CN107306972A - Thymol and combinations thereof - Google Patents
Thymol and combinations thereof Download PDFInfo
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- CN107306972A CN107306972A CN201710440817.4A CN201710440817A CN107306972A CN 107306972 A CN107306972 A CN 107306972A CN 201710440817 A CN201710440817 A CN 201710440817A CN 107306972 A CN107306972 A CN 107306972A
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- composition
- medicament
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of medicament for preventing and treating agricultural disease and combinations thereof.Agent activity component is Thymol.The present invention carries out monomer or binary mixture so that Thymol is with benziothiazolinone and waits other pesticide species.Applied to the preventing and treating of agricultural disease, disease prevention and control performance can be greatly improved.Two groups of active ingredients show as synergistic effect in composition, it is allowed to amount of application reduction, more longlasting prevention effect, by a small number of applying only once or several times preferably control plant pest bacterium and broadening the possible administration interval time.
Description
Technical field
The invention belongs to agricultural protection technical field, and in particular to a kind of medicament and composition of preventing and treating agricultural disease.
Background technology
Plant disease development of drug resistance is rapid, and chemical control is difficult.Trigger agricultural product to drop in production over a large area, cause serious commercial
Loss.
The pharmacy variety of controlling plant diseases relatively enriches in agricultural production, but resistance development is quickly.Dedicated for preventing and treating
The medicament of bacterial disease, species is less.Predominantly copper agent.This kind of medicament resistance to the action of a drug is serious, and preventive effect is relatively low, right in the environment
Soil, water body and food formation pollution, trigger environment and food safety risk.Other can be used for the only few of agriculture bacterium treatment
Kind is measured, by the dual limitation of resistance and preventive effect in actual production, popularizing area is smaller.
Thymol is a kind of natural volatile oil, from thyme extract and name.Natural thymol is white crystal, is had
Pleasant aromatic odor.Chemical name：5- methyl -2- isopropyls-phenol.No. CAS：89-83-8.With good suppression
Bacterium activity, has good prevention effect to fungi and bacterium.Not yet reported in application agriculturally.
Benziothiazolinone, trade name：Bacterium is vertical to go out, english common name：Benzisothiazolinone, chemical name：1,2
Benzisothiazole-3-ketone, CAS 2634-33-5.It is main most as microbicide and fungus control agent at home and abroad,
For in anti-corrosion, paint, adhesive, detergent, fuel and paper-making industry.Agriculture plant protection industry also has some applications, main to use
In the preventing and treating of agriculture fungi.
To prevent and treat, resistance is fast-developing, is mixed by other medicaments different from the mechanism of action, can alleviate resistance development,
Medicament is set to serve agricultural production for a long time.
The content of the invention
It is an object of the invention to provide a kind of medicament and composition for preventing and treating agricultural disease.
A kind of medicament for preventing and treating agricultural disease, its active component is Thymol.The active component of composition is benziothiazolinone
And Thymol.
The medicament and composition also include insecticides adjuvant, and the content of insecticides adjuvant is 2-98wt%；The insecticides adjuvant is
One or more in solvent, solid carrier, surfactant.
The solvent is toluene, and mixed xylenes thing, trisubstituted benzene, Dibutyl phthalate, phthalandione two is sad, thiacyclohexane,
Gasoline, ethylene glycol, methanol, ethanol, glycol monoethyl ether, the double methyl ethers of ethylene glycol, cyclohexanone, cyclopentanone, 1-METHYLPYRROLIDONE,
Dimethyl sulfoxide (DMSO), dimethylformamide, soybean oil.
The solid carrier be talcum powder, kaolin, montmorillonite, atlapulgite, float stone, bentonite, bentonite, calcite,
One or more in sand.
The surfactant be lignin sulfonic acid, naphthalene sulfonic acids, the alkali salt or amine salt of phenolsulfonic acid, sulfonate,
The condensation product of sulfate, aliphatic acid and sulphated fatty alcohol glycol ether, sulfonated naphthalene, naphthalene derivatives and formaldehyde, naphthalene or naphthalene sulfonic acids
With phenol and the condensation product of formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol, alkyl virtue
Base polyglycol ether, tributyl benzene polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, ethyoxyl
Change castor oil, polyoxyethylene alkyl ether, ethylene oxide condensation product, ethoxylation polyoxypropylene, laurate polyglycol ether acetal,
Sorbitol ester, dodecyl benzyl dimethyl ammonium chloride, myristyl benzyl dimethyl ammonium chloride, hexadecyldimethyl benzyl ammonium benzyl
Ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, tetradecyl dimethyl benzyl ammonium, hexadecyldimethyl benzyl ammonium benzyl bromide a-bromotoluene
Change the one or more in ammonium, lignin sulfite waste liquor, methylcellulose.
The plant pathogen is xanthomonas campestris, bacillus subtilis, Bacillus cereus, the raw yellow unit cell of tree
Bacterium, blister spot Xanthomonas campestris, the graceful streptomycete of Ah fluorine, clavibacter, pseudomonad, carrot soft rot Erwinia, currant grape seat
Chamber bacterium, Rhizoctonia solani Kuhn, Phytophthora capsici, pseudomonas syringae, narrow shell post spore, the narrow shell post spore of big spore, bacillus anthracis, beak angle load
One or more in bacterium, grey pears spore, alternaric bacteria, grey grape born of the same parents bacterium, big spot Exserohilum etc..
Above-mentioned composition preventing and treating corps diseases in purposes, particularly prevent and treat angular leaf spot of cucumber, muskmelon fruit blotch,
Bacterial blight of rice, Tomato mottle disease, soft rot of Chinese cabbage, wheat cecospora spot, cucurbita pepo soft rot, pepper bacterial tikka
Disease, potato scab, ring rot, balck shank, bacterial wilt and soft rot, canker of apple fruit, walnut black spot, paddy rice base are rotten
Disease, tomato macula disease, citrus ulcer, the mould heart of apple and heartrot, Prospect on Kiwifruit Bacterial Canker, potato scab, mango anthrax
Disease, damping-off, phytophthora root rot, angular leaf spot, corn dry rot, wheat sharp eyespot, rice blast, wheat leaf blight, purple blotch of onion, corn
Use in leaf blight, eggplant early blight, the disease that the bacterium such as Cabbage Leaf Spot, gray mold, leaf blight, fungi or mixing trigger
On the way.
Suitable auxiliary agent can be solid or liquid, the material commonly used typically during formulation, such as mineral matter
Filler, Chemical Solvents, dispersant, wetting agent, solvent, adhesive, thickener, film forming agent, adhesive etc..
The application process of above-mentioned medicament and composition includes the aerial part or under ground portion for plant growth, including spray
Apply, smear, soaking seed, pouring root, seed dressing and soil disinfection.Above-mentioned composition only can be administered comprising active component, also may be used
To be mixed together with auxiliary agent.
Above-mentioned medicament and composition can be prepared into acceptable formulation on agricultural chemicals, such as wettable powder, suspending agent, water
Dispersible granule, aqueous emulsion, soluble concentrate, pulvis, microcapsule suspending agent, emulsifiable concentrate, missible oil or microemulsion.According to these compositions
Property and the purpose to be reached using composition and ambient conditions, can select composition to spray, atomizing, dust,
The method poured or the like is disseminated or sprinkles to apply.
Compared with prior art, the present invention has the advantages that：The medicament and composition of the present invention, with Thymol
With other pesticide species such as benziothiazolinone, unitary or binary mixture are carried out.Applied to the preventing and treating of agricultural disease, it can greatly improve
Prevention and control performance.Two groups of active ingredients show as synergistic effect in composition, it is allowed to amount of application reduction, more longlasting prevention effect,
By only once or it is a small number of apply preferably control plant pest germ several times and broaden possible administration interval when
Between.The prevention effect having had to the disease that the germ for having produced resistance triggers.
Embodiment
The embodiment to the present invention is described in detail below, it is to be understood that protection scope of the present invention is not
Limited by embodiment.
Embodiment 1The preventing and treating of downy mildew of garpe
Test method：About 550 plants/acre of wine-growing density (m of spacing in the rows 0.4, the m of line-spacing 3).In young fruit period, (fallen flowers are about
2 weeks), progress sprays processing, prevents and treats downy mildew of garpe.Pass through the prevention effect of the various medicaments of analysis of experiments.Setup Experiments 3
Hillslope processes, each square meter of cell 20.The state of an illness of the whole grape leaves of investigation, the state of an illness at different levels are recorded by cell, disease is calculated respectively
Feelings index.
Soluble reagents are made into according to following ratio
Thymol 20%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 70%；
The preparation being made into according to the above ratio, dilution 2000ppm is tested.Compareed with clear water, to the preventive effect of downy mildew of garpe
More than 82%.
Embodiment 2The preventing and treating of bacterial blight of rice
Test method：Once sprayed at the initial stage of a disease, each 3 cells of processing, each square meter of cell 20.In before medicine and
10 days investigation statisticses incidences after medicine, each 5 grab sample of cell investigate the lesion area in whole strain per blade and account for leaf
The percentage of piece area, calculates disease index and prevention effect.
Soluble reagents are made into according to following ratio
Thymol 20%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 70%；
The preparation being made into according to the above ratio, 2000 times of dilution is sprayed, and is compareed with clear water, to the bacterial leaf-blight preventive effect of paddy rice
More than 55%.
Embodiment 3The preventing and treating of potato scab
Test method：Initial stage is formed in potato potato wedge, root irrigation is carried out, prevents and treats potato scab.Pass through analysis of experiments
The prevention effect of various medicaments.3 hillslope processes of Setup Experiments, each square meter of cell 20.The sick potato rate of the whole potato wedges of investigation, is pressed
Cell records sick potato numbers at different levels respectively, calculates disease index.
Soluble reagents are made into according to following ratio
Benziothiazolinone 20%；
Thymol 0.2%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 69.8%；
The preparation being made into according to the above ratio, according to every mu of 5 grams of active ingredients, carries out dispenser.Compareed with 20% benziothiazolinone, it is right
The preventive effect of potato scab is more than 80%.The preventive effect 60% of control.It is mixed that there is obvious synergistic effect.
Embodiment 4The preventing and treating of citrus ulcer
Test method：Citrus autumn growth is about 2cm and starts dispenser.Every 10 d or so dispenser 1 time, spray altogether 3 times.Last dispenser
20 d investigate autumn growth blade incidence afterwards.5 grab sample of each cell, investigate the lesion area in whole strain per blade and account for
The percentage of blade area, calculates disease index and prevention effect.
Soluble reagents are made into according to following ratio
Benziothiazolinone 10%；
Thymol 10%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 70%；
The preparation being made into according to the above ratio, 4000 times of dilution is sprayed, and is compareed with 20% benziothiazolinone, to citrus ulcer
Preventive effect more than 75%, the preventive effect of control is only capable of reaching 40%.
The preventing and treating of the bacterial blight of rice of embodiment 5
Test method：Once sprayed at the initial stage of a disease, each 3 cells of processing, each square meter of cell 20.In before medicine and
10 days investigation statisticses incidences after medicine, each 5 grab sample of cell investigate the lesion area in whole strain per blade and account for leaf
The percentage of piece area, calculates disease index and prevention effect.
Soluble reagents are made into according to following ratio
Benziothiazolinone 0.1%；
Thymol 10%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 79.9%；
The preparation being made into according to the above ratio, 2000 times of dilution is sprayed, and is compareed with 11% benziothiazolinone, to the white leaf of paddy rice
Rot preventive effect is more than 62%, and the preventive effect of control is only capable of reaching 23%.
Embodiment 6Preventing and treating to paddy rice basal stem rot
Test method：In rice plant of tillering stage and boot stage, early stage is once sprayed, each 3 cells of processing, Mei Ge little
The square meter of area 20.The sick clump number of investigation and diseased plant number.Prevention effect is calculated with diseased plant rate.
Soluble reagents are made into according to following ratio
Benziothiazolinone 5%；
Thymol 10%；
Dispersant (lignin sulfonic acid) 10%；
Solvent (dimethylformamide) 75%；
The preparation being made into according to the above ratio, 2000 times of dilution is sprayed, and is compareed with 20% benziothiazolinone, to rotten to paddy rice base
Disease more than 90%, the preventive effect of control is only capable of reaching 60%.
Disclosed above is only the specific embodiment of the present invention, and still, the present invention is not limited to this, the technology of any this area
What personnel can think change should all fall into protection scope of the present invention.
Claims (6)
1. a kind of medicament for preventing and treating agricultural disease and combinations thereof, it is characterised in that its active component is Thymol, composition
For Thymol and benziothiazolinone.
2. the medicament and composition of preventing and treating agricultural disease according to claim 1, it is characterised in that the composition is also wrapped
Containing insecticides adjuvant, the content of insecticides adjuvant is 2-98wt%；The insecticides adjuvant is in solvent, solid carrier, surfactant
It is one or more kinds of.
3. the medicament and composition of preventing and treating agricultural disease according to claim 2, it is characterised in that the solvent is first
Benzene, mixed xylenes thing, trisubstituted benzene, Dibutyl phthalate, the octanoic acid of phthalandione two, thiacyclohexane, gasoline, ethylene glycol, methanol, second
Alcohol, glycol monoethyl ether, the double methyl ethers of ethylene glycol, cyclohexanone, cyclopentanone, 1-METHYLPYRROLIDONE, dimethyl sulfoxide (DMSO), dimethyl methyl
Acid amides, soybean oil.
4. the medicament and composition of preventing and treating agricultural disease according to claim 2, it is characterised in that the solid carrier is
One or more in talcum powder, kaolin, montmorillonite, atlapulgite, float stone, bentonite, bentonite, calcite, sand.
5. the medicament and composition of preventing and treating agricultural disease according to claim 2, it is characterised in that the surfactant
For lignin sulfonic acid, naphthalene sulfonic acids, the alkali salt or amine salt of phenolsulfonic acid, sulfonate, sulfate, aliphatic acid and sulphation fat
The condensation product of fat alcohol glycol ether, sulfonated naphthalene, naphthalene derivatives and formaldehyde, naphthalene or naphthalene sulfonic acids and phenol and the condensation product of formaldehyde, gather
Oxygen ethene octyl phenyl ether, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol, alkylaryl polyglycol ether, tributyl benzene gathers
Glycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, ethoxylated castor oil, polyoxyethylene alkyl ether,
Ethylene oxide condensation product, ethoxylation polyoxypropylene, laurate polyglycol ether acetal, sorbitol ester, dodecyl dimethyl
Benzyl ammonium chloride, myristyl benzyl dimethyl ammonium chloride, cetalkonium chloride, dodecyl dimethyl benzyl
Base ammonium bromide, tetradecyl dimethyl benzyl ammonium, cetyl dimethyl benzyl ammonium bromide, lignin sulfite gives up
One or more in liquid, methylcellulose.
6. the application of medicament and composition in plant pathogen is killed described in claim 1, it is characterised in that the plant
Pathogenic bacteria are xanthomonas campestris, bacillus subtilis, Bacillus cereus, set raw Xanthomonas campestris, blister spot Xanthomonas campestris, Ah
The graceful streptomycete of fluorine, clavibacter, pseudomonad is carrot soft rot Erwinia, currant grape seat chamber bacterium, Rhizoctonia solani Kuhn, peppery
Green pepper phytophthora, pseudomonas syringae, narrow shell post spore, the narrow shell post spore of big spore, bacillus anthracis, beak angle load bacterium, grey pears spore, alternaric bacteria,
One or more in grey grape born of the same parents bacterium, grey grape born of the same parents bacterium, big spot Exserohilum etc..
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710440817.4A CN107306972A (en) | 2017-06-13 | 2017-06-13 | Thymol and combinations thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710440817.4A CN107306972A (en) | 2017-06-13 | 2017-06-13 | Thymol and combinations thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107306972A true CN107306972A (en) | 2017-11-03 |
Family
ID=60183214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710440817.4A Pending CN107306972A (en) | 2017-06-13 | 2017-06-13 | Thymol and combinations thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN107306972A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112674105A (en) * | 2021-01-19 | 2021-04-20 | 中国科学院微生物研究所 | Bactericide for preventing and treating xanthomonas and application thereof |
| CN115039774A (en) * | 2022-06-29 | 2022-09-13 | 苏州艾科尔化工科技有限公司 | Compound disinfectant for controlling banana march disease and panama disease and application thereof |
| CN116019130A (en) * | 2023-02-06 | 2023-04-28 | 青岛农业大学 | Application of thyme essential oil in preparation of bacteriostat for inhibiting plant rot pathogens |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112674105A (en) * | 2021-01-19 | 2021-04-20 | 中国科学院微生物研究所 | Bactericide for preventing and treating xanthomonas and application thereof |
| CN112674105B (en) * | 2021-01-19 | 2021-10-12 | 中国科学院微生物研究所 | Bactericide for preventing and treating xanthomonas and application thereof |
| CN115039774A (en) * | 2022-06-29 | 2022-09-13 | 苏州艾科尔化工科技有限公司 | Compound disinfectant for controlling banana march disease and panama disease and application thereof |
| CN115039774B (en) * | 2022-06-29 | 2024-04-30 | 苏州艾科尔化工科技有限公司 | Compound disinfectant for controlling banana equine diseases and panama diseases and application thereof |
| CN116019130A (en) * | 2023-02-06 | 2023-04-28 | 青岛农业大学 | Application of thyme essential oil in preparation of bacteriostat for inhibiting plant rot pathogens |
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Application publication date: 20171103 |
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