CN107286536A - A kind of fire protection flame retarding polyvinyl chloride cable sheath - Google Patents

A kind of fire protection flame retarding polyvinyl chloride cable sheath Download PDF

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Publication number
CN107286536A
CN107286536A CN201710675120.5A CN201710675120A CN107286536A CN 107286536 A CN107286536 A CN 107286536A CN 201710675120 A CN201710675120 A CN 201710675120A CN 107286536 A CN107286536 A CN 107286536A
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CN
China
Prior art keywords
parts
polyvinyl chloride
fire protection
flame retarding
protection flame
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Pending
Application number
CN201710675120.5A
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Chinese (zh)
Inventor
王万虎
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Anhui Jieao Electric Co Ltd
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Anhui Jieao Electric Co Ltd
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Priority to CN201710675120.5A priority Critical patent/CN107286536A/en
Publication of CN107286536A publication Critical patent/CN107286536A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of fire protection flame retarding polyvinyl chloride cable sheath, it is constituted according to the parts by weight of following raw material:50 100 parts of polyvinyl chloride, 10 20 parts of modified epoxy, 15 parts of silicon rubber, 10 15 parts of zinc oxide, 10 20 parts of magnesium hydroxide, 35 parts of calcium carbonate, 5 10 parts of aluminium hydroxide, 13 parts of Firebrake ZB, 0.5 1 parts of 1,2 dihyaroquinoline, 12 parts of stabilizer, 15 parts of vulcanizing agent, 0.1 0.5 parts of vulcanization accelerator, 0.3 0.5 parts of magnesia, 0.1 0.2 parts of TRA antiscorching agent, 0.3 1.5 parts of preservative, 12 parts of repefral, 12 parts of DL171 coupling agents.The fire protection flame retarding polyvinyl chloride cable sheath of the present invention has very strong weather resisteant, reduces influence of the environment to cable cover(ing), and good insulation preformance, softness is good, and impact resistance is strong, while tensile strength is high, stability is excellent, and high mechanical strength and fire resistance are good.

Description

A kind of fire protection flame retarding polyvinyl chloride cable sheath
Technical field
The present invention relates to a kind of cable cover(ing), more particularly to a kind of fire protection flame retarding polyvinyl chloride cable sheath.
Background technology
At present, with the development of the social economy, China constantly expands to cable market demand and the scientific research of cable is thrown What is entered deepens continuously, while also constantly being improved to the quality requirement of cable, the particularly requirement to cable cover(ing) is higher, it is desirable to The side such as its insulating properties, high and low temperature resistance, fatigue durability, anti-broken string ability, antijamming capability, mechanical resistant damage, water proofing property Face requires all especially high.
The content of the invention
The purpose of the present invention is that to solve the above problems and provide a kind of fire protection flame retarding polychlorostyrene second of fire protection flame retarding Alkene cable cover(ing).
To achieve these goals, the present invention is achieved by the following technical solutions, and a kind of fire protection flame retarding polyvinyl chloride is electric Cable sheath, it is constituted according to the parts by weight of following raw material:50-100 parts of polyvinyl chloride, 10-20 parts of modified epoxy, silicon rubber 1-5 parts of glue, 10-15 parts of zinc oxide, 10-20 parts of magnesium hydroxide, 3-5 parts of calcium carbonate, 5-10 parts of aluminium hydroxide, 1-3 parts of Firebrake ZB, 0.5-1 parts of 1,2- dihyaroquinolines, 1-2 parts of stabilizer, 1-5 parts of vulcanizing agent, 0.1-0.5 parts of vulcanization accelerator, magnesia 0.3- 0.5 part, 0.1-0.2 parts of TRA antiscorching agent, 0.3-1.5 parts of preservative, 1-2 parts of repefral, DL171 coupling agents 1-2 Part.
Further, a kind of fire protection flame retarding polyvinyl chloride cable sheath, it is constituted according to the parts by weight of following raw material:It is poly- 70-90 parts of vinyl chloride, 15-18 parts of modified epoxy, 3-5 parts of silicon rubber, 11-13 parts of zinc oxide, 15-18 parts of magnesium hydroxide, 3-5 parts of calcium carbonate, 6-9 parts of aluminium hydroxide, 1-3 parts of Firebrake ZB, 0.5-1 parts of 1,2- dihyaroquinolines, 1-2 parts of stabilizer, vulcanization 1-5 parts of agent, 0.1-0.5 parts of vulcanization accelerator, 0.3-0.5 parts of magnesia, 0.1-0.2 parts of TRA antiscorching agent, preservative 0.3-1.5 Part, 1-2 parts of repefral, 1-2 parts of DL171 coupling agents.
Further, a kind of fire protection flame retarding polyvinyl chloride cable sheath, it is constituted according to the parts by weight of following raw material: 80 parts of polyvinyl chloride, 16 parts of modified epoxy, 4 parts of silicon rubber, 12 parts of zinc oxide, 16 parts of magnesium hydroxide, 4 parts of calcium carbonate, hydrogen 8 parts of aluminum oxide, 2 parts of Firebrake ZB, 0.5 part of 1,2- dihyaroquinolines, 2 parts of stabilizer, 3 parts of vulcanizing agent, 0.3 part of vulcanization accelerator, 0.4 part of magnesia, 0.1 part of TRA antiscorching agent, 0.8 part of preservative, 2 parts of repefral, 1 part of DL171 coupling agents.
Particularly, the modified epoxy is that epoxy resin immersion phenol resin solution modification is formed.
The beneficial effects of the invention are as follows:The fire protection flame retarding polyvinyl chloride cable sheath of the present invention has very strong weather resisteant, Influence of the environment to cable cover(ing), and good insulation preformance are reduced, softness is good, impact resistance is strong, while tensile strength Height, stability is excellent, and high mechanical strength and fire resistance are good.
Embodiment
Specific embodiment 1:A kind of fire protection flame retarding polyvinyl chloride cable sheath, its according to following raw material parts by weight array Into:50 parts of polyvinyl chloride, 10 parts of modified epoxy, 1 part of silicon rubber, 10 parts of zinc oxide, 10 parts of magnesium hydroxide, 3 parts of calcium carbonate, 5 parts of aluminium hydroxide, 1 part of Firebrake ZB, 0.5 part of 1,2- dihyaroquinolines, 1 part of stabilizer, 1 part of vulcanizing agent, vulcanization accelerator 0.1 Part, 0.3 part of magnesia, 0.1 part of TRA antiscorching agent, 0.3 part of preservative, 1 part of repefral, 1 part of DL171 coupling agents.
Wherein modified epoxy is that epoxy resin immersion phenol resin solution modification is formed.
Specific embodiment 2:A kind of fire protection flame retarding polyvinyl chloride cable sheath, its according to following raw material parts by weight array Into:80 parts of polyvinyl chloride, 16 parts of modified epoxy, 4 parts of silicon rubber, 12 parts of zinc oxide, 16 parts of magnesium hydroxide, 4 parts of calcium carbonate, 8 parts of aluminium hydroxide, 2 parts of Firebrake ZB, 0.5 part of 1,2- dihyaroquinolines, 2 parts of stabilizer, 3 parts of vulcanizing agent, vulcanization accelerator 0.3 Part, 0.4 part of magnesia, 0.1 part of TRA antiscorching agent, 0.8 part of preservative, 2 parts of repefral, 1 part of DL171 coupling agents.
Wherein modified epoxy is that epoxy resin immersion phenol resin solution modification is formed.
Specific embodiment 3:A kind of fire protection flame retarding polyvinyl chloride cable sheath, its according to following raw material parts by weight array Into:100 parts of polyvinyl chloride, 20 parts of modified epoxy, 5 parts of silicon rubber, 15 parts of zinc oxide, 20 parts of magnesium hydroxide, calcium carbonate 5 Part, 10 parts of aluminium hydroxide, 3 parts of Firebrake ZB, 1 part of 1,2- dihyaroquinolines, 2 parts of stabilizer, 5 parts of vulcanizing agent, vulcanization accelerator 0.5 Part, 0.5 part of magnesia, 0.2 part of TRA antiscorching agent, 1.5 parts of preservative, 2 parts of repefral, 2 parts of DL171 coupling agents.
Wherein modified epoxy is that epoxy resin immersion phenol resin solution modification is formed.
Embodiment provided above is the better embodiment of the present invention, only illustrates the present invention for convenient, not to this hair It is bright to make any formal limitation, any those of ordinary skill in the art, if putting forward skill not departing from the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from the technical characteristic content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (4)

1. a kind of fire protection flame retarding polyvinyl chloride cable sheath, it is characterised in that:Constituted according to the parts by weight of following raw material:Polychlorostyrene 50-100 parts of ethene, 10-20 parts of modified epoxy, 1-5 parts of silicon rubber, 10-15 parts of zinc oxide, 10-20 parts of magnesium hydroxide, carbon Sour calcium 3-5 parts, 5-10 parts of aluminium hydroxide, 1-3 parts of Firebrake ZB, 0.5-1 parts of 1,2- dihyaroquinolines, 1-2 parts of stabilizer, vulcanizing agent 1-5 parts, 0.1-0.5 parts of vulcanization accelerator, 0.3-0.5 parts of magnesia, 0.1-0.2 parts of TRA antiscorching agent, 0.3-1.5 parts of preservative, 1-2 parts of repefral, 1-2 parts of DL171 coupling agents.
2. a kind of fire protection flame retarding polyvinyl chloride cable sheath according to claim 1, it is characterised in that:According to following raw material Parts by weight composition:70-90 parts of polyvinyl chloride, 15-18 parts of modified epoxy, 3-5 parts of silicon rubber, 11-13 parts of zinc oxide, 15-18 parts of magnesium hydroxide, 3-5 parts of calcium carbonate, 6-9 parts of aluminium hydroxide, 1-3 parts of Firebrake ZB, 0.5-1 parts of 1,2- dihyaroquinolines, 1-2 parts of stabilizer, 1-5 parts of vulcanizing agent, 0.1-0.5 parts of vulcanization accelerator, 0.3-0.5 parts of magnesia, TRA antiscorching agent 0.1-0.2 Part, 0.3-1.5 parts of preservative, 1-2 parts of repefral, 1-2 parts of DL171 coupling agents.
3. a kind of fire protection flame retarding polyvinyl chloride cable sheath according to claim 1, it is characterised in that:According to following raw material Parts by weight composition:80 parts of polyvinyl chloride, 16 parts of modified epoxy, 4 parts of silicon rubber, 12 parts of zinc oxide, magnesium hydroxide 16 Part, 4 parts of calcium carbonate, 8 parts of aluminium hydroxide, 2 parts of Firebrake ZB, 0.5 part of 1,2- dihyaroquinolines, 2 parts of stabilizer, 3 parts of vulcanizing agent, sulphur Change 0.3 part of accelerator, 0.4 part of magnesia, 0.1 part of TRA antiscorching agent, 0.8 part of preservative, 2 parts of repefral, 1 part of DL171 coupling agents.
4. a kind of fire protection flame retarding polyvinyl chloride cable sheath according to claim 1 or 2 or 3, it is characterised in that:It is described to change Property epoxy resin be epoxy resin immersion phenol resin solution be modified form.
CN201710675120.5A 2017-08-09 2017-08-09 A kind of fire protection flame retarding polyvinyl chloride cable sheath Pending CN107286536A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108084713A (en) * 2017-12-22 2018-05-29 安徽高盛化工股份有限公司 A kind of high fire-retardance synthetic resin and preparation method thereof
CN109749364A (en) * 2018-12-29 2019-05-14 安徽天康(集团)股份有限公司 A kind of high temperature resistant Plastic-sheathed Cable
CN109852095A (en) * 2018-11-12 2019-06-07 铜陵市铜都特种线缆有限公司 A kind of low-smoke halogen-free cable jacket layer material
CN110256779A (en) * 2019-06-24 2019-09-20 安徽华泰电缆有限公司 A kind of potent insulation PVC cable sheath material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105602156A (en) * 2016-03-08 2016-05-25 苏州科茂电子材料科技有限公司 Fireproof high-flame-resistance cable material and preparation method thereof
CN105860425A (en) * 2016-05-07 2016-08-17 淄博夸克医药技术有限公司 High-temperature-resistant flame-retardant cable material and preparation method thereof
CN106397954A (en) * 2016-08-31 2017-02-15 裴秀琴 Cable sheath material for electric engineering and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105602156A (en) * 2016-03-08 2016-05-25 苏州科茂电子材料科技有限公司 Fireproof high-flame-resistance cable material and preparation method thereof
CN105860425A (en) * 2016-05-07 2016-08-17 淄博夸克医药技术有限公司 High-temperature-resistant flame-retardant cable material and preparation method thereof
CN106397954A (en) * 2016-08-31 2017-02-15 裴秀琴 Cable sheath material for electric engineering and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108084713A (en) * 2017-12-22 2018-05-29 安徽高盛化工股份有限公司 A kind of high fire-retardance synthetic resin and preparation method thereof
CN109852095A (en) * 2018-11-12 2019-06-07 铜陵市铜都特种线缆有限公司 A kind of low-smoke halogen-free cable jacket layer material
CN109749364A (en) * 2018-12-29 2019-05-14 安徽天康(集团)股份有限公司 A kind of high temperature resistant Plastic-sheathed Cable
CN110256779A (en) * 2019-06-24 2019-09-20 安徽华泰电缆有限公司 A kind of potent insulation PVC cable sheath material and preparation method thereof

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Application publication date: 20171024

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