CN107286384A - A kind of blackish green rubber hold-down calendering glue of calendering type - Google Patents
A kind of blackish green rubber hold-down calendering glue of calendering type Download PDFInfo
- Publication number
- CN107286384A CN107286384A CN201610192956.5A CN201610192956A CN107286384A CN 107286384 A CN107286384 A CN 107286384A CN 201610192956 A CN201610192956 A CN 201610192956A CN 107286384 A CN107286384 A CN 107286384A
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- CN
- China
- Prior art keywords
- calendering
- glue
- blackish green
- green rubber
- rubber hold
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of blackish green rubber hold-down calendering glue of calendering type, it is characterised in that calculates in parts by weight, including：Standard rubbers 80 90, cis-butadiene cement 10 20, zinc oxide 5 10, stearic acid 13, carbon black 0.32, phthalocyanine blue 0.22, deep chrome yellow 5.8, white carbon 20, industrial fat 35, vaseline 13, anti-aging agent RD 0.6 0.8, antioxidant MB 0.6 0.8, sulphur 1.5 2.5, altax 1.5 1.8, diphenylguanidine 0.1 0.3, coumarone 8 10, calcium carbonate 55.Anti-skidding its adhesive force of liberation footwear and cohesive produced with this foxing formula is higher, can greatly improve the service life of anti-skidding liberation footwear.
Description
Technical field
The present invention relates to elastomeric material preparation field, it is related to footwear side glue formula, more particularly to a kind of calendering type is blackish green
Rubber hold-down calendering glue.
Background technology
Foxing glue for liberating footwear side glue, the combination adhesive force of the adhesive glue of itself and sole rubber and brush on upper of a shoe
It is required that higher, tearing strength requires higher, to adapt to the activity and motion of high intensity, it is ensured that side glue does not come unglued with upper of a shoe, do not taken off
Glue, without from side phenomenon.Especially for anti-skidding liberation footwear, the sizing material hardness requirement of foxing glue in itself is higher, and sizing material hardness is small, makes
Into foxing glue out-of-flatness, sizing material hardness is big, then causes foxing glue not enough with upper of a shoe viscous force, often come unglued in wearing process,
From the situation on side, adhesive force is less than or equal to 2.2kN/m, make shoes to wear the life-span shorter.
The content of the invention
The purpose of the present invention is in view of the shortcomings of the prior art, and to provide a kind of calendering type blackish green rubber hold-down calendering glue, is used
Its adhesive force of the foxing glue of formula production is higher, and the bonding strength with anti-skidding big bottom is higher, is not susceptible in wearing process
Come unglued, from the situation on side, the service life of anti-skidding liberation footwear can be greatly improved.
Realizing the technical scheme of the object of the invention is：
A kind of blackish green rubber hold-down calendering glue of calendering type, is calculated in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, carbon black 0.32, phthalocyanine blue 0.22, deep chromium
Huang 5.8, white carbon 20, industrial fat 3-5, vaseline 1-3, anti-aging agent RD 0.6-0.8, antioxidant MB 0.6-0.8, sulphur
1.5-2.5, altax 1.5-1.8, diphenylguanidine 0.1-0.3, coumarone 8-10, calcium carbonate 55.
Compared with prior art, the advantage of the invention is that：Gum base ingredients are using the 80-90 parts of extraordinary standards of adhesive force
Rubber, makes foxing glue have good bond properties, can be used for a long time under the motion of high intensity, the feelings that will not be come unglued
Condition；Using the 8-10 parts of extraordinary coumarones of tack in gum base ingredients, make foxing glue that there is good bond properties；White carbon
20 parts, sizing material has preferable hardness and flatness.Therefore, with this foxing formula produce anti-skidding its adhesive force of liberation footwear and
Cohesive is higher, can greatly improve the service life of anti-skidding liberation footwear.
Embodiment
Present invention is further elaborated below by embodiment, but is not limitation of the invention.
A kind of blackish green rubber hold-down calendering glue of calendering type, is calculated in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, carbon black 0.32, phthalocyanine blue 0.22, deep chromium
Huang 5.8, white carbon 20, industrial fat 3-5, vaseline 1-3, anti-aging agent RD 0.6-0.8, antioxidant MB 0.6-0.8, sulphur
1.5-2.5, altax 1.5-1.8, diphenylguanidine 0.1-0.3, coumarone 8-10, calcium carbonate 55.
The formula can be carried out two sections of mixings by banbury and be completed, to improve the cohesive of sizing material.
Standard rubbers are No. 5 smoke sheet rubbers, and standard rubbers, cis-butadiene cement add up to content to be 100 parts by weight.
Embodiment 1：
A kind of blackish green rubber hold-down calendering glue of calendering type, is calculated in parts by weight, including：
No. 5 smoke sheet rubbers 80, cis-butadiene cement 20, zinc oxide 5, stearic acid 1, carbon black 0.32, phthalocyanine blue 0.22, deep chrome yellow 5.8, hard charcoal
Black 20, industrial fat 3, vaseline 1, anti-aging agent RD 0.6, antioxidant MB 0.6, sulphur 1.5, altax 1.5, diphenylguanidine
0.1st, coumarone 8, calcium carbonate 55.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：62；
Pull apart strength/MPa：8.1；
Elongation at break %：470；
Setafter break %：26；
Conditions of vulcanization：143℃×60′；
Deflect（It is secondary/just to split）：16500；
Adhesive force（kN/m）：2.7.
Wherein, adhesive force（kN/m）：2.7 are more than 2.2, and adhesive force is higher.
Embodiment 2：
A kind of blackish green rubber hold-down calendering glue of calendering type, is calculated in parts by weight, including：
No. 5 smoke sheet rubbers 85, cis-butadiene cement 15, zinc oxide 8, stearic acid 2, carbon black 0.32, phthalocyanine blue 0.22, deep chrome yellow 5.8, hard charcoal
Black 20, industrial fat 4, vaseline 2, anti-aging agent RD 0.7, antioxidant MB 0.7, sulphur 2, altax 1.6, diphenylguanidine
0.2nd, coumarone 9, calcium carbonate 55.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：67；
Pull apart strength/MPa：8.3；
Elongation at break %：475；
Setafter break %：28；
Conditions of vulcanization：143℃×60′；
Deflect（It is secondary/just to split）：16600；
Adhesive force（kN/m）：2.8.
Wherein, adhesive force（kN/m）：2.8 are more than 2.2, and adhesive force is higher.
Embodiment 3：
A kind of blackish green rubber hold-down calendering glue of calendering type, is calculated in parts by weight, including：
No. 5 smoke sheet rubbers 90, cis-butadiene cement 10, zinc oxide 10 are stearic acid 3, carbon black 0.32, phthalocyanine blue 0.22, deep chrome yellow 5.8, white
Carbon black 20, industrial fat 5, vaseline 3, anti-aging agent RD 0.8, antioxidant MB 0.8, sulphur 2.5, altax 1.8, promotion
Agent D 0.3, coumarone 10, calcium carbonate 55.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：69；
Pull apart strength/MPa：8.5；
Elongation at break %：480；
Setafter break %：27；
Conditions of vulcanization：143℃×60′；
Deflect（It is secondary/just to split）：16700；
Adhesive force（kN/m）：2.8.
Wherein, adhesive force（kN/m）：2.8 are more than 2.2, and adhesive force is higher.
Claims (2)
1. a kind of blackish green rubber hold-down calendering glue of calendering type, it is characterised in that calculate in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, carbon black 0.32, phthalocyanine blue 0.22, deep chromium
Huang 5.8, white carbon 20, industrial fat 3-5, vaseline 1-3, anti-aging agent RD 0.6-0.8, antioxidant MB 0.6-0.8, sulphur
1.5-2.5, altax 1.5-1.8, diphenylguanidine 0.1-0.3, coumarone 8-10, calcium carbonate 55.
2. the blackish green rubber hold-down calendering glue of calendering type according to claim 1, it is characterised in that calculate in parts by weight, bag
Include：
No. 5 smoke sheet rubbers 85, cis-butadiene cement 15, zinc oxide 8, stearic acid 2, carbon black 0.32, phthalocyanine blue 0.22, deep chrome yellow 5.8, hard charcoal
Black 20, industrial fat 4, vaseline 2, anti-aging agent RD 0.7, antioxidant MB 0.7, sulphur 2, altax 1.6, diphenylguanidine
0.2nd, coumarone 9, calcium carbonate 55.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192956.5A CN107286384A (en) | 2016-03-30 | 2016-03-30 | A kind of blackish green rubber hold-down calendering glue of calendering type |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192956.5A CN107286384A (en) | 2016-03-30 | 2016-03-30 | A kind of blackish green rubber hold-down calendering glue of calendering type |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107286384A true CN107286384A (en) | 2017-10-24 |
Family
ID=60086652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610192956.5A Pending CN107286384A (en) | 2016-03-30 | 2016-03-30 | A kind of blackish green rubber hold-down calendering glue of calendering type |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107286384A (en) |
-
2016
- 2016-03-30 CN CN201610192956.5A patent/CN107286384A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171024 |
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| WD01 | Invention patent application deemed withdrawn after publication |