CN107275657A - A kind of simple method for preparing of anode of solid oxide fuel cell supporter - Google Patents
A kind of simple method for preparing of anode of solid oxide fuel cell supporter Download PDFInfo
- Publication number
- CN107275657A CN107275657A CN201710435073.7A CN201710435073A CN107275657A CN 107275657 A CN107275657 A CN 107275657A CN 201710435073 A CN201710435073 A CN 201710435073A CN 107275657 A CN107275657 A CN 107275657A
- Authority
- CN
- China
- Prior art keywords
- anode
- slurry
- ysz
- glued membrane
- nio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
- H01M8/1226—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material characterised by the supporting layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The present invention relates to the preparing technical field of SOFC, and in particular to a kind of simple method for preparing of anode of solid oxide fuel cell supporter, and it uses following method and step：Step one：Slurry is configured：Weight is compared 1:1 NiO and YSZ, graphite powder and the 4h of organic additive ball milling mixing 3 formation suspended nitrides；Wherein：Organic additive is polyvinyl butyral resin, triethanolamine, polyethylene glycol, di-n-octyl phthalate and absolute ethyl alcohol；Above-mentioned NiO, YSZ, graphite powder, polyvinyl butyral resin, triethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol are 16 18%：16 18%：2 4%：5 8%：1.5 2%：3 4%：3 4%：45 47%；Step 2：Scraper is molded：Anode slurry is poured on glass plate, slurry uniform ground is filled to the glass carrier drape forming between adhesive tape with scraper；Step 3：High temperature sintering；It has shaping fast, easy to operate, and can realize the advantages of small lot is produced.
Description
【Technical field】
The present invention relates to the preparing technical field of SOFC, and in particular to a kind of solid oxide fuel
The simple method for preparing of galvanic anode supporter.
【Background technology】
SOFC (abbreviation SOFC) is a kind of energy conversion device of all solid state component, including solid electricity
Material, anode material, cathode material and connecting material are solved, is all full ceramic structure, compared with other types of fuel cell,
The material used is less expensive, participates in fuel cell without liquid, and electrolyte is relatively stable, thus SOFC have it is following bright
Aobvious advantage and feature, makes it more more attractive than other kinds of fuel cell：1. all solid state component is used, in the absence of material
The problem of material corrosion and electrolyte are leaked；2. all solid state component, the problem of being leaked in the absence of material corrosion and electrolyte are used；③
Noble metal electrode material need not be used, battery cost of manufacture is greatly reduced；4. operating temperature is high, and kinetics is fast, production
Raw high-quality waste heat is suitable for cogeneration of heat and power, can improve energy utilization overall efficiency (up to 80%)；5. the fuel scope of application
Extensively, H can not only be used2Make fuel with CO etc., and can directly use natural gas, coal gasification gas and other nytrons
Thing or liquid alcohols etc. make fuel；6. electrode process is quite rapid, can bear the sulfide of higher concentration and CO poison
Evil, is substantially reduced to electrode requirement.Therefore, SOFC is auxiliary in large-scale power station, distributed power station, household cogeneration systems, automobile
The fields such as power supply are helped to have broad application prospects.
Anode is SOFC important component, and the performance of anode material can directly affect SOFC performance.Usual SOFC
Anode material must is fulfilled for claimed below.1. it must provide the place of fueled electrochemical oxidation reaction, with good catalysis
Active and high electronic conductivity, enables electronics smoothly to pass to external circuit and produces electric current；2. have well chemically and thermally
Stability, the material being in contact with it has the matching of good chemical compatibility and thermal expansion；3. there is suitable porosity,
Fuel gas is diffused into anode and participate in electrochemical reaction, and the gas and accessory substance that simultaneously produce reaction are taken away.Anode branch
Support type SOFC has the advantages that preparation is simple, battery performance is high and is widely used, and it is by multihole anode support, fine and close electricity
The three-decker of plasma membrane and porous cathode composition is solved, one of most critical technology prepared by wherein anode support type SOFC is exactly porous
The preparation of anode support.Anode support is in addition to needing to meet the requirement of above-mentioned anode, in addition it is also necessary to certain thickness
Spend with mechanical strength to play a part of supporting dielectric film.
The technique for preparing anode support generally used at present has slip casting, extrusion molding and traditional the tape casting
Deng.But requirement of the above-mentioned forming preparation process to slurry is higher, and technological process is more complicated, very flexible, causes work
Make inefficiency, the shortcomings of cost is high.
【The content of the invention】
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of SOFC sun
The simple method for preparing of pole supporter, it can realize preparation of the technological process compared with relatively simple and flexible multihole anode support,
And the problem of uniform mixed slurry of two kinds of powders is difficult to prepare is not present, save cost and improve preparation efficiency, it
It is fast with shaping, it is easy to operate, and the advantages of small lot is produced can be realized.
A kind of simple method for preparing of anode of solid oxide fuel cell supporter of the present invention, it is using as follows
Method and step：
Step one：Slurry preparation, the step of it is used is as follows：
I) by nickel oxide (NiO), zirconium oxide (YSZ), graphite powder and the organic additive ball milling of 8mol% stabilized with yttrium oxide
Mix 3-4h formation suspended nitrides；Wherein：NiO and YSZ weight ratio 1：1；
II) organic additive in step I is polyvinyl butyral resin, triethanolamine, polyethylene glycol, phthalic acid two
N-octyl and absolute ethyl alcohol；
III nickel oxide) in suspended nitride, the zirconium oxide of 8mol% stabilized with yttrium oxide, graphite powder, polyvinyl alcohol contracting fourth
Aldehyde, triethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol are 16-18%：16-
18%：2-4%：5-8%：1.5-2%：3-4%：3-4%：45-47%；
When IV) preparing, it is very easy to introduce bubble in its high speed mechanical milling process, in slurry, and bubble is in next step
Scraper shaping be very unfavorable, the defects such as stomata can be left on the surface or inside of green compact, therefore slurry is removed before
Bubble, using the method vacuumized, slurry is placed in vacuum rotary evaporator and is depressured to -2MPa, you can obtain the sun of stable and uniform
Pole slurry；
Step 2：Scraper be molded, using the step of it is as follows：
I two sealant tapes) are abreast sticked on smooth glass plate first, length is 20cm, two adhesive tapes
Spacing is 5cm, i.e., regard 20 × 5cm glass plate as carrier；
II) and then by the obtained anode slurries of appropriate step I pour on the glass plate between adhesive tape, made with transparent triangle
Slurry uniform ground is filled to the glass carrier region between adhesive tape for scraper；
III) after after slurry drying formation glued membrane, glued membrane is cut out along tape edge with pocket knife, carefully glued membrane is lifted
Rise, obtain 20 × 5cm anode glued membrane with standby；
IV) glued membrane is cut into 5 × 5cm shape, the glued membrane superposition of the different numbers of plies is obtained into certain anode as needed
Thickness, with tablet press machine, the pressure compacting with 200~300MPa and pressurize 15-20min, make multilayer laminate closely combine one
Rise, then can get button NiO-YSZ anode support green compact with card punch；
Step 3：High temperature sintering：Using the step of it is as follows：
I) in order to ensure not having in sintering temperature is less than 400 DEG C in crackle, high-temperature sintering process when heating rate it is best
It is less than 1 DEG C/min；
II) if heating rate is too fast when being less than 400 DEG C, it would be possible to can produce the multihole anode support after sintering and split
Line.
Further, the weight of graphite powder is the zirconia ceramics powder gross weight of nickel oxide and 8mol% stabilized with yttrium oxide
10%-20%.
The present invention has following advantage relative to traditional preparation method：
Advantage one：The present invention prepares multihole anode support using painting method is suspended to, the porous anode support prepared
Body green strength is higher, and with good toughness and processing characteristics, can following process obtain special shape or size；Burn
Shape size is consistent after knot, is not susceptible to deformation, shrinkage factor is low, prepares the porous ceramic bodies of variously-shaped size；Yield rate exists
More than 90%；The preparation of complex-shaped multihole anode support can be realized, and in the absence of the uniform mixing of two kinds of powders
The problem of slurry is difficult to prepare, shaping is fast, easy to operate, and can realize that small lot is produced.
Advantage two：The inventive method, in addition to it can prepare SOFC porous anode ceramic components, can also prepare YSZ electrolyte
Ceramic component.
The present invention has the beneficial effect that：A kind of simple system of anode of solid oxide fuel cell supporter of the present invention
Preparation Method, it can realize preparation of the technological process compared with relatively simple and flexible multihole anode support, and in the absence of two kinds of powders
Uniform mixed slurry the problem of be difficult to prepare, saved cost and improved preparation efficiency, it has shaping fast, operation letter
Just, and the advantages of small lot is produced can be realized
【Brief description of the drawings】
Accompanying drawing described herein be for providing a further understanding of the present invention, constituting the part of the application, but
Inappropriate limitation of the present invention is not constituted, in the accompanying drawings：
Fig. 1 is that SOFC monocells prepared by embodiment one use output of the humidification hydrogen as fuel at different temperatures
Energy；
Fig. 2 is the battery cross sectional scanning after SOFC monocells prepared by embodiment one are tested using humidification hydrogen as fuel
Electron microscope；
Fig. 3 is that porous NiO-YSZ anode supports prepared by embodiment two use the cross-sectional scans after humidification hydrogen reducing
Electron microscope.
【Embodiment】
Describe the present invention in detail below in conjunction with accompanying drawing and specific embodiment, illustrative examples therein and say
It is bright to be only used for explaining the present invention but not as a limitation of the invention.
As shown in Figure 1-Figure 3, a kind of anode of solid oxide fuel cell supporter described in present embodiment
Simple method for preparing, it uses following method and step：
Step one：Slurry preparation, the step of it is used is as follows：
I) by nickel oxide (NiO), zirconium oxide (YSZ), graphite powder and the organic additive ball milling of 8mol% stabilized with yttrium oxide
Mix 3-4h formation suspended nitrides；Wherein：NiO and YSZ weight ratio 1：1；
II) organic additive in step I is polyvinyl butyral resin, triethanolamine, polyethylene glycol, phthalic acid two
N-octyl and absolute ethyl alcohol；
III nickel oxide) in suspended nitride, the zirconium oxide of 8mol% stabilized with yttrium oxide, graphite powder, polyvinyl alcohol contracting fourth
Aldehyde, triethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol are 16-18%：16-
18%：2-4%：5-8%：1.5-2%：3-4%：3-4%：45-47%；
When IV) preparing, it is very easy to introduce bubble in its high speed mechanical milling process, in slurry, and bubble is in next step
Scraper shaping be very unfavorable, the defects such as stomata can be left on the surface or inside of green compact, therefore slurry is removed before
Bubble, using the method vacuumized, slurry is placed in vacuum rotary evaporator and is depressured to -2MPa, you can obtain the sun of stable and uniform
Pole slurry；
Step 2：Scraper be molded, using the step of it is as follows：
I two sealant tapes) are abreast sticked on smooth glass plate first, length is 20cm, two adhesive tapes
Spacing is 5cm, i.e., regard 20 × 5cm glass plate as carrier；
II) and then by the obtained anode slurries of appropriate step I pour on the glass plate between adhesive tape, made with transparent triangle
Slurry uniform ground is filled to the glass carrier region between adhesive tape for scraper；
III) after after slurry drying formation glued membrane, glued membrane is cut out along tape edge with pocket knife, carefully glued membrane is lifted
Rise, obtain 20 × 5cm anode glued membrane with standby；
IV) glued membrane is cut into 5 × 5cm shape, the glued membrane superposition of the different numbers of plies is obtained into certain anode as needed
Thickness, with tablet press machine, the pressure compacting with 200~300MPa and pressurize 15-20min, make multilayer laminate closely combine one
Rise, then can get button NiO-YSZ anode support green compact with card punch；
Step 3：High temperature sintering：Using the step of it is as follows：
I) in order to ensure not having in sintering temperature is less than 400 DEG C in crackle, high-temperature sintering process when heating rate it is best
It is less than 1 DEG C/min；
II) if heating rate is too fast when being less than 400 DEG C, it would be possible to can produce the multihole anode support after sintering and split
Line.
Preferred as one kind of the present invention, the weight of graphite powder is made pottery for the zirconium oxide of nickel oxide and 8mol% stabilized with yttrium oxide
The 10%-20% of porcelain powder gross weight.
Embodiment one：
As Figure 1-Figure 2, the preparation method of the multihole anode support of SOFC of the invention, is adopted
With following method and step：
Step one：Slurry preparation：
By nickel oxide (NiO), zirconium oxide (YSZ) (NiO the and YSZ weight ratio 1 of 8mol% stabilized with yttrium oxide:1), graphite powder
With organic additive ball milling mixing 3h formation suspended nitrides；The organic additive is polyvinyl butyral resin, triethanolamine, gathered
Ethylene glycol, di-n-octyl phthalate and absolute ethyl alcohol；The nickel oxide, the zirconium oxide of 8mol% stabilized with yttrium oxide, graphite
Powder, polyvinyl butyral resin, triethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol
For 18%：18%：4%：5%：1.5%：3%：3%：47%.Using the method vacuumized, slurry is placed in vacuum rotary evaporator
In be depressured to -2MPa, the bubble removed in slurry is the anode slurry that can obtain stable and uniform.
Step 2：Scraper is molded：
Two sealant tapes are abreast sticked on smooth glass plate first, length is between 20cm, two adhesive tapes
Away from for 5cm, i.e., it regard 20 × 5cm glass plate as carrier.Then the anode slurry appropriate step (1) obtained pour into adhesive tape it
Between glass plate on, slurry uniform ground is filled to the glass carrier region between adhesive tape as scraper with transparent triangle.
After after slurry drying formation glued membrane, glued membrane is cut out along tape edge with pocket knife, carefully glued membrane is started, obtain 20 ×
5cm anode glued membrane is with standby.Glued membrane is cut into 5 × 5cm shape, 18 layers of glued membrane superposition is obtained certain as needed
Anode thickness, with tablet press machine, the pressure compacting with 300MPa and pressurize 20min, make multilayer laminate closely be combined together, so
The card punch for being afterwards 14mm with internal diameter can get button NiO-YSZ anode support green compact, a diameter of 14mm, and thickness is
0.7mm。
Step 3：High temperature sintering：
The button NiO-YSZ anode supports green compact that the above method is obtained sinter 2h in 1100 DEG C of air atmospheres, make
It has enough mechanical strengths, that is, obtains the NiO-YSZ multihole anode supports of pre-sintering.
YSZ dielectric films are prepared on the NiO-YSZ multihole anode supports surface that pre-sintering is crossed using infusion process again afterwards,
Then NiO-YSZ anode supports/YSZ dielectric films are put into high temperature Muffle furnace and sinter 4h in 1400 DEG C of air atmospheres.
Finally, that one layer of La0.8Sr0.2MnO3 (LSM)/LSM-YSZ is applied in the way of brushing on sintered YSZ dielectric films surface is multiple
Negative electrode is closed, the SOFC monocells of button NiO-YSZ anode-supporteds are can be obtained by after 1100 DEG C sinter 2h, wherein negative electrode has
Effect area is 0.25cm2.
The output performance of monocell manufactured in the present embodiment is measured using four electrode method, silver wire is as leading in test
Line, silver paste is as connecting material, to be saturated the hydrogen of water vapour at room temperature as fuel (25mL/min), the air of free-flowing
For oxidant, the output performance under different temperatures is as shown in figure 1, test shows that the open-circuit voltage of monocell is at 800 DEG C
1.05V, peak power output density is 786mW/cm2, shows excellent performance.It is completed, the section of monocell is entered
Go the analysis of microstructure, be illustrated in figure 2 the cross-sectional scans electron microscope of monocell.It can be seen that prepared
The YSZ Electrolyte film thickness of monocell is 25 μm, very fine and close and without hole and any defect, has sintered out highdensity electricity
Solve matter thin layer.Observe that three-decker is all very smooth and uniform simultaneously, anode and electrolyte, negative electrode is with electrolyte in interface
Contact is close, well.Cathode electrode layer thickness is 30 μm, and bulk multi-hole is conducive to diffusion and the electrochemical reaction of oxygen.
Specific embodiment two：
The preparation method of the multihole anode support of the SOFC of the present invention, is walked using following method
Suddenly：
Step one：Slurry preparation：
By nickel oxide (NiO), zirconium oxide (YSZ) (NiO the and YSZ weight ratio 1 of 8mol% stabilized with yttrium oxide:1), graphite powder
With organic additive ball milling mixing 4h formation suspended nitrides；The organic additive is polyvinyl butyral resin, triethanolamine, gathered
Ethylene glycol, di-n-octyl phthalate and absolute ethyl alcohol；The nickel oxide, the zirconium oxide of 8mol% stabilized with yttrium oxide, graphite
Powder, polyvinyl butyral resin, triethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol
For 16%：16%：2%：5%：1.5%：3%：3%：45%.Using the method vacuumized, slurry is placed in vacuum rotary evaporator
In be depressured to -2MPa, the bubble removed in slurry is the anode slurry that can obtain stable and uniform.
Step 2：Scraper is molded：
Two sealant tapes are abreast sticked on smooth glass plate first, length is between 20cm, two adhesive tapes
Away from for 5cm, i.e., it regard 20 × 5cm glass plate as carrier.Then the anode slurry appropriate step one obtained pour into adhesive tape it
Between glass plate on, slurry uniform ground is filled to the glass carrier region between adhesive tape as scraper with transparent triangle.
After after slurry drying formation glued membrane, glued membrane is cut out along tape edge with pocket knife, carefully glued membrane is started, obtain 20 ×
5cm anode glued membrane is with standby.Glued membrane is cut into 5 × 5cm shape, 18 layers of glued membrane superposition is obtained certain as needed
Anode thickness, with tablet press machine, the pressure compacting with 200MPa and pressurize 15min, make multilayer laminate closely be combined together, so
The card punch for being afterwards 14mm with internal diameter can get button NiO-YSZ anode support green compact, a diameter of 14mm, and thickness is
0.7mm。
Step 3：High temperature sintering：
The button NiO-YSZ anode supports green compact that the above method is obtained sinter 2h in 1100 DEG C of air atmospheres, make
It has enough mechanical strengths, that is, obtains NiO-YSZ multihole anode supports.
Anode is reduced completely at 750 DEG C using the hydrogen atmosphere (25mL/min) for being saturated water vapour at room temperature, it is cold
But room temperature is arrived, Micro-Structure Analysis is carried out to anode section, the cross-sectional scans electron microscope of anode after reduction is illustrated in figure 3, can
To see that Ni particles are evenly distributed in above YSZ skeletons, the structure of holey is formed.This structure causes it and fuel gas
Body contact interface is very big, is conducive to the reaction of gentle, the solid two-phase of the diffusion (reduction concentration polarization) of fuel gas and product gas, together
When the YSZ skeletons that interconnect can transmit oxonium ion and participate in reaction to conversion zone.By script electrode, electrolyte and fuel gas
The conversion zone of three-phase junctional area is expanded on whole anode YSZ skeletons, the fluffy continuous structure of anode and larger active region
Domain is conducive to the progress of electrochemical reaction, illustrate the Simple scraping knife technique that is used in the design prepare many empty anode supports be can
Capable.
Described above is only the better embodiment of the present invention, therefore all constructions according to described in present patent application scope,
The equivalent change or modification that feature and principle are done, is included in the range of present patent application.
Claims (2)
1. a kind of simple method for preparing of anode of solid oxide fuel cell supporter, it is characterised in that：It uses following
Method and step：
Step one：Slurry preparation, the step of it is used is as follows：
I) by zirconium oxide (YSZ), graphite powder and the organic additive ball milling mixing of nickel oxide (NiO), 8mol% stabilized with yttrium oxide
3-4h formation suspended nitrides；Wherein：NiO and YSZ weight ratio 1：1；
II) organic additive in step I is that polyvinyl butyral resin, triethanolamine, polyethylene glycol, phthalic acid two are just pungent
Ester and absolute ethyl alcohol；
III nickel oxide) in suspended nitride, the zirconium oxide of 8mol% stabilized with yttrium oxide, graphite powder, polyvinyl butyral resin, three
Monoethanolamine, polyethylene glycol, the percentage by weight of di-n-octyl phthalate and absolute ethyl alcohol are 16-18%：16-18%：2-
4%：5-8%：1.5-2%：3-4%：3-4%：45-47%；
When IV) preparing, it is very easy to introduce bubble in its high speed mechanical milling process, in slurry, and bubble is to scraping in next step
Knife shaping is very unfavorable, can leave the defects such as stomata on the surface or inside of green compact, thus before will to slurry bubble removing,
Using the method vacuumized, slurry is placed in vacuum rotary evaporator and is depressured to -2MPa, you can obtain the anode slurry of stable and uniform
Material；
Step 2：Scraper be molded, using the step of it is as follows：
I two sealant tapes) are abreast sticked on smooth glass plate first, length is 20cm, two adhesive tape spacing
For 5cm, i.e., it regard 20 × 5cm glass plate as carrier；
II) and then by the obtained anode slurries of appropriate step I pour on the glass plate between adhesive tape, with transparent triangle as scraping
Knife fills slurry uniform ground in the glass carrier region between adhesive tape；
III) after after slurry drying formation glued membrane, glued membrane is cut out along tape edge with pocket knife, carefully glued membrane is started, obtained
Anode glued membrane to 20 × 5cm is with standby；
IV) glued membrane is cut into 5 × 5cm shape, the glued membrane superposition of the different numbers of plies is obtained into certain anode thickness as needed,
With tablet press machine, the pressure compacting with 200~300MPa and pressurize 15-20min, make multilayer laminate closely be combined together, then
Button NiO-YSZ anode support green compact can be got with card punch；
Step 3：High temperature sintering：Using the step of it is as follows：
I) in order to ensure not having in sintering temperature is less than 400 DEG C in crackle, high-temperature sintering process when heating rate be less than 1
℃/min；
II) if heating rate is too fast when being less than 400 DEG C, it would be possible to can crack the multihole anode support after sintering.
2. a kind of simple method for preparing of anode of solid oxide fuel cell supporter according to claim 1, it is special
Levy and be：The weight of graphite powder is the 10%- of the zirconia ceramics powder gross weight of nickel oxide and 8mol% stabilized with yttrium oxide
20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710435073.7A CN107275657A (en) | 2017-06-10 | 2017-06-10 | A kind of simple method for preparing of anode of solid oxide fuel cell supporter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710435073.7A CN107275657A (en) | 2017-06-10 | 2017-06-10 | A kind of simple method for preparing of anode of solid oxide fuel cell supporter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107275657A true CN107275657A (en) | 2017-10-20 |
Family
ID=60066595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710435073.7A Pending CN107275657A (en) | 2017-06-10 | 2017-06-10 | A kind of simple method for preparing of anode of solid oxide fuel cell supporter |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107275657A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109065929A (en) * | 2018-08-06 | 2018-12-21 | 张健 | A kind of simple preparation method of anode of solid oxide fuel cell supporter |
| CN111302768A (en) * | 2020-03-24 | 2020-06-19 | 东莞市煜田新材料有限公司 | Novel porous oxide ceramic and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314523A (en) * | 2007-05-28 | 2008-12-03 | 比亚迪股份有限公司 | Titanium dioxide thin film and preparation thereof |
| CN102082284A (en) * | 2010-12-30 | 2011-06-01 | 上海交通大学 | Method for preparing anode supporting type intermediate-temperate solid oxide fuel cell (SOFC) |
| CN106784882A (en) * | 2017-03-10 | 2017-05-31 | 佛山索弗克氢能源有限公司 | The preparation method of the anode support tube of fuel cell |
-
2017
- 2017-06-10 CN CN201710435073.7A patent/CN107275657A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314523A (en) * | 2007-05-28 | 2008-12-03 | 比亚迪股份有限公司 | Titanium dioxide thin film and preparation thereof |
| CN102082284A (en) * | 2010-12-30 | 2011-06-01 | 上海交通大学 | Method for preparing anode supporting type intermediate-temperate solid oxide fuel cell (SOFC) |
| CN106784882A (en) * | 2017-03-10 | 2017-05-31 | 佛山索弗克氢能源有限公司 | The preparation method of the anode support tube of fuel cell |
Non-Patent Citations (1)
| Title |
|---|
| 任园女: ""锌基染料敏化太阳能电池及大面积化研制"", 《中国优秀硕士学位论文全文数据库（工程科技II辑）》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109065929A (en) * | 2018-08-06 | 2018-12-21 | 张健 | A kind of simple preparation method of anode of solid oxide fuel cell supporter |
| CN111302768A (en) * | 2020-03-24 | 2020-06-19 | 东莞市煜田新材料有限公司 | Novel porous oxide ceramic and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100648144B1 (en) | High performance anode-supported solide oxide fuel cell | |
| CN102903945B (en) | Method for preparing large-size flat plate type metal supporting solid oxide fuel cell | |
| CN101359746B (en) | Large size tubular solid oxide fuel cell and preparation thereof | |
| CN100589271C (en) | Method for preparing hollow fiber-type solid-oxide fuel battery | |
| Liu et al. | Fabrication and characterization of micro-tubular cathode-supported SOFC for intermediate temperature operation | |
| CN103236548B (en) | Preparation method of multihole anode support of solid oxide fuel cell | |
| CN103219525B (en) | low-temperature solid oxide fuel cell and preparation method thereof | |
| CN103928693A (en) | Metal support half-cell of solid oxide fuel cell and preparation method thereof | |
| Jin et al. | Fabrication and characterization of Ni-SSZ gradient anodes/SSZ electrolyte for anode-supported SOFCs by tape casting and co-sintering technique | |
| CN103811789A (en) | Solid oxide fuel cell with symmetrical electrodes, and preparation method and application thereof | |
| CN112436171B (en) | Solid electrolyte support body and preparation method and application thereof | |
| CN113337834B (en) | Asymmetric-structure electrolytic cell made of symmetric materials and preparation method thereof | |
| CN107195938A (en) | A kind of simple SOFC preparation method | |
| CN111384421A (en) | Five-layer structure single cell, preparation method thereof and prepared product | |
| CN107785598A (en) | A kind of symmetrical SOFC of half-cell | |
| CN103474687B (en) | A kind of preparation method of high performance flat solid oxide fuel monocell | |
| CN114890787A (en) | Oxygen electrode supporting type solid oxide electrolytic cell and preparation method thereof | |
| KR101341969B1 (en) | Segment-in-series type sofc sub-module, manufacturing method thereof and segment-in-series type sofc module using the same | |
| CN107275657A (en) | A kind of simple method for preparing of anode of solid oxide fuel cell supporter | |
| CN114171769A (en) | Method for preparing solid oxide fuel cell stack by adopting 3D printing technology | |
| Han et al. | Fabrication and properties of anode-supported solid oxide fuel cell | |
| CN209071518U (en) | A kind of fuel cell system of high-output power density | |
| CN103811787A (en) | Method for producing flat-plate-type solid oxide fuel cell anode support electrolyte composite membrane | |
| CN112250437A (en) | Solid oxide electrolytic cell supported by oxygen electrode and preparation method thereof | |
| CN109326812A (en) | A kind of fuel cell system and preparation method of high-output power density |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171020 |