CN107298869A - A kind of flame-retardant wood-plastic composite material - Google Patents

A kind of flame-retardant wood-plastic composite material Download PDF

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Publication number
CN107298869A
CN107298869A CN201710735177.XA CN201710735177A CN107298869A CN 107298869 A CN107298869 A CN 107298869A CN 201710735177 A CN201710735177 A CN 201710735177A CN 107298869 A CN107298869 A CN 107298869A
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CN
China
Prior art keywords
parts
flame
wood
retardant
plastic composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710735177.XA
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Chinese (zh)
Inventor
汪漭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongcheng City Jin Yu Plastic Packing Co
Original Assignee
Tongcheng City Jin Yu Plastic Packing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongcheng City Jin Yu Plastic Packing Co filed Critical Tongcheng City Jin Yu Plastic Packing Co
Priority to CN201710735177.XA priority Critical patent/CN107298869A/en
Publication of CN107298869A publication Critical patent/CN107298869A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of flame-retardant wood-plastic composite material, by weight, include the raw material components of following parts by weight:20 40 parts of polypropylene, 40 55 parts of wood fibre, 20 30 parts of maleic anhydride grafted polyethylene, 10 15 parts of fire retardant, 35 parts of plasticizer, 46 parts of light stabilizer, 25 parts of antioxidant, 13 parts of lubricant.This flame-retardant wood-plastic composite material excellent in mechanical performance of the present invention, with fabulous rigidity, impact property and good dimensional stability;Fire retardant is added in the present invention, the thermal degradation speed of wood plastic composite is reduced, 800 DEG C of carbon yields of material are improved, flame retardant effect is notable.

Description

A kind of flame-retardant wood-plastic composite material
Technical field
The present invention relates to wood plastic composite field, specifically a kind of flame-retardant wood-plastic composite material.
Background technology
Wood plastic composite is composited by string and plastics, has the feature performance benefit of timber and plastics concurrently, is one New environment-friendly materials are planted, its product is mainly used as the substitute of timber, but due to the primary raw material wood in wood plastic composite Fiber and plastics belong to combustible material, using there is certain potential safety hazard, it is necessary to carry out flame retardant treatment.Polyolefin and timber It is fire-retardant frequently with inorganic combustion inhibitor, halogen containing flame-retardant and phosphonium flame retardant etc..Due to unfavorable shadow of the halogen containing flame-retardant to environment Ring, the halogen-free flameproof of material is paid much attention to by people, and inorganic combustion inhibitor flame retarding efficiency is low, Flame Retardancy is reached Certain requirement, filling quality fraction need to be up to 40-60%, so can be very big on the mechanical mechanics property influence of material, it is difficult to Reach use requirement.
The content of the invention
The invention provides a kind of flame-retardant wood-plastic composite material, to solve above-mentioned technical problem.
A kind of flame-retardant wood-plastic composite material, by weight, includes the raw material components of following parts by weight:Polypropylene 20-40 Part, 40-55 parts of wood fibre, 20-30 parts of maleic anhydride grafted polyethylene, 10-15 parts of fire retardant, 3-5 parts of plasticizer, light are stable 4-6 parts of agent, 2-5 parts of antioxidant, 1-3 parts of lubricant.
It is preferred that, the fire retardant is in ammonium phosphate, sulfamic acid, sulfamic acid ammonia, phosphoguanidine or Guanidine Sulfamate 99 One or more.
It is preferred that, the lubricant is microcrystalline wax.
It is preferred that, a kind of flame-retardant wood-plastic composite material by weight, includes the raw material components of following parts by weight:Poly- third 30 parts of alkene, 48 parts of wood fibre, 25 parts of maleic anhydride grafted polyethylene, 13 parts of fire retardant, 4 parts of plasticizer, 5 parts of light stabilizer, 3.5 parts of antioxidant, 2 parts of lubricant.
Beneficial effects of the present invention:
This flame-retardant wood-plastic composite material excellent in mechanical performance of the present invention, with fabulous rigidity, impact property With good dimensional stability;Fire retardant is added in the present invention, the thermal degradation speed of wood plastic composite is reduced, improves material 800 DEG C of carbon yields of material, flame retardant effect is notable.The addition of other fire retardant influences not on the tensile strength of wood plastic composite Greatly, the bending strength to wood plastic composite is significantly improved.It is fire-retardant in the case where the mechanical mechanics property of material is basically unchanged Effect significantly, is worthy to be popularized.
Embodiment
Embodiments of the invention are described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Below by way of specific embodiment, the present invention will be described in detail.
The present invention includes embodiment in detail below:
Embodiment 1
A kind of flame-retardant wood-plastic composite material, by weight, includes the raw material components of following parts by weight:20 parts of polypropylene, 40 parts of wood fibre, 20 parts of maleic anhydride grafted polyethylene, 10 parts of fire retardant, 3 parts of plasticizer, 4 parts of light stabilizer, antioxidant 2 parts, 1 part of lubricant.
Above-mentioned fire retardant be ammonium phosphate, sulfamic acid, sulfamic acid ammonia, phosphoguanidine or one kind in Guanidine Sulfamate 99 or It is a variety of.
Above-mentioned lubricant is microcrystalline wax.
Embodiment 2
A kind of flame-retardant wood-plastic composite material, by weight, includes the raw material components of following parts by weight:30 parts of polypropylene, 48 parts of wood fibre, 25 parts of maleic anhydride grafted polyethylene, 13 parts of fire retardant, 4 parts of plasticizer, 5 parts of light stabilizer, antioxidant 3.5 parts, 2 parts of lubricant.
Above-mentioned fire retardant be ammonium phosphate, sulfamic acid, sulfamic acid ammonia, phosphoguanidine or one kind in Guanidine Sulfamate 99 or It is a variety of.
Above-mentioned lubricant is microcrystalline wax.
Embodiment 3
A kind of flame-retardant wood-plastic composite material, by weight, includes the raw material components of following parts by weight:40 parts of polypropylene, 55 parts of wood fibre, 30 parts of maleic anhydride grafted polyethylene, 15 parts of fire retardant, 5 parts of plasticizer, 6 parts of light stabilizer, antioxidant 5 parts, 3 parts of lubricant.
Above-mentioned fire retardant be ammonium phosphate, sulfamic acid, sulfamic acid ammonia, phosphoguanidine or one kind in Guanidine Sulfamate 99 or It is a variety of.
Above-mentioned lubricant is microcrystalline wax.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention Spirit and principle within the modifications, equivalent substitutions and improvements made etc., should be included in the claim protection model of the present invention Within enclosing.

Claims (4)

1. a kind of flame-retardant wood-plastic composite material, it is characterised in that by weight, includes the raw material components of following parts by weight:It is poly- 20-40 parts of propylene, 40-55 parts of wood fibre, 20-30 parts of maleic anhydride grafted polyethylene, 10-15 parts of fire retardant, plasticizer 3-5 Part, 4-6 parts of light stabilizer, 2-5 parts of antioxidant, 1-3 parts of lubricant.
2. the flame-retardant wood-plastic composite material according to claims 1, it is characterised in that the fire retardant is ammonium phosphate, ammonia One or more in base sulfonic acid, sulfamic acid ammonia, phosphoguanidine or Guanidine Sulfamate 99.
3. the flame-retardant wood-plastic composite material according to claims 1, it is characterised in that the lubricant is microcrystalline wax.
4. the flame-retardant wood-plastic composite material according to claims 1, it is characterised in that by weight, including it is following heavy Measure the raw material components of part:30 parts of polypropylene, 48 parts of wood fibre, 25 parts of maleic anhydride grafted polyethylene, 13 parts of fire retardant, plasticising 4 parts of agent, 5 parts of light stabilizer, 3.5 parts of antioxidant, 2 parts of lubricant.
CN201710735177.XA 2017-08-24 2017-08-24 A kind of flame-retardant wood-plastic composite material Withdrawn CN107298869A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710735177.XA CN107298869A (en) 2017-08-24 2017-08-24 A kind of flame-retardant wood-plastic composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710735177.XA CN107298869A (en) 2017-08-24 2017-08-24 A kind of flame-retardant wood-plastic composite material

Publications (1)

Publication Number Publication Date
CN107298869A true CN107298869A (en) 2017-10-27

Family

ID=60132541

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710735177.XA Withdrawn CN107298869A (en) 2017-08-24 2017-08-24 A kind of flame-retardant wood-plastic composite material

Country Status (1)

Country Link
CN (1) CN107298869A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110467771A (en) * 2019-07-24 2019-11-19 宣城福美达新材料有限公司 A kind of preparation method of high temperature resistant Wood-plastic material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812237A (en) * 2010-04-23 2010-08-25 杭州师范大学 Flame-retardant wood-plastic composite material and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812237A (en) * 2010-04-23 2010-08-25 杭州师范大学 Flame-retardant wood-plastic composite material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110467771A (en) * 2019-07-24 2019-11-19 宣城福美达新材料有限公司 A kind of preparation method of high temperature resistant Wood-plastic material

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Application publication date: 20171027