WO2018196432A1 - Method for manufacturing brazed honeycomb panel and honeycomb panel - Google Patents

Method for manufacturing brazed honeycomb panel and honeycomb panel Download PDF

Info

Publication number
WO2018196432A1
WO2018196432A1 PCT/CN2017/120295 CN2017120295W WO2018196432A1 WO 2018196432 A1 WO2018196432 A1 WO 2018196432A1 CN 2017120295 W CN2017120295 W CN 2017120295W WO 2018196432 A1 WO2018196432 A1 WO 2018196432A1
Authority
WO
WIPO (PCT)
Prior art keywords
aluminum
honeycomb
manufacturing
honeycomb core
adhesive
Prior art date
Application number
PCT/CN2017/120295
Other languages
French (fr)
Chinese (zh)
Inventor
雷煜
王立铮
刘建伟
郑涛
王胜江
Original Assignee
中车唐山机车车辆有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 中车唐山机车车辆有限公司 filed Critical 中车唐山机车车辆有限公司
Publication of WO2018196432A1 publication Critical patent/WO2018196432A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/016Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of aluminium or aluminium alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/008Soldering within a furnace
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/20Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding

Definitions

  • the present application relates to the field of rail transit, and in particular to a method of manufacturing a brazed honeycomb panel and a honeycomb panel.
  • ceramsite sand In the field of rail transit, floors, roofs, etc. used in transportation vehicles such as subways and urban rail vehicles are mostly ceramsite sand and adhesive aluminum honeycomb materials.
  • the ceramsite sand was gradually eliminated due to its inability to meet the design's weight reduction requirements.
  • Adhesive aluminum honeycomb panels are easily connected by the surrounding environment and the properties of the adhesive due to the bonding between the honeycomb cores and the honeycomb cores and the aluminum sheets. For example, in the high altitude environment, it is easy to degumming, drumming, and unrepairable.
  • the patent application No. 200910094562.6 discloses a method for preparing a brazed metal honeycomb panel.
  • the preparation of the aluminum honeycomb core is assembled into a honeycomb shape by roll forming, and the assembly precision of the honeycomb core is difficult to meet. Inefficient, it is difficult to achieve industrial production.
  • the patent application No. 201410796743.7 discloses a glueless composite board and a manufacturing process thereof, although a welding process similar to the present application is mentioned, but a honeycomb finning machine is used for roll forming, not mentioned. To the honeycomb manufacturing process.
  • the patent application No. 201210177885.3 discloses a method for preparing an aluminum honeycomb core material and a honeycomb panel by preparing a brazed aluminum honeycomb core by a stretching method after vacuum brazing, and then vacuum welding with the aluminum plate.
  • Vacuum brazing consumes energy, has low production efficiency, and secondary welding greatly increases production costs.
  • a method of preparing a metal honeycomb core material and a honeycomb sandwich panel is disclosed in the patent application No. 201310003242.1.
  • the honeycomb core is prepared by the stretching method, it is directly coated with the solder-coated aluminum plate by using a rubber or solder on the non-composite aluminum foil, and the rubber compound does not ensure the metallurgical connection between the honeycomb cores. .
  • After brazing with a brazing material and then stretching into a honeycomb shape it belongs to secondary brazing, which is low in efficiency and energy consuming.
  • Adhesive aluminum honeycomb is easily degummed due to environmental and working conditions. After being rolled and formed into a honeycomb shape, the assembly precision of the honeycomb core is difficult to meet and the efficiency is low, and it is difficult to realize industrial production;
  • the brazed aluminum honeycomb core is prepared by a stretching method, and then vacuum brazed and then brazed with an aluminum plate vacuum or an atmosphere furnace. Vacuum brazing consumes energy, has low production efficiency, and secondary welding increases energy consumption and increases production costs.
  • a method for manufacturing a brazed honeycomb panel and a honeycomb panel are provided to solve the problem that the adhesive aluminum honeycomb is easy to be degummed in the prior art, and the honeycomb core assembly precision is low; the brazed aluminum honeycomb core has high cost and low efficiency. problem.
  • the present application provides a method of manufacturing a brazed honeycomb panel, the method comprising the steps of:
  • the layered structure fixed by the card is brazed under a nitrogen atmosphere to obtain a honeycomb panel.
  • the present application forms a double-sided composite aluminum foil into an aluminum honeycomb by a gluing process, and brazes the honeycomb and the single-sided composite aluminum plate, and the welding only needs to spray the flux on the honeycomb and the composite aluminum plate, and the welding is performed.
  • the metallurgical bond between the core materials is completely unaffected by the adhesive.
  • the metallurgical combination between the core materials and the honeycomb and the plate material is high in strength, light in weight, soundproof, fireproof, environmentally friendly, weldable and completely recoverable. It not only overcomes the shortcomings of low efficiency and energy consumption in the preparation of honeycomb core by molding method, but also overcomes the disadvantages of high energy consumption and low efficiency of aluminum brazing prepared by vacuum brazing or secondary brazing.
  • the brazing aluminum honeycomb assembly of the present application has high assembly precision and simple operation, can greatly improve production efficiency, and is suitable for industrial production.
  • FIG. 1 is a schematic view showing a method of manufacturing a brazed honeycomb panel according to the present application
  • FIG. 2 is a schematic view of a single rubber strip printing roller according to the present application.
  • Figure 3 is a schematic view of the double-strip printing roller of the present application.
  • FIG. 4 is a schematic view showing a cross section of a single-glue rubber-coated aluminum foil stack according to the present application
  • Figure 5 is a schematic view showing a cross section of a double-glue rubber-coated aluminum foil stack according to the present application
  • Figure 6 is a schematic view of the plate body loading device of the present application.
  • Figure 7 is a schematic view of a pressing mechanism of the plate body loading device of the present application.
  • Figure 8 is a schematic exploded view of the plate body loading device after assembly of the plate body according to the present application.
  • FIG. 9 is a process flow diagram of a single rubber strip brazing honeycomb panel according to the present application.
  • FIG. 10 is a process flow diagram of a double-adhesive brazed honeycomb panel according to the present application.
  • the core idea of the application is that the double-sided composite aluminum foil coated with epoxy glue is stretched into a honeycomb shape by a stretching method, and the single-sided composite aluminum plate coated with the brazing material is directly brazed after the cracking of the glue, after welding.
  • the metallurgical core material and the core material and the aluminum plate are completely metallurgically combined to achieve high efficiency and low energy consumption.
  • the present application provides a method for manufacturing a brazed honeycomb panel, which mainly includes the following steps:
  • the degummed aluminum honeycomb core was fixed between two green sheets having a solder layer to be brazed to obtain a honeycomb panel.
  • the aluminum honeycomb core stretched into a honeycomb shape may be directly fixed between the two blank plates, and then brazed directly to obtain a honeycomb plate.
  • the advantage of the simplification step is that the high temperature in the brazing furnace can be utilized, while the colloid on the cracked aluminum honeycomb core and the layered structure formed by placing the aluminum honeycomb core between the two blanks are brazed, only need to be controlled Good brazing and cracking timing.
  • the blank plate may be a single or multi-layered plate material, for example, a composite aluminum plate, a steel plate, a steel-aluminum composite plate, or the like.
  • the composite aluminum foil may be a double-sided composite aluminum foil.
  • a transition material may be first plated on the steel plate, and the transition material is brazed with the aluminum honeycomb core to ensure the stability after brazing.
  • the steel-aluminum composite plate is used, the aluminum material surface is in contact with the aluminum honeycomb core, so that the stability of the holding plate and the honeycomb filler can be well achieved after brazing.
  • the step of bonding the composite aluminum foil comprises: coating the adhesive on the surface of the composite aluminum foil in an array; and stacking at least two composite aluminum foils coated with the adhesive in such a manner that the adhesive is misaligned Fixed to form a composite aluminum foil formed by bonding;
  • the method of the present scheme further comprises spraying a flux on the surface of the aluminum honeycomb core and the blank of the blank having a solder after the degumming treatment.
  • the flux is in the form of a powder or a liquid.
  • the flux is a potassium fluoroaluminate flux.
  • the aluminum foil may be a double-sided composite aluminum foil, and the thickness is guaranteed to be between 0.08 and 0.6 mm, and the composite ratio may be between 8% and 12%.
  • the aluminum plate may be a multi-layer or single-layer composite aluminum plate, and the thickness is guaranteed to be between 1.0 mm and 5 mm, and the composite ratio may be between 8% and 12%.
  • the composite plate is made of a composite aluminum plate
  • the honeycomb core material is made of a composite aluminum foil. Since an oxide film or oil is deposited on the aluminum foil and the aluminum plate, it is necessary to remove the oxidation of the composite aluminum foil and the composite aluminum plate by using an alkaline aqueous solution of trisodium phosphate in advance. Membrane and oil so that these materials will not be affected by dirt during subsequent use.
  • the glue application tool on the composite aluminum foil can be directly treated by a glue applicator.
  • the adhesive may be an epoxy, phenolic or rubber mixed adhesive which is volatilized at 300 ° C to 450 ° C.
  • a single strip or a double strip can be used.
  • the width of the rubber strip coating method is xL
  • the distance between the rubber rollers is 4L
  • the speed of coating the aluminum foil printing is 2-80 m/min.
  • the printing speed can be 8-40.
  • the printed aluminum foil is dried at room temperature to 150 °C.
  • the double rubber strip rubber roller is designed as shown in the figure.
  • the double rubber strip rubber roller is designed according to the required aluminum honeycomb side length L.
  • the total width of the double rubber strip and the uncoated rubber part is xL, and the uncoated portion is
  • the shape can be designed by itself, the width is ⁇ yxL, and the coefficient y can be taken as 0.8.
  • the distance between the rubber rollers is 4 L, and the speed of the aluminum foil printing is 2 to 80 m/min. Preferably, the printing speed can be 8 to 40 m/min.
  • the structure for stretching into a honeycomb core may be a non-normal hexagon. Therefore, by adjusting the magnitude of x in the width of the rubber roller, the hexagonal shape of the subsequently stretched honeycomb core can be changed.
  • the contact surface of the aluminum foil is the glued part, the residue after the rubber crack is volatilized will affect the brazing strength of the contact position.
  • the entire contact surface of the single rubber strip is coated with glue, and the metallurgical bonding part after brazing is defective; the double rubber strip is not coated between the rubber strips, and there is no residue after the volatilization of the glue affects the contact position brazing, and the glue is realized.
  • the parts are completely metallurgically bonded to increase the strength of the core contact surface. Therefore, the present application preferably coats the adhesive with a double strip.
  • the two composite aluminum foils coated with the adhesive are stacked in a staggered manner according to the manner of the adhesive coating, as shown in FIG. 4 or FIG. 5, respectively.
  • an aluminum honeycomb core was obtained by hot pressing and slicing treatment, respectively.
  • the requirements of hot pressing need to meet: pressure 0.3-0.5Mpa, curing temperature 170 ° C-200 ° C, holding time 2.5h-3h.
  • the requirements for slicing need to be met: cutting accuracy ⁇ 0.05mm.
  • the adhesive is coated in the form of an array on the surface of the composite aluminum foil; the two composite aluminum foils coated with the adhesive are stacked and fixed in such a manner that the adhesive is misaligned to form a composite aluminum foil which is bonded and formed, and then pulled. Stretching to form a honeycomb aluminum honeycomb core.
  • degumming the aluminum honeycomb core uses the specific steps of degumming to determine whether the aluminum honeycomb core is degumming the aluminum honeycomb core.
  • the specific steps of degumming include: placing the drawn honeycomb into a continuous nitrogen protection furnace, and setting an exhaust gas recovery device in the furnace, the temperature in the furnace is 300-450 ° C, the protective atmosphere is nitrogen, and the speed is 1.2 m / min. Running for 5 to 80 minutes, preferably, the running time is 10-20 minutes, the colloid is removed from the cooling system after volatilization, and the core is removed when the predetermined temperature is reached. At this time, the core can maintain a stable connection state without Fix it again.
  • the degumming process is mainly to ensure that the honeycomb structure of the aluminum honeycomb core can achieve a good welding effect with the composite aluminum plate, and the odor generated by the colloidal cracking is removed in advance by degumming to prevent the colloidal cracking and volatilizing black core during the welding process, and the brazed honeycomb
  • the board is beautiful and firm.
  • the honeycomb aluminum honeycomb core After the degumming treatment by the honeycomb aluminum honeycomb core, it is possible to selectively spray the flux on the surface of the aluminum honeycomb core and the blank having the solder after the degumming treatment.
  • a powdered or liquid flux is sprayed onto the solder layer of the honeycomb and composite aluminum sheets.
  • a potassium fluoroaluminate flux is preferably used as the flux.
  • an aluminum honeycomb core is fixed between two green sheets to form a layered structure.
  • brazing can be performed after the aluminum honeycomb core is placed in a layered structure formed between two blank plates, but, in the process of brazing, it is carried out under a nitrogen atmosphere, and at the same time The higher brazing temperature results in deformation of the layered structure, which affects the quality of the final brazed product and reduces the yield. Therefore, in this solution, a card loading process is added before brazing.
  • the aluminum honeycomb core and the blank were assembled using a plate assembly device as shown in FIG.
  • the aluminum honeycomb core and the upper and lower composite panels are fixed on the tooling platform 1 by a clamp, and the pressing head 23 of the pressing mechanism 2 is pressed to ensure an average force of 0.1-0.3 bar.
  • the specific steps for card loading are:
  • the tooling platform 1 is first penetrated, and the thread on the screw sleeve 21 of the pressing mechanism 2 shown in FIG. 7 is initially fastened to the tooling, and then the flux is sprayed.
  • the layered structure formed by the aluminum honeycomb core between the two blank plates is assembled and placed in the tooling platform 1, and the fixed platen is slowly pressed against the honeycomb panel.
  • the four pins 22 of the pressing mechanism 2 are screwed out so that the ram 23 of the pressing mechanism 2 acts on the sizing plate by the high temperature resistant pressing spring 24 of the pressing mechanism 2.
  • the compression nut 21 of the pressing mechanism is screwed with a hexagonal wrench, and at this time, the compression nut 21 and the tooling are tightened so that the compression spring contracts to generate a larger force acting on the shaping plate 3.
  • a layered structure formed by placing an aluminum honeycomb core between two blank plates is brazed.
  • the specific step of brazing comprises: placing the assembled layered structure consisting of an aluminum honeycomb core and two blank plates in a brazing furnace having nitrogen, the brazing furnace being intermittent or continuous
  • the inert atmosphere brazing furnace has a brazing temperature of 600 ° C to 650 ° C.
  • the brazing temperature is controlled at 615 ° C to 640 ° C.
  • the brazing furnace is cooled by inert gas air cooling, and the cooling interval is 640 ° C to 250 ° C.
  • honeycomb panels for support or load bearing are removed from the cooling zone by final cooling.
  • the program is further illustrated by a set of examples:
  • the present scheme designs a method for manufacturing a brazed honeycomb panel, and the specific steps are as follows:
  • the composite aluminum foil is double-sided composite, the thickness is 0.08 to 0.6 mm, the inner layer is a 3 series aluminum alloy, and the solder layer is a 4 series aluminum alloy, and the composite ratio is 8%-12%.
  • the composite aluminum plate is a single-sided composite having a thickness of 1.0 mm to 5 mm, and the solder layer is a 4-series aluminum alloy, and the composite ratio is 8% to 12%.
  • the deoxidized film and the oil stain are washed with an alkaline aqueous solution of trisodium phosphate to add a small amount of a surfactant.
  • the glue is a resin
  • the hot pressing temperature is 150 to 200 degrees
  • the resin glue is dried and cracked and volatilized at 250 to 450 degrees.
  • the composite aluminum foil is double-sided composite, the thickness is 0.08 to 0.6 mm, and the inner layer is 3 series aluminum.
  • the alloy and the solder layer are 4 series aluminum alloys, and the composite ratio is 8%-12%.
  • the stacked aluminum foil is placed in a hot press for hot pressing at a temperature of 150 ° C - 200 ° C;
  • the stretched honeycomb has a hexagonal shape with a side length of 3 to 35 mm.
  • the flux is a potassium fluoroaluminate flux.
  • the resin-based glue is cleaved and volatilized at 250 to 450 degrees.
  • the brazing furnace is a batch or continuous inert atmosphere brazing furnace with a temperature of 615 to 640 degrees.
  • the brazing honeycomb panel is cooled by inert gas air cooling, and the cooling interval is 640 to 250 degrees.
  • the honeycomb panel prepared by the scheme of the present invention can ensure the metallurgical bond between the honeycomb core and the honeycomb core and the aluminum plate, overcomes the shortage of the adhesive strength of the adhesive and is not affected by the environment, is not subject to environmental constraints, and has high peel strength and resistance. Pressure, environmental protection, recyclability and many other excellent properties, while improving the positioning accuracy of the honeycomb core, reducing processing costs, and broad application prospects in rail transit, aerospace, shipbuilding, construction and other fields.
  • embodiments of the present application can be provided as a method, system, or computer program product.
  • the present application can take the form of an entirely hardware embodiment, an entirely software embodiment, or an embodiment in combination of software and hardware.
  • the application can take the form of a computer program product embodied on one or more computer-usable storage media (including but not limited to disk storage, CD-ROM, optical storage, etc.) including computer usable program code.
  • the computer program instructions can also be stored in a computer readable memory that can direct a computer or other programmable data processing device to operate in a particular manner, such that the instructions stored in the computer readable memory produce an article of manufacture comprising the instruction device.
  • the apparatus implements the functions specified in one or more blocks of a flow or a flow and/or block diagram of the flowchart.
  • These computer program instructions can also be loaded onto a computer or other programmable data processing device such that a series of operational steps are performed on a computer or other programmable device to produce computer-implemented processing for execution on a computer or other programmable device.
  • the instructions provide steps for implementing the functions specified in one or more of the flow or in a block or blocks of a flow diagram.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

A method for manufacturing a brazed honeycomb panel, comprising the following steps: stretching a composite aluminum foil, which is formed by pre-gumming, stacking, and binding and has a brazing filler metal layer, as a honeycombed aluminum honeycomb core; press-fixing the aluminum honeycomb core between two blank panels that have brazing filler metal layers by using a clamping device to form a layered structure; and performing brazing treatment on the layered structure fixed by clamping at a nitrogen atmosphere to obtain a honeycomb panel. In the present application, the glued aluminum foil is stretched as honeycombed by means of a stretching method, and then brazing is directly performed with an aluminum panel after glue cracking treatment, such that complete metallurgical bonding is achieved between honeycomb core materials as well as between core materials and aluminum panels, and high efficiency and low energy consumption are achieved.

Description

一种钎焊蜂窝板的制造方法及蜂窝板Method for manufacturing brazed honeycomb panel and honeycomb panel 技术领域Technical field
本申请涉及轨道交通领域,具体地,涉及一种钎焊蜂窝板的制造方法及蜂窝板。The present application relates to the field of rail transit, and in particular to a method of manufacturing a brazed honeycomb panel and a honeycomb panel.
背景技术Background technique
在轨道交通领域中,例如地铁、城轨车辆等交通车辆中使用的地板、顶板等大多为陶粒砂和胶粘铝蜂窝材料。陶粒砂由于无法满足设计的减重要求,逐渐被淘汰。而胶粘铝蜂窝板由于蜂窝芯之间、蜂窝芯与铝板之间用胶接的方式连接,很容易受到周围环境及胶粘剂自身性能的制约。比如在高原环境容易脱胶、起鼓、不可修复等局限。In the field of rail transit, floors, roofs, etc. used in transportation vehicles such as subways and urban rail vehicles are mostly ceramsite sand and adhesive aluminum honeycomb materials. The ceramsite sand was gradually eliminated due to its inability to meet the design's weight reduction requirements. Adhesive aluminum honeycomb panels are easily connected by the surrounding environment and the properties of the adhesive due to the bonding between the honeycomb cores and the honeycomb cores and the aluminum sheets. For example, in the high altitude environment, it is easy to degumming, drumming, and unrepairable.
例如,申请号:200910094562.6的专利申请中公开了一种钎焊式金属蜂窝板的制备方法,其铝蜂窝芯的制备都是采用辊压成型后组装成蜂窝状,蜂窝芯组装精度很难满足且效率低,很难实现工业化生产。For example, the patent application No. 200910094562.6 discloses a method for preparing a brazed metal honeycomb panel. The preparation of the aluminum honeycomb core is assembled into a honeycomb shape by roll forming, and the assembly precision of the honeycomb core is difficult to meet. Inefficient, it is difficult to achieve industrial production.
例如,申请号:201410796743.7的专利申请中公开了一种无胶复合板及其制造工艺,虽然提到了与本申请是类似的焊接工艺,但是提到蜂窝状用翅片机辊压成型,未提到蜂窝状的制造工艺。For example, the patent application No. 201410796743.7 discloses a glueless composite board and a manufacturing process thereof, although a welding process similar to the present application is mentioned, but a honeycomb finning machine is used for roll forming, not mentioned. To the honeycomb manufacturing process.
例如,申请号:201210177885.3的专利申请中公开了一种铝蜂窝芯材及蜂窝板的制备方法是在真空钎焊后采用拉伸法制备钎焊铝蜂窝芯,之后再与铝板真空焊接。真空钎焊耗能、生产效率低、且二次 焊接大大增加生产成本。For example, the patent application No. 201210177885.3 discloses a method for preparing an aluminum honeycomb core material and a honeycomb panel by preparing a brazed aluminum honeycomb core by a stretching method after vacuum brazing, and then vacuum welding with the aluminum plate. Vacuum brazing consumes energy, has low production efficiency, and secondary welding greatly increases production costs.
例如,申请号:201310003242.1的专利申请中公开了一种金属蜂窝芯材及蜂窝三明治板的制备方法。虽然提到了用拉伸法制备蜂窝芯,但是用胶料或钎料涂在非复合铝箔上直接与涂了钎料的铝板焊接,此种工序用胶料并不能保证蜂窝芯之间的冶金连接。用钎料后再拉伸成蜂窝状则属于二次钎焊,效率低、耗能。For example, a method of preparing a metal honeycomb core material and a honeycomb sandwich panel is disclosed in the patent application No. 201310003242.1. Although it is mentioned that the honeycomb core is prepared by the stretching method, it is directly coated with the solder-coated aluminum plate by using a rubber or solder on the non-composite aluminum foil, and the rubber compound does not ensure the metallurgical connection between the honeycomb cores. . After brazing with a brazing material and then stretching into a honeycomb shape, it belongs to secondary brazing, which is low in efficiency and energy consuming.
综上所述,现有技术中存在的不足之处在于:In summary, the shortcomings in the prior art are:
1、胶粘铝蜂窝受环境和工作条件的影响,容易脱胶。采用辊压成型后组装成蜂窝状,蜂窝芯组装精度很难满足且效率低,很难实现工业化生产;1. Adhesive aluminum honeycomb is easily degummed due to environmental and working conditions. After being rolled and formed into a honeycomb shape, the assembly precision of the honeycomb core is difficult to meet and the efficiency is low, and it is difficult to realize industrial production;
2、采用拉伸法制备钎焊铝蜂窝芯,真空钎焊后之后再与铝板真空或者气氛炉钎焊。真空钎焊耗能、生产效率低、且二次焊接增加能耗提高生产成本。2. The brazed aluminum honeycomb core is prepared by a stretching method, and then vacuum brazed and then brazed with an aluminum plate vacuum or an atmosphere furnace. Vacuum brazing consumes energy, has low production efficiency, and secondary welding increases energy consumption and increases production costs.
发明内容Summary of the invention
本申请实施例中提供了一种钎焊蜂窝板的制造方法及蜂窝板,以解决现有技术中胶粘铝蜂窝容易脱胶,蜂窝芯组装精度低;钎焊铝蜂窝芯成本高,效率低的问题。In the embodiment of the present application, a method for manufacturing a brazed honeycomb panel and a honeycomb panel are provided to solve the problem that the adhesive aluminum honeycomb is easy to be degummed in the prior art, and the honeycomb core assembly precision is low; the brazed aluminum honeycomb core has high cost and low efficiency. problem.
本申请提供了一种钎焊蜂窝板的制造方法,该方法的步骤包括:The present application provides a method of manufacturing a brazed honeycomb panel, the method comprising the steps of:
将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝状的铝蜂窝芯;Forming a composite aluminum foil having a solder layer formed by pre-gluing and stacking into a honeycomb-shaped aluminum honeycomb core;
利用装卡装置将铝蜂窝芯压固在两块具有钎料层的胚板之间形成层状结构;Pressing the aluminum honeycomb core between the two blank plates having the solder layer to form a layered structure by using a card loading device;
在氮气环境下对装卡固定的层状结构进行钎焊处理,获得蜂窝板。The layered structure fixed by the card is brazed under a nitrogen atmosphere to obtain a honeycomb panel.
一种利用权利要求1所述方法制成的蜂窝板。A honeycomb panel produced by the method of claim 1.
本申请的有益效果如下:The beneficial effects of the application are as follows:
与现有技术相比,本申请通过涂胶工艺将双面复合铝箔制成铝蜂窝状,在将蜂窝状与单面复合铝板钎焊,焊接只需要在蜂窝状与复合铝板喷涂钎剂,焊后芯材之间冶金结合完全不受胶粘影响,芯材之间、蜂窝状与板材之间冶金结合,强度高、重量轻、隔音、防火、环保、可焊接、可完全回收。既克服成型法制备蜂窝芯装配效率低且耗能的缺点,也克服了真空钎焊或二次钎焊制备铝蜂窝耗能高、效率低的不足。本申请钎焊铝蜂窝状装配精度高,操作简单,可大幅提高生产效率,适合工业化生产。Compared with the prior art, the present application forms a double-sided composite aluminum foil into an aluminum honeycomb by a gluing process, and brazes the honeycomb and the single-sided composite aluminum plate, and the welding only needs to spray the flux on the honeycomb and the composite aluminum plate, and the welding is performed. The metallurgical bond between the core materials is completely unaffected by the adhesive. The metallurgical combination between the core materials and the honeycomb and the plate material is high in strength, light in weight, soundproof, fireproof, environmentally friendly, weldable and completely recoverable. It not only overcomes the shortcomings of low efficiency and energy consumption in the preparation of honeycomb core by molding method, but also overcomes the disadvantages of high energy consumption and low efficiency of aluminum brazing prepared by vacuum brazing or secondary brazing. The brazing aluminum honeycomb assembly of the present application has high assembly precision and simple operation, can greatly improve production efficiency, and is suitable for industrial production.
附图说明DRAWINGS
此处所说明的附图用来提供对本申请的进一步理解,构成本申请的一部分,本申请的示意性实施例及其说明用于解释本申请,并不构成对本申请的不当限定。在附图中:The drawings described herein are intended to provide a further understanding of the present application, and are intended to be a part of this application. In the drawing:
图1为本申请所述一种钎焊蜂窝板的制造方法的示意图;1 is a schematic view showing a method of manufacturing a brazed honeycomb panel according to the present application;
图2为本申请所述单胶条印胶辊的示意图;2 is a schematic view of a single rubber strip printing roller according to the present application;
图3为本申请所述双胶条印胶辊的示意图;Figure 3 is a schematic view of the double-strip printing roller of the present application;
图4为本申请所述单胶条涂胶铝箔堆叠的断面的示意图;4 is a schematic view showing a cross section of a single-glue rubber-coated aluminum foil stack according to the present application;
图5为本申请所述双胶条涂胶铝箔堆叠的断面的示意图;Figure 5 is a schematic view showing a cross section of a double-glue rubber-coated aluminum foil stack according to the present application;
图6为本申请所述板体装卡装置的示意图;Figure 6 is a schematic view of the plate body loading device of the present application;
图7为本申请所述板体装卡装置中压紧机构的示意图;Figure 7 is a schematic view of a pressing mechanism of the plate body loading device of the present application;
图8为本申请所述板体装配后板体装卡装置的爆炸示意图;Figure 8 is a schematic exploded view of the plate body loading device after assembly of the plate body according to the present application;
图9为本申请所述单胶条钎焊蜂窝板的工艺流程图;9 is a process flow diagram of a single rubber strip brazing honeycomb panel according to the present application;
图10为本申请所述双胶条钎焊蜂窝板的工艺流程图;。10 is a process flow diagram of a double-adhesive brazed honeycomb panel according to the present application;
1、工装平台,2、压紧机构,3、石墨压板,4、层状胚板;21、螺套,22、插销,23、压头,24、压紧弹簧。1, tooling platform, 2, pressing mechanism, 3, graphite plate, 4, layered embryo; 21, screw sleeve, 22, bolt, 23, indenter, 24, compression spring.
具体实施方式detailed description
为了使本申请实施例中的技术方案及优点更加清楚明白,以下结合附图对本申请的示例性实施例进行进一步详细的说明,显然,所描述的实施例仅是本申请的一部分实施例,而不是所有实施例的穷举。需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。The exemplary embodiments of the present application are further described in detail below with reference to the accompanying drawings. Not all embodiments are exhaustive. It should be noted that the embodiments in the present application and the features in the embodiments may be combined with each other without conflict.
本申请的核心思路是,采用拉伸法将涂了环氧胶的双面复合铝箔拉伸成蜂窝状,胶裂解后再与涂了钎料的单面复合铝板直接进行一次钎焊,焊后蜂窝芯材之间、芯材与铝板之间完全冶金结合,达到高效、低能耗的目的。The core idea of the application is that the double-sided composite aluminum foil coated with epoxy glue is stretched into a honeycomb shape by a stretching method, and the single-sided composite aluminum plate coated with the brazing material is directly brazed after the cracking of the glue, after welding. The metallurgical core material and the core material and the aluminum plate are completely metallurgically combined to achieve high efficiency and low energy consumption.
如图1所示,本申请提供了一种钎焊蜂窝板的制造方法,该方法的主要包括如下步骤:As shown in FIG. 1 , the present application provides a method for manufacturing a brazed honeycomb panel, which mainly includes the following steps:
将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝 状的铝蜂窝芯;Forming a composite aluminum foil having a solder layer formed by pre-gluing and stacking into a honeycomb-shaped aluminum honeycomb core;
对蜂窝状的铝蜂窝芯进行脱胶处理;Degumming the honeycomb aluminum honeycomb core;
将脱胶处理后的铝蜂窝芯固定在两块具有钎料层的胚板之间进行钎焊处理,获得蜂窝板。The degummed aluminum honeycomb core was fixed between two green sheets having a solder layer to be brazed to obtain a honeycomb panel.
根据实际工艺的情况,也可以将拉伸成蜂窝状的铝蜂窝芯固定在两块胚板之间后直接进行钎焊处理,获得蜂窝板。简化步骤的优势在于,可以利用钎焊炉中的高温,同时实现裂解铝蜂窝芯上的胶体和对由铝蜂窝芯置于两块胚板之间形成的层状结构进行钎焊,仅需控制好钎焊与裂解的时机即可。According to the actual process, the aluminum honeycomb core stretched into a honeycomb shape may be directly fixed between the two blank plates, and then brazed directly to obtain a honeycomb plate. The advantage of the simplification step is that the high temperature in the brazing furnace can be utilized, while the colloid on the cracked aluminum honeycomb core and the layered structure formed by placing the aluminum honeycomb core between the two blanks are brazed, only need to be controlled Good brazing and cracking timing.
本实例中,所述胚板可以采用单层或多层的板材料,例如,复合铝板、钢板和钢铝复合板等。所述复合铝箔可以采用双面复合铝箔。在使用钢板时可以在钢板上先镀上一层过渡材料,通过过渡材料与铝蜂窝芯钎焊,保证在钎焊后的稳固性。在使用钢铝复合板时,利用铝材料面与铝蜂窝芯接触,这样,在钎焊后可以良好的实现夹持板和蜂窝填料的稳固性。In the present example, the blank plate may be a single or multi-layered plate material, for example, a composite aluminum plate, a steel plate, a steel-aluminum composite plate, or the like. The composite aluminum foil may be a double-sided composite aluminum foil. When the steel plate is used, a transition material may be first plated on the steel plate, and the transition material is brazed with the aluminum honeycomb core to ensure the stability after brazing. When the steel-aluminum composite plate is used, the aluminum material surface is in contact with the aluminum honeycomb core, so that the stability of the holding plate and the honeycomb filler can be well achieved after brazing.
本实例中,复合铝箔黏结成型的步骤包括:在复合铝箔的表面以阵列的形式涂覆胶黏剂;将至少两个涂覆有胶黏剂的复合铝箔以使胶黏剂错位布置的方式堆叠固定,形成黏结成型的复合铝箔;In the present example, the step of bonding the composite aluminum foil comprises: coating the adhesive on the surface of the composite aluminum foil in an array; and stacking at least two composite aluminum foils coated with the adhesive in such a manner that the adhesive is misaligned Fixed to form a composite aluminum foil formed by bonding;
本方案所述方法进一步包括:在脱胶处理后的铝蜂窝芯和胚板的具有钎料的表面上喷洒钎剂。其中,所述钎剂为粉末状或液态状。优选地,所述钎剂采用氟铝酸钾钎剂。The method of the present scheme further comprises spraying a flux on the surface of the aluminum honeycomb core and the blank of the blank having a solder after the degumming treatment. Wherein, the flux is in the form of a powder or a liquid. Preferably, the flux is a potassium fluoroaluminate flux.
本实例中,所述铝箔可以选用双面复合铝箔,厚度保证在0.08 至0.6毫米之间,复合比在8%至12%之间即可。所述铝板可以选用多层或者单层复合铝板,厚度保证在1.0毫米到5毫米之间即可,复合比在8%至12%之间即可。In the present example, the aluminum foil may be a double-sided composite aluminum foil, and the thickness is guaranteed to be between 0.08 and 0.6 mm, and the composite ratio may be between 8% and 12%. The aluminum plate may be a multi-layer or single-layer composite aluminum plate, and the thickness is guaranteed to be between 1.0 mm and 5 mm, and the composite ratio may be between 8% and 12%.
本方案中,为了保证所有材料的黏结、组装、钎焊等过程中,不受材料表面的污垢影响,在蜂窝板制造过程前,可以先判断采用的材料是否需要进行预处理。例如,本实例中,胚板选用复合铝板,蜂窝芯材料采用复合铝箔,则由于铝箔和铝板上沉积有氧化膜或油污,需要事先采用磷酸三钠的碱性水溶液去除复合铝箔和复合铝板的氧化膜及油污,以便这些材料在后续使用过程中不会由于污垢而影响加工。In this solution, in order to ensure that all materials are bonded, assembled, brazed, etc., it is not affected by the dirt on the surface of the material. Before the honeycomb panel manufacturing process, it can be judged whether the material to be used needs to be pretreated. For example, in the present example, the composite plate is made of a composite aluminum plate, and the honeycomb core material is made of a composite aluminum foil. Since an oxide film or oil is deposited on the aluminum foil and the aluminum plate, it is necessary to remove the oxidation of the composite aluminum foil and the composite aluminum plate by using an alkaline aqueous solution of trisodium phosphate in advance. Membrane and oil so that these materials will not be affected by dirt during subsequent use.
本实例中,对于复合铝箔上的涂胶工具可以直接采用涂胶机处理。所述胶黏剂可以采用环氧、酚醛、橡胶混合的胶黏剂,此种胶在300℃到450℃挥发裂解。对于涂胶的工艺可以采用单胶条或双胶条。如图2所示,单胶条涂覆方式的胶辊宽度为xL,胶辊间距为4L进行涂覆铝箔印胶速度为2-80米/分钟,优选地,印胶速度可以为8-40米/分钟,将印胶完的铝箔在室温到150℃范围内烘干。如图3所示,双胶条胶辊设计如图,按照所需铝蜂窝状边长L设计双胶条胶辊,双胶条与未涂胶部位的总宽度为xL,未涂胶部位的形状可自行设计,宽度≤yxL,其中,系数y可以取0.8。胶辊间距为4L,铝箔印胶速度:2-80米/分钟,优选地,印胶速度可以为8-40米/分钟。由于实际工程需要,对于拉伸成蜂窝芯的结构可能是非正六边形,因此,通过调整上述胶辊宽度中x的量值即可改变后续拉伸蜂窝芯的六边形形态,一般x的取值规则为:x<1,蜂窝状为扁六边形;x=1,蜂窝状为正六 边形;x>1,蜂窝状为长六边形。In this example, the glue application tool on the composite aluminum foil can be directly treated by a glue applicator. The adhesive may be an epoxy, phenolic or rubber mixed adhesive which is volatilized at 300 ° C to 450 ° C. For the glue coating process, a single strip or a double strip can be used. As shown in Fig. 2, the width of the rubber strip coating method is xL, the distance between the rubber rollers is 4L, and the speed of coating the aluminum foil printing is 2-80 m/min. Preferably, the printing speed can be 8-40. In meters/minute, the printed aluminum foil is dried at room temperature to 150 °C. As shown in Figure 3, the double rubber strip rubber roller is designed as shown in the figure. The double rubber strip rubber roller is designed according to the required aluminum honeycomb side length L. The total width of the double rubber strip and the uncoated rubber part is xL, and the uncoated portion is The shape can be designed by itself, the width is ≤ yxL, and the coefficient y can be taken as 0.8. The distance between the rubber rollers is 4 L, and the speed of the aluminum foil printing is 2 to 80 m/min. Preferably, the printing speed can be 8 to 40 m/min. Due to actual engineering needs, the structure for stretching into a honeycomb core may be a non-normal hexagon. Therefore, by adjusting the magnitude of x in the width of the rubber roller, the hexagonal shape of the subsequently stretched honeycomb core can be changed. The value rule is: x < 1, the honeycomb is a flat hexagon; x = 1, the honeycomb is a regular hexagon; x > 1, the honeycomb is a long hexagon.
但需要注意的是:单胶条由于铝箔接触面为涂胶部位,胶裂挥发后残留物会影响到接触位置的钎焊强度。单胶条整个接触面接涂胶,钎焊后冶金结合部位会有缺陷;双胶条则在胶条之间未涂胶,也不存在胶挥发后残留物影响接触位置钎焊,实现为涂胶部位完全冶金结合,提高芯体接触面的强度。因此,本申请优选的采用双胶条方式涂覆胶黏剂。However, it should be noted that because the contact surface of the aluminum foil is the glued part, the residue after the rubber crack is volatilized will affect the brazing strength of the contact position. The entire contact surface of the single rubber strip is coated with glue, and the metallurgical bonding part after brazing is defective; the double rubber strip is not coated between the rubber strips, and there is no residue after the volatilization of the glue affects the contact position brazing, and the glue is realized. The parts are completely metallurgically bonded to increase the strength of the core contact surface. Therefore, the present application preferably coats the adhesive with a double strip.
按照胶黏剂涂覆方式的不同,分别按照如图4或者图5所示的方式,将涂覆完胶黏剂的两个复合铝箔错位堆叠。再分别通过热压和切片处理,获得铝蜂窝芯。其中,热压的要求需要满足:压力0.3-0.5Mpa,固化温度170℃-200℃,保温时间2.5h-3h。切片的要求需要满足:切割精度≤0.05mm。The two composite aluminum foils coated with the adhesive are stacked in a staggered manner according to the manner of the adhesive coating, as shown in FIG. 4 or FIG. 5, respectively. Then, an aluminum honeycomb core was obtained by hot pressing and slicing treatment, respectively. Among them, the requirements of hot pressing need to meet: pressure 0.3-0.5Mpa, curing temperature 170 ° C-200 ° C, holding time 2.5h-3h. The requirements for slicing need to be met: cutting accuracy ≤ 0.05mm.
通过在复合铝箔的表面以阵列的形式涂覆胶黏剂;将两个涂覆有胶黏剂的复合铝箔以使胶黏剂错位布置的方式堆叠固定,形成黏结成型的复合铝箔,再经过拉伸,形成蜂窝状的铝蜂窝芯。The adhesive is coated in the form of an array on the surface of the composite aluminum foil; the two composite aluminum foils coated with the adhesive are stacked and fixed in such a manner that the adhesive is misaligned to form a composite aluminum foil which is bonded and formed, and then pulled. Stretching to form a honeycomb aluminum honeycomb core.
接下来可以选择对铝蜂窝芯进行脱胶处理。脱胶的具体步骤包括:将拉伸后的蜂窝状放入连续式氮气保护炉内,炉内设置废气回收装置,炉内温度:300-450℃,保护气氛为氮气,以速度为1.2米/分钟运行5-80分钟,优选地,运行时间为10-20分钟,胶体挥发裂解后从冷却系统处取下,达到预定温度时取下芯体,此时,芯体能够保持稳固的连接状态,无需再次加装固定。Next, you can choose to degumming the aluminum honeycomb core. The specific steps of degumming include: placing the drawn honeycomb into a continuous nitrogen protection furnace, and setting an exhaust gas recovery device in the furnace, the temperature in the furnace is 300-450 ° C, the protective atmosphere is nitrogen, and the speed is 1.2 m / min. Running for 5 to 80 minutes, preferably, the running time is 10-20 minutes, the colloid is removed from the cooling system after volatilization, and the core is removed when the predetermined temperature is reached. At this time, the core can maintain a stable connection state without Fix it again.
脱胶工艺主要是为了保证铝蜂窝芯的蜂窝状结构能够与复合铝 板实现良好的焊接效果,并且通过脱胶提前去除胶体裂解产生的气味,防止焊接过程中胶体裂解挥发熏黑芯体,钎焊后蜂窝板美观牢固。The degumming process is mainly to ensure that the honeycomb structure of the aluminum honeycomb core can achieve a good welding effect with the composite aluminum plate, and the odor generated by the colloidal cracking is removed in advance by degumming to prevent the colloidal cracking and volatilizing black core during the welding process, and the brazed honeycomb The board is beautiful and firm.
通过蜂窝状的铝蜂窝芯进行脱胶处理后,可以选择在脱胶处理后的铝蜂窝芯和胚板的具有钎料的表面上喷洒钎剂。喷钎剂时,需将粉状或液态钎剂喷到蜂窝状和复合铝板的钎料层的上。本实例中,优选地采用氟铝酸钾钎剂作为钎剂。After the degumming treatment by the honeycomb aluminum honeycomb core, it is possible to selectively spray the flux on the surface of the aluminum honeycomb core and the blank having the solder after the degumming treatment. In the case of fluxing, a powdered or liquid flux is sprayed onto the solder layer of the honeycomb and composite aluminum sheets. In the present example, a potassium fluoroaluminate flux is preferably used as the flux.
本实例中,将铝蜂窝芯固定在两块胚板之间形成层状结构。在现有技术中,获得由铝蜂窝芯置于两块胚板之间形成的层状结构之后就可以进行钎焊,但是,由于在钎焊的过程中,是在氮气保护环境下进行,同时钎焊温度较高,导致该层状结构的变形,从而影响最终的钎焊成品质量,降低产率。因此,本方案中,在钎焊之前增加一道装卡工序。利用如图6所示的板体装配装置对铝蜂窝芯和胚板进行装配。用夹具将铝蜂窝芯与上、下复合面板固定在工装平台1上,压紧机构2的压头23压紧后保证平均受力在0.1-0.3bar。本方案中,装卡的具体步骤为:In this example, an aluminum honeycomb core is fixed between two green sheets to form a layered structure. In the prior art, brazing can be performed after the aluminum honeycomb core is placed in a layered structure formed between two blank plates, but, in the process of brazing, it is carried out under a nitrogen atmosphere, and at the same time The higher brazing temperature results in deformation of the layered structure, which affects the quality of the final brazed product and reduces the yield. Therefore, in this solution, a card loading process is added before brazing. The aluminum honeycomb core and the blank were assembled using a plate assembly device as shown in FIG. The aluminum honeycomb core and the upper and lower composite panels are fixed on the tooling platform 1 by a clamp, and the pressing head 23 of the pressing mechanism 2 is pressed to ensure an average force of 0.1-0.3 bar. In this scenario, the specific steps for card loading are:
如图6所示和图8所示,先将穿入工装平台1,通过如图7所示的压紧机构2的螺套21上的螺纹与工装初步紧固,再将喷完钎剂的由铝蜂窝芯置于两块胚板之间形成的层状结构组装好放入工装平台1,再将固定压板缓慢压在蜂窝板上。拧出压紧机构2的4个插销22,使得压紧机构2的压头23通过压紧机构2的耐高温的压紧弹簧24作用在定型板上。用六角扳手拧动压紧机构的压紧螺套21,此时压紧螺套21与工装紧固使得压紧弹簧收缩产生更大的作用力作用在定型 板3上。As shown in FIG. 6 and FIG. 8, the tooling platform 1 is first penetrated, and the thread on the screw sleeve 21 of the pressing mechanism 2 shown in FIG. 7 is initially fastened to the tooling, and then the flux is sprayed. The layered structure formed by the aluminum honeycomb core between the two blank plates is assembled and placed in the tooling platform 1, and the fixed platen is slowly pressed against the honeycomb panel. The four pins 22 of the pressing mechanism 2 are screwed out so that the ram 23 of the pressing mechanism 2 acts on the sizing plate by the high temperature resistant pressing spring 24 of the pressing mechanism 2. The compression nut 21 of the pressing mechanism is screwed with a hexagonal wrench, and at this time, the compression nut 21 and the tooling are tightened so that the compression spring contracts to generate a larger force acting on the shaping plate 3.
对装配成型的由铝蜂窝芯置于两块胚板之间形成的层状结构进行钎焊处理。本实例中,钎焊的具体步骤包括:将装配好的由铝蜂窝芯和两块胚板组成的层状结构置于具有氮气的钎焊炉中,所述钎焊炉为间歇式或连续式惰性气氛钎焊炉,钎焊温度为600℃到650℃摄氏度,优选地,钎焊温度控制在615℃到640℃。所述钎焊炉冷方式采用惰性气体风冷,冷却区间为640℃到250℃。A layered structure formed by placing an aluminum honeycomb core between two blank plates is brazed. In the present example, the specific step of brazing comprises: placing the assembled layered structure consisting of an aluminum honeycomb core and two blank plates in a brazing furnace having nitrogen, the brazing furnace being intermittent or continuous The inert atmosphere brazing furnace has a brazing temperature of 600 ° C to 650 ° C. Preferably, the brazing temperature is controlled at 615 ° C to 640 ° C. The brazing furnace is cooled by inert gas air cooling, and the cooling interval is 640 ° C to 250 ° C.
通过最终的冷却,从冷却区取出用于支撑或承重的蜂窝板。The honeycomb panels for support or load bearing are removed from the cooling zone by final cooling.
如图9和图10所示,分别为单胶条和双胶条涂覆方式下的钎焊蜂窝板制造流程。As shown in FIG. 9 and FIG. 10, the manufacturing process of the brazed honeycomb panel in the single strip and the double strip coating mode, respectively.
下面通过一组实例对本方案作进一步说明:The program is further illustrated by a set of examples:
本方案设计一种钎焊蜂窝板的制造方法,其具体的步骤如下:The present scheme designs a method for manufacturing a brazed honeycomb panel, and the specific steps are as follows:
1):复合铝箔、复合铝板表面预处理,去除氧化膜及油污;1): Pretreatment of composite aluminum foil and composite aluminum plate to remove oxide film and oil stain;
所述复合铝箔为双面复合,厚度为0.08至0.6毫米,里层为3系铝合金,钎料层为4系铝合金,复合比为8%-12%。所述复合铝板为单面复合,厚度为1.0毫米到5毫米,钎料层为4系铝合金,复合比为8%-12%。去氧化膜及油污用磷酸三钠的碱性水溶液清洗加少许表面活性剂。The composite aluminum foil is double-sided composite, the thickness is 0.08 to 0.6 mm, the inner layer is a 3 series aluminum alloy, and the solder layer is a 4 series aluminum alloy, and the composite ratio is 8%-12%. The composite aluminum plate is a single-sided composite having a thickness of 1.0 mm to 5 mm, and the solder layer is a 4-series aluminum alloy, and the composite ratio is 8% to 12%. The deoxidized film and the oil stain are washed with an alkaline aqueous solution of trisodium phosphate to add a small amount of a surfactant.
2):复合铝箔进入涂胶机,按照一定的间距进行涂覆;2): The composite aluminum foil enters the coating machine and is coated at a certain interval;
所述胶为树脂类,热压温度150到200度,树脂类胶在250至450度烘干裂解挥发,所述复合铝箔为双面复合,厚度为0.08至0.6毫米,里层为3系铝合金,钎料层为4系铝合金,复合比为8%-12%。The glue is a resin, the hot pressing temperature is 150 to 200 degrees, and the resin glue is dried and cracked and volatilized at 250 to 450 degrees. The composite aluminum foil is double-sided composite, the thickness is 0.08 to 0.6 mm, and the inner layer is 3 series aluminum. The alloy and the solder layer are 4 series aluminum alloys, and the composite ratio is 8%-12%.
3):将涂胶的铝箔错位堆叠;3): stacking the glued aluminum foils in a wrong position;
4):堆叠后的铝箔放在热压机进行热压,温度为150℃-200℃;4): the stacked aluminum foil is placed in a hot press for hot pressing at a temperature of 150 ° C - 200 ° C;
5):热压后按照蜂窝状厚度进行裁切;5): cutting according to the thickness of the honeycomb after hot pressing;
6):裁切后拉伸成蜂窝状6): After cutting, it is stretched into a honeycomb
拉伸后的蜂窝状为六边形,边长为3至35毫米。The stretched honeycomb has a hexagonal shape with a side length of 3 to 35 mm.
7):将粉状或液态钎剂喷到蜂窝状和有钎料的面的复合铝板上;7): spraying powder or liquid flux onto the composite aluminum plate of the honeycomb and soldered surface;
所述钎剂为氟铝酸钾钎剂。The flux is a potassium fluoroaluminate flux.
8):用夹具将蜂窝状与喷完钎剂面的上、下复合铝板固定;8): Fixing the honeycomb and the upper and lower composite aluminum plates with the flux surface by a clamp;
9):烘干。9): Drying.
所述树脂类胶在250至450度烘干裂解挥发。The resin-based glue is cleaved and volatilized at 250 to 450 degrees.
10):炉中钎焊,将夹装好的铝蜂窝板送至炉中焊接;10): brazing in the furnace, sending the clamped aluminum honeycomb panel to the furnace for welding;
所述钎焊炉为间歇式或连续式惰性气氛钎焊炉,温度为615到640度。The brazing furnace is a batch or continuous inert atmosphere brazing furnace with a temperature of 615 to 640 degrees.
11):冷却11): Cooling
所述钎焊蜂窝板的冷却方式采用惰性气体风冷,冷却区间为640到250度。The brazing honeycomb panel is cooled by inert gas air cooling, and the cooling interval is 640 to 250 degrees.
本方案所述方案制成的蜂窝板能够保证蜂窝芯之间、蜂窝芯与铝板间是冶金结合,克服了胶粘剂粘接强度易受环境影响的不足,不受环境制约,具有剥离强度高、抗压、环保、可回收等诸多优良性能,同时提高了蜂窝芯的定位精度,降低了加工成本,在轨道交通、航空航天、船舶、建筑等领域应用前景广阔。The honeycomb panel prepared by the scheme of the present invention can ensure the metallurgical bond between the honeycomb core and the honeycomb core and the aluminum plate, overcomes the shortage of the adhesive strength of the adhesive and is not affected by the environment, is not subject to environmental constraints, and has high peel strength and resistance. Pressure, environmental protection, recyclability and many other excellent properties, while improving the positioning accuracy of the honeycomb core, reducing processing costs, and broad application prospects in rail transit, aerospace, shipbuilding, construction and other fields.
本领域内的技术人员应明白,本申请的实施例可提供为方法、系 统、或计算机程序产品。因此,本申请可采用完全硬件实施例、完全软件实施例、或结合软件和硬件方面的实施例的形式。而且,本申请可采用在一个或多个其中包含有计算机可用程序代码的计算机可用存储介质(包括但不限于磁盘存储器、CD-ROM、光学存储器等)上实施的计算机程序产品的形式。Those skilled in the art will appreciate that embodiments of the present application can be provided as a method, system, or computer program product. Thus, the present application can take the form of an entirely hardware embodiment, an entirely software embodiment, or an embodiment in combination of software and hardware. Moreover, the application can take the form of a computer program product embodied on one or more computer-usable storage media (including but not limited to disk storage, CD-ROM, optical storage, etc.) including computer usable program code.
本申请是参照根据本申请实施例的方法、设备(系统)、和计算机程序产品的流程图和/或方框图来描述的。应理解可由计算机程序指令实现流程图和/或方框图中的每一流程和/或方框、以及流程图和/或方框图中的流程和/或方框的结合。可提供这些计算机程序指令到通用计算机、专用计算机、嵌入式处理机或其他可编程数据处理设备的处理器以产生一个机器,使得通过计算机或其他可编程数据处理设备的处理器执行的指令产生用于实现在流程图一个流程或多个流程和/或方框图一个方框或多个方框中指定的功能的装置。The present application is described with reference to flowchart illustrations and/or block diagrams of methods, apparatus (system), and computer program products according to embodiments of the present application. It will be understood that each flow and/or block of the flowchart illustrations and/or FIG. These computer program instructions can be provided to a processor of a general purpose computer, special purpose computer, embedded processor, or other programmable data processing device to produce a machine for the execution of instructions for execution by a processor of a computer or other programmable data processing device. Means for implementing the functions specified in one or more of the flow or in a block or blocks of the flow chart.
这些计算机程序指令也可存储在能引导计算机或其他可编程数据处理设备以特定方式工作的计算机可读存储器中,使得存储在该计算机可读存储器中的指令产生包括指令装置的制造品,该指令装置实现在流程图一个流程或多个流程和/或方框图一个方框或多个方框中指定的功能。The computer program instructions can also be stored in a computer readable memory that can direct a computer or other programmable data processing device to operate in a particular manner, such that the instructions stored in the computer readable memory produce an article of manufacture comprising the instruction device. The apparatus implements the functions specified in one or more blocks of a flow or a flow and/or block diagram of the flowchart.
这些计算机程序指令也可装载到计算机或其他可编程数据处理设备上,使得在计算机或其他可编程设备上执行一系列操作步骤以产生计算机实现的处理,从而在计算机或其他可编程设备上执行的指令提供用于实现在流程图一个流程或多个流程和/或方框图一个方框 或多个方框中指定的功能的步骤。These computer program instructions can also be loaded onto a computer or other programmable data processing device such that a series of operational steps are performed on a computer or other programmable device to produce computer-implemented processing for execution on a computer or other programmable device. The instructions provide steps for implementing the functions specified in one or more of the flow or in a block or blocks of a flow diagram.
尽管已描述了本申请的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本申请范围的所有变更和修改。While the preferred embodiment of the present application has been described, it will be apparent that those skilled in the art can make further changes and modifications to the embodiments. Therefore, the appended claims are intended to be interpreted as including the preferred embodiments and the modifications and
显然,本领域的技术人员可以对本申请进行各种改动和变型而不脱离本申请的精神和范围。这样,倘若本申请的这些修改和变型属于本申请权利要求及其等同技术的范围之内,则本申请也意图包含这些改动和变型在内。It will be apparent to those skilled in the art that various modifications and changes can be made in the present application without departing from the spirit and scope of the application. Thus, it is intended that the present invention cover the modifications and variations of the present invention.

Claims (21)

  1. 一种钎焊蜂窝板的制造方法,其特征在于,该方法的步骤包括:A method of manufacturing a brazed honeycomb panel, characterized in that the steps of the method comprise:
    将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝状的铝蜂窝芯;Forming a composite aluminum foil having a solder layer formed by pre-gluing and stacking into a honeycomb-shaped aluminum honeycomb core;
    利用装卡装置将铝蜂窝芯压固在两块具有钎料层的胚板之间形成层状结构;Pressing the aluminum honeycomb core between the two blank plates having the solder layer to form a layered structure by using a card loading device;
    在氮气环境下对装卡固定的层状结构进行钎焊处理,获得蜂窝板。The layered structure fixed by the card is brazed under a nitrogen atmosphere to obtain a honeycomb panel.
  2. 根据权利要求1所述的制造方法,其特征在于,所述胚板采用单层或多层复合铝板;或,The manufacturing method according to claim 1, wherein the blank plate is a single-layer or multi-layer composite aluminum plate; or
    钢板;或,Steel plate; or,
    钢铝复合板。Steel-aluminum composite board.
  3. 根据权利要求1所述的制造方法,其特征在于,所述将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝状的铝蜂窝芯的前一步骤包括:The manufacturing method according to claim 1, wherein the step of stretching the pre-glued stack-bonded composite aluminum foil having a solder layer into a honeycomb-shaped aluminum honeycomb core comprises:
    在复合铝箔的表面以阵列的形式涂覆胶黏剂;Applying an adhesive in the form of an array on the surface of the composite aluminum foil;
    将至少两个涂覆有胶黏剂的复合铝箔以使胶黏剂错位布置的方式堆叠固定,形成黏结成型的复合铝箔。At least two composite aluminum foils coated with an adhesive are stacked and fixed in such a manner that the adhesive is misaligned to form a bonded composite aluminum foil.
  4. 根据权利要求1所述的制造方法,其特征在于,所述利用装卡装置将铝蜂窝芯压固在两块具有钎料层的胚板之间形成层状结构的步骤包括:The manufacturing method according to claim 1, wherein the step of pressing the aluminum honeycomb core between the two blank sheets having the solder layer by the card loading device to form a layered structure comprises:
    将蜂窝状的铝蜂窝芯置于两个胚板之间,并通过工装夹具固定在工装平台(1)上;The honeycomb aluminum honeycomb core is placed between the two blank plates and fixed on the tooling platform (1) by the fixture;
    在上层胚板的上表面压盖定型板(3);Pressing the shaping plate (3) on the upper surface of the upper layer;
    通过压紧机构(2)将定型板(3)紧压在由铝蜂窝芯和两块胚板组成的层状结构上,定型所述层状结构。The layered structure is shaped by pressing the shaping plate (3) against a layered structure composed of an aluminum honeycomb core and two blank plates by a pressing mechanism (2).
  5. 根据权利要求4所述的制造方法,其特征在于,用于将脱胶处理后的铝蜂窝芯固定在两块具有钎料层的胚板之间的装配装置包括:工装平台(1)、压紧机构(2)和定型板(3);The manufacturing method according to claim 4, wherein the assembling means for fixing the degummed aluminum honeycomb core between the two blank sheets having the solder layer comprises: a tooling platform (1), pressing Institution (2) and stereotype plate (3);
    所述工装平台(1)设有多个用于支撑压紧机构(2)的支撑部;The tooling platform (1) is provided with a plurality of support portions for supporting the pressing mechanism (2);
    所述两块胚板和铝蜂窝芯依次放置工装平台(1)上,所述定型板(3)压盖在上层胚板的表面,通过压紧机构(2)将定型板(3)紧压在上层胚板上。The two blank plates and the aluminum honeycomb core are sequentially placed on the tooling platform (1), and the shaping plate (3) is pressed over the surface of the upper layer of the blank plate, and the shaping plate (3) is pressed by the pressing mechanism (2). On the upper layer of the embryo.
  6. 根据权利要求5所述的制造方法,其特征在于,所述压紧机构包括:螺套(21)、压头(23)和压紧弹簧(24);The manufacturing method according to claim 5, wherein the pressing mechanism comprises: a threaded sleeve (21), a pressing head (23) and a pressing spring (24);
    所述压紧弹簧(24)和压头(23)依次置于所述螺套(21)内;The pressing spring (24) and the pressing head (23) are sequentially placed in the screw sleeve (21);
    所述螺套(21)的套壁上进一步设有销孔,通过插销(22)对所述压头(23)进行限位。The sleeve wall of the screw sleeve (21) is further provided with a pin hole, and the pressure head (23) is restricted by a bolt (22).
  7. 根据权利要求1所述的制造方法,其特征在于,所述钎焊的步骤包括:The manufacturing method according to claim 1, wherein the step of brazing comprises:
    将装卡固定的层状结构置于氮气中;Place the carded fixed layer structure in nitrogen;
    保持温度在600℃至650℃之间,对装卡固定的层状结构进行钎焊;Maintaining the temperature between 600 ° C and 650 ° C to braze the layered structure fixed by the card;
    对钎焊后的板体进行冷却处理,获得蜂窝板。The brazed plate body is subjected to a cooling treatment to obtain a honeycomb plate.
  8. 根据权利要求1所述的制造方法,其特征在于,该方法进一步 包括:在铝蜂窝芯和胚板的具有钎料的表面上喷洒钎剂。The method of manufacturing of claim 1 further comprising: spraying a flux on the surface of the aluminum honeycomb core and the preform having the solder.
  9. 根据权利要求8所述的制造方法,其特征在于,所述钎剂为粉末状或液态状。The method according to claim 8, wherein the flux is in the form of a powder or a liquid.
  10. 根据权利要求8所述的制造方法,其特征在于,所述钎剂采用氟铝酸钾钎剂。The method according to claim 8, wherein the flux is a potassium fluoroaluminate flux.
  11. 根据权利要求8所述的制造方法,其特征在于,所述在复合铝箔的表面以阵列的形式涂覆胶黏剂的前一步骤包括:对复合铝箔和胚板表面的污垢进行预处理。The manufacturing method according to claim 8, wherein the step of applying the adhesive in the form of an array on the surface of the composite aluminum foil comprises: pretreating the dirt on the surface of the composite aluminum foil and the blank.
  12. 根据权利要求8所述的制造方法,其特征在于,所述预处理是采用磷酸三钠的碱性水溶液去除所述复合铝箔和胚板上的污垢。The manufacturing method according to claim 8, wherein the pretreatment is to remove dirt on the composite aluminum foil and the seed board using an alkaline aqueous solution of trisodium phosphate.
  13. 根据权利要求3所述的制造方法,其特征在于,所述复合铝箔上胶黏剂的涂覆方式为横向阵列或纵向阵列。The method of manufacturing according to claim 3, wherein the adhesive on the composite aluminum foil is applied in a lateral array or a longitudinal array.
  14. 根据权利要求3所述的制造方法,其特征在于,所述胶黏剂采用环氧、酚醛、橡胶混合的胶黏剂。The manufacturing method according to claim 3, wherein the adhesive is an epoxy, phenolic or rubber-mixed adhesive.
  15. 根据权利要求3所述的制造方法,其特征在于,所述涂覆胶黏剂是采用涂胶机对复合铝箔进行胶黏剂涂覆处理。The manufacturing method according to claim 3, wherein the coating adhesive is an adhesive coating treatment of the composite aluminum foil by a glue applicator.
  16. 根据权利要求15所述的制造方法,其特征在于,所述胶黏剂的涂胶工艺采用单胶条或双胶条的方式涂覆。The manufacturing method according to claim 15, wherein the adhesive coating process is applied by a single rubber strip or a double rubber strip.
  17. 根据权利要求3所述的制造方法,其特征在于,所述胶黏剂错位布置的错位宽度小于或等于2倍的胶黏剂宽度。The manufacturing method according to claim 3, wherein the offset ratio of the adhesive misalignment is less than or equal to 2 times the width of the adhesive.
  18. 根据权利要求3所述的制造方法,其特征在于,所述将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝状的铝蜂 窝芯的后一步包括:对黏结成型的复合铝箔进行热压和切片处理。The manufacturing method according to claim 3, wherein the step of stretching the pre-glued stack-bonded composite aluminum foil having a solder layer into a honeycomb-shaped aluminum honeycomb core comprises: compounding the bonded molding The aluminum foil is hot pressed and sliced.
  19. 根据权利要求3所述的制造方法,其特征在于,所述将预先涂胶堆叠黏结成型的具有钎料层的复合铝箔拉伸成蜂窝状的铝蜂窝芯的后一步包括:对蜂窝状的铝蜂窝芯进行脱胶处理。The manufacturing method according to claim 3, wherein the step of stretching the pre-glued stack-bonded composite aluminum foil having a solder layer into a honeycomb-shaped aluminum honeycomb core comprises: a honeycomb-shaped aluminum The honeycomb core is degummed.
  20. 根据权利要求19所述的制造方法,其特征在于,所述脱胶处理的步骤包括:The manufacturing method according to claim 19, wherein the step of degumming treatment comprises:
    将拉伸成蜂窝状的铝蜂窝芯置于氮气中;The aluminum honeycomb core stretched into a honeycomb shape is placed in a nitrogen gas;
    在保持温度在300℃至450℃的条件下,以预定时间和速度进行胶裂解处理;Glue cracking treatment at a predetermined time and speed while maintaining the temperature at 300 ° C to 450 ° C;
    对裂解处理后的铝蜂窝芯进行冷却处理,获得脱胶处理后的铝蜂窝芯。The aluminum honeycomb core after the cracking treatment is subjected to a cooling treatment to obtain an aluminum honeycomb core after degumming treatment.
  21. 一种利用权利要求1所述方法制成的蜂窝板。A honeycomb panel produced by the method of claim 1.
PCT/CN2017/120295 2017-04-28 2017-12-29 Method for manufacturing brazed honeycomb panel and honeycomb panel WO2018196432A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710296405.8A CN108790296A (en) 2017-04-28 2017-04-28 A kind of manufacturing method and cellular board of soldering cellular board
CN201710296405.8 2017-04-28

Publications (1)

Publication Number Publication Date
WO2018196432A1 true WO2018196432A1 (en) 2018-11-01

Family

ID=63919439

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/120295 WO2018196432A1 (en) 2017-04-28 2017-12-29 Method for manufacturing brazed honeycomb panel and honeycomb panel

Country Status (2)

Country Link
CN (1) CN108790296A (en)
WO (1) WO2018196432A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111231428A (en) * 2019-12-13 2020-06-05 中航复合材料有限责任公司 Preparation method of high-density energy-absorbing aluminum honeycomb core material

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111376535A (en) * 2018-12-29 2020-07-07 泰州市龙洋木业有限公司 High-strength bending-resistant light composite structural board and manufacturing method thereof
CN113211886A (en) * 2021-04-13 2021-08-06 岳西县汇达包装制品有限公司 Stool supporter production facility

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101579766A (en) * 2009-06-08 2009-11-18 昆明理工大学 Preparation method of braze welding type metal honeycomb plate
CN104607746A (en) * 2014-12-19 2015-05-13 江苏龙禾轻型材料有限公司 Self-bonding composite board and manufacturing process thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102689066A (en) * 2012-06-01 2012-09-26 青岛泰泓轨道装备有限公司 Preparation method of aluminum honeycomb core materials and honey comb plates
CN104527205B (en) * 2014-12-26 2017-02-08 佛山市华瑞蜂窝科技有限公司 Method for manufacturing aluminum honeycomb core
CN106256484A (en) * 2016-09-30 2016-12-28 张汉民 A kind of preparation technology of glue-free honeycomb core

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101579766A (en) * 2009-06-08 2009-11-18 昆明理工大学 Preparation method of braze welding type metal honeycomb plate
CN104607746A (en) * 2014-12-19 2015-05-13 江苏龙禾轻型材料有限公司 Self-bonding composite board and manufacturing process thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111231428A (en) * 2019-12-13 2020-06-05 中航复合材料有限责任公司 Preparation method of high-density energy-absorbing aluminum honeycomb core material

Also Published As

Publication number Publication date
CN108790296A (en) 2018-11-13

Similar Documents

Publication Publication Date Title
CN110181227B (en) Method for preparing aluminum/magnesium/aluminum composite board by three-dimensional layer interface
WO2018196432A1 (en) Method for manufacturing brazed honeycomb panel and honeycomb panel
CN108788356A (en) A kind of manufacturing method and cellular board of soldering cellular board
CN101269553B (en) Magnesium alloy cellular board and manufacturing technique
CN105798062B (en) A kind of method of oblique ripple roll Rolling compund strip
CN101920393A (en) Low-temperature diffusion welding method for magnesium alloy and aluminum alloy
CN104399859B (en) Thin plate self-locking is solidly connected method and system
CN103009013A (en) Method for preparing metal honeycomb core and honeycomb sandwich board
CN102581006B (en) Hot-rolling compounding method for titanium/aluminum/titanium three-layer composite plate
CN101579766A (en) Preparation method of braze welding type metal honeycomb plate
CN105618479B (en) A kind of method of herringbone corrugating roll Rolling compund strip
US9527571B2 (en) Superplastically formed ultrasonically welded metallic structure
CN101817015A (en) Method for rolling and molding low-oxygen content aero titanium alloy precision sheet
CN104607746A (en) Self-bonding composite board and manufacturing process thereof
CN107186308B (en) Weld the manufacturing process of honeycomb core
CN105149714B (en) Metallic plate is without impression glue welding connection method
CN110732842B (en) Preparation method of brazing aluminum honeycomb plate
CN107214388B (en) Preparation method of aluminum honeycomb panel
CN111420990A (en) Preparation method of rolled magnesium-aluminum laminated plate prefabricated blank
CN108746312B (en) Method for eliminating surface groove of superplastic forming/diffusion bonding four-layer structure
CN108790321A (en) A kind of manufacturing method and cellular board of soldering cellular board
CN204234651U (en) Thin plate self-locking is solidly connected system
KR20080006724U (en) Stainless steel / copper clad plate
EP3023189B1 (en) Brazing sheet for surface joining
CN103358102B (en) The processing method of metal corrugated sandwich boards and volume brake apparatus thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17907154

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17907154

Country of ref document: EP

Kind code of ref document: A1