KR101724631B1 - Hydrogen generating device - Google Patents

Abstract

In the hydrogen generator, the electrolytic electrode is electrolyzed, and the porous ceramic catalyst is combined with oxygen generated during electrolysis to prevent the generation of ozone. In addition, the resistance value of water is measured, and the change according to the kind of the electrolyte dissolved in the water and the concentration of the electrolyte is measured. By varying the voltage according to the measured resistance value, Thereby preventing the generation of harmful components in the human body.

Description

Hydrogen generating device

And more particularly to a technique for generating electrolyzed hydrogen water by generating a hydrogen gas by applying a voltage to an electrode plate contained in water.

Active oxygen, also called harmful oxygen, is produced by excessive production of oxygen due to chemical substances, ultraviolet rays, stress, blood circulation disorder, etc. Such active oxygen oxidizes in the human body and damages the cell membrane, DNA and cells. It also oxidizes several amino acids in the body, resulting in protein degradation. The effect of these active oxygen causes physiological function deterioration, and causes various diseases and aging. It is known that about 90% of modern diseases are related to active oxygen.

Hydrogen can be used to remove this active oxygen. Hydrogen is chemically combined with activated oxygen to obtain an antioxidant effect. Therefore, when a person drinks dissolved water containing hydrogen dissolved in water, touches the skin, or breathes hydrogen itself, an antioxidant effect can be obtained. In recent years, drinking and drinking water have been popular.

An apparatus for producing hydrogen water by electrolysis of water is disclosed in the hydrogen production plant of Publication No. 10-2013-0073831, published on Mar. 03, 2013.

To make hydrogen by electrolyzing water, electrolytes must be present in water. In the case of distilled water, there is no electrolyte and no current flows, so electrolysis can not be performed. However, when water is electrolyzed, the electrolyte itself can be electrolyzed because it causes an electrochemical reaction depending on the dissolved concentration. Specifically, the dissolved electrolyte may be reduced to the extent that the electrolyte is dissolved in water to remain as ions, that is, due to the reactivity, and water may be reduced to generate hydrogen.

Among the cations of electrolytes, K ⁺ , Ca2 +, Mg2 +, Al +, etc. are highly reactive and are reduced to ions to generate H2, and Au, Pt, Ag, Hg and Cu are less reactive than hydrogen ions to reduce the electrolyte. Among the anions of the electrolyte, ions such as F, NO3, CO3, and SO4 have a high reactivity and are likely to remain as ions, so that water is oxidized to generate O2, and Cl is oxidized when the reactivity is smaller than that of oxygen ions. Ultimately, the electrolyte that can be used in the electrolysis of water is an electrolyte consisting of an anion having a high reactivity and a cation having a high reactivity, and the cation and anion having low reactivity, that is, distilled water, can not be electrolyzed.

In the case of salt water, it can be classified into electrolysis of aqueous solution of sodium chloride (NaCl) and electrolysis of sodium chloride (NaCl) according to the concentration of salt dissolved in water. Salt water melt in which pure salt (NaCl) The formula

+ Pole: 2Cl ^{- -} > Cl2 (g) + 2e ^-

- pole: 2Na + + 2e-? 2Na (s)

Cl- [ionic state] becomes a gaseous state while discharging electrons, and Na + [ionic state] obtains electrons and becomes a solid state. In the NaCl solution, if Na precipitates, one species of Na and water will meet and explode, but the Na will not precipitate and hydrogen gas will come out.

When the salt concentration is high depending on the concentration of salt in the water, the brine is electrolyzed and NaCl + H ₂ O → Na ⁺ + Cl ^- + H ₂ O

That is, electrolysis of brine

(Oxidation): 2Cl ^- (Ag) ^- > Cl ₂ (g) + 2e ^-

(Reduction): 2H ₂ O (l) + 2e ^- ? H ₂ (g) + 2OH ^-

The overall reaction is _{^{Cl - (Ag) + H 2}} O (l) → Cl 2 (g) + H 2 (g) + 2OH - (Ag)

That is, chlorine gas and hydrogen gas are produced and the solution becomes NaOH alkali.

As described above, devices that generate hydrogen by electrolyzing various commercialized water in the market cause various chemical reactions according to electrolytes dissolved in water. Therefore, depending on how the water to be electrolyzed is mixed with salt You may have a situation that violates your original purpose.

In one aspect, the hydrogen generator comprises an electrolytic electrode part for electrolyzing water, in which a porous ceramic catalyst for preventing the generation of ozone is formed by bonding with oxygen generated during electrolysis, the resistance value of water being measured, A resistance value measuring unit for measuring a change depending on the kind of the dissolved electrolyte and the concentration of the electrolyte, a power supply unit for applying a voltage insulated from the power supply unit to the electrolysis electrode, And a relay unit that is controlled to apply a voltage to the electrolysis electrode by changing the direction of the current at a predetermined time interval.

In an aspect, the hydrogen generating apparatus may further include a light emitting diode that flashes or illuminates to inform the operation and interruption of the electrolysis in a combination of red, blue, or green. In addition, when the resistance value of the water when the salinity is 10% or more is measured in the resistance value measuring unit, the control unit controls the relay unit to stop the electrolysis by interrupting the power supply, and informs of the interruption by controlling the light emitting diode.

In one aspect, when the resistance value of water when the salinity is less than 4% and less than 10% is measured in the resistance value measuring unit, the control unit lowers the applied voltage and adds a voltage application time corresponding to the lowered voltage So that the relay unit can be controlled to electrolyze.

In one aspect, the control unit may control the power supply unit and the relay unit to electrolyze water for a predetermined time at a maximum voltage when the resistance value of water when the salinity is less than 3% is measured in the resistance value measuring unit.

In one aspect, the resistance value measuring unit measures a variation amount of the resistance value according to the amount of water, and the control unit controls the relay unit so as to vary the time for electrolyzing the water by supplying power according to the variation amount of the measured resistance value. can do.

In one aspect, the control unit controls the voltage supply unit to apply an initial voltage insulated from the power supply voltage without measuring the resistance value across the electrolysis electrode, and to apply a voltage lower than the initial voltage when excessive current flows across the electrode .

 In one aspect, the hydrogen generator may further include a gyro sensor for sensing a slope of the water bottle, and the control unit may control the power supply unit to stop the power supply when the slope of the water bottle measured by the gyro sensor is greater than a predetermined angle.

In one aspect, the hydrogen generator further includes a water level sensing electrode for sensing whether water is in contact, and the control unit may control the power supply unit to stop power supply when the water level sensing electrode senses contact of water.

In one aspect, the hydrogen generating apparatus further includes a pressure sensor for sensing the pressure of hydrogen generated by the electrolysis, and the control unit can control the power supply unit to stop the electrolysis when the pressure detected by the pressure sensor is equal to or higher than a predetermined pressure have.

In one aspect, the hydrogen generating apparatus further includes a usage management unit for managing usage information of the user according to the control contents of the control unit, wherein the usage management unit may further include a storage unit for storing usage information, have.

In an aspect, the hydrogen generator may further include a communication unit connected to the apparatus use expert system to transmit the use information or receive a guide on usage information.

In an aspect, the hydrogen generator may include a first magnetism sensitive power supply isolation switch that operates by the magnetic force of the magnet without physical contact with the magnet to regulate the on-off power of the hydrogen generator.

In one aspect, the hydrogen generating device may further include a waterproof space separated from the electrolysis electrode part and watertight so as to prevent water from coming into contact therewith.

According to an aspect of the present invention, the waterproof space includes a second magnetically sensitive power source insulated switch controlled by the magnetic force of the magnet without physical contact with the magnet, and a magnetically sensitive power source insulated switch protruded outside the waterproof space, And a quick-charge exposing unit including a fast-charge exposure electrode that charges the electrode.

According to an aspect of the present invention, the hydrogen generator includes a main body including the waterproof space therein. The main body includes a water bottle coupling portion having a female screw formed at a lower end of the main body so as to connect the main body and the water bottle, A cylindrical electrolytic electrode bar including a rotating switch which is rotated and operated, an electrolytic electrode portion, a power supply portion, and a protrusion formed on an upper end of the electrolytic electrode bar, and a fixing groove And the electrolytic electrode bar protrudes in the lower end direction of the main body after the protrusion and the fixing groove are coupled to each other, and can enter the main body when the main body is connected to the main body.

In one aspect, the main body may further include a vertical passage through which water can pass, and a lid coupling portion in which a male screw is formed so that a cover for opening and closing the passage is coupled to the upper portion.

In an aspect, the body or lid may further include a nozzle connected to the hose of the hydrogen respirator.

In one aspect, the hydrogen generator of the electronic cigarette model includes a power supply unit including a charging circuit, a secondary battery, and an insulated DC-DC converter, a hydrogen generating unit which is coupled to the power supply unit at one side thereof, The hydrogen generating unit may include a porous ceramic catalyst for preventing generation of ozone by binding with oxygen generated when water is electrolyzed, wherein the hydrogen generating unit includes a cylindrical electric motor having a vertical passage, And a liquid absorber including a part of the electrolysis electrode embedded in one side of the decomposition electrode and the suction port.

In an aspect, the suction portion may include a suction hole through which the user can suck hydrogen, a fine hole through which the user enters the outside air to be mixed with hydrogen at the time of suction into the suction hole, and an adjusting portion that rotates to open and close the fine hole.

Depending on the component dissolved in the water, the voltage to be applied is regulated to improve the dependence on water by proper electrolysis. In addition, the hydrogen issuing device is combined with a water bottle which is easily provided in everyday life, thereby improving the accessibility of a small number of people to the public.

1 is a block diagram showing a configuration of an internal circuit of a hydrogen generator.
FIG. 2 is a graph showing the magnitude of a voltage, a current, and a measured resistance value applied over time when the hydrogen generator is operated.
FIG. 3 shows an algorithm for varying the size of a power source to be applied according to the value measured by the resistance value measuring unit of the hydrogen generator.
4 is a view showing a configuration of a hydrogen generator comprising a water bottle and a main body.
5 shows an embodiment in which the hydrogen generator is composed of a body that can be coupled to a general bottled water bottle.
FIG. 6 shows an embodiment of a hydrogen generator having a nozzle in a lid and a person breathing with a hydrogen respirator attached to the nozzle.
7 is a view of an embodiment showing an electric electrode bar.
FIG. 8 is a block diagram of a hydrogen generator having an electronic cigarette model. FIG.
9, 10, 11, and 12 are views showing a hydrogen generator capable of being immersed in water.
Fig. 13 shows an embodiment in which the hydrogen generator for immersing in water is decomposed.

The foregoing and further aspects of the present invention will become more apparent through the following examples. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the like elements throughout.

1 is a block diagram showing a configuration of an internal circuit of a hydrogen generator according to the present invention. Fig. 2 is a block diagram showing a simplified configuration of the drawing of Fig. 1, the hydrogen generator may include an electrolysis electrode unit 3, a resistance value measuring unit 10, a power supply unit 11, a control unit 12, and a relay unit 9.

In one embodiment, the electrolysis electrode unit 3 includes a positive electrode and a negative electrode, and the electrodes are disposed so as to be in contact with the water 1. When power is supplied to the electrodes, the water 1 that is in contact is electrolyzed.

In one aspect, the porous electrolytic catalyst unit 4 is disposed in the electrolytic electrode unit 3, and the catalyst is combined with oxygen generated when water is electrolyzed to prevent ozone generation. 1 shows an example of the appearance of the porous ceramic catalyst 4 placed in the electrolysis electrode parts 3-1 and 3-2. The porous ceramic catalyst (4) is a ceramic made by synthesizing various minerals such as magnesium, iron oxide, and tourmaline. When the water (1) is electrolyzed and decomposed into two hydrogen and one oxygen, ozone can be generated. When the catalyst (4) is placed in the electrolysis electrode unit (3), oxygen and a ceramic catalyst 4) are combined to prevent ozone from being generated. In one embodiment, the hydrogen-producing formula is 2H ₂ O + Mg -> Mg (OH) ₂ + H ₂ , with _two magnesium in K electron shell, eight in L electron shell, and two electrons in M shell And two outermost electrons among these electrons have a reducing power because electrons can easily be emitted in an unstable state. When magnesium reacts with water, one molecule of magnesium reacts with two molecules of water, where magnesium is not liberated and magnesium hydroxide is formed, in which part of the electrons from magnesium are used to form hydrogen gas and the remaining electrons Remains in the water. Magnesium hydroxide is ionized to form a hydroxyl group (OH ^- ). At this time, the mononuclear oxygen is bonded to ozone (O ₃ ) instead of oxygen molecule. In other words, magnesium is oxidized, water is reduced instead of water, and hydrogen is electrolyzed. Breathing of drinking water and hydrogen gas produced by synthesizing electrolytic hydrogen gas and ceramics minerals such as magnesium, iron oxide and tourmaline (tourmaline) The most radical of the hydroxy radicals is selectively bound to H ₂ O, resulting in antioxidative effects. These antioxidants have a reduction potential of -100mV - 1989mV with a negative (-) oxidation-reduction potential.

In one aspect, the resistance value measuring unit 10 measures the resistance value of the water 1, and can measure the change depending on the type of the electrolyte dissolved in the water and the concentration of the electrolyte. In one embodiment, the resistance value measuring unit 10 is an analog-to-digital converter.

The resistance value measuring unit 10 measures the resistance value of water for a predetermined time in a state in which the power supply is cut off. At this time, as will be described later, the relay unit 9 can cut off the power supply.

 In one embodiment, the resistance value of the water measured by the resistance value measuring unit 10 can be measured in consideration of the type of the electrolyte dissolved in water and the concentration of the electrolyte. For example, when the concentration of salt, that is, the salt concentration, which has the greatest influence on the electrical resistance value among the various electrolytes dissolved in water, the resistance value measuring unit 10 measures the current resistance value, Based on the current salinity can be measured. Alternatively, the resistance value measuring unit 10 can detect a change in salinity which is dissolved in water based on a change in the electrical resistance value of water. In addition to salinity, other electrolytes may be considered, which can become toxic gases due to chemical reactions during electrolysis.

In an aspect, the power supply unit 11 may apply an insulated voltage to the electrolysis electrode 3 from the power supply unit. In one embodiment, the power supply 11 is a DC-DC converter. The power supply unit 11 applies a voltage to the electrolytic electrode with a step-up DC-DC conversion circuit in which the primary side and the secondary side are completely insulated from each other in order to supply the electrode unit in contact with water and the power supply unit completely independently. Also, the power supply unit 11 supplies power to the control unit 12 and the like, which will be described later, to enable operation of the hydrogen generator.

In one aspect, the control unit 12 controls the power supply unit 11 so as to vary the voltage according to the resistance value measured by the resistance value measuring unit 10. That is, the measured resistance value is the same as changing the voltage depending on the kind and concentration of the electrolyte, since the type and concentration of the electrolyte can be known as described above. As will be described later, depending on the measured resistance value, the magnitude of the applied voltage is changed in consideration of the result of the electrolytic concentration of the electrolytic substance on the human body. For example, if the resistance value of the electrolyte such as salt iron is small, the electrolysis voltage and the current are reduced, and when the electrolyte resistance value is high, the maximum rated voltage and the appropriate current are supplied. The graphs of 35 and 36 in FIG. 2 show an embodiment in which the magnitude of the voltage to be applied is changed to V1 and V2 according to the resistance value.

In an aspect, the relay unit 9 can control the voltage to be applied to the electrolysis electrode while changing the direction of the current at a predetermined time interval. In one embodiment, the relay portion 9 may be a latch relay or a solid state relay circuit. The polarity of the power source supplied to the electrode by the relay unit 9 is inverted at a predetermined time interval to prevent the chemical transition of the electrodes.

In an aspect, the hydrogen generating device may include a light emitting diode 56. The light emitting diode 56 may be blinked or illuminated to inform the operation and interruption of the electrolysis in a combination of red, blue or green. The control unit 12 can control the blinking and illumination of the light emitting diode 56. [ In one embodiment, the color of the light emitting diode 56 may be composed of a color other than the color mentioned.

3 is an algorithm showing the operation of the hydrogen generator according to the measured resistance value. The contents of the algorithm of FIG. 3 will be described below with reference to the block diagram of FIG.

In an aspect, the control unit 12 controls the relay unit 9 to stop the electrolysis when the resistance value of the water when the salinity is 10% or more is measured by the resistance value measuring unit 10 . At the same time, the light emitting diode 56 can be controlled to notify of the interruption. If the salinity of the water is more than 10% (for example, in seawater), the current is larger than the applied voltage due to the high electrolyte content, and as a result, the current becomes higher than the allowable value. It is for this reason.

Also, as described above, the control unit 12 controls the light emitting diode unit 56 to inform that the red light is blinking or illuminated and the electrolysis is stopped.

In another aspect, the control unit 12 controls the power supply unit 11 so as to lower the voltage applied when the resistance value of water is measured when the salinity is less than 4% and less than 10% in the resistance value measuring unit 10 Can be controlled. When the salinity is less than 4% and less than 10%, it is possible to prevent gas other than hydrogen from being generated by applying a voltage lowering, so electrolysis is not stopped immediately as when the salinity is 10%. In addition, by controlling the relay unit 9 to electrolytically add a voltage application time corresponding to the lowered voltage, an appropriate amount of hydrogen gas can be generated. Then, the user can inform the user of the current electrolysis state by blinking or illuminating the light emitting diode 56 in green. In one embodiment, when the salinity is less than 4% and less than 10% and the voltage is applied at a lower voltage and the current flows into the range of the resistance value when the salinity is less than 3% The light emitting diode 56 may be blinked or illuminated to inform the current electrolysis state.

In an aspect, the control unit 12 controls the power supply unit 11 and the power supply unit 12 to electrolyze water for a predetermined time at a maximum voltage when the resistance value of water when the salinity is less than 3% is measured in the resistance value measuring unit 10 The relay unit 9 can be controlled. In this case, the rate of salinity is low, so even if the voltage is applied to the maximum, the current does not flow over the allowable value. FIG. 4 is a graph for applying a voltage of Vmax for a predetermined time. As shown in the algorithm of FIG. 3, when the current is applied to the electrolysis electrode unit 3 at Vmax, the current is electrolyzed for a predetermined time, and the blue LED 56 is blinked or illuminated. Can be informed.

In one aspect, the resistance value measuring unit 10 can measure the amount of change of the resistance value according to the amount of water. In one embodiment, the resistance value measuring unit 10 can measure that the area of contact between the electrolytic electrode and water changes according to the amount of water, and the resistance value becomes finer or smaller. The resistance value measuring unit 10 transmits information on the amount of change to the control unit 12 whenever the resistance value measured by a change in the amount of water changes slightly.

In one aspect, when the resistance value measuring unit 10 measures a change in the resistance value due to the change in the amount of water, the control unit 12 controls the relay unit 10 to vary the time for electrolyzing the water according to the change amount. Can be controlled. As described above, when the amount of water contained in the container changes and the area of contact between the electrolysis electrode 3 and the water changes, the resistance value measuring unit 10 measures the resistance value according to the change, The control unit 12 immediately transmits the control signal to the control unit 12 to control the relay unit 9. In one embodiment, as the contact area increases due to an increase in the amount of water, the resistance value becomes finer. Therefore, the switching of the relay unit 9 is controlled so as to reduce the electrolysis time. Conversely, Since the resistance value becomes finer, the switching of the relay unit 9 is controlled so as to increase the electrolysis time.

In an aspect, the control unit 12 applies an initial voltage insulated from the power supply voltage without measuring the resistance value at both ends of the electrolysis electrode 3, and when an excessive current flows across the electrode, a voltage lower than the initial voltage The voltage supply unit 11 can be controlled. 4, the control unit 12 controls the voltage supply unit 11 to lower the voltage to V4, and the current (Ip) is supplied to the control unit 12. When the voltage V3 is applied to the electrolytic electrode 3, . In this control process, the resistance value is measured after the current is lowered by controlling the voltage without measuring the resistance value as shown in 40 of FIG.

In an aspect, the hydrogen generator may include a water bottle 2, a gyro sensor 6, and the like. The water bottle (1) is a container capable of holding water to be brought into contact with the electrode (3) of the hydrogen generator. The gyro sensor 6 senses the inclination of the water bottle 2, and the operation principle of the sensor is obvious to a person skilled in the art, and a description thereof will be omitted.

In an aspect, the control unit 12 can control the power supply unit 11 to stop power supply when the slope of the water bottle measured by the gyro sensor 6 is equal to or greater than a predetermined angle. If the water bottle 2 is inclined at a certain angle or more, water may be accumulated, so that the power supply is controlled to be blocked in advance.

In one aspect, it may further include a water level sensing electrode 7 for sensing whether water is in contact. The water level sensing electrode 7 is located at the upper end of the water tank 2 to allow the user to gauge how much water 1 is filled in the water tank 2. The water level sensing electrode 7 can be placed at an appropriate position according to the size and shape of the water tank 2.

In an aspect, the control unit 12 can control the power supply unit 11 to stop the power supply when the water level sensing electrode 7 senses contact of water. In one embodiment, when the contact of water with the water level sensing electrode 7 is detected, it means that water is present in the water tank up to the water level sensing electrode 7 or more, and there is not much spare space in the water tank 2 . In this case, if the hydrogen gas continues to be generated by continuing the electrolysis, the pressure inside the water tank 2 may become excessively high. Therefore, when the water level sensing electrode 7 senses the contact of water, the control unit 12 immediately transmits the sensing signal to the control unit 12 so that the power supply unit 11 is controlled.

In an aspect, the hydrogen generating apparatus may further include a pressure sensor 5. [ The pressure sensor 5 can sense the pressure of hydrogen generated by the electrolysis of water. The pressure sensor 5 senses the pressure of the hydrogen gas in the water bottle and transmits a sensing signal to the control unit 12 to control the electrolysis according to the sensed pressure.

In an aspect, the control unit 12 can control the power supply unit 11 to stop the electrolysis when the pressure sensed by the pressure sensor 5 is equal to or higher than a predetermined pressure. In one embodiment, when the electrolyzed water is a small space such as a plastic bottle or a PET bottle, safety problems such as explosion may occur when the pressure of the hydrogen gas electrolyzed with water is higher than a certain level. Accordingly, when the pressure sensor 5 senses a predetermined pressure or more, the control unit 12 transmits a detection signal to the control unit 12 so that the pressure no longer reaches the danger level, and the control unit 12 controls the power supply unit 11 to stop power supply.

In an aspect, the hydrogen generating apparatus may include a usage management unit. The usage management unit may further include a storage unit 13 and a communication unit 18. [

In one aspect, the use management unit can manage the usage information of the user according to the control content of the control unit 12. [ In one embodiment, the usage information is information about the user using hydrogen decomposition apparatus, for example, the time of electrolysis of water, the amount of water electrolysis, resistance value, electrolyte type, electrolyte concentration, . Or the magnitude of the voltage that has been electrolyzed, the magnitude of the current, and the like.

In an aspect, the storage unit 13 may store usage information of a user managed by the usage management unit. At this time, the storage unit 13 may disable the modification of the stored contents. As a result, the user can safely manage the usage information.

In one aspect, the communication unit 18 may connect to the device use expert system 30 to transmit usage information, or receive a guide on usage information. In one embodiment, the communication unit 18 is a wireless communication module capable of communicating with a short distance communication module such as Bluetooth of a smart phone or a tablet PC, or with a proximity communication module such as NFC, ISO1443 PXD. The device usage expert system 30 may be a system of a provider providing the hydrogen generating device or a system of a technician who professionally manages the use of the device. The system can receive usage information of the user's hydrogen generator through the communication unit 18, analyze the information, and generate the user's guide on the basis of the analysis result of the usage information. By transmitting the guide information to the user, it is possible to induce correct use of the hydrogen generator. The hydrogen generator may receive the information through the communication unit 18 and notify the user.

In an aspect, the hydrogen generating device includes a watertight space. The waterproof space is separated from the electrolysis electrode unit 3, and is a space sealed and waterproof so that water does not come into contact therewith. The first magnetism sensitive power supply isolation switch 24 may be included in the waterproof space. The first magnetism sensitive power source isolation switch can be operated by the magnetic force of the magnet without physically contacting the magnet to control the on-off power of the hydrogen generator.

In a further aspect, the waterproof space may further include a second magnetism sensitive power supply isolation switch 24 and a rapid charge exposure unit 25. [ The second magnetism sensitive power source isolation switch 24 is controlled by the magnetic force of the magnet without physical contact with the magnet. The rapid charging and exposing unit 25 can protrude out of the waterproof space and charge the secondary battery by connecting the magnetism sensitive power source insulation switch when the magnet touches it. In one embodiment, the first magnetization sensitive power supply isolation switch and the second magnetization sensitive power supply isolation switch are connected to the secondary battery fast charge circuit. When the magnet is brought into contact with the rapid charging and exposing unit 25, the first magnetism sensitive power source insulated switch and the second magnetism sensitive power source insulated switch are switched by the magnetic force so that the charging current flows into the sealed hydrogen generator. Therefore, the charging current flows through the secondary battery quick charging circuit and the secondary battery to charge the secondary battery. 5 is a view showing the first and second magnetism sensitive power source isolation switches 24a and 24b, the quick charge exposure unit 25, and the quick charging electrode unit magnet 27. FIG.

6 is a view showing an embodiment of a hydrogen generator including the circuit of FIG. 1 inside. Fig. 7 shows a state in which the hydrogen generator of Fig. 6 is combined with a water bottle. FIG. 8 is an exploded view of the hydrogen generator of FIG. 6. FIG.

In an aspect, the hydrogen generating apparatus includes a main body 41. [ The main body 41 may include the aforementioned waterproof space 23 therein. In a specific aspect, the main body 41 further includes a water bottle coupling portion, a rotation switch 42, an electrolysis electrode rod 3, and a fixing groove.

The water bottle coupling portion is formed with a female screw at the lower end of the main body so as to connect the main body 41 and the water bottle 2. The rotary switch 42 is a ring structure in which the magnetism sensitive power source isolation switch is rotated and operated. For example, the rotary switch 42 has a magnet 22, and when the rotary switch is rotated, the magnet is also rotated, and the magnetism sensitive power source isolation switch operates according to the movement of the magnet.

In a specific aspect, the electrolysis electrode rod 3 may further include the electrolysis electrode portion 3, the power supply portion 11, and the projection portion described above. In one embodiment, the electrolysis electrode portion 3 may be a cylinder-shaped bar. FIG. 8 is a view showing a specific shape of the electric electrode bar 3. FIG.

In a specific aspect, the electrolysis electrode rod 3 protrudes in the lower end direction of the main body after the protruding portion and the fixing groove are coupled, and is inserted into the water bottle when the main body is connected to the main body. In one embodiment, the protruding portion is fitted on the upper end of the electrolysis electrode rod 3 by a fixing bump existing in the main body, so that the electrolysis electrode rod is not shaken to the main body. FIG. 6 shows a state in which the electrolysis electrode rod 3 is joined to the lower end of the main body 41 after being joined.

In an aspect, the body may further include a vertical passage, a lid engagement portion. Vertical passages are vertical passages through which water can pass. As shown in FIG. 5, when the main body is coupled to the water bottle, there is a vertical passage in the main body so that the water contained in the water bottle flows into the hole at the upper end of the main body. The lid-engaging portion is formed with a male screw so as to engage with a lid for opening and closing the passage.

In one aspect, the body 41 may include a nozzle. The nozzle 70 is a nozzle that can be connected to the hose of the hydrogen respirator. Or the cover covering the main body 41 may include a nozzle. Figures 6, 7 and 11 show the shape of the nozzle in the lid and the hydrogen respirator 69 connected to the nozzle. The user 70 can suck the hydrogen gas by connecting the hydrogen ventilator 69 to the nozzle 70 and using the hydrogen ventilator.

12 is a view showing a hydrogen generator of the electronic cigarette model. The hydrogen generator of the electronic cigarette model includes a power supply unit 11, a hydrogen generator, and a suction unit 61.

In one embodiment, the power supply 11 may include a charging circuit 15, a secondary battery, and an isolated DC-DC converter.

In an aspect, the hydrogen generating portion is coupled to the power supply portion on one side and may be separated.

In an aspect, the suction portion 61 may be combined with the hydrogen generating portion at one side opposite to the one side where the hydrogen generating portion is coupled to the power supply portion 11. [

In a specific aspect, the hydrogen generating unit is provided with a porous ceramic catalyst (4) for preventing generation of ozone by combining oxygen generated when water is electrolyzed, wherein the water tank (2) of the hydrogen generator has a vertical passage And a liquid absorbing material 65 in which a part of the electrolysis electrode 3 is embedded at one side where the cylindrical electrolysis electrode 3 and the inlet 61 are coupled. The electrolysis electrode is cylindrical and concentric with a central opening (3). Therefore, the area of the electrode in contact with the water can be increased. The liquid absorbent 65 may isolate water with a porous sponge to prevent water from leaking and allow only hydrogen bubbles 66 to pass through.

In an aspect, the suction portion 61 may further include a suction port, a fine hole 63, and a regulating portion 62. The suction port is a hole through which the user can suck hydrogen, and the fine hole 63 is a hole through which external air to be mixed with hydrogen can be introduced when the user sucks in the suction port. The adjusting portion 62 can rotate and close the fine holes 63. [ In one embodiment, when the fine holes are opened by rotating the regulating portion 62, hydrogen and air are mixed, and the user can drink the air mixed hydrogen when he / she sucks in the suction port and sucks it.

1. Water 2. Water bottle, water bottle
3. Electrolysis electrode part 4. Ceramic catalyst
5. Pressure sensor 6. Gyro (tilt measurement) sensor
7. Water level sensing electrode 8. Bottle cap with pressure valve
9. Relay section 10. Resistance value measuring section
11. Power supply 12. Control unit
13. Storage unit 14. Secondary battery
15. Rechargeable battery fast charge circuit 16. Non-contact charge receiver
17. Non-contact charge transfer unit 18. Communication unit
19. AC-DC adapter 20. Smartphone
21A. Magnetic Sensing Power Switch 21B.Magnetic Sensing Mode 1 Switch
21C. Magnetically sensitive mode 2 switch 22. Magnet
23. Waterproof space 24a. Magnetically-sensitive power isolated switch
24b. Magnetically-sensitive power isolated switch
25. Rapid charge exposure section 27. Quick charge electrode section magnet
28. Communication network 29. Wireless communication
30. Device usage expert system server 31. Local communication department
32. Induction wireless charging 33. Rapid charge contact exposed part insulation structure
34. Power supply voltage supply waveform 35. Water electrolyte resistance measurement
36. Water electrolysis voltage pole conversion supply
37. Water electrolysis current waveform 38. Voltage step down waveform
39. Current measurement waveform 40. Measurement of water electrolyte resistance value
V1. Electrolysis maximum voltage V2. Electrolysis voltage step-down
V3. Initial maximum voltage V4. Overcurrent Prevention Step-Down Voltage
Ip: Maximum allowable current 41. Body
42. Power / Mode Selection Rotary Switch
43. Bottled water bottle 44. Hydrogen generator for bottled water
45. Bottled water bottle cap 46. USB rapid charge cable
47. Bottled water passage structure 48. Hydroponic storage bottle
49. Hydrogen generator for water immersion IP65 level sealed waterproof part
50. Submerged hydrogen generator cover 51. Hydrogen generator tank in air
52. Portable and storage mode of immersion hydrogen generator
53. Hydrogen generator for flooding IP65 seal rubber O-ring
54. Disassembly prevention assembly structure water tank 55. Light guide tube
56. Red, blue, green light emitting diode 57. Cylindrical electrolysis electrode insertion part
58. Cylindrical Electrolysis Internal and External Electrode Gap (GAP)
59. Non-contact wireless charging loop coil 60. Insulator
61. Suction part
62. Adjustment part 63. Micro hole
64. Air mixing passage 65. Liquid absorbing material
66. Hydrogen Bubble 67. Magnets
68. Magnetic contact charging connector 69. Breathing tube (CANNULA)
70. Bottles of breathing tube instead of bottled water bottle pressure valve
71. Sports water bottle lid Nozzle for breathing tube instead of pressure valve
72. Person breathing hydrogen with breathing tube

Claims (17)

An apparatus for generating hydrogen by electrolyzing water,
An electrolytic electrode part in which a porous ceramic catalyst is disposed for electrolyzing water, the porous ceramic catalyst being combined with oxygen generated during electrolysis to prevent the generation of ozone;
A resistance value measuring unit for measuring a resistance value of water, the resistance value measuring unit measuring a change depending on the kind of the electrolyte dissolved in the water and the concentration of the electrolyte;
A voltage is applied to the electrolysis electrode by using a step-up DC-DC conversion circuit in which a primary side connected to the power source device and a secondary side connected to the electrolysis electrode are insulated to apply an insulated voltage from the power source device to the electrolysis electrode Power supply;
A control unit for controlling the power supply unit to vary the voltage according to the resistance value measured by the resistance value measuring unit;
A relay unit controlled to apply a voltage to the electrolysis electrode while changing the direction of the current at a predetermined time interval; And
And a light emitting diode for flashing or illuminating the operation and interruption of the electrolysis so as to be notified by a combination of red, blue or green,
The resistance value measuring unit
Measuring a change amount of the resistance value according to an amount of water,
The control unit
Wherein when the resistance value of the water when the salinity is 10% or more is measured by the resistance value measuring unit, the relay unit is controlled so as to stop the electrolysis by interrupting the power supply,
The resistance value measuring unit may lower the applied voltage when the resistance value of water is measured when the salinity is less than 4% and less than 10%, and may further reduce the voltage applied to the relay unit Control,
The resistance value measuring unit controls the power supply unit and the relay unit to electrolyze water for a predetermined time at a maximum voltage when the resistance value of water when the salinity is less than 3%
And controls the relay unit to vary the time for electrolysis of water by supplying power according to the variation of the measured resistance value. delete delete delete delete The apparatus of claim 1, wherein the control unit
And an initial voltage insulated from the power supply voltage is applied without measuring a resistance value across the electrolysis electrode, and when the excessive current flows across the electrode, the power supply unit is controlled to apply a voltage lower than the initial voltage. The method according to claim 1,
Further comprising a gyro sensor for sensing a slope of the water bottle,
The control unit
And controls the power supply unit to stop power supply when the slope of the water bottle measured by the gyro sensor is equal to or greater than a predetermined angle. The method according to claim 1,
And a water level sensing electrode for sensing whether or not the water contact is made,
The control unit
And controls the power supply unit to stop power supply when the water level sensing electrode senses contact of water. The method according to claim 1,
Further comprising a pressure sensor for sensing the pressure of hydrogen generated by the electrolysis of water,
The control unit
And controls the power supply unit to stop the electrolysis when the pressure detected by the pressure sensor is equal to or higher than a predetermined pressure. The method according to claim 1,
And a usage management unit for managing usage information of the user according to the control contents of the control unit,
The use management unit
A storage unit for storing the usage information, wherein the storage unit can not be modified after the usage information is stored;
A communication unit connected to the device use expert system to transmit the use information or receive a guide on usage information;
Further comprising a hydrogen generator. The method according to claim 1,
And a first magnetism sensitive power source isolation switch which is operated by the magnetic force of the magnet without physically contacting the magnet to adjust the on-off power of the hydrogen generator, and is separated from the electrolysis electrode part, Waterproof space;
Further comprising: 12. The apparatus of claim 11, wherein the water-
A second magnetically sensitive power source isolation switch controlled by the magnetic force of the magnet without physical contact with the magnet; And
A quick charge exposure unit including a quick charge exposure unit for charging the secondary battery by connecting the magnetism sensitive power source insulation switch when the magnet protrudes out of the waterproof space;
Further comprising a hydrogen generator. 13. The method according to claim 11 or 12,
A main body including the waterproof space therein;
The body
A bucket coupling portion having a female screw formed at a lower end of the main body to couple the main body and the bucket;
A rotary switch having a ring structure in which the first magnetism sensitive power source insulation switch is rotated and operated;
A cylindrical electrolytic electrode rod including the electrolytic electrode portion, the power supply portion, and a protrusion formed on an upper end thereof; And
A fixing groove through which the electrolytic electrode bar can be engaged with the main body through the projection; / RTI >
The electrolytic electrode rod
And a protrusion protruding in a lower end direction of the main body after the protrusion and the fixing groove are coupled to each other,
Hydrogen generator. 14. The apparatus of claim 13, wherein the body
A vertical passage through which water can pass;
A lid engaging portion at the upper end of which a male screw is formed so as to engage with a lid opening and closing;
Further comprising a hydrogen generator. 15. The apparatus of claim 14, wherein the body or cover
A nozzle connected to the hose of the hydrogen respirator;
Further comprising: An electronic cigarette-like hydrogen generator, comprising:
A charging circuit, a secondary battery, and a step-up DC-DC converter insulated from a secondary side connected to the electrolysis electrode and a primary side connected to the power source device, A power supply unit for applying a voltage to the electrolysis electrode using a step-up DC-DC conversion circuit in which a primary side and a secondary side are insulated;
A hydrogen generating unit coupled to the power supply unit at one side thereof and being separable;
A suction unit coupled to the hydrogen generating unit at one side opposite to the one side; And
A light emitting diode for flashing or illuminating the operation and interruption of the electrolysis to inform a combination of red, blue or green; , ≪ / RTI &
The hydrogen generator
The electrolytic cell according to any one of claims 1 to 3, wherein the porous electrolytic electrode is a porous ceramic catalyst which is combined with oxygen generated when water is electrolyzed to prevent the generation of ozone, A water bottle containing a liquid absorbent;
A resistance value measuring unit for measuring a resistance value of water, the resistance value measuring unit measuring a change depending on the kind of the electrolyte dissolved in the water and the concentration of the electrolyte;
A control unit for controlling the power supply unit to vary the voltage according to the resistance value measured by the resistance value measuring unit; And
A relay unit controlled to apply a voltage to the electrolysis electrode while changing the direction of the current at a predetermined time interval; / RTI >
The resistance value measuring unit
Measuring a change amount of the resistance value according to an amount of water,
The control unit
Wherein when the resistance value of the water when the salinity is 10% or more is measured by the resistance value measuring unit, the relay unit is controlled so as to stop the electrolysis by interrupting the power supply,
The resistance value measuring unit may lower the applied voltage when the resistance value of water is measured when the salinity is less than 4% and less than 10%, and may further reduce the voltage applied to the relay unit Control,
The resistance value measuring unit controls the power supply unit and the relay unit to electrolyze water for a predetermined time at a maximum voltage when the resistance value of water when the salinity is less than 3%
And controls the relay unit to vary the time for electrolysis of water by supplying power according to the variation of the measured resistance value. 17. The apparatus of claim 16, wherein the suction portion
An inlet through which the user can suck hydrogen;
A fine hole through which external air to be mixed with hydrogen enters when the user sucks the air through the inlet; And
A control unit for rotating and opening the fine holes;
Further comprising:

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