CN107298913A - A kind of novel wet sliver - Google Patents
A kind of novel wet sliver Download PDFInfo
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- CN107298913A CN107298913A CN201610237864.4A CN201610237864A CN107298913A CN 107298913 A CN107298913 A CN 107298913A CN 201610237864 A CN201610237864 A CN 201610237864A CN 107298913 A CN107298913 A CN 107298913A
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- Prior art keywords
- sliver
- parts
- weight
- wet
- wet sliver
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a kind of novel wet sliver.The wet sliver includes：8 12 parts by weight emulsions, 0.1 1 parts by weight color stuffings, 0.1 4.5 parts by weight cosolvents, 0.5 2 parts by weight polyphosphazene polymer carbohydrates and 80.5 91.3 parts by weight water.The wet sliver of the present invention can replace traditional dry sliver, the artistic effect of existing traditional sliver, and with low cost, color controllable, energy-conserving and environment-protective.
Description
Technical field
The invention belongs to coating material field, in particular it relates to a kind of novel wet of alternative conventional dry sliver
Sliver, the various artistic effects of its existing conventional dry sliver have with low cost, color controllable, energy-saving ring again
The characteristics such as guarantor.
Background technology
The true mineral varnish of sliver, is also artificial grantie paint, category novel pure Water-borne modification without any solvent-borne type material
Sand textured building coating, is the upgrading kind of traditional natural real stone paint.The single uninteresting true mineral varnish of sand wall-like or
Other building coatings lack granitic spot effect, it is impossible to compared favourably with it.
As Coating Market share shared by the true mineral varnish of sliver is increasing, critical materials sliver consumption is also increasingly
Greatly.At present, traditional sliver of in the market large usage quantity is dry sliver, and power consumption is big and price is high.
In summary, this area is a kind of new, energy-conserving and environment-protective, cheap in the urgent need to developing,
And the wet sliver with dry sliver performance, the wet sliver can be made different colours, specification to produce not on demand
Same visual effect.
The content of the invention
It is an object of the invention to provide a kind of novel wet sliver, its preparation method of alternative conventional dry sliver
And application, the artistic effect of the wet existing conventional dry sliver of sliver, be again it is a kind of it is new, energy-conserving and environment-protective,
Cheap coating material.
First aspect present invention includes there is provided a kind of wet sliver, the wet sliver：8-12 parts by weight emulsion, 0.1-1
Parts by weight color stuffing, 0.1-4.5 parts by weight cosolvent, 0.5-2 parts by weight polyphosphazene polymer carbohydrates and 80.5-91.3 weights
Measure part water.
In another preference, the emulsion is 9-11 parts by weight.
In another preference, the cosolvent is 2-4 parts by weight.
In another preference, the polyphosphazene polymer carbohydrate is 1-1.8 parts by weight.
In another preference, described emulsion is selected from the group：Silicone acrylic emulsion, pure-acrylic emulsion or its combination.
In another preference, described color stuffing is selected from the group：Titanium dioxide, kaolin or its combination.
In another preference, described color stuffing is common rutile type titanium white R996 (purchased from the imperial boa titanium in Sichuan
White Co., Ltd).
In another preference, described cosolvent is selected from the group：Thickener, pH adjusting agent, wetting dispersing agent,
Defoamer, coalescents, bactericide, antifreezing agent or its combination in tank.
In another preference, described thickener is selected from the group：It is cellulose thickener, alkali swollen thickener, poly-
Urethane thickener or its combination.
In another preference, described thickener is selected from the group：250HBR (Ya Shilan), AR6159 (Tao Shi),
RM-2020 (Tao Shi) or its combination.
In another preference, described pH adjusting agent is selected from the group：Multifunction amine cosolvent, organosilicon hydrotropy
Agent or its combination.
In another preference, described pH adjusting agent is selected from the group：AMP-95 (Tao Shi), BS-16 (Wa Ke),
Or its combination.
In another preference, described wetting dispersing agent is selected from the group：Ammonium salt dispersant, nonionic wetting and dispersing
Agent or its combination.
In another preference, described wetting dispersing agent is selected from the group：SN5027 (Nuo Puke), LCN-407 (sections
Lai En) or its combination.
In another preference, described defoamer is selected from the group：Mineral oil defoaming agent, organic silicon defoamer,
Or its combination.
In another preference, described defoamer is selected from the group：NXZ (Nuo Puke), SN345 (Nuo Puke),
Or its combination.
In another preference, described coalescents are Lauryl Alcohol ester.
In another preference, described antifreezing agent is selected from the group：Propane diols, ethylene glycol or its combination.
In another preference, bactericide is selected from the group in described tank：Formaldehyde (623A), Kathon CG, BIT or
It is combined.
In another preference, the polyphosphazene polymer carbohydrate is (bright purchased from Qinghai for synthesis sodium alginate APAGNT
Glue).
There is provided a kind of wet sliver base for being used to form the wet sliver of first aspect present invention for second aspect of the present invention
Material, the wet sliver base-material includes：8-12 parts by weight emulsion, 0.1-1 parts by weight color stuffing, 0.1-4.5 parts by weight
Cosolvent, 0.5-2 parts by weight polyphosphazene polymer carbohydrates and 80.5-91.3 parts by weight water.
In another preference, described wet sliver base-material has the one or more features being selected from the group：
(1) 4 weeks, outward appearance, viscosity Non Apparent Abnormality under normal temperature (21 DEG C -25 DEG C)；
(2) high temperature (50-60 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(3) low temperature (2-8 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(4) freeze thawing 3 is circulated, outward appearance, viscosity Non Apparent Abnormality；And/or
(5) mill base addition 1%, the visual color no significant difference of color developing, aberration is less than or equal to 0.5.
In another preference, above-mentioned is characterized in respectively to be determined in the case where humidity is 45%-55%.
In another preference, the wet sliver base-material is crushed by section to be made as described in the first aspect of the invention
Wet sliver.
Third aspect present invention is there is provided a kind of wet sliver coating, and the wet sliver coating is to use such as first party of the present invention
Wet sliver coating described in face is obtained, or described wet sliver coating includes as described in the first aspect of the invention wet
Sliver.
Fourth aspect present invention includes there is provided a kind of wet sliver stone paint, the wet sliver stone paint：
(1) wet sliver as described in the first aspect of the invention, and
(2) true mineral varnish.
In another preference, in the wet sliver stone paint, the mass fraction of wet sliver is 0.1-15wt%,
Preferably 2-10wt%, is more preferably 5-10wt%.
In another preference, the wet sliver stone paint has following one or more features：
(1) 55 DEG C stores 30 days without gelatinization, no gel；Construction is without gelatinization；And/or
(2) 3 circulations of freeze thawing are without gelatinization, no gel；And/or
(3) mechanical agitation 10 minutes, size is without significant change, and true mineral varnish is without obvious discoloration；And/or
(4) artificial ageing 1000H grades are not more than 1 grade.
Fifth aspect present invention includes there is provided a kind of product, the product：
(1) base material, priming paint and the true stone of wet sliver as described in fourth aspect present invention being coated on the priming paint
Coating；And
(2) it is coated in the protective layer on coating film.
In another preference, described base material is cement or concrete.
In another preference, described priming paint is true mineral varnish base paint special.
In another preference, the protective layer is selected from：Coating varnish, the agent of resistant cover or its combination, preferably
Ground is coating varnish and resistant cover agent.
Sixth aspect present invention includes step there is provided a kind of wall construction method, methods described：
(1) metope is coated with priming paint；
(2) after 2h, second is carried out on the priming paint with the wet sliver stone paint as described in fourth aspect present invention
Secondary coating；
(3) after 24h, third time coating is carried out on the wet sliver coating with coating varnish.
In another preference, described metope is cement wall surface.
It should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the invention and below (such as embodiment)
It can be combined with each other between each technical characteristic of middle specific descriptions, so as to constitute new or preferred technical side
Case.As space is limited, no longer tire out one by one herein and state.
Embodiment
The present inventor is surprised to find that a kind of new to replace biography by extensively and in depth studying, first
Unite the wet sliver of dry sliver, wet sliver of the invention had both had the various special artistic effects of conventional dry sliver, and again might be used
With effectively energy-saving and emission-reduction, cost is reduced.The present invention is completed on this basis.
Term explanation
Unless otherwise defined, otherwise whole technologies used herein are respectively provided with such as institute of the present invention with scientific terminology
The identical meanings that the those of ordinary skill in category field is generally understood that.
As used herein, in use, term " about " means that the value can be from the numerical value specifically enumerated is mentioned
The value enumerated, which changes, is not more than 1%.For example, as used herein, " about 100 " include 99 and 101 Hes for statement
Between whole values (for example, 99.1,99.2,99.3,99.4 etc.).
As used herein, term " containing " or " including (including) " can be it is open, semi-enclosed and
It is enclosed.In other words, the term also include " substantially by ... constitute " or " by ... constitute ".
Wet sliver base-material
The invention provides a kind of wet sliver base-material, the wet sliver base-material includes：8-12 parts by weight emulsions, 0.1-1
Parts by weight color stuffing, 0.1-4.5 parts by weight cosolvents, 0.5-2 parts by weight polyphosphazene polymer carbohydrates and 80.5-91.3 weights
Measure part water.
In another preference, described emulsion species is not particularly limited, and is preferably selected from the group：The breast of silicon third
Liquid, pure-acrylic emulsion or its combination.
In another preference, described emulsion is that RS996AD silicone acrylic emulsions (are purchased from the limited public affairs of the well-off industry of Ahmedabad
Department).
In another preference, described titanium dioxide is not particularly limited, preferably rutile type titanium white.
In another preference, described color stuffing is to be common rutile type titanium white R996 (purchased from the imperial boa in Sichuan
Titanium white Co., Ltd).
In another preference, described cosolvent is selected from the group：Thickener, PH conditioning agents, wetting dispersing agent,
Defoamer, coalescents, bactericide, antifreezing agent or its combination in tank.
In another preference, described thickener is selected from the group：Cellulose thickener 250HBR (Ya Shilan),
Alkali swollen thickener AR6159 (Tao Shi), polyurethane thickener RM-2020 (Tao Shi) or its combination.
In another preference, described pH adjusting agent is selected from the group:Multifunction amine cosolvent AMP-95 (Tao Shi),
Organosilicon cosolvent BS-16 (Wa Ke).
In another preference, described wetting dispersing agent is selected from the group:Ammonium salt dispersant (Nuo Pu section SN5027),
Nonionic wetting dispersing agent (Clariant LCN-407) or its combination.
In another preference, described defoamer is selected from the group：Mineral oil defoaming agent, organic silicon defoamer,
Or its combination.
In another preference, described coalescents are Lauryl Alcohol ester.
In another preference, described polyphosphazene polymer carbohydrate is synthesis sodium alginate AP AGNT (Qinghai gelatin).
In another preference, described wet sliver base-material has the one or more features being selected from the group：
(1) normal temperature (21 DEG C -25 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(2) high temperature (50-55 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(3) low temperature (2-8 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(4) freeze thawing 3 is circulated, outward appearance, viscosity Non Apparent Abnormality；And/or
(5) mill base addition 1%, the visual color no significant difference of color developing, aberration is less than or equal to 0.5.
Wet sliver
The wet sliver base-material is made to 400-600 μm of wet film, cured 2-3 points of liquid solidification of membrane equipment
Zhong Hou, crushing obtains the wet sliver.
In another preference, contain preservative in wet sliver, can be placed with the closing of long period
In another preference, described solidify liquid is a kind of chemistry examination that reaction is participated in wet sliver binder systems for use
Agent solution, concentration 0-2%.
In another preference, the wet sliver size is selected from the group：Large stretch of 0.5cm*0.5cm, middle
0.3cm*0.3cm, small pieces 0.1cm*0.1cm or its combination.
In another preference, described membrane equipment includes roller, spout of funnel, spray equipment.
In another preference, described membrane equipment, which has, is selected from the group one or more feature：
(1) roller：Roller is manufactured using the technique of improved corrosion, and obtained roller size is big, circularity is good, surface
Smooth coefficients are high, durable reliable.In addition, the control system and deceleration system excellent performance of roller, speed arbitrarily may be used
Adjust；
(2) spout of funnel：Bell mouth stability of flow, flow is adjustable, automatic switch, and discharging is uniform；And/or
(3) spray equipment：Automatic start-stop, starts spray, time-delay closing after shutdown, to ensure that roller is washed during start
And delay time is adjustable only,.
In another preference, the disintegrating apparatus includes cutter.
In another preference, the cutter adjusts rotating speed, the spray of roller by controlling the frequency of cutting knife
Discharge rate size be made needed for length, the wet sliver of size.
Wet sliver stone paint
Wet sliver of the present invention is according to specific color, specific specification, specific ratio and specific true stone
Paint mixing, is made the wet true mineral varnish coating of sliver.
The present invention provides a kind of wet true mineral varnish coating of sliver, and the wet true mineral varnish coating of sliver includes：
(1) wet sliver as described in the first aspect of the invention, and
(2) true mineral varnish.
In another preference, in the wet sliver stone paint, the mass fraction of wet sliver is 0.1-15wt%,
Preferably 2-10wt%, is more preferably 5-10wt%.
In another preference, the wet sliver stone paint has following one or more features：
(1) 55 DEG C stores 30 days without gelatinization, no gel；Construction is without gelatinization；And/or
(2) 3 circulations of freeze thawing are without gelatinization, no gel；And/or
(3) mechanical agitation 10 minutes, size is without significant change, and true mineral varnish is without obvious discoloration；And/or
(4) artificial ageing 1000H grades are not more than 1 grade.
Product
The present invention provides a kind of product, and the product includes：
(1) base material, priming paint and the true stone of wet sliver as described in fourth aspect present invention being coated on the priming paint
Coating；And
(2) it is coated in the protective layer on coating film.
In another preference, described base material has no particular limits, and described base material is cement or concrete.
In another preference, described priming paint is true mineral varnish base paint special.
In another preference, the protective layer is selected from：Coating varnish, the agent of resistant cover or its combination, preferably
Ground is coating varnish and resistant cover agent.
Construction method
The construction method of the present invention has no particular limits.
In another preference, a kind of wall construction method of the invention, including step：
The metope is coated with priming paint；
After 2h, carried out with the wet sliver stone paint as described in fourth aspect present invention on the priming paint second
Coating；
After 24h, third time coating is carried out on the wet sliver coating with coating varnish.
In another preference, described metope is cement wall surface.
Main advantages of the present invention are：
The special-effect that has of the existing traditional sliver of wet sliver product of the present invention, but it is energy-conserving and environment-protective, cheap.
It can be accomplished scale production there is provided the wet sliver of multiple color, plurality of specifications by specific production equipment, and
It can be placed with the storage of long period.
Compared with the market like product, the present invention is advantageous in that：
(1) wet sliver of the invention and the overall cost of true mineral varnish coating reduce at least 50%；
(2) mix colours convenient, random color can be produced as requested, is as good as with latex paint toning；
(3) color chips toughness is strong, can be cut with knife, be resistant to true mineral varnish and mix for a long time, be not gelatinized, do not fade；
(4) lead-free pigment is used, meets environmental requirement；
(5) weatherability, colour retention are good；
(6) mildew and algae is good；
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are only used for
The bright present invention rather than limitation the scope of the present invention.The experiment side of unreceipted actual conditions in the following example
Method, generally according to normal condition, or according to the condition proposed by manufacturer.Unless otherwise indicated, otherwise
Percentage and number are percentage by weight and parts by weight.
Experiment material and reagent used can be obtained from commercially available channel unless otherwise instructed in following examples.
Raw material used in the following example is as follows.
1. silicone acrylic emulsion
Species：Organosilicon-modified acrylic polymer
2. titanium dioxide
Species：Rutile-type
Fineness：2000 mesh
3. thickener
Species：Cellulose family
4.PH conditioning agents
Species：Multifunction amine
5. wetting dispersing agent
Species：Non-ionic wetting agent
6. defoamer
Species：NXZ、SN345
7. coalescents
Species：Alcohol ester-12
8. dry film mildew and algae agent
9. bactericide in tank
Species：BIT
10. polyphosphazene polymer carbohydrate
Species：Sodium alginate
11. solidify liquid
Species：Small molecule inorganic salts
12. dispersant
Species：Polyacrylic acid sodium salt
13. antifreezing agent
Species：Propane diols
Embodiment 1
By the pure water of 51.4 parts by weight, the thickener hydroxyethyl cellulose (250HBR) of 0.7 parts by weight, 0.9 weight
The wetting dispersing agent SN5027 of part, pH adjusting agent AMP-95, the defoamer of 0.3 parts by weight of 0.1 parts by weight
NXZ, the R996 titanium dioxides of 1 parts by weight, the polyphosphazene polymer carbohydrate sodium alginate AP AGNT of 1.2 parts by weight,
Pre- slurry 1-1 is made for 30 minutes in scattered (1500r/min) at a high speed after well mixed.
Will it is scattered after the completion of pre- slurry 1-1 and the silicone acrylic emulsion RS996AD of 10 parts by weight, 0.5 parts by weight
Lauryl Alcohol ester, the propane diols of 1 parts by weight, the defoamer NXZ of 0.3 parts by weight, the preservative of 0.1 parts by weight
623A, 32.5 parts by weight pure water, stirring at low speed, mixing (800r/min) are until uniform, obtained wet sliver base-material
1。
The component table of 1 embodiment of table 1
The wet performance of sliver base-material 1 of table 2
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
By above-mentioned wet sliver base-material, it is film-made by 600 micron thickness, calcium chloride (I for being placed in parts by weight 1.5%
Fourth AR99.5%) in solution, 1-2min is reacted, film is completely fallen off；Film is collected in tank, with the edge of a knife
Three leaf oar high speed point of contacts are to needing size (large stretch of 0.5cm*0.5cm, middle 0.3cm*0.3cm, small pieces
Untill 0.1cm*0.1cm), wet sliver 1 is made.
The wet performance of sliver 1 of table 3
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The wet sliver 1 of 10 parts by weight is added in the true mineral varnish QA-357B of ippon sliver, propeller agitation is used
15min, until stirring, is made the wet true mineral varnish 1 of sliver.Will the obtained wet true stone of sliver with true mineral varnish spray gun
Paint 1 is uniformly sprayed by way of spraying on the model or metope that have rolled priming paint in advance, by every square metre
2KG consumption is calculated；Dry after 24h, coat finishing varnish.
The true performance of mineral varnish 1 of the wet sliver of table 4
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
Embodiment 2
Pre- slurry 1-1 preparation in be the same as Example 1, difference is to increase the wetting agent of 0.1 parts by weight
LCN407, is made pre- slurry 2-1.
The silicone acrylic emulsion RS996AD of pre- slurry 2-1 and 10 parts by weight after the completion of scattered, the ten of 0.5 parts by weight
Two carbon alcohol esters, the propane diols of 1 parts by weight, the wetting agent LCN407 of 0.1 parts by weight, the defoamer of 0.3 parts by weight
NXZ, the preservative 623A of 0.1 parts by weight, the pure water stirring at low speed (800r/min) of 32 parts by weight, mixing, directly
To uniform, wet sliver base-material 2 is made.
The component table of 5 embodiment of table 2
The wet performance of sliver base-material 2 of table 6
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
Ibid, by wet sliver base-material 2, by 600 micron thickness be film-made, be placed in parts by weight 1.5% calcium chloride (Ah
Latin AR99.5%) in solution, 1-2min is reacted, film is completely fallen off；Film is collected in tank, with the band edge of a knife
Three leaf oar (customized) high speed point of contacts to needing size (large stretch of 0.5cm*0.5cm, middle 0.3cm*0.3cm, small pieces
0.1cm*0.1cm), wet sliver 2 is made.
The wet performance of sliver 2 of table 7
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The wet sliver 2 prepared of 10 parts by weight is added in the true mineral varnish QA-357B of ippon sliver, spiral shell is used
Oar stirring 15min is revolved, until stirring, the wet true mineral varnish 2 of sliver is made.Will be obtained wet with true mineral varnish spray gun
The true mineral varnish 1 of sliver is uniformly sprayed by way of spraying on the model or metope that have rolled priming paint in advance, is pressed
Every square metre of 2KG consumption is calculated；Dry after 24h, coat finishing varnish.
The true performance of mineral varnish 2 of the wet sliver of table 8
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
Traditional dry sliver is contrasted by wet sliver 2 and on the market, indices such as table 10 below
The wet sliver 2 of table 9 and commercially available prod comparative result
| Performance | Wet sliver 2 | Commercially available prod |
| Cost | About 6 yuan/KG | About 25 yuan/KG |
| Color diversity | Color is various | Color is various |
| Resistance to stirring | Be placed in true mineral varnish stir 10 minutes it is without exception | Easily diminish |
| Store points for attention | Note fungus-proof antisepsis | Note the moisture absorption |
| Effect | A variety of imitation stone effects | A variety of imitation stone effects |
The result of table 9 shows, compared with commercially available prod (conventional dry sliver), wet sliver of the invention can not only and market
Upper traditional dry sliver effect quite, and has obvious price advantage.
Comparative example 1
By the pure water of 50 parts by weight, the hydroxyethyl cellulose 250HBR, the PH of 0.1 parts by weight of 0.7 parts by weight
Conditioning agent AMP95, the defoamer NXZ of 0.3 parts by weight, the titanium dioxide R996 of 1 parts by weight, 5 parts by weight are forged
Kaolin DG-80, the polyphosphazene polymer carbohydrate sodium alginate APAGNT of 1.2 parts by weight are burnt, it is high after being well mixed
Pre- slurry C1-1 is made for 30 minutes in speed scattered (1500r/min).
The silicone acrylic emulsion RS996AD of pre- slurry C1-1 and 10 parts by weight after the completion of scattered, the ten of 0.5 parts by weight
Two carbon alcohol esters, the propane diols of 1 parts by weight, the defoamer NXZ of 0.3 parts by weight, the preservative 623A of 0.1 parts by weight,
The pure water of 31.2 parts by weight continues stirring at low speed (800r/min), mixing, until it is uniform, wet sliver base-material C1 is made.
The wet sliver base-material C1 performances of table 10
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
By above-mentioned wet sliver base-material, it is film-made by 600 micron thickness, calcium chloride (I for being placed in parts by weight 1.5%
Fourth AR99.5%) in solution, 1-2min is reacted, film is completely fallen off；Film is collected in tank, with the edge of a knife
Wet sliver C1 is made to size is needed in three leaf oar (customized) high speed point of contacts.
The wet sliver C1 performances of table 11
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The wet sliver C1 prepared of 10 parts by weight is added in special true mineral varnish, propeller agitation 15min is used,
Until stirring, the wet true mineral varnish C1 of sliver is made.
The true mineral varnish C1 performances of the wet sliver of table 12
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
Increase by 5 parts by weight calcined kaolins, easy dry linting, the appearance of powder when can cause the wet sliver to cut into slices.
Comparative example 2
By the pure water of 51.4 parts by weight, the thickener hydroxyethyl cellulose 250HBR of 0.7 parts by weight, 0.1 weight
Part PH conditioning agents AMP95, the defoamer NXZ of 0.3 parts by weight, the titanium dioxide R996 of 1 parts by weight, 1.2
The polyphosphazene polymer carbohydrate sodium alginate APAGNT of parts by weight, 30 points of high speed scattered (1500r/min) after being well mixed
Pre- slurry C2-1 is made in clock.
The silicone acrylic emulsion RS996AD of pre- slurry C2-1 and 5 parts by weight after the completion of scattered, the ten of 0.5 parts by weight
Two carbon alcohol esters, the propane diols of 1 parts by weight, the wetting agent LCN407 of 0.1 parts by weight, the NXZ of 0.3 parts by weight,
The preservative 623A of 0.1 parts by weight, the pure water of 38.3 parts by weight continue stirring at low speed (800r/min), mixing, directly
To uniform, wet sliver base-material C2 is made.
The wet sliver base-material C2 performances of table 13
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
By above-mentioned wet sliver base-material C2, it is film-made by 200/400/500 micron thickness, is placed in parts by weight 1.5%
In calcium chloride (Aladdin AR99.5%) solution, 1-2min is reacted, film is completely fallen off；Film is collected in tank,
With three leaf oar (customized) the high speed point of contacts with the edge of a knife untill size is needed, wet sliver C2 is made.
The wet sliver C2 performances of table 14
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The wet sliver C2 of 500 microns of films of 10 parts by weight is added to the true mineral varnish QA357B of ippon sliver, used
Propeller agitation 15min, until stirring, is made the wet true mineral varnish C2 of sliver.
The true mineral varnish C2 performances of the wet sliver of table 15
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
Emulsion content is too low to cause the poor toughness of color dot, and resistance to stirring is poor, and glossiness is low；And when being film-made,
Relatively thin film is easily crimped, bad mechanical property.
Comparative example 3
By the pure water of 51.4 parts by weight, the thickener hydroxyethyl cellulose 250HBR of 0.7 parts by weight, 0.1 weight
Part PH conditioning agents AMP95, the defoamer NXZ of 0.3 parts by weight, the titanium dioxide R996 of 1 parts by weight, 0.4
The polyphosphazene polymer carbohydrate sodium alginate APAGNT of parts by weight, 30 points of high speed scattered (1500r/min) after being well mixed
Pre- slurry C3-1 is made in clock.
The silicone acrylic emulsion RS996AD of pre- slurry C3-1 and 5 parts by weight after the completion of scattered, the ten of 0.5 parts by weight
Two carbon alcohol esters, the propane diols of 1 parts by weight, the wetting agent LCN407, the NXZ of 0.3 parts by weight of 0.1 parts by weight,
The preservative 623A of 0.1 parts by weight, the pure water of 39 parts by weight continue stirring at low speed, mixing (800r/min), until
Uniformly, wet sliver base-material C3 is made.
The wet sliver base-material C3 performances of table 16
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
By above-mentioned wet sliver base-material C3, be film-made by 600 micron thickness, be placed in parts by weight 1.5% calcium chloride (Ah
Latin AR99.5%) in solution, 1-2min is reacted, film is completely fallen off；Film is collected in tank, with the band edge of a knife
Three leaf oar (customized) high speed point of contacts untill size is needed, be made wet sliver C3.
The wet sliver C3 performances of table 17
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The wet sliver C3 of 500 microns of films of 10 parts by weight is added to the true mineral varnish QA357B of ippon sliver, used
Propeller agitation 15min, until stirring, is made the wet true mineral varnish C3 of sliver.
The true mineral varnish C3 performances of the wet sliver of table 18
(data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%)
The content of polyphosphazene polymer carbohydrate is very big to wet sliver performance impact, and APAGNT content is too low to be caused to prepare
Color dot thermmal storage be easily gelatinized, and it is poor to add resistance to stirring property in true mineral varnish.
Compared with existing dry sliver, wet sliver of the invention has identical fidelity in stone-like coating,
Perception, texture, touch sense, rough sense have all reached stone effect.
All documents referred in the present invention are all incorporated as reference in this application, just as each document
It is individually recited as with reference to such.In addition, it is to be understood that after the above-mentioned instruction content of the present invention has been read,
Those skilled in the art can make various changes or modifications to the present invention, and these equivalent form of values equally fall within this Shen
Please appended claims limited range.
Claims (10)
1. a kind of wet sliver, it is characterised in that the wet sliver includes：
8-12 parts by weight emulsion, 0.1-1 parts by weight color stuffing, 0.1-4.5 parts by weight cosolvent, 0.5-2 parts by weight are high
Molecule glycan class and 80.5-91.3 parts by weight water.
2. wet sliver as claimed in claim 1, it is characterised in that described emulsion is selected from the group：The breast of silicon third
Liquid, pure-acrylic emulsion or its combination.
3. wet sliver as claimed in claim 1, it is characterised in that described cosolvent is selected from the group：Thickening
Agent, pH adjusting agent, wetting dispersing agent, defoamer, coalescents, bactericide, antifreezing agent or its group in tank
Close.
4. wet sliver as claimed in claim 1, it is characterised in that described wetting dispersing agent is selected from the group：
Ammonium salt dispersant, nonionic wetting dispersing agent or its combination.
5. a kind of wet sliver base-material for being used to form the wet sliver of claim 1, it is characterised in that described wet
Sliver base-material includes：
8-12 parts by weight emulsion, 0.1-1 parts by weight color stuffing, 0.1-4.5 parts by weight cosolvent, 0.5-2 parts by weight are high
Molecule glycan class and 80.5-91.3 parts by weight water.
6. wet sliver base-material as claimed in claim 5, it is characterised in that described wet sliver base-material has choosing
From one or more features of the following group：
(1) 4 weeks, outward appearance, viscosity Non Apparent Abnormality under normal temperature (21 DEG C -25 DEG C)；
(2) high temperature (50-60 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(3) low temperature (2-8 DEG C) 4 weeks, outward appearance, viscosity Non Apparent Abnormality；
(4) freeze thawing 3 is circulated, outward appearance, viscosity Non Apparent Abnormality；And/or
(5) mill base addition 1%, the visual color no significant difference of color developing, aberration is less than or equal to 0.5.
7. a kind of wet sliver coating, the wet sliver coating is coated with wet sliver as claimed in claim 1
Arrive, or described wet sliver coating includes wet sliver as claimed in claim 1.
8. a kind of wet sliver stone paint, it is characterised in that the wet sliver stone paint includes：
(1) wet sliver as claimed in claim 1, and
(2) true mineral varnish.
9. a kind of product, the product includes：
(1) base material, priming paint and the wet sliver stone paint as claimed in claim 8 being coated on the priming paint；
And
(2) it is coated in the protective layer on coating film.
10. a kind of wall construction method, methods described includes step：
(1) metope is coated with priming paint；
(2) after 2h, second is carried out on the priming paint with wet sliver stone paint as claimed in claim 8 and is applied
Cover；
(3) after 24h, third time coating is carried out on the wet sliver coating with coating varnish.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610237864.4A CN107298913B (en) | 2016-04-15 | 2016-04-15 | Novel wet rock slice |
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|---|---|---|---|
| CN201610237864.4A CN107298913B (en) | 2016-04-15 | 2016-04-15 | Novel wet rock slice |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101492577A (en) * | 2008-01-23 | 2009-07-29 | 吴钢 | Process for producing watersoluble stone design imitating color slice and use scheme |
| CN105131755A (en) * | 2015-10-09 | 2015-12-09 | 浙江华特实业集团华特化工有限公司 | Self-crosslinking liquid slice true stone paint preparing method |
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2016
- 2016-04-15 CN CN201610237864.4A patent/CN107298913B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101492577A (en) * | 2008-01-23 | 2009-07-29 | 吴钢 | Process for producing watersoluble stone design imitating color slice and use scheme |
| CN105131755A (en) * | 2015-10-09 | 2015-12-09 | 浙江华特实业集团华特化工有限公司 | Self-crosslinking liquid slice true stone paint preparing method |
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| CN107298913B (en) | 2020-05-05 |
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