CN107282634A - A kind of method that utilization scale effect prepares foam stratiform foil - Google Patents

A kind of method that utilization scale effect prepares foam stratiform foil Download PDF

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Publication number
CN107282634A
CN107282634A CN201710447880.0A CN201710447880A CN107282634A CN 107282634 A CN107282634 A CN 107282634A CN 201710447880 A CN201710447880 A CN 201710447880A CN 107282634 A CN107282634 A CN 107282634A
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CN
China
Prior art keywords
foil
copper foil
aluminium
foam
copper
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Application number
CN201710447880.0A
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Chinese (zh)
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CN107282634B (en
Inventor
喻海良
崔晓辉
王青山
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Central South University
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Central South University
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Publication of CN107282634B publication Critical patent/CN107282634B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/40Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2261/00Product parameters
    • B21B2261/02Transverse dimensions
    • B21B2261/04Thickness, gauge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2265/00Forming parameters
    • B21B2265/12Rolling load or rolling pressure; roll force

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Metal Rolling (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of method that utilization scale effect prepares foam stratiform foil, using copper foil and aluminium foil as raw material, it is processed into the sheet material of identical size, stacked according to copper foil/aluminium foil/copper foil, by being welded product front end soldering, the material of leading portion soldering is subjected to ply rolling, repeat ply rolling to foil thickness and reach 10 200 μm, the present invention utilizes the principle that scale effect occurs in the metal material operation of rolling, prepare high-quality ultrathin copper foil/foam aluminium foil/copper foil laminar composite, in the case of microcosmic, the material is the laminar composite being made up of copper foil and foam aluminium foil, for copper foil/foam aluminium foil/copper foil multilayer materials, in material, copper and aluminum interfacial weld are intact, do not form intermetallic compound.

Description

A kind of method that utilization scale effect prepares foam stratiform foil
Technical field
It is more particularly to a kind of to prepare froth bed using scale effect the invention belongs to composite material rolling technical field The method of shape foil.
Background technology
At present, there is foam aluminium alloy small density, strong absorption impact capacity, high-damping shock stability and HI high impact energy to inhale The advantages of yield, sound insulation and noise reduction.Obtain the common concern of scientific circles and industrial quarters.The layer of metallic plate/foamed aluminium/metallic plate formation Shape result inherits the advantage of foamed aluminium material, and application is had been obtained in fields such as green building, automotive light weight technologies.
As microelectronic, microsecond delay manufacture the fast development in field, people to the demand of very thin stratified material gradually Increase.However, preparing very thin " metal foil/foam aluminium foil/metal foil " layer using the method for tradition machinery interfacial weld Shape material has very big difficulty.
The content of the invention
In order to overcome the shortcoming of above-mentioned prior art, bubble is prepared using scale effect it is an object of the invention to provide one kind The method of foam layer shape foil, using the principle of scale effect occurs in the metal material operation of rolling, prepares high-quality very thin copper Paper tinsel/foam aluminium foil/copper foil laminar composite, in the case of microcosmic, the material is the stratiform being made up of copper foil and foam aluminium foil Composite, is that copper and aluminum interfacial weld are intact, not shape in copper foil/foam aluminium foil/copper foil multilayer materials, material Into intermetallic compound.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of method that utilization scale effect prepares foam stratiform foil, comprises the following steps:
The first step:Using copper foil and aluminium foil as raw material;
Second step:Aluminium foil and copper foil are processed into the sheet material of identical size;
3rd step:Stacked according to copper foil/aluminium foil/copper foil, by being welded product front end soldering;
4th step:The material of front end soldering is subjected to ply rolling;
5th step:Material after ply rolling is taken out, the 4th step is repeated, until foil thickness reaches 10-200 μm.
In the first step, aluminium foil material is commercial-purity aluminium AA1230, and the thickness before copper foil rolling is 100-300 μm, aluminium Thickness before paper tinsel rolling is 15-50 μm.
In 4th step, single pass reduction ratio is between 40%-60%.
Compared with prior art, the present invention utilizes the scale effect in foil plastic history and high speed plastic deformation In the case of aluminum alloy materials hole is formed by core of constituent phases, and at the same time, with the reduction of aluminum foil thickness, plastic deformation Hole ratio present in aluminium foil is gradually stepped up afterwards, so as to become the principle of foam shape.Prepare high-quality ultrathin copper foil/ Foam aluminium foil/copper foil laminar composite.The present invention is adapted to prepare copper foil, aluminium foil and is combined using ply rolling and scale effect technology Foil, gained composite copper foil/foam aluminium foil/copper foil stratified material has in fields such as microelectric technique, sound insulation and noise reduction, microsecond delays Bright prospects.
Brief description of the drawings
Fig. 1 is the ply rolling rolling preparation flow figure of copper foil/foam aluminium foil/copper foil composite foil of layer structure of the present invention.
Fig. 2 show the interface microstructure for rolling and terminating between rear copper foil and foam aluminium foil.
Fig. 3 is the microstructure of aluminum before rolling.
Fig. 4 is shown after rolling terminates, the nano aperture distribution situation in aluminium.
Embodiment
Describe embodiments of the present invention in detail with reference to the accompanying drawings and examples.
As shown in figure 1, the method that the present invention prepares foam stratiform foil using scale effect, flow is as follows:
The first step:It is raw material with copper foil 1 and aluminium foil 2, the thickness before copper foil 1 is rolled is 100-300 μm, before aluminium foil 2 is rolled Thickness be 15-50 μm.Aluminium foil 2 is commercial-purity aluminium AA1230 foils, and copper foil 1 is general industry copper foil.
Second step:Metal aluminum foil and metal copper foil are processed into the sheet material of identical size.
3rd step:According to copper/aluminium/copper stack obtaining sheet material 3, carried out the front end of the i.e. sheet material 3 of rolled piece by being welded Soldering.
4th step:Material 4 after soldering is placed between upper lower compression roller 5, ply rolling is carried out, single pass reduction ratio is in 40%- Between 60%.
5th step:Material is taken out, the 4th step is repeated, material 6 after the foil thickness suitable until reaching is rolled is thick Degree at 10-200 μm, wherein, roll rear aluminium matrix 7 positioned at rolling for two layers between rear copper material matrix 8, roll has greatly on rear aluminium matrix 7 The hole 9 of amount, but without hole at aluminum bronze interface 10.
The experiment case study of the present invention, uses the thickness of copper foil 1 for 300 μm, and the thickness of aluminium foil 2 is 16 μm.Copper is technical pure Copper, aluminium is AA1230.Stacked according to such scheme according to copper foil/aluminium foil/copper foil, then, carry out ply rolling.Rolled by 4 After passage processed, the thickness of rolled piece is 160 μm.
Fig. 2 show ply rolling and terminates rear copper/aluminium interface distributions situation, and interface cohesion is intact.
Fig. 3 show AA1230 aluminium alloy microstructures before rolling, and material internal is without hole.
Fig. 4 is shown after ply rolling terminates, the distribution of aluminium alloy microstructure, and there is substantial amounts of nano aperture the inside.

Claims (3)

1. a kind of method that utilization scale effect prepares foam stratiform foil, it is characterised in that comprise the following steps:
The first step:Using copper foil and aluminium foil as raw material;
Second step:Aluminium foil and copper foil are processed into the sheet material of identical size;
3rd step:Stacked according to copper foil/aluminium foil/copper foil, by being welded product front end soldering;
4th step:The material of leading portion soldering is subjected to ply rolling;
5th step:Material after ply rolling is taken out, the 4th step is repeated, until foil thickness reaches 10-200 μm.
2. the method for foam stratiform foil is prepared using scale effect according to claim 1, it is characterised in that described first In step, aluminium foil material is commercial-purity aluminium AA1230, and the thickness before copper foil rolling is that the thickness before 100-300 μm, aluminum foil rolling is 15-50μm。
3. the method for foam stratiform foil is prepared using scale effect according to claim 1, it is characterised in that the described 4th In step, single pass reduction ratio is between 40%-60%.
CN201710447880.0A 2017-06-14 2017-06-14 A method of foam stratiform foil is prepared using scale effect Active CN107282634B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710447880.0A CN107282634B (en) 2017-06-14 2017-06-14 A method of foam stratiform foil is prepared using scale effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710447880.0A CN107282634B (en) 2017-06-14 2017-06-14 A method of foam stratiform foil is prepared using scale effect

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CN107282634A true CN107282634A (en) 2017-10-24
CN107282634B CN107282634B (en) 2019-05-10

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626868A (en) * 2017-11-02 2018-01-26 中国科学院金属研究所 Manufacturing process is constructed in the classification of hourglass shape metal
CN109174965A (en) * 2018-08-17 2019-01-11 中南大学 A method of preparing very thin high-performance multilayer copper/copper Al intermetallic/aluminum composite foil material
CN113798322A (en) * 2021-08-05 2021-12-17 福建巨电新能源股份有限公司 Preparation method of composite foil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01224183A (en) * 1988-03-04 1989-09-07 Ishikawajima Harima Heavy Ind Co Ltd Manufacture of composite material
CN102357525A (en) * 2011-07-22 2012-02-22 西安建筑科技大学 Preparation method for multilayer copper/molybdenum structure composite plate
CN102501457A (en) * 2011-09-30 2012-06-20 哈尔滨工业大学 Ceramic-TiAl micro-laminated composite material board and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01224183A (en) * 1988-03-04 1989-09-07 Ishikawajima Harima Heavy Ind Co Ltd Manufacture of composite material
CN102357525A (en) * 2011-07-22 2012-02-22 西安建筑科技大学 Preparation method for multilayer copper/molybdenum structure composite plate
CN102501457A (en) * 2011-09-30 2012-06-20 哈尔滨工业大学 Ceramic-TiAl micro-laminated composite material board and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘相华: "金属极薄带轧制研究新进展", 《世界金属导报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626868A (en) * 2017-11-02 2018-01-26 中国科学院金属研究所 Manufacturing process is constructed in the classification of hourglass shape metal
CN109174965A (en) * 2018-08-17 2019-01-11 中南大学 A method of preparing very thin high-performance multilayer copper/copper Al intermetallic/aluminum composite foil material
CN109174965B (en) * 2018-08-17 2019-11-01 中南大学 A method of preparing very thin high-performance multilayer copper/copper Al intermetallic/aluminum composite foil material
CN113798322A (en) * 2021-08-05 2021-12-17 福建巨电新能源股份有限公司 Preparation method of composite foil

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