CN107286385A - A kind of calendering type ivory buff rubber hold-down calendering glue - Google Patents
A kind of calendering type ivory buff rubber hold-down calendering glue Download PDFInfo
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- CN107286385A CN107286385A CN201610192957.XA CN201610192957A CN107286385A CN 107286385 A CN107286385 A CN 107286385A CN 201610192957 A CN201610192957 A CN 201610192957A CN 107286385 A CN107286385 A CN 107286385A
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- Prior art keywords
- glue
- calendering
- antioxidant
- foxing
- parts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of calendering type ivory buff rubber hold-down calendering glue, calculate in parts by weight, including：3L standard rubbers 85, cis-butadiene cement 15, zinc oxide 8, stearic acid 2, white carbon 20, titanium dioxide 45, industrial fat 9, vaseline 4, antioxidant SP C 2.0, antioxidant MB 0.6, sulphur 1.7, altax 1.6, diphenylguanidine 0.15, captax 0.5, the resins 9 of RX 80, glycerine 2, calcium carbonate 85.Gum base ingredients are made foxing glue have good bond properties, can be used for a long time under the motion of high intensity, situation about will not come unglued using 80 90 parts of extraordinary standard rubbers of adhesive force；The extraordinary resins of RX 80 of 8 10 parts of tacks are used in gum base ingredients, make foxing glue that there is good bond properties；Therefore, its foxing side glue adhesive force of post-cure footwear and cohesive produced with this foxing formula is higher, can greatly improve the service life of post-cure footwear.
Description
Technical field
The present invention relates to elastomeric material preparation field, it is related to footwear side glue formula, more particularly to a kind of calendering type is ivory white
Color rubber hold-down calendering glue.
Background technology
For the foxing glue of post-cure footwear side glue, the combination of the adhesive glue of itself and sole rubber and brush on upper of a shoe is attached
Put forth effort requirement higher, tearing strength requires higher, to adapt to the activity and motion of high intensity, it is ensured that side glue and upper of a shoe do not come unglued,
Not degumming, without from side phenomenon.Especially for the post-cure footwear of sports type, the sizing material hardness requirement of foxing glue in itself is higher,
Sizing material hardness is small, causes foxing glue out-of-flatness, and sizing material hardness is big, then causes foxing glue not enough with upper of a shoe viscous force, in wearing process
In often come unglued, from the situation on side, adhesive force is less than or equal to 2.2kN/m, make shoes to wear the life-span shorter.
The content of the invention
The purpose of the present invention is in view of the shortcomings of the prior art, and to provide a kind of calendering type ivory buff rubber hold-down calendering glue,
With the foxing glue of formula production, its adhesive force is higher, and the bonding strength with upper of a shoe is higher, is not susceptible to out in wearing process
Glue, the situation from side, can greatly improve shoes wears service life.
Realizing the technical scheme of the object of the invention is：
A kind of calendering type ivory buff rubber hold-down calendering glue, is calculated in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, white carbon 20, titanium dioxide 45, industrial fat
8-10, vaseline 3-5, antioxidant SP-C 1.5-2.5, antioxidant MB 0.5-0.7, sulphur 1.5-2.0, altax 1.5-
1.8th, diphenylguanidine 0.1-0.2, captax 0.4-0.6, RX-80 resin 8-10, glycerine 1-3, calcium carbonate 85.
Compared with prior art, the advantage of the invention is that：Gum base ingredients are using the 80-90 parts of extraordinary standards of adhesive force
Rubber, makes foxing glue have good bond properties, can be used for a long time under the motion of high intensity, the feelings that will not be come unglued
Condition；The extraordinary RX-80 resins of 8-10 parts of tacks are used in gum base ingredients, make foxing glue that there is good bond properties；Cause
This, the post-cure footwear produced with this foxing formula, sizing material hardness is moderate, the smooth of footwear side glue has both been maintained, with upper of a shoe
Adhesive force and cohesive are higher, can greatly improve the service life of post-cure footwear.
Embodiment
Present invention is further elaborated below by embodiment, but is not limitation of the invention.
A kind of calendering type ivory buff rubber hold-down calendering glue, is calculated in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, white carbon 20, titanium dioxide 45, industrial fat
8-10, vaseline 3-5, antioxidant SP-C 1.5-2.5, antioxidant MB 0.5-0.7, sulphur 1.5-2.0, altax 1.5-
1.8th, diphenylguanidine 0.1-0.2, captax 0.4-0.6, RX-80 resin 8-10, glycerine 1-3, calcium carbonate 85.
The formula can be carried out two sections of mixings by banbury and be completed, to improve the cohesive of sizing material.
Standard rubbers are 3L standard rubbers, and standard rubbers, cis-butadiene cement add up to content to be 100 parts by weight.
Embodiment 1：
A kind of calendering type ivory buff rubber hold-down calendering glue, is calculated in parts by weight, including：
3L standard rubbers 80, cis-butadiene cement 20, zinc oxide 5, stearic acid 1, white carbon 20, titanium dioxide 45, industrial fat 8, vaseline 3,
Antioxidant SP-C 1.5, antioxidant MB 0.5, sulphur 1.5, altax 1.5, diphenylguanidine 0.1, captax 0.4, RX-
80 resins 8, glycerine 1, calcium carbonate 85.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：62；
Pull apart strength/MPa：8.0；
Elongation at break %：490；
Setafter break %：29；
Conditions of vulcanization：133℃×45′；
Deflect（It is secondary/just to split）：17500；
Adhesive force（kN/m）：2.8.
Wherein, adhesive force（kN/m）：2.8 are more than 2.2, and adhesive force is higher.
Embodiment 2：
A kind of calendering type ivory buff rubber hold-down calendering glue, is calculated in parts by weight, including：
3L standard rubbers 85, cis-butadiene cement 15, zinc oxide 8, stearic acid 2, white carbon 20, titanium dioxide 45, industrial fat 9, vaseline 4,
Antioxidant SP-C 2.0, antioxidant MB 0.6, sulphur 1.7, altax 1.6, diphenylguanidine 0.15, captax 0.5, RX-
80 resins 9, glycerine 2, calcium carbonate 85.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：67；
Pull apart strength/MPa：8.0；
Elongation at break %：495；
Setafter break %：26；
Conditions of vulcanization：133℃×60′；
Deflect（It is secondary/just to split）：17500；
Adhesive force（kN/m）：2.9.
Wherein, adhesive force（kN/m）：2.9 are more than 2.2, and adhesive force is higher.
Embodiment 3：
A kind of calendering type ivory buff rubber hold-down calendering glue, is calculated in parts by weight, including：
Standard rubbers 90, cis-butadiene cement 10, zinc oxide 10, stearic acid 3, white carbon 20, titanium dioxide 45, industrial fat 10, vaseline
5th, antioxidant SP-C 2.5, antioxidant MB 0.7, sulphur 2.0, altax 1.8, diphenylguanidine 0.2, captax 0.6,
RX-80 resins 10, glycerine 3, calcium carbonate 85.
After tested, physical data is as follows for this foxing glue：
Shore hardness/degree：59；
Pull apart strength/MPa：7.9；
Elongation at break %：495；
Setafter break %：28；
Conditions of vulcanization：133℃×60′；
Deflect（It is secondary/just to split）：18500；
Adhesive force（kN/m）：3.1.
Wherein, adhesive force（kN/m）：3.1 are more than 2.2, and adhesive force is higher.
Claims (2)
1. a kind of calendering type ivory buff rubber hold-down calendering glue, it is characterised in that calculate in parts by weight, including：
Standard rubbers 80-90, cis-butadiene cement 10-20, zinc oxide 5-10, stearic acid 1-3, white carbon 20, titanium dioxide 45, industrial fat
8-10, vaseline 3-5, antioxidant SP-C 1.5-2.5, antioxidant MB 0.5-0.7, sulphur 1.5-2.0, altax 1.5-
1.8th, diphenylguanidine 0.1-0.2, captax 0.4-0.6, RX-80 resin 8-10, glycerine 1-3, calcium carbonate 85.
2. calendering type ivory buff rubber hold-down calendering glue according to claim 1, it is characterised in that calculate in parts by weight,
Including：
3L standard rubbers 85, cis-butadiene cement 15, zinc oxide 8, stearic acid 2, white carbon 20, titanium dioxide 45, industrial fat 9, vaseline 4,
Antioxidant SP-C 2.0, antioxidant MB 0.6, sulphur 1.7, altax 1.6, diphenylguanidine 0.15, captax 0.5, RX-
80 resins 9, glycerine 2, calcium carbonate 85.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192957.XA CN107286385A (en) | 2016-03-30 | 2016-03-30 | A kind of calendering type ivory buff rubber hold-down calendering glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192957.XA CN107286385A (en) | 2016-03-30 | 2016-03-30 | A kind of calendering type ivory buff rubber hold-down calendering glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107286385A true CN107286385A (en) | 2017-10-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610192957.XA Pending CN107286385A (en) | 2016-03-30 | 2016-03-30 | A kind of calendering type ivory buff rubber hold-down calendering glue |
Country Status (1)
| Country | Link |
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| CN (1) | CN107286385A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484992A (en) * | 2018-03-31 | 2018-09-04 | 浙江中瑞橡胶高分子材料股份有限公司 | Wear-resisting white foxing formula of a kind of vulcanized shoes and preparation method thereof |
-
2016
- 2016-03-30 CN CN201610192957.XA patent/CN107286385A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484992A (en) * | 2018-03-31 | 2018-09-04 | 浙江中瑞橡胶高分子材料股份有限公司 | Wear-resisting white foxing formula of a kind of vulcanized shoes and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171024 |
|
| WD01 | Invention patent application deemed withdrawn after publication |