CN107304478B - Portable Electrolyzer - Google Patents
Portable Electrolyzer Download PDFInfo
- Publication number
- CN107304478B CN107304478B CN201610260150.5A CN201610260150A CN107304478B CN 107304478 B CN107304478 B CN 107304478B CN 201610260150 A CN201610260150 A CN 201610260150A CN 107304478 B CN107304478 B CN 107304478B
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- Prior art keywords
- hydrogen
- tank
- electrolysis unit
- electrolysis
- portable
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000001257 hydrogen Substances 0.000 claims abstract description 108
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 108
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 41
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 25
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 9
- 229920005597 polymer membrane Polymers 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 230000035622 drinking Effects 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000010902 straw Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- 229920006254 polymer film Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 229920000557 Nafion® Polymers 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
本申请提供便携型电解装置。可搬运到无电源的场所而用于氢的吸入和富氢水的饮用这双方。具备：带盖(2)的罐(1)，收容原水(W)；电解单元(3)，设置于罐(1)的底部，对原水(W)进行电解而产生氢；以及电池(9)，设置于罐(1)的外部，与电解单元(3)连接，驱动电解单元(3)。在罐(1)的内部，设置：导引筒(4)，使在电解单元(3)中产生的氢的气泡(H)向罐(1)的上部引导集合；以及储氢部(5)，在导引筒(4)的上部膨出形成，积存集合的氢的气泡，在储氢部(5)的上部与罐(1)的外部之间设置氢吐出管(7)。
The present application provides a portable electrolysis device. It can be transported to places without power supply and used for both inhalation of hydrogen and drinking of hydrogen-rich water. comprising: a tank (1) with a lid (2) for containing raw water (W); an electrolysis unit (3) provided at the bottom of the tank (1) for electrolyzing the raw water (W) to generate hydrogen; and a battery (9) is arranged outside the tank (1), is connected with the electrolysis unit (3), and drives the electrolysis unit (3). Inside the tank (1), there are provided: a guide cylinder (4) for guiding and collecting the hydrogen bubbles (H) generated in the electrolysis unit (3) to the upper part of the tank (1); and a hydrogen storage part (5) A hydrogen discharge pipe (7) is provided between the upper part of the hydrogen storage part (5) and the outside of the tank (1), bulging and forming on the upper part of the guide cylinder (4), and accumulating the collected hydrogen bubbles.
Description
Technical Field
The present invention relates to a portable electrolysis device which can be transported to a location without a power supply and used for hydrogen inhalation and hydrogen-rich water drinking.
Background
Recently, hydrogen-rich water has been consumed to neutralize excess active oxygen in the body and promote health. For the generation of hydrogen-rich water, a means of electrolyzing raw water such as tap water is generally employed. Therefore, after outdoor exercise or the like in which active oxygen is likely to accumulate, hydrogen-rich water cannot be generated due to the power supply, and there is a situation in which hydrogen-rich water cannot be efficiently drunk. Therefore, development of a portable hydrogen-rich water generation device capable of generating hydrogen-rich water even in a place without a power supply is desired.
Conventionally, as a portable hydrogen-rich water generation device, for example, an example described in patent document 1 is known.
The portable hydrogen-rich water generation device of patent document 1 can generate hydrogen-rich water even in a place without a power supply by dissolving hydrogen generated by electrolysis of raw water by an electrolysis unit driven by a battery in the raw water in the tank.
[ patent document 1 ] Japanese patent No. 3175997
Disclosure of Invention
In the portable hydrogen-rich water generation device of patent document 1, there is a problem that the following cannot be used: directly ingesting hydrogen which is effective for neutralization of active oxygen.
The present invention has been made in view of such problems, and an object thereof is to provide a portable electrolysis apparatus which can be transported to a location without a power supply and used for both hydrogen intake and hydrogen-rich water drinking.
In order to solve the above problems, the portable electrolysis apparatus of the present invention employs the units described in the claims.
That is, claim 1 provides a portable electrolysis apparatus comprising: a tank with a lid for containing raw water; an electrolysis unit disposed at the bottom of the tank, and configured to electrolyze raw water to generate hydrogen; and a battery disposed outside the tank, connected to the electrolysis unit, for driving the electrolysis unit, and disposed inside the tank: a guide cylinder for guiding and collecting hydrogen bubbles generated in the electrolysis unit to the upper part of the tank; and a hydrogen storage part formed by bulging at the upper part of the guide cylinder and storing the gathered hydrogen bubbles, wherein a hydrogen discharge pipe is arranged between the upper part of the hydrogen storage part and the outside of the tank.
In this aspect, the guide tube and the hydrogen storage part are provided inside the tank, and the hydrogen discharge pipe is provided between the upper part of the hydrogen storage part and the outside of the tank, whereby hydrogen bubbles generated in the electrolysis unit and dissolved in the raw water in the tank to generate hydrogen-rich water can be guided to be collected and discharged from the hydrogen discharge pipe.
Further, in the portable electrolytic device according to claim 2, in the electrolytic device according to claim 1, the guide cylinder has a funnel shape which is opened to face the electrolytic cell and is narrowed toward an upper portion.
In this embodiment, the guide cylinder has a funnel shape, and the bubbles of hydrogen generated in the electrolysis cell are smoothly guided toward the hydrogen discharge pipe located above.
Further, the portable electrolytic device according to claim 3 is the portable electrolytic device according to claim 1 or 2, wherein the guide cylinder is supported by the cover and is insertable into and removable from the tank.
In this embodiment, the guide cylinder is supported by the cover and can be inserted into and withdrawn from the tank, so that the guide cylinder does not interfere with the injection of raw water into the tank or the drinking of hydrogen-rich water produced in the tank.
Further, according to claim 4, in the portable electrolytic device according to any one of claims 1 to 3, a suction pipe capable of sucking hydrogen-rich water generated inside the tank is attached to the lid.
In this technical scheme, through installing the straw on the lid, need not to follow jar and pull down the lid and can inhale and drink hydrogen-rich water.
In the portable electrolysis apparatus according to the present invention, the guide tube and the hydrogen storage part are provided inside the tank, and the hydrogen discharge pipe is provided between the upper part of the hydrogen storage part and the outside of the tank, whereby hydrogen bubbles generated in the electrolysis unit and dissolved in the raw water in the tank to generate hydrogen-rich water can be guided to be collected and discharged from the hydrogen discharge pipe, and therefore, the portable electrolysis apparatus has an effect that the apparatus can be transported to a place without a power source and used for both the intake of hydrogen and the drinking of hydrogen-rich water.
Further, according to claim 2, since the guide cylinder is formed in a funnel shape, the bubbles of hydrogen generated in the electrolysis cell are smoothly guided toward the hydrogen storage part located upward, and therefore, the amount of hydrogen discharged from the hydrogen discharge pipe can be reliably secured, and an effect suitable for the intake of hydrogen is obtained.
Further, according to claim 3, since the guide tube is supported by the cover and is insertable into and removable from the tank, the guide tube does not interfere with the injection of raw water into the tank or the drinking of hydrogen-rich water generated in the tank, and therefore, the guide tube has an effect of improving usability.
Further, according to claim 4, since the suction pipe is attached to the lid, it is possible to suck and drink hydrogen-rich water without detaching the lid from the tank, and therefore, there is an effect that hydrogen can be drunk without unnecessarily leaking out hydrogen.
Drawings
FIG. 1 is a sectional view of a mode for carrying out the portable electrolytic device of the present invention.
Fig. 2 is an X-X sectional view of fig. 1.
Fig. 3 is an enlarged sectional view of a main portion of fig. 1.
Fig. 4 is a front view showing the use example of fig. 1.
Detailed Description
Hereinafter, embodiments of the portable electrolysis device according to the present invention will be described with reference to the drawings.
This embodiment shows a relatively small device having portability.
In this embodiment, as shown in fig. 1 to 3, the electrolytic cell is composed of a tank 1, a lid 2, an electrolytic unit 3, a guide tube 4, a hydrogen storage part 5, a suction tube 6, a hydrogen discharge tube 7, a bottom case 8, a battery 9, a control circuit 10, and a switch 20.
The tank 1 is formed of a corrosion-resistant material into a cylindrical shape having an open upper portion and a closed lower portion, and has a certain capacity capable of storing raw water W such as tap water therein.
The lid 2 is formed of a corrosion-resistant material into a cylindrical shape having a closed upper portion and an open lower portion, and the side surface portion 21 is fitted or screwed to the upper portion of the can 1 so as to be detachable, thereby forming a sealed tea-caddy-type structure together with the can 1. In the top surface portion 22 of the lid 2, a cylindrical support hole 23 for supporting the hydrogen discharge pipe 7 is provided in the central portion, a straw insertion hole 24 for inserting the straw 6 is opened in the peripheral portion, and an ozone discharge port 25 for discharging gas (ozone) generated when hydrogen-rich water is generated is opened in the other peripheral portion.
The electrolysis unit 3 is constituted by a square disk shape provided at the bottom of the tank 1. As shown in detail in fig. 2, the electrolytic module 3 includes a housing 31, a polymer film 32, electrode plates 33 and 34, and a spring 35.
The casing 31 of the electrolysis unit 3 is formed in a square window frame shape in which the volume of the reaction chamber 311 is secured, and is provided with: a rectangular window hole 312 opened substantially over the entire surface of the top portion, a claw-shaped stopper 313 protruding from 4 peripheral edges of the window hole 312 toward the center of the window hole 312, and a communication hole 314 perforated in the side portion so as to communicate the outside with the reaction chamber 311.
The polymer membrane 32 of the electrolytic unit 3 is formed of a thin film having an ion exchange function for restricting the passage of ions (for example, "perfluorosulfonic acid resin Nafion" manufactured by dupont) and has a rectangular shape having a size for closing the window 312 of the housing 31. The thickness of the polymer film 32 is about 127 to 183 μm if "Nafion" perfluorosulfonic acid resin manufactured by DuPont is selected, for example.
The electrode plates 33 and 34 of the electrolysis unit 3 are formed by weaving a wire material, which is made of titanium as a base material and is platinum-plated, into a rhombic net shape, and laminating the wire material on the entire surfaces of both surfaces of the polymer film 32 to form both positive and negative electrodes. The electrode plates 33 and 34 are finally connected to lead wires and electric wires, not shown, connected to the control circuit 10.
The spring 35 of the electrolysis unit 3 is formed as a coil spring which is compressed and housed inside the reaction chamber 311 of the housing 31, and elastically compresses the laminated polymer film 32 and the electrode plates 33 and 34 toward the stopper 313 of the housing 31. The spring 35 can also serve as a lead of the electrode plate 34 on the reaction chamber 311 side of the housing 31.
The guide tube 4 has a port 41 that is open opposite the electrolytic cell 3, and is formed in a funnel shape that decreases toward the upper portion 42.
The hydrogen storage part 5 is formed to be expanded in a substantially spherical shape at the upper part of the guide cylinder 4, and a straw receiving groove 52 that avoids the inserted straw 6 is provided in a part of the spherical body part 51.
The straw 6 is formed by attaching an openable lid 62 to the upper end of a tubular body 61, and the body 61 is inserted into the straw insertion hole 24 and reaches the lower part of the can 1.
The hydrogen discharge pipe 7 is provided between the upper part of the hydrogen storage part 5 and the outside of the tank 1, and is inserted through a support hole 23 supported by the lid 2. Further, the hydrogen discharge pipe 7 and the guide tube 4 are integrated, so that the guide tube 4 and the hydrogen storage part 5 are also supported by the support hole 23 of the lid 2. Further, a tube of an inhaler attached near the nose can be connected to the port of the hydrogen discharge tube 7 on the outside of the tank 1.
The battery 9 becomes a driving source of the electrolysis unit 3, and is replaceable or rechargeable.
The control circuit 10 is a circuit connected between the battery 9 and the electrolysis unit 3, and controls the driving of the electrolysis unit 3.
According to this embodiment, as shown in fig. 4, the lid 2, the guide tube 4, the hydrogen storage part 5, and the hydrogen discharge pipe 7 are integrally removed from the tank 1, and raw water W such as tap water is stored in the tank 1 and used. At this time, since the guide tube 4 is supported by the cover 2 and is insertable into and removable from the tank 1, the guide tube 4 and the hydrogen storage part 5 do not interfere with the injection of the raw water into the tank 1, and the usability is good.
In this mode, the lid 2, the guide tube 4, the hydrogen storage part 5, and the hydrogen discharge pipe 7 are integrally attached to the tank 1 containing the raw water W, and the switch 20 is directly turned on without searching for a power source. That is, the device can be transported to a location without a power supply and used.
When the switch 20 is turned on, the entire electrolytic unit 3 is immersed in the raw water W, and current is applied to the electrode plate 33 on the window 312 side of the casing 31 as a negative electrode and the electrode plate 34 on the reaction chamber 311 side as a positive electrode. As a result, the raw water W is electrically decomposed, hydrogen ions and electrons are generated in the positive electrode plate 34 in the reaction chamber 311 of the housing 31, and hydrogen (gas) is generated in the negative electrode plate 33 exposed in the window hole 312 of the housing 31 through the polymer film 32. This hydrogen forms fine bubbles H, and is therefore efficiently dissolved in the raw water W, and electrolyzed water formed of a hydrogen-rich water is generated inside the tank 1. In addition, if the raw water W is electrically decomposed, ozone (gas) is also generated in the electrode plate 34 of the positive electrode. However, ozone is accumulated in the reaction chamber 311 of the housing 31 without passing through the polymer membrane 32, and if the retention pressure in the reaction chamber 311 of the housing 31 is increased, ozone is discharged from the communication hole 314 of the housing 31. The discharged ozone is formed into large bubbles, and therefore, is not easily dissolved in the raw water W and rises, and is discharged from the ozone discharge port 25 of the cap 2.
Therefore, as shown in fig. 4, by integrally removing the lid 2, the guide tube 4, the hydrogen storage part 5, and the hydrogen discharge pipe 7 from the tank 1, the hydrogen-rich water generated inside the tank 1 can be drunk. At this time, since the guide tube 4 and the hydrogen storage part 5 are supported by the lid 2 and can be inserted into and removed from the tank 1, the guide tube 4 and the hydrogen storage part 5 do not interfere with drinking the hydrogen-rich water in the tank 1, and the usability is good.
Further, by inserting the straw 6 from the lid 2 into the interior of the tank 1, hydrogen-rich water can be drunk. If the suction pipe 6 is used, the generated hydrogen can be prevented from leaking out uselessly.
The hydrogen bubbles H that are not dissolved in the raw water W rise in the raw water W in the tank 1, but are smoothly guided to the hydrogen storage part 5 above by the funnel-shaped guide tube 4. Then, the hydrogen bubbles H guided to be collected are accumulated in the hydrogen storage part 5 which is formed by expanding in a spherical shape in the upper part of the guide tube 4 and has a large volume.
Therefore, the hydrogen can be sucked by bringing the port into contact with the hydrogen discharge pipe 7. Further, the hydrogen bubbles H are efficiently guided and collected by the funnel-shaped guide tube 4, a considerable amount of hydrogen is stored in the hydrogen storage part 5, and the amount of hydrogen discharged from the hydrogen discharge pipe 7 is reliably secured, so that the hydrogen supply device is suitable for hydrogen suction.
As described above, in addition to the illustrated embodiment, a plurality of hydrogen discharge pipes 7 may be connected to or branched from the hydrogen storage unit 5.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260150.5A CN107304478B (en) | 2016-04-25 | 2016-04-25 | Portable Electrolyzer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260150.5A CN107304478B (en) | 2016-04-25 | 2016-04-25 | Portable Electrolyzer |
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| Publication Number | Publication Date |
|---|---|
| CN107304478A CN107304478A (en) | 2017-10-31 |
| CN107304478B true CN107304478B (en) | 2020-05-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610260150.5A Expired - Fee Related CN107304478B (en) | 2016-04-25 | 2016-04-25 | Portable Electrolyzer |
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| Country | Link |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6696058B2 (en) * | 2017-11-09 | 2020-05-20 | 株式会社アクアバンク | Health management system and program of the health management system |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59462U (en) * | 1982-06-23 | 1984-01-05 | 株式会社日立製作所 | Temperature difference hydrogen/oxygen gas generator |
| JP2006218385A (en) * | 2005-02-10 | 2006-08-24 | Shiga Pref Gov | Hydrogen recovery type electrolytic water quality improvement device and hydrogen recovery type electrolytic water quality improvement method. |
| JP2007160171A (en) * | 2005-12-12 | 2007-06-28 | Tsutomu Itaya | Drinking water and / or functional water supply system |
| JP2011526965A (en) * | 2008-07-02 | 2011-10-20 | モレキュラー パワー システムズ エルエルシー | Sonochemical hydrogen generation system with cavitation assistance |
| JP3175997U (en) * | 2012-03-23 | 2012-06-07 | 株式会社日省エンジニアリング | Portable beverage hydrogen water generator |
| JP2014205874A (en) * | 2013-04-11 | 2014-10-30 | 株式会社健康支援センター | Electrolytic device |
| JP3198704U (en) * | 2015-05-01 | 2015-07-16 | 株式会社日省エンジニアリング | Portable electrolyzer |
-
2016
- 2016-04-25 CN CN201610260150.5A patent/CN107304478B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59462U (en) * | 1982-06-23 | 1984-01-05 | 株式会社日立製作所 | Temperature difference hydrogen/oxygen gas generator |
| JP2006218385A (en) * | 2005-02-10 | 2006-08-24 | Shiga Pref Gov | Hydrogen recovery type electrolytic water quality improvement device and hydrogen recovery type electrolytic water quality improvement method. |
| JP2007160171A (en) * | 2005-12-12 | 2007-06-28 | Tsutomu Itaya | Drinking water and / or functional water supply system |
| JP2011526965A (en) * | 2008-07-02 | 2011-10-20 | モレキュラー パワー システムズ エルエルシー | Sonochemical hydrogen generation system with cavitation assistance |
| JP3175997U (en) * | 2012-03-23 | 2012-06-07 | 株式会社日省エンジニアリング | Portable beverage hydrogen water generator |
| JP2014205874A (en) * | 2013-04-11 | 2014-10-30 | 株式会社健康支援センター | Electrolytic device |
| JP3198704U (en) * | 2015-05-01 | 2015-07-16 | 株式会社日省エンジニアリング | Portable electrolyzer |
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| CN107304478A (en) | 2017-10-31 |
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