CN107286562A - ABS color master batch - Google Patents
ABS color master batch Download PDFInfo
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- CN107286562A CN107286562A CN201710532865.6A CN201710532865A CN107286562A CN 107286562 A CN107286562 A CN 107286562A CN 201710532865 A CN201710532865 A CN 201710532865A CN 107286562 A CN107286562 A CN 107286562A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of ABS color master batch, it is prepared from by the raw material of following weight parts：48 52 parts of ethylene acrylic acid co polymer, 6 12 parts of pigment, 6 12 parts of polyacrylamide, 0.2 0.8 parts of N phenyl N' cyclohexyl p-phenylenediamine, 13 parts of di-2-ethylhexyl maleate, 24 parts of antiseptic, 24 parts of ultraviolet absorber.ABS color master batch of the present invention, its good dispersion in ABS products, uniform coloring, solve conventional Masterbatch on the market and realize the problem of weather-proof, acidproof, heat-resisting, cold tolerance cost is high, ultraviolet absorber and antiseptic are added simultaneously, the service life and security of ABS products is greatly improved.
Description
Technical field
The present invention relates to a kind of Masterbatch, more particularly to a kind of ABS color master batch.
Background technology
Color masterbatch be using colouring agent, vector resin, dispersant, coupling agent, surfactant, plasticizer made from raw material
The coloured pellet of high concentration.Function color masterbatch in addition to above-mentioned raw materials, according to the requirement of function need to add light stabilizer, antistatic additive,
The auxiliary agents such as fire retardant, foaming agent.Function color masterbatch is the function both with common color masterbatch, while assigning plastic products other work(
The masterbatch of energy.These functions include weather-proof function, anti-static function, anti-flaming function, frothing function etc..The production of function color masterbatch
Technical process is after being surface-treated to colouring agent, the surfactant of general color masterbatch, to coordinate with function additive, disperse
Auxiliary agent, then mediated, plasticated, crushed, granulated.Function color masterbatch is one of trend of color masterbatch industry technology development.
Due to pigment during storage and use direct ingress of air, can then occur the moisture absorption, oxidation, conglomeration etc. existing
As directly using that can occur color dot in surface of plastic product, change is easily taken off in form and aspect obfuscation, color, and causes dirt in mixing
Soil is flown upward, and influences the health of operating personnel.And Masterbatch has been carried out at refinement in process of production through over mechanical processing to pigment
Pigment and resin carrier, dispersant, are filled part mixing, pigment is isolated with air, moisture, so as to enhance the weather-proof of pigment by reason
Property, improve the dispersiveness and tinting strength, tinting power of pigment, form and aspect light.Because Masterbatch is close with resin particle shape, so in meter
It is accurate to be more convenient in amount, will not be adhered to during mixing on container, therefore saves time and the clear of cleaning container and machine
Raw material used.
Using color masterbatch or function color masterbatch production plastic products, good dispersion of the colouring agent in product, it is bright-colored,
Product surface achromic point or aberration, exchange that color is convenient, cost is relatively low, environmentally friendly, labor intensity is small, be widely used,
The coloring plastic method of good development prospect.
The content of the invention
For above shortcomings in the prior art, the technical problems to be solved by the invention are to provide a kind of ABS colors
Master batch.
The present invention seeks to what is be achieved through the following technical solutions：
A kind of ABS color master batch, is prepared from by the raw material of following weight parts：
48-52 parts of ethylene-acrylic acid copolymer, 6-12 parts of pigment, 6-12 parts of polyacrylamide, N- phenyl-N'- cyclohexyl
0.2-0.8 parts of p-phenylenediamine, 1-3 parts of di-2-ethylhexyl maleate, 2-4 parts of antiseptic, 2-4 parts of ultraviolet absorber.
Preferably, described ultraviolet absorber is 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5- tri-
Piperazine, 2- (double (2,4- the 3,5-dimethylphenyls) -1,3,5- triazine -2- bases of 4,6-) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5-
Triazine -2- bases) mixture one or more in -5- hexyls epoxide-phenol.
It is highly preferred that described ultraviolet absorber is by 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5- tri-
Piperazine, 2- (double (2,4- the 3,5-dimethylphenyls) -1,3,5- triazine -2- bases of 4,6-) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5-
Triazine -2- bases) -5- hexyls epoxide-phenol mixes, described 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,
5- triazines, 2- (4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,
3,5- triazine -2- bases) -5- hexyls epoxide-phenol mass ratio be (1-3)：(1-3)：(1-3).
Preferably, described antiseptic is mixture one or more in MENTHOL, Hinokitiol, phenoxetol.
It is highly preferred that described antiseptic is mixed by MENTHOL, Hinokitiol, phenoxetol, the L- peppermints
Alcohol, Hinokitiol, the mass ratio of phenoxetol are (1-3)：(1-3)：(1-3).
Preferably, the pigment is mixture one or more in sunset yellow, algocyan, carrotene.
ABS color master batch of the present invention, its good dispersion in ABS products, uniform coloring is solved and commonly used on the market
Masterbatch realizes the problem of cost of weather-proof, acidproof, heat-resisting, cold-resistant function is high, while adding UV absorption in Masterbatch
Agent and antiseptic, greatly improve the service life and security of ABS products.
Embodiment
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, not does the limitation of other forms, any those skilled in the art are possibly also with the disclosure above to the present invention
Technology contents be changed to the equivalent embodiment changed on an equal basis.It is every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Each raw material introduction in embodiment：
Ethylene-acrylic acid copolymer, use Exxon Mobil company provide the trade mark for 5100 ethylene-acrylic acid
Copolymer.
Polyacrylamide, No. CAS：9003-05-8, the model provided using Beijing Chemical Co., Ltd. of Hua Weirui sections
HWG13059 polyacrylamide.
N- phenyl-N'- cyclohexyl p-phenylenediamine, No. CAS：101-87-1.
Di-2-ethylhexyl maleate, No. CAS：2915-53-9.
Sunset yellow, No. CAS：2783-94-0, use this hundred full chemistries (Shanghai) Co., Ltd. provide production code member for
FD155 sunset yellow.
2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5-triazines, No. CAS：108-80-5.
2- (4,6- double (2,4- 3,5-dimethylphenyl) -1,3,5-triazines -2- bases) -5- octyloxy phenol, No. CAS：2725-22-
6。
2- (4,6- diphenyl -1,3,5-triazines -2- bases) -5- hexyls epoxide-phenol, No. CAS：147315-50-2.
MENTHOL, No. CAS：2216-51-5, use AlfaAesar (China) Chemical Co., Ltd. provide product compile for
A10474 MENTHOL.
Hinokitiol, No. CAS：499-44-5, the product provided using uncommon love (Shanghai) the chemical conversion industry Development Co., Ltd of ladder
Compile the Hinokitiol for H0142.
Phenoxetol, No. CAS：122-99-6.
ABS resin, No. CAS：9003-56-9, the ABS trees provided using Jilin Xingyun Chemical Co., Ltd. Of Jilin Chemical Group Corp.
Fat.
Embodiment 1
ABS color master batch raw material (parts by weight)：52 parts of ethylene-acrylic acid copolymer, 6 parts of sunset yellow, 8 parts of polyacrylamide,
0.6 part of N- phenyl-N'- cyclohexyl p-phenylenediamine, 2 parts of di-2-ethylhexyl maleate, 2.7 parts of antiseptic, 2.8 parts of ultraviolet absorber.
Described ultraviolet absorber by 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5- triazines, 2- (4,
Double (2,4- the 3,5-dimethylphenyls) -1,3,5- triazine -2- bases of 6-) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazines -2-
Base) -5- hexyls epoxide-phenol in mass ratio be 1：1：1 is uniformly mixed and obtains.
Described antiseptic is 1 in mass ratio by MENTHOL, Hinokitiol, phenoxetol：1：1 is uniformly mixed
Arrive.
The method for preparing above-mentioned ABS color master batch, comprises the following steps：
(1) raw material for weighing each parts by weight in proportion is mixed in mixing and blending machine, and mixing rotating speed is 500 revs/min
Clock, mixing temperature control is at 70 DEG C, and the time is 10 minutes, obtains compound；
(2) compound is put into taper double screw extruder hopper, four humidity provinces, first area's temperature is divided into extruder
Spend for 190 DEG C, second area's temperature is 195 DEG C, the 3rd area's temperature is 195 DEG C, and the 4th area's temperature is 200 DEG C, and head temperature is 195
DEG C, the rotating speed of screw rod is 350 revs/min, and two screw rods axis is into 11 °, and extruder axis is with horizontal line into 15 °, and compound is heated
Change, in the case where the screw rod of double screw extruder is promoted, carry out physical and chemical reaction, flowed out through poroid mouth mold, after extrudate water cooling,
The cylindrical pellets that size is 3 × 3mm are cut into by pelleter；
(3) by pellet in hot air circulation type drying machine 80 DEG C of dryings 3 hours.Obtain the ABS color master batch of embodiment 1.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described ultraviolet absorber is by 2- (double (the 2,4- dimethyl of 4,6-
Phenyl) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls epoxide -
Phenol is 1 in mass ratio：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described ultraviolet absorber is by (2'- hydroxyls-the 4'- of 2,4,6- tri-
N-butoxyphenyl) -1,3,5- triazines, 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls epoxide-phenol press quality
Than for 1：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described ultraviolet absorber is by (2'- hydroxyls-the 4'- of 2,4,6- tri-
N-butoxyphenyl) -1,3,5- triazines, 2- (4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies
Phenol is 1 in mass ratio：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described antiseptic presses quality by Hinokitiol, phenoxetol
Than for 1：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 5.
Embodiment 6
It is substantially the same manner as Example 1, differ only in：Described antiseptic presses matter by MENTHOL, phenoxetol
Amount is than being 1：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 6.
Embodiment 7
It is substantially the same manner as Example 1, differ only in：Described antiseptic by MENTHOL, Hinokitiol in mass ratio
For 1：1 is uniformly mixed and obtains.Obtain the ABS color master batch of embodiment 7.
Test case 1
Take respectively 2 parts by weight of example 1-7 ABS color master batch and 200 parts by weight ABS resins in agitator using rotating speed as
300 revs/min are stirred 20 minutes, obtain well mixed compound.By compound use injection machine injection be 20 for size ×
50 × 1mm ABS models, feeding section temperature is 180 DEG C, and compression section temperature is 200 DEG C, and homogenizing zone temperature is 220 DEG C, head temperature
Spend for 220 DEG C, mold temperature is 60 DEG C, and injection pressure is 120MPa, injection total time is 15s.Obtain embodiment 1-7 ABS
Model.
The illumination aging resisting performance of embodiment 1-7 ABS models is tested, by the plastics of GB/T16422.2-1999
Laboratory light source exposure test method, is placed in xenon lamp exposure light aging test case and irradiates, then yellow by the plastics of GB2409-80
Colour index test method, surveys its yellow colour index, obtains its yellowness index △ YI as shown in table 1 below.
Table 1：Illumination aging resisting performance tests table
Yellowness index △ YI are an important indicators for characterizing photooxidative aging performance, and △ YI are smaller, represent illumination aging resisting
Performance is better.
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,
5- triazines, 2- (4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,
3,5- triazine -2- bases) -5- hexyls epoxide-phenol compounding) illumination aging resisting performance is substantially better than embodiment 2-4 (2,4,6- tri-
(2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5- triazines, 2- (double (2,4- the 3,5-dimethylphenyls) -1,3,5- triazines -2- of 4,6-
Base) -5- octyloxies phenol, in 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls epoxide-phenol it is any the two compound)；
Comparing embodiment 1 and embodiment 5-7, embodiment 1 (MENTHOL, Hinokitiol, phenoxetol compounding) illumination aging resisting performance
It is substantially better than embodiment 5-7 (the two any compounding in MENTHOL, Hinokitiol, phenoxetol).
Test case 2
The anti-microbial property of embodiment 1-7 ABS models is tested, with reference to GB/T21510-2008 detections, large intestine bar
Bacterium ATYCC 25922, staphylococcus aureus ATCC 6538.Specific test result is shown in Table 2.
Table 2：Anti-microbial property test tables of data
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,
5- triazines, 2- (4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,
3,5- triazine -2- bases) -5- hexyls epoxide-phenol compounding) anti-microbial property is substantially better than embodiment 2-4 ((the 2'- hydroxyls of 2,4,6- tri-
Base -4'- n-butoxyphenyls) -1,3,5- triazines, 2- (4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5-
The two any compounding in octyloxy phenol, 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls epoxide-phenol)；Compare reality
Example 1 and embodiment 5-7 are applied, embodiment 1 (MENTHOL, Hinokitiol, phenoxetol compounding) anti-microbial property is substantially better than implementation
Example 5-7 (the two any compounding in MENTHOL, Hinokitiol, phenoxetol).
Claims (1)
1. a kind of ABS color master batch, it is characterised in that be prepared from by the raw material of following weight parts：Ethylene-acrylic acid copolymer
48-52 parts, 6-12 parts of pigment, 6-12 parts of polyacrylamide, 0.2-0.8 parts of N- phenyl-N'- cyclohexyl p-phenylenediamine, maleic acid
1-3 parts of dioctyl ester, 2-4 parts of antiseptic, 2-4 parts of ultraviolet absorber；
(4,6- is double by 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5- triazines, 2- for described ultraviolet absorber
(2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -
5- hexyls epoxide-phenol is mixed, described 2,4,6- tri- (2'- hydroxyl -4'- n-butoxyphenyls) -1,3,5-triazines, 2-
(4,6- double (2,4- 3,5-dimethylphenyls) -1,3,5- triazine -2- bases) -5- octyloxies phenol, 2- (4,6- diphenyl -1,3,5- triazines -
2- yls) -5- hexyls epoxide-phenol mass ratio be (1-3)：(1-3)：(1-3)；
Described antiseptic is mixed by MENTHOL, Hinokitiol, phenoxetol, the MENTHOL, Hinokitiol, benzene oxygen
The mass ratio of base ethanol is (1-3)：(1-3)：(1-3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710532865.6A CN107286562A (en) | 2017-07-03 | 2017-07-03 | ABS color master batch |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710532865.6A CN107286562A (en) | 2017-07-03 | 2017-07-03 | ABS color master batch |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102200A (en) * | 2017-12-05 | 2018-06-01 | 韩其洋 | ABS color master batch |
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| 隋昭德等: "《光稳定剂及其应用技术》", 31 January 2010, 中国轻工业出版社 * |
| 黄可龙: "《精细化学品技术手册》", 30 June 1994, 中南工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102200A (en) * | 2017-12-05 | 2018-06-01 | 韩其洋 | ABS color master batch |
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