resin 2124,5 parts of polyvinyl alcohol, 3 parts of NPEs, 30 parts of diluents and 200 parts of filter cakes,
Phenolic resin 2124, polyvinyl alcohol, NPE and diluent are added in beaker, stirring mixing 20min is obtained
To phenolic resin adhesive, phenolic resin adhesive is poured into cement dipping machine, and filter cake is placed in phenolic resin adhesive,
Impregnation 2h under 5MPa, will move into baking oven after the filter cake natural air drying 50min after impregnation, 4h is dried at 110 DEG C, impregnation is obtained
Thin bamboo strips used for weaving afterwards, during the thin bamboo strips used for weaving after impregnation is placed in using steam as the hot press of thermal source, it is 85 DEG C to control press temperature, and pressure is
4MPa, suppresses 30min, obtains blank, blank is naturally cooled into room temperature, obtain bamboo slab rubber.Described catalyst is dodecane
Base trimethyl ammonium chloride.Described diluent is glycerine.
Reference examples：The bamboo slab rubber of Yixing City company production.
The bamboo slab rubber of bamboo slab rubber obtained by above-described embodiment and reference examples is detected, specific detection is as follows：
Bonding strength：Tested according to the product glue performance method of testing in JC/T2124-2012.
As a result as shown in Table 1.
Table one：
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Bonding strength/MPa | 1.4 | 1.7 | 2.1 | 1.0 |
As seen from the above table, bamboo slab rubber of the present invention is difficult buckling deformation and degumming after having preferable bonding strength, use, is worth pushing away
Extensively with using.
Claims (4)
1. a kind of bamboo slab rubber, it is characterised in that include the raw material of following parts by weight：
40~50 parts of phenolic resin 2124,3~5 parts of polyvinyl alcohol, 1~3 part of NPE, 20~30 parts of diluents
With 180~200 parts of filter cakes；
Described filter cake is obtained by following steps：
（1）It is with biogas slurry to soak 5~8 after the thin bamboo strips used for weaving that 10~20mm, thickness are 1.0~1.5mm that 1~2kg bamboos are split into width
My god, after immersion terminates, thin bamboo strips used for weaving is taken out and dried, obtain pre-processing thin bamboo strips used for weaving；
（2）It is 25% salpeter solution and 400~500mL mass that 200~300g is pre-processed into thin bamboo strips used for weaving, 150~200mL mass fractions
Fraction is 50% sulfuric acid solution, reacts and is filtered after 3~4h at 80~90 DEG C, obtains filter residue, after filter residue is washed with water, obtain
Clean filter residue；
（3）After clean filter residue, 400~500mL epoxychloropropane and 10~15g hydroquinones are mixed, 1~3g catalysis is added
Agent, and filtered after 110~120 DEG C of 3~4h of reaction, obtain filter cake.
2. a kind of bamboo slab rubber according to claim 1, it is characterised in that described diluent is glycerine, ethylene glycol
One or both of.
3. a kind of bamboo slab rubber according to claim 1, it is characterised in that described catalyst is triethylbenzyl chlorination
One or more in ammonium, tetrabutylammonium chloride, DTAC.
4. the preparation method of the bamboo slab rubber in claims 1 to 3 described in any one, it is characterised in that specifically preparation process is：
（1）Match by weight, progress takes raw material；
（2）After the stirring mixing of phenolic resin 2124, polyvinyl alcohol, NPE and diluent, phenolic aldehyde tree is obtained
Fat adhesive, phenolic resin adhesive is poured into cement dipping machine, and filter cake is placed in phenolic resin adhesive, in 4~5MPa
1~2h of lower impregnation, by the filtration cakes torrefaction after impregnation, obtains the thin bamboo strips used for weaving after impregnation；
（3）During thin bamboo strips used for weaving after impregnation is put into using steam as the hot press of thermal source, it is 75~85 DEG C to control press temperature, and pressure is
3~4MPa, suppresses 20~30min, obtains blank, blank is cooled down, obtain bamboo slab rubber.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501153A (en) * | 2018-04-02 | 2018-09-07 | 裴泽民 | A kind of preparation method of high-intensity and high-tenacity bamboo slab rubber |
| CN112824444A (en) * | 2019-11-20 | 2021-05-21 | 桃江县鑫盛竹业有限公司 | Phenolic resin bamboo plywood manufacturing process |
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| JP2001105793A (en) * | 1999-08-05 | 2001-04-17 | Hideo Shimada | Durable storage treatment method for bamboo glass leaf for decorating food |
| CN102935650A (en) * | 2012-11-27 | 2013-02-20 | 浙江凯森板业有限责任公司 | Production method of bamboo plywood |
| CN103541266A (en) * | 2013-10-12 | 2014-01-29 | 陕西科技大学 | Pumping filtration-based preparation method of paper-based friction material |
| CN105291234A (en) * | 2015-10-23 | 2016-02-03 | 中国建筑材料科学研究总院 | Method for producing sandwich composite wallboard through waste bamboo plywood |
| CN105690520A (en) * | 2016-03-22 | 2016-06-22 | 江苏祥豪实业有限公司 | Novel waterproof material for artificial board, and preparation method and application thereof |
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2017
- 2017-06-28 CN CN201710509447.5A patent/CN107310001B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001105793A (en) * | 1999-08-05 | 2001-04-17 | Hideo Shimada | Durable storage treatment method for bamboo glass leaf for decorating food |
| CN102935650A (en) * | 2012-11-27 | 2013-02-20 | 浙江凯森板业有限责任公司 | Production method of bamboo plywood |
| CN103541266A (en) * | 2013-10-12 | 2014-01-29 | 陕西科技大学 | Pumping filtration-based preparation method of paper-based friction material |
| CN105291234A (en) * | 2015-10-23 | 2016-02-03 | 中国建筑材料科学研究总院 | Method for producing sandwich composite wallboard through waste bamboo plywood |
| CN105690520A (en) * | 2016-03-22 | 2016-06-22 | 江苏祥豪实业有限公司 | Novel waterproof material for artificial board, and preparation method and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501153A (en) * | 2018-04-02 | 2018-09-07 | 裴泽民 | A kind of preparation method of high-intensity and high-tenacity bamboo slab rubber |
| CN108501153B (en) * | 2018-04-02 | 2019-11-12 | 湖北鑫晨光建设工程有限公司 | A kind of preparation method of high-intensity and high-tenacity bamboo slab rubber |
| CN112824444A (en) * | 2019-11-20 | 2021-05-21 | 桃江县鑫盛竹业有限公司 | Phenolic resin bamboo plywood manufacturing process |
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| CN107310001B (en) | 2019-05-24 |
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