CN107297943B - A kind of preparation process of environmental protection wall paper - Google Patents

A kind of preparation process of environmental protection wall paper Download PDF

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Publication number
CN107297943B
CN107297943B CN201710440281.6A CN201710440281A CN107297943B CN 107297943 B CN107297943 B CN 107297943B CN 201710440281 A CN201710440281 A CN 201710440281A CN 107297943 B CN107297943 B CN 107297943B
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bamboo
wallpaper
bamboo chip
cattail
stem
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CN107297943A (en
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董晶龙
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Zhejiang Ya Qinuo ornament materials Co., Ltd
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Zhejiang Ya Qinuo Ornament Materials Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27JMECHANICAL WORKING OF CANE, CORK, OR SIMILAR MATERIALS
    • B27J7/00Mechanical working of tree or plant materials not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/003Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
    • B27K5/0055Radio-waves, e.g. microwaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/06Softening or hardening of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27LREMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
    • B27L7/00Arrangements for splitting wood
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Forests & Forestry (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of preparation processes of environmental protection wall paper, and any pollution will not be caused to environment, uses bamboo and the stem or leaf of cattail not only low in cost as wallpaper made of raw material, but also environmental protection;Bamboo fibre increases the intensity and toughness of wallpaper, improves wallpaper quality, makes it easier to fitting metope, durable and will not blister, bamboo chip increases its functionality by sterilization and mothproof processing, the PVC film on wallpaper surface plays fire-retardant effect, it is therefore prevented that a possibility that burning;The present invention has rational design, low in cost, safety and environmental protection, is suitable for production and promotes and applies.

Description

A kind of preparation process of environmental protection wall paper
Technical field
The present invention relates to wallpaper preparation technical fields, more specifically more particularly to a kind of preparation process of environmental protection wall paper.
Background technique
Wallpaper, also referred to as wallpaper, it is a kind of quite extensive indoor hardware fitting of application.Because wallpaper has color more Sample, pattern is abundant, and a variety of other house decorative materials such as luxurious style, safety and environmental protection, easy for construction, affordable can not compare Quasi- feature, therefore obtain in developed countries and regions such as Europe, America and Japan considerable degree of universal.Wallpaper is divided into many classes, such as covers Membranous wall paper, coating wallpaper, embossing wallpaper etc..Body paper, then the working process through different processes usually are produced with bleached wood pulp, If modeling is covered on coating, printing, embossing or surface, dispatch from the factory after last cut, packaging.Because having certain intensity, toughness, beauty Appearance and good water repelling property, be widely used in house, office, interior decoration of hotel etc..With living standard Continuous improvement, the decorating and renovating materials such as wall are widely used.Wall have wearability, resistance tocrocking, anti-cracking function, compared with Strong decorative effect, the features such as convenient for keeping a public place clean, but the environmental issue being exposed is also more and more.According to the technique of domestic production Feature, wall may be detrimental to health there are three classes harmful substance, i.e. formaldehyde, heavy metal, vinyl chloride monomer.
It would therefore be highly desirable to need to provide a kind of environmental protection wall paper, to solve wall in the prior art, there are three classes harmful substances, i.e. first Aldehyde, heavy metal, vinyl chloride monomer, the problem of may being detrimental to health.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of preparation of the environmental protection wall paper proposed Technique.
To achieve the goals above, present invention employs following technical solutions:
A kind of preparation process of environmental protection wall paper, includes the following steps:
S1, raw bamboo cutting:Raw bamboo is truncated into bamboo section along the position close to ring two sides, removes ring, leaves thick bamboo tube, Thick bamboo tube is longitudinally cutd open into thick bamboo sheet, the width of each thick bamboo sheet is in 10cm-12cm;
S2, sterilization processing:By bamboo chip in micro-wave oven microwave treatment 8min-10min, power is in 35kw-45kw, by bamboo chip In remaining worm's ovum and bacterium kill, and be slightly carbonized to bamboo chip;
S3, sofening treatment:Bamboo chip after microwave treatment is immersed in the sodium hydroxide solution that concentration is 3%-5% and is boiled It boils, time 2h-3h;
S4, tabletting slice:Bamboo chip after sofening treatment is flattened under the action of press, then it is cut Piece, thickness is in 3mm-5mm;
S5, the stem or leaf of cattail draw item:After the stem or leaf of cattail is soaked with cold water, it is cut into long section, length 0.8m-1m with blade, then incited somebody to action with knife The stem or leaf of cattail considers two halves from centre point, removes inner core, crust is divided into the strip of 2mm-3mm wide;
S6, yarn treatment:Starch is blunged into paste to boil, yarn is put into slurries, is stirred so that slurries fill Sub-dip enters yarn interior, takes out and dries after 2min-3min;
S7, woven processing:It is passed through with yarn, stem or leaf of cattail item makees latitude, woven at wallpaper semi-finished product, every two wefts by machine Interphase is away from 2mm-3mm;
S8, combination gluing:It, by the bamboo chip of slice, will then be placed on the upper and lower surfaces uniform fold of semi-finished product On glue laminated machine, polyvinyl alcohol glue is opened with cremating, is rotated by glue laminated machine, is slowly immersed in glue between bamboo chip and the stem or leaf of cattail;
S9, surface layer fitting:One layer of PVC film is pasted on its surface layer after gluing, it is bonded using compounding machine;
S10, drying and processing:Wallpaper after fitting, which enters barn, to carry out for dry, time 25min-35min;
S11, embossing shearing:Upper decorative pattern is pressed on wallpaper surface using embossing machine, according to the specification requirement that user needs, with cutting While machine by while trim, become wallpaper finished product.
Preferably, the bamboo chip in the S4 after slice, which is put into anti-mould and anti-moth liquid, impregnates 10min-20min, then passes through Mothproof bamboo chip is formed after crossing drying process.
Preferably, the preparation method of the PVC film in the S9 is:Polyvinyl chloride and epoxidized soybean oil is taken to be heated to 80 DEG C It is mixed, dioctyl phthalate mill 1h at 100 DEG C is then added, ethylene propylene diene rubber is added, its hardness is made to exist Fire retardant and colorant, last extrusion molding is added in 60P-100P.
Technical effect and advantage of the invention:Bamboo and the stem or leaf of cattail belong to natural prodcuts, and any dirt will not be caused to environment Dye, uses bamboo and the stem or leaf of cattail not only low in cost as wallpaper made of raw material, but also environmental protection;Bamboo fibre increases the intensity of wallpaper And toughness, wallpaper quality is improved, fitting metope is made it easier to, durable and will not blister, bamboo chip is by sterilization and anti- Moth processing increases its functionality, and the PVC film on wallpaper surface plays fire-retardant effect, it is therefore prevented that a possibility that burning;This hair Rationally, low in cost, safety and environmental protection is suitable for production and promotes and applies for bright design.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
Embodiment 1
A kind of preparation process of environmental protection wall paper, includes the following steps:
S1, raw bamboo cutting:Raw bamboo is truncated into bamboo section along the position close to ring two sides, removes ring, leaves thick bamboo tube, Thick bamboo tube is longitudinally cutd open into thick bamboo sheet, the width of each thick bamboo sheet is in 10cm;
S2, sterilization processing:By bamboo chip in micro-wave oven microwave treatment 8min, power is in 35kw, by worm remaining in bamboo chip Ovum and bacterium kill, and are slightly carbonized to bamboo chip;
S3, sofening treatment:Bamboo chip after microwave treatment is immersed in boil in the sodium hydroxide solution that concentration is 3% and is boiled, when Between be 2h;
S4, tabletting slice:Bamboo chip after sofening treatment is flattened under the action of press, then it is cut Piece, for thickness in 3mm, the bamboo chip after slice, which is put into anti-mould and anti-moth liquid, impregnates 10min, is then formed after being dried Mothproof bamboo chip;
S5, the stem or leaf of cattail draw item:After the stem or leaf of cattail is soaked with cold water, long section is cut into blade, length 0.8m, then with knife by the stem or leaf of cattail Two halves are considered from centre point, remove inner core, crust is divided into the strip of 2mm wide;
S6, yarn treatment:Starch is blunged into paste to boil, yarn is put into slurries, is stirred so that slurries fill Sub-dip enters yarn interior, takes out and dries after 2min;
S7, woven processing:It is passed through with yarn, stem or leaf of cattail item makees latitude, woven at wallpaper semi-finished product, every two wefts by machine Interphase is away from 2mm;
S8, combination gluing:It, by the bamboo chip of slice, will then be placed on the upper and lower surfaces uniform fold of semi-finished product On glue laminated machine, polyvinyl alcohol glue is opened with cremating, is rotated by glue laminated machine, is slowly immersed in glue between bamboo chip and the stem or leaf of cattail;
S9, surface layer fitting:One layer of PVC film is pasted on its surface layer after gluing, it is bonded using compounding machine, The preparation method of PVC film is:It takes polyvinyl chloride and epoxidized soybean oil to be heated to 80 DEG C of mixings, O-phthalic is then added Ethylene propylene diene rubber is added in dioctyl phthalate mill 1h at 100 DEG C, makes its hardness in 60P, fire retardant and colorant is added, finally Extrusion molding;
S10, drying and processing:Wallpaper after fitting, which enters barn, to carry out for dry, time 25min;
S11, embossing shearing:Upper decorative pattern is pressed on wallpaper surface using embossing machine, according to the specification requirement that user needs, with cutting While machine by while trim, become wallpaper finished product.
Embodiment 2
A kind of preparation process of environmental protection wall paper, includes the following steps:
S1, raw bamboo cutting:Raw bamboo is truncated into bamboo section along the position close to ring two sides, removes ring, leaves thick bamboo tube, Thick bamboo tube is longitudinally cutd open into thick bamboo sheet, the width of each thick bamboo sheet is in 11cm;
S2, sterilization processing:By bamboo chip in micro-wave oven microwave treatment 9min, power is in 40kw, by worm remaining in bamboo chip Ovum and bacterium kill, and are slightly carbonized to bamboo chip;
S3, sofening treatment:Bamboo chip after microwave treatment is immersed in boil in the sodium hydroxide solution that concentration is 4% and is boiled, when Between be 2.5h;
S4, tabletting slice:Bamboo chip after sofening treatment is flattened under the action of press, then it is cut Piece, for thickness in 4mm, the bamboo chip after slice, which is put into anti-mould and anti-moth liquid, impregnates 15min, is then formed after being dried Mothproof bamboo chip;
S5, the stem or leaf of cattail draw item:After the stem or leaf of cattail is soaked with cold water, long section is cut into blade, length 0.9m, then with knife by the stem or leaf of cattail Two halves are considered from centre point, remove inner core, crust is divided into the strip of 2.5mm wide;
S6, yarn treatment:Starch is blunged into paste to boil, yarn is put into slurries, is stirred so that slurries fill Sub-dip enters yarn interior, takes out and dries after 2.5min;
S7, woven processing:It is passed through with yarn, stem or leaf of cattail item makees latitude, woven at wallpaper semi-finished product, every two wefts by machine Interphase is away from 2.5mm;
S8, combination gluing:It, by the bamboo chip of slice, will then be placed on the upper and lower surfaces uniform fold of semi-finished product On glue laminated machine, polyvinyl alcohol glue is opened with cremating, is rotated by glue laminated machine, is slowly immersed in glue between bamboo chip and the stem or leaf of cattail;
S9, surface layer fitting:One layer of PVC film is pasted on its surface layer after gluing, it is bonded using compounding machine, The preparation method of PVC film is:It takes polyvinyl chloride and epoxidized soybean oil to be heated to 80 DEG C of mixings, O-phthalic is then added Ethylene propylene diene rubber is added in dioctyl phthalate mill 1h at 100 DEG C, makes its hardness in 80P, fire retardant and colorant is added, finally Extrusion molding;
S10, drying and processing:Wallpaper after fitting, which enters barn, to carry out for dry, time 30min;
S11, embossing shearing:Upper decorative pattern is pressed on wallpaper surface using embossing machine, according to the specification requirement that user needs, with cutting While machine by while trim, become wallpaper finished product.
Embodiment 3
A kind of preparation process of environmental protection wall paper, includes the following steps:
S1, raw bamboo cutting:Raw bamboo is truncated into bamboo section along the position close to ring two sides, removes ring, leaves thick bamboo tube, Thick bamboo tube is longitudinally cutd open into thick bamboo sheet, the width of each thick bamboo sheet is in 12cm;
S2, sterilization processing:By bamboo chip in micro-wave oven microwave treatment 10min, power is in 45kw, by worm remaining in bamboo chip Ovum and bacterium kill, and are slightly carbonized to bamboo chip;
S3, sofening treatment:Bamboo chip after microwave treatment is immersed in boil in the sodium hydroxide solution that concentration is 5% and is boiled, when Between be 3h;
S4, tabletting slice:Bamboo chip after sofening treatment is flattened under the action of press, then it is cut Piece, for thickness in 5mm, the bamboo chip after slice, which is put into anti-mould and anti-moth liquid, impregnates 20min, is then formed after being dried Mothproof bamboo chip;
S5, the stem or leaf of cattail draw item:After the stem or leaf of cattail is soaked with cold water, be cut into long section with blade, length 1m, then with knife by the stem or leaf of cattail from Two halves are considered in centre point, remove inner core, crust is divided into the strip of 3mm wide;
S6, yarn treatment:Starch is blunged into paste to boil, yarn is put into slurries, is stirred so that slurries fill Sub-dip enters yarn interior, takes out and dries after 3min;
S7, woven processing:It is passed through with yarn, stem or leaf of cattail item makees latitude, woven at wallpaper semi-finished product, every two wefts by machine Interphase is away from 3mm;
S8, combination gluing:It, by the bamboo chip of slice, will then be placed on the upper and lower surfaces uniform fold of semi-finished product On glue laminated machine, polyvinyl alcohol glue is opened with cremating, is rotated by glue laminated machine, is slowly immersed in glue between bamboo chip and the stem or leaf of cattail;
S9, surface layer fitting:One layer of PVC film is pasted on its surface layer after gluing, it is bonded using compounding machine, The preparation method of PVC film is:It takes polyvinyl chloride and epoxidized soybean oil to be heated to 80 DEG C of mixings, O-phthalic is then added Ethylene propylene diene rubber is added in dioctyl phthalate mill 1h at 100 DEG C, makes its hardness in 100P, fire retardant and colorant is added, finally Extrusion molding;
S10, drying and processing:Wallpaper after fitting, which enters barn, to carry out for dry, time 35min;
S11, embossing shearing:Upper decorative pattern is pressed on wallpaper surface using embossing machine, according to the specification requirement that user needs, with cutting While machine by while trim, become wallpaper finished product.
Note:Antibacterial test:Test method:Various moulds are configured to 105cfu/ml bacterium solution, every kind of fungi count in aqueous solution It measures identical.The made wallpaper basement membrane of above three embodiments is coated on putty plate according to constructing operation respectively, it will be mould after dry The aqueous solution of bacterium mixed liquor is uniformly sprayed.It is placed in 37 DEG C or so of mold incubator, observes mouldy situation.It is greasy after 28 days Not having the mould proof grade of fungus growth on daughter board is 0 grade, and having the mould proof grade of fungus growth less than 10% area is I grade.
Test strain:Aspergillus flavus, aspergillus niger, Aspergillus terreus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, ball hair shell It is mould.
In summary:A kind of preparation process of environmental protection wall paper provided by the invention, compared with tradition prepares wallpaper technique, bamboo Son and the stem or leaf of cattail belong to natural prodcuts, and any pollution will not be caused to environment, uses bamboo and the stem or leaf of cattail as wallpaper made of raw material It is not only low in cost, but also environmental protection;Bamboo fibre increases the intensity and toughness of wallpaper, improves wallpaper quality, holds that it more Metope easy to attach, durable and will not blister, bamboo chip is not polluted by sterilization and mothproof processing, increases its functionality, wall The PVC film on paper surface plays fire-retardant effect, it is therefore prevented that a possibility that burning;The present invention has rational design, low in cost, safety Environmental protection is suitable for production and promotes and applies.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (3)

1. a kind of preparation process of environmental protection wall paper, it is characterised in that:Include the following steps:
S1, raw bamboo cutting:Raw bamboo is truncated into bamboo section along the position close to ring two sides, removes ring, leaves thick bamboo tube, by bamboo Cylinder is longitudinal to cut open into thick bamboo sheet, and the width of each thick bamboo sheet is in 10cm-12cm;
S2, sterilization processing:By bamboo chip, microwave treatment 8min-10min, power, will be residual in bamboo chip in 35kw-45kw in micro-wave oven The worm's ovum stayed and bacterium kill, and are slightly carbonized to bamboo chip;
S3, sofening treatment:Bamboo chip after microwave treatment is immersed in boil in the sodium hydroxide solution that concentration is 3%-5% and is boiled, when Between be 2h-3h;
S4, tabletting slice:Bamboo chip after sofening treatment is flattened under the action of press, then it is sliced, it is thick Degree is in 3mm-5mm;
S5, the stem or leaf of cattail draw item:After the stem or leaf of cattail is soaked with cold water, long section is cut into blade, length 0.8m-1m, then with knife by the stem or leaf of cattail Two halves are considered from centre point, remove inner core, crust is divided into the strip of 2mm-3mm wide;
S6, yarn treatment:Starch is blunged into paste to boil, yarn is put into slurries, is stirred so that slurries sufficiently soak Enter yarn interior, takes out and dry after 2min-3min;
S7, woven processing:It being passed through with yarn, stem or leaf of cattail item makees latitude, and it is woven at wallpaper semi-finished product by machine, among every two wefts At a distance of 2mm-3mm;
S8, combination gluing:, by the bamboo chip of slice, glue will be then placed on the upper and lower surfaces uniform fold of semi-finished product On press, polyvinyl alcohol glue is opened with cremating, is rotated by glue laminated machine, is slowly immersed in glue between bamboo chip and the stem or leaf of cattail;
S9, surface layer fitting:One layer of PVC film is pasted on its surface layer after gluing, it is bonded using compounding machine;
S10, drying and processing:Wallpaper after fitting, which enters barn, to carry out for dry, time 25min-35min;
S11, embossing shearing:Upper decorative pattern is pressed on wallpaper surface using embossing machine, according to the specification requirement that user needs, uses bead cutter Side is trimmed, wallpaper finished product is become.
2. a kind of preparation process of environmental protection wall paper according to claim 1, it is characterised in that:In the S4 after slice Bamboo chip be put into anti-mould and anti-moth liquid and impregnate 10min-20min, then form mothproof bamboo chip after being dried.
3. a kind of preparation process of environmental protection wall paper according to claim 1, it is characterised in that:PVC film in the S9 Preparation method be:It takes polyvinyl chloride and epoxidized soybean oil to be heated to 80 DEG C of mixings, it is pungent that phthalic acid two is then added Ethylene propylene diene rubber is added in ester mill 1h at 100 DEG C, makes its hardness in 60P-100P, fire retardant and colorant is added, finally squeezes It forms out.
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CN111851145A (en) * 2020-06-28 2020-10-30 杭州壹澍美生态科技发展有限公司 Antibacterial and mothproof Wula sedge wallpaper and processing technology thereof

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CN103074810A (en) * 2011-10-26 2013-05-01 孟莉莉 Braided wallpaper
CN104763121A (en) * 2015-02-04 2015-07-08 滁州市莎朗新材料科技有限公司 Environment-friendly composite wallpaper and production process thereof
CN104708681A (en) * 2015-02-06 2015-06-17 林勇 Production technology for bamboo wallpaper
CN105200660A (en) * 2015-08-17 2015-12-30 陈杰 Straw fiber and bast fiber mixed nonwoven fabric for water-resistant and heat-resistant seamless wallpaper and preparation method of straw fiber and bast fiber mixed nonwoven fabric

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