CN107275093A - A kind of 600V electrolyte and preparation method thereof - Google Patents
A kind of 600V electrolyte and preparation method thereof Download PDFInfo
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- CN107275093A CN107275093A CN201710525596.0A CN201710525596A CN107275093A CN 107275093 A CN107275093 A CN 107275093A CN 201710525596 A CN201710525596 A CN 201710525596A CN 107275093 A CN107275093 A CN 107275093A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/035—Liquid electrolytes, e.g. impregnating materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/145—Liquid electrolytic capacitors
Abstract
The present invention relates to technical field of electrolyte, and in particular to a kind of 600V electrolyte and preparation method thereof, the electrolyte includes the raw material of following parts by weight：20 40 parts of high pressure solute, 15 25 parts of diethylene glycol (DEG), 1.5 2.5 parts of polyethylene glycol, 1.5 2.5 parts of polyvinyl alcohol, 0.3 0.7 parts of ammoniacal liquor, 0.2 0.6 parts of ammonium hypophosphite, 0.4 0.8 parts of p nitrobenzyl alcohol, 30 60 parts of ethylene glycol.The electrolyte flash over voltage of the present invention can reach 630V, and electrical conductivity can reach 0.65ms/cm, with good electrochemical properties, have the advantages that high conductivity and super-pressure, can be applied to the manufacture of 600V aluminium electrolutic capacitors.
Description
Technical field
The present invention relates to technical field of electrolyte, and in particular to a kind of 600V electrolyte and preparation method thereof.
Background technology
Aluminium electrolutic capacitor is one of base components of electronic product.Continuous improvement and aluminium electricity with Quality of electronic products
The expansion of electrolysis condenser application, higher requirement is proposed to its performance.The electronic products such as Switching Power Supply, electricity-saving lamp are to high pressure
The security performance of electrolytic capacitor requires very high.In filter circuit, capacitor bears high voltage, high ripple current, if feed
It is unstable or apply overvoltage, you can the accident such as to cause the destruction of capacitor, catch fire, burn.Aluminum electrolytic capacitor electrolyte is electricity
Actual negative electrode in container whole work process, the performance to capacitor has a major impact, wherein：Temperature in use scope, work
Life-span, reliability, leakage current, loss, volume change etc. play a decisive role to electrical property.
At present it is known that or medium-high voltage aluminum electrolytic capacitor Working electrolyte, have passed through following development
Process：First, using ethylene glycol as main solvent, the inorganic compound such as boric acid or ammonium pentaborate is main solute.The work electricity so prepared
There is the problem of electrical conductivity is low in solution liquid, and boric acid and its salt easily occur esterification with ethylene glycol at high temperature and generated a large amount of
Condensation water, cause the moisture inside electrolyte to raise, the vapour pressure of electrolyte increase, capacitor internal pressure is raised and caused
Capacitor valve opening fails；2nd, using ethylene glycol as main solvent, using the direct-connected hydrocarbon saturation two such as azelaic acid, decanedioic acid or 12 diacid
Carboxylic acid and its salt are electrolyte solution, and although the electrolyte of this class avoid a part of esterification, but be due to this
Solubility of the linear paraffin of one class in ethylene glycol is smaller, causes the impedance of product larger, easily generates heat and makes under big ripple
Solvent volatilizees, so as to produce vicious circle, causes capacitor withered and fails, while acid amides easily occurs at high temperature for linear paraffin
Change side reaction generation water, also easily cause capacitor initial failure；3rd, using the 1 of some branched acid or its salt, such as report,
6-DDA and its salt and 2- butyl suberic acid and its salt, this kind of branched carboxylic acid and its salt compare straight chain to the solubility of solvent
Alkane increases, thus generates effect to a certain extent, but simultaneously, and this kind of acid or its salt rely primarily on import, thus into
This height and restraining factors are more.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of 600V electrolysis
Liquid, the electrolyte flash over voltage can reach 630V, and electrical conductivity can reach 0.65ms/cm, with good electrochemical properties,
There is high conductivity and super-pressure, the manufacture of 600V aluminium electrolutic capacitors is can be applied to.
Another object of the present invention is to provide a kind of preparation method of 600V electrolyte, the preparation method technique is simple,
Convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of 600V electrolyte, includes the raw material of following parts by weight：
20-40 parts of high pressure solute
15-25 parts of diethylene glycol (DEG)
1.5-2.5 parts of polyethylene glycol
1.5-2.5 parts of polyvinyl alcohol
0.3-0.7 parts of ammoniacal liquor
0.2-0.6 parts of ammonium hypophosphite
0.4-0.8 parts of p nitrobenzyl alcohol
30-60 parts of ethylene glycol.
The electrolyte of the present invention strictly controls the weight of each raw material to match somebody with somebody by using the interaction between above-mentioned raw materials
Than obtained electrolyte flash over voltage can reach 630V, and electrical conductivity can reach 0.65ms/cm, with good electrochemistry
Characteristic, has the advantages that high conductivity and super-pressure, can be applied to the manufacture of 600V aluminium electrolutic capacitors.
It is preferred that, include the raw material of following parts by weight：
20-30 parts of high pressure solute
15-20 parts of diethylene glycol (DEG)
1.5-2.0 parts of polyethylene glycol
1.5-2.0 parts of polyvinyl alcohol
0.3-0.5 parts of ammoniacal liquor
0.2-0.4 parts of ammonium hypophosphite
0.4-0.6 parts of p nitrobenzyl alcohol
30-44.5 parts of ethylene glycol.
It is preferred that, include the raw material of following parts by weight：
25-35 parts of high pressure solute
18-22 parts of diethylene glycol (DEG)
1.8-2.2 parts of polyethylene glycol
1.8-2.2 parts of polyvinyl alcohol
0.4-0.6 parts of ammoniacal liquor
0.3-0.5 parts of ammonium hypophosphite
0.5-0.7 parts of p nitrobenzyl alcohol
40-50 parts of ethylene glycol.
It is preferred that, include the raw material of following parts by weight：
30-40 parts of high pressure solute
20-25 parts of diethylene glycol (DEG)
2.0-2.5 parts of polyethylene glycol
2.0-2.5 parts of polyvinyl alcohol
0.5-0.7 parts of ammoniacal liquor
0.4-0.6 parts of ammonium hypophosphite
0.6-0.8 parts of p nitrobenzyl alcohol
44.5-60 parts of ethylene glycol.
It is preferred that, include the raw material of following parts by weight：
25 parts of high pressure solute
18 parts of diethylene glycol (DEG)
1.8- parts of polyethylene glycol
1.8- parts of polyvinyl alcohol
0.4 part of ammoniacal liquor
0.3 part of ammonium hypophosphite
0.5 part of p nitrobenzyl alcohol
40 parts of ethylene glycol.
It is preferred that, include the raw material of following parts by weight：
30 parts of high pressure solute
20 parts of diethylene glycol (DEG)
2.0 parts of polyethylene glycol
2.0 parts of polyvinyl alcohol
0.5 part of ammoniacal liquor
0.4 part of ammonium hypophosphite
0.6 part of p nitrobenzyl alcohol
44.5 parts of ethylene glycol.
It is preferred that, include the raw material of following parts by weight：
35 parts of high pressure solute
22 parts of diethylene glycol (DEG)
2.2 parts of polyethylene glycol
2.2 parts of polyvinyl alcohol
0.6 part of ammoniacal liquor
0.5 part of ammonium hypophosphite
0.7 part of p nitrobenzyl alcohol
50 parts of ethylene glycol.
It is preferred that, the high pressure solute compares 5-15 by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight：10-20：
5-15：50-80 is constituted.
It is preferred that, the high pressure solute is by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight ratio 10：15：10：65
Composition.
Also include 3-5 parts of high polymer additive, hinder 2-4 parts of carboxylate agent, 1-3 parts of high-temperature stabilizer, anti-corrosion addition
1-2 parts of agent, 1-2 parts of scintillation additive and 0.5-1.5 parts of the hydrogen additive that disappears.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Compare 0.4-0.8:0.8-1.2:The mixture of 1 composition.The present invention by strictly controlling the species of high polymer additive, compound and match somebody with somebody
Than that can shield extra electric field, the dielectric properties of deielectric-coating be protected, because both or two or more organic big point dissolved each other
Sub- collective effect can adjust the viscosity of electrolyte solution, reduce the saturated vapour pressure of capacitor internal, improve flash over voltage, improve
Stability.
The obstruction carboxylate agent is by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids, 3- third
Glycol and neopentyl glycol are with weight ratio 1: 0.4-0.8:The mixture of 0.2-0.6 compositions.The present invention hinders carboxylic by strictly controlling
Species, compounding and the proportioning of acid esters agent, can hinder carboxylic esterification.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
0.5-1.5:1:1.5-2.5 the mixture of composition.Species, compounding and proportioning of the invention by strictly controlling high-temperature stabilizer,
The high temperature resistant service life of electrolyte can be improved.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:0.8-1.2:
1.5-2.5 the mixture of composition.The present invention is by strictly controlling the species of anticorrosive additive, compounding and proportioning, it is possible to reduce electricity
Solve corrosion of the liquid to capacitor.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.4-1.8:1.5-2.5 the mixture of composition.The present invention is by strictly controlling scintillation additive kind
Class, compounding and proportioning, can improve the flash over voltage of electrolyte to strengthen the effect of aluminium electrolutic capacitor voltage endurance capability.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Compare 0.4-0.8:0.8-1.2:The mixture of 1 composition.The present invention is by the hydrogen additive types that strictly control to disappear, compounding and matches,
The Hydrogen Energy power that disappears that electrolyte can be improved plays drum failure phenomenon so as to reduce aluminium electrolutic capacitor aerogenesis.
Another object of the present invention is achieved through the following technical solutions：A kind of preparation method of 600V electrolyte, it is sweet by two
Alcohol, high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol are incubated 2.5-3.5h in 120-130 DEG C, are cooled to 95-105 DEG C,
Surplus stock mixing is added, 600V electrolyte is made.
The beneficial effects of the present invention are：The electrolyte flash over voltage of the present invention can reach 630V, and electrical conductivity can reach
To 0.65ms/cm, with good electrochemical properties, there is high conductivity and super-pressure, 600V aluminium electricity is can be applied to
The manufacture of electrolysis condenser.
The preparation method technique of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of 600V electrolyte, includes the raw material of following parts by weight：
20 parts of high pressure solute
15 parts of diethylene glycol (DEG)
1.5 parts of polyethylene glycol
1.5 parts of polyvinyl alcohol
0.3 part of ammoniacal liquor
0.2 part of ammonium hypophosphite
0.4 part of p nitrobenzyl alcohol
30 parts of ethylene glycol.
The high pressure solute compares 5-15 by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight：10：5：50 compositions.
A kind of preparation method of 600V electrolyte, by diethylene glycol (DEG), high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol
2.5h is incubated in 120 DEG C, 95 DEG C are cooled to, surplus stock mixing is added, 600V electrolyte is made.
Embodiment 2
A kind of 600V electrolyte, includes the raw material of following parts by weight：
25 parts of high pressure solute
18 parts of diethylene glycol (DEG)
1.8 parts of polyethylene glycol
1.8 parts of polyvinyl alcohol
0.4 part of ammoniacal liquor
0.3 part of ammonium hypophosphite
0.5 part of p nitrobenzyl alcohol
40 parts of ethylene glycol.
The high pressure solute is by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight ratio 8：12：8：60 compositions.
A kind of preparation method of 600V electrolyte, by diethylene glycol (DEG), high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol
2.8h is incubated in 12 DEG C, 98 DEG C are cooled to, surplus stock mixing is added, 600V electrolyte is made.
Embodiment 3
A kind of 600V electrolyte, includes the raw material of following parts by weight：
30 parts of high pressure solute
20 parts of diethylene glycol (DEG)
2.0 parts of polyethylene glycol
2.0 parts of polyvinyl alcohol
0.5 part of ammoniacal liquor
0.4 part of ammonium hypophosphite
0.6 part of p nitrobenzyl alcohol
44.5 parts of ethylene glycol.
The high pressure solute is by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight ratio 10：15：10：65 compositions.
A kind of preparation method of 600V electrolyte, by diethylene glycol (DEG), high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol
3h is incubated in 125 DEG C, 100 DEG C are cooled to, surplus stock mixing is added, 600V electrolyte is made.
Embodiment 4
A kind of 600V electrolyte, includes the raw material of following parts by weight：
35 parts of high pressure solute
22 parts of diethylene glycol (DEG)
2.2 parts of polyethylene glycol
2.2 parts of polyvinyl alcohol
0.6 part of ammoniacal liquor
0.5 part of ammonium hypophosphite
0.7 part of p nitrobenzyl alcohol
50 parts of ethylene glycol.
The high pressure solute is by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight ratio 12：18：21：70 compositions.
A kind of preparation method of 600V electrolyte, by diethylene glycol (DEG), high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol
3.2h is incubated in 128 DEG C, 102 DEG C are cooled to, surplus stock mixing is added, 600V electrolyte is made.
Embodiment 5
A kind of 600V electrolyte, includes the raw material of following parts by weight：
40 parts of high pressure solute
25 parts of diethylene glycol (DEG)
2.5 parts of polyethylene glycol
2.5 parts of polyvinyl alcohol
0.7 part of ammoniacal liquor
0.6 part of ammonium hypophosphite
0.8 part of p nitrobenzyl alcohol
60 parts of ethylene glycol.
The high pressure solute is by mannitol, boric acid, dodecandioic acid and ethylene glycol with weight ratio 15： 20：15：80 compositions.
A kind of preparation method of 600V electrolyte, by diethylene glycol (DEG), high pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol
3.5h is incubated in 130 DEG C, 105 DEG C are cooled to, surplus stock mixing is added, 600V electrolyte is made.
Embodiment 6
The difference of the present embodiment and above-described embodiment is：Also include 3 parts of high polymer additive, hinder carboxylate agent 2
Part, 1 part of high-temperature stabilizer, 1 part of anticorrosive additive, 1 part of scintillation additive, disappear 1 part of 0.5 part of hydrogen additive and waterproof mixture.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Than 0.4:0.8:The mixture of 1 composition.
The obstruction carboxylate agent is the 3- the third two by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids
Alcohol and neopentyl glycol are with weight ratio 1:0.4:The mixture of 0.2 composition.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
0.5-1.5:1:1.5-2.5 the mixture of composition.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:0.8:1.5
The mixture of composition.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.4:The mixture of 1.5 compositions.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Than 0.4:0.8:The mixture of 1 composition.
Embodiment 7
The difference of the present embodiment and above-described embodiment is：Also include 3.5 parts of high polymer additive, hinder carboxylate agent
2.5 parts, 1.5 parts of high-temperature stabilizer, 1.2 parts of anticorrosive additive, 1.2 parts of scintillation additive, disappear 0.8 part of hydrogen additive and methanol
1.2 parts of agent.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Than 0.5:0.9:The mixture of 1 composition.
The obstruction carboxylate agent is the 3- the third two by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids
Alcohol and neopentyl glycol are with weight ratio 1:0.5:The mixture of 0.3 composition.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
0.5-1.5:1:1.5-2.5 the mixture of composition.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:0.9:1.8
The mixture of composition.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.5:The mixture of 1.8 compositions.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Than 0.5:0.9:The mixture of 1 composition.
Embodiment 8
The difference of the present embodiment and above-described embodiment is：Also include 4 parts of high polymer additive, hinder carboxylate agent 3
Part, 2 parts of high-temperature stabilizer, 1.5 parts of anticorrosive additive, 1.5 parts of scintillation additive, disappear 1 part of hydrogen additive and waterproof mixture 1.5
Part.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Than 0.6:1:The mixture of 1 composition.
The obstruction carboxylate agent is the 3- the third two by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids
Alcohol and neopentyl glycol are with weight ratio 1:0.6:The mixture of 0.4 composition.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
1:1:The mixture of 2 compositions.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:1:2 compositions
Mixture.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.6:The mixture of 2 compositions.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Than 0.6:1:The mixture of 1 composition.
Embodiment 9
The difference of the present embodiment and above-described embodiment is：Also include 4.5 parts of high polymer additive, hinder carboxylate agent
3.5 parts, 2.5 parts of high-temperature stabilizer, 1.8 parts of anticorrosive additive, 1.8 parts of scintillation additive, disappear 1.2 parts of hydrogen additive and methanol
1.8 parts of agent.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Than 0.7:1.1:The mixture of 1 composition.
The obstruction carboxylate agent is the 3- the third two by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids
Alcohol and neopentyl glycol are with weight ratio 1:0.7:The mixture of 0.5 composition.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
1.2:1:The mixture of 2.2 compositions.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:1.1:2.2
The mixture of composition.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.7:The mixture of 2.2 compositions.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Than 0.7:1.1:The mixture of 1 composition.
Embodiment 10
The difference of the present embodiment and above-described embodiment is：Also include 5 parts of high polymer additive, hinder carboxylate agent 4
Part, 3 parts of high-temperature stabilizer, 2 parts of anticorrosive additive, 2 parts of scintillation additive, disappear 2 parts of 1.5 parts of hydrogen additive and waterproof mixture.
The high polymer additive is with weight by polyvinyl alcohol, polypropylene glycol and PEO-PPO
Than 0.8:1.2:The mixture of 1 composition.
The obstruction carboxylate agent is the 3- the third two by 2- butyl -2- ethyls -1,3-PD, 2- butyl -2- methyl isophthalic acids
Alcohol and neopentyl glycol are with weight ratio 1:0.8:The mixture of 0.6 composition.
The high-temperature stabilizer is with weight ratio by polyvinyl acetal, polyvinylpyrrolidone and p-aminobenzene sulfonic acid
1.5:1:The mixture of 2.5 compositions.
The anticorrosive additive is with weight ratio 1 by ethylenediamine tetra-acetic acid, 8- carboxyl quinolines and metasilicic acid ammonium:1.2:2.5
The mixture of composition.
The scintillation additive is selected from poly- 1,4- succinates, poly- neopentyl glycol sebacate, POLYPROPYLENE GLYCOL and polyethylene
Butyral compares 1 with weight:1.8:The mixture of 2.5 compositions.
The hydrogen additive that disappears is with weight by ortho-nitroanisole, paranitrobenzoic acid ammonium and 2,4,6- trinitrophenols
Than 0.8:1.2:The mixture of 1 composition.
The electrolyte flash over voltage of the present invention can reach 630V, and electrical conductivity can reach 0.65ms/cm, with good
Electrochemical properties, have the advantages that high conductivity and super-pressure, can be applied to the manufacture of 600V aluminium electrolutic capacitors.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of 600V electrolyte, it is characterised in that：Include the raw material of following parts by weight：
20-40 parts of high pressure solute
15-25 parts of diethylene glycol (DEG)
1.5-2.5 parts of polyethylene glycol
1.5-2.5 parts of polyvinyl alcohol
0.3-0.7 parts of ammoniacal liquor
0.2-0.6 parts of ammonium hypophosphite
0.4-0.8 parts of p nitrobenzyl alcohol
30-60 parts of ethylene glycol.
2. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
20-30 parts of high pressure solute
15-20 parts of diethylene glycol (DEG)
1.5-2.0 parts of polyethylene glycol
1.5-2.0 parts of polyvinyl alcohol
0.3-0.5 parts of ammoniacal liquor
0.2-0.4 parts of ammonium hypophosphite
0.4-0.6 parts of p nitrobenzyl alcohol
30-44.5 parts of ethylene glycol.
3. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
25-35 parts of high pressure solute
18-22 parts of diethylene glycol (DEG)
1.8-2.2 parts of polyethylene glycol
1.8-2.2 parts of polyvinyl alcohol
0.4-0.6 parts of ammoniacal liquor
0.3-0.5 parts of ammonium hypophosphite
0.5-0.7 parts of p nitrobenzyl alcohol
40-50 parts of ethylene glycol.
4. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
30-40 parts of high pressure solute
20-25 parts of diethylene glycol (DEG)
2.0-2.5 parts of polyethylene glycol
2.0-2.5 parts of polyvinyl alcohol
0.5-0.7 parts of ammoniacal liquor
0.4-0.6 parts of ammonium hypophosphite
0.6-0.8 parts of p nitrobenzyl alcohol
44.5-60 parts of ethylene glycol.
5. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
25 parts of high pressure solute
18 parts of diethylene glycol (DEG)
1.8- parts of polyethylene glycol
1.8- parts of polyvinyl alcohol
0.4 part of ammoniacal liquor
0.3 part of ammonium hypophosphite
0.5 part of p nitrobenzyl alcohol
40 parts of ethylene glycol.
6. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
30 parts of high pressure solute
20 parts of diethylene glycol (DEG)
2.0 parts of polyethylene glycol
2.0 parts of polyvinyl alcohol
0.5 part of ammoniacal liquor
0.4 part of ammonium hypophosphite
0.6 part of p nitrobenzyl alcohol
44.5 parts of ethylene glycol.
7. a kind of 600V electrolyte according to claim 1, it is characterised in that：Include the raw material of following parts by weight：
35 parts of high pressure solute
22 parts of diethylene glycol (DEG)
2.2 parts of polyethylene glycol
2.2 parts of polyvinyl alcohol
0.6 part of ammoniacal liquor
0.5 part of ammonium hypophosphite
0.7 part of p nitrobenzyl alcohol
50 parts of ethylene glycol.
8. a kind of 600V electrolyte according to claim 1, it is characterised in that：The high pressure solute by mannitol, boric acid,
Dodecandioic acid and ethylene glycol compare 5-15 with weight：10-20：5-15：50-80 is constituted.
9. a kind of 600V electrolyte according to claim 1, it is characterised in that：The high pressure solute by mannitol, boric acid,
Dodecandioic acid and ethylene glycol are with weight ratio 10：15：10：65 compositions.
10. a kind of preparation method of 600V electrolyte as described in claim any one of 1-9, it is characterised in that：By diethylene glycol (DEG),
High pressure solute, polyethylene glycol, polyvinyl alcohol and ethylene glycol are incubated 2.5-3.5h in 120-130 DEG C, are cooled to 95-105 DEG C, addition
Surplus stock is mixed, and 600V electrolyte is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710525596.0A CN107275093B (en) | 2017-06-30 | 2017-06-30 | A kind of 600V electrolyte and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710525596.0A CN107275093B (en) | 2017-06-30 | 2017-06-30 | A kind of 600V electrolyte and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107275093A true CN107275093A (en) | 2017-10-20 |
| CN107275093B CN107275093B (en) | 2019-04-02 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107731534A (en) * | 2017-11-29 | 2018-02-23 | 南通江海电容器股份有限公司 | A kind of capacitor electrolyte and the capacitor using the electrolyte |
| CN112687472A (en) * | 2020-12-03 | 2021-04-20 | 盐城星晨科技有限公司 | High-frequency electrolyte and preparation method thereof |
| CN114420455A (en) * | 2022-02-28 | 2022-04-29 | 珠海格力新元电子有限公司 | Sparking voltage improver, preparation method thereof and electrolyte |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101599367A (en) * | 2009-07-10 | 2009-12-09 | 南通江海电容器股份有限公司 | 600V ultra-high voltage aluminum working electrolyte of electrolytic capacitor and preparation thereof and application |
| CN101866752A (en) * | 2010-06-23 | 2010-10-20 | 深圳清华大学研究院 | Electrolyte for driving ultrahigh voltage large-sized aluminium electrolytic capacitor and solute thereof |
| CN103779096A (en) * | 2014-01-25 | 2014-05-07 | 南通瑞达电子材料有限公司 | Working electrolyte for high voltages in electrolytic capacitor |
| CN105244166A (en) * | 2015-09-08 | 2016-01-13 | 南通三鑫电子科技股份有限公司 | 650V ultrahigh voltage aluminum electrolytic capacitor working electrolyte, and preparation method and applications thereof |
-
2017
- 2017-06-30 CN CN201710525596.0A patent/CN107275093B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101599367A (en) * | 2009-07-10 | 2009-12-09 | 南通江海电容器股份有限公司 | 600V ultra-high voltage aluminum working electrolyte of electrolytic capacitor and preparation thereof and application |
| CN101866752A (en) * | 2010-06-23 | 2010-10-20 | 深圳清华大学研究院 | Electrolyte for driving ultrahigh voltage large-sized aluminium electrolytic capacitor and solute thereof |
| CN103779096A (en) * | 2014-01-25 | 2014-05-07 | 南通瑞达电子材料有限公司 | Working electrolyte for high voltages in electrolytic capacitor |
| CN105244166A (en) * | 2015-09-08 | 2016-01-13 | 南通三鑫电子科技股份有限公司 | 650V ultrahigh voltage aluminum electrolytic capacitor working electrolyte, and preparation method and applications thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107731534A (en) * | 2017-11-29 | 2018-02-23 | 南通江海电容器股份有限公司 | A kind of capacitor electrolyte and the capacitor using the electrolyte |
| CN107731534B (en) * | 2017-11-29 | 2019-08-20 | 南通江海电容器股份有限公司 | A kind of capacitor electrolyte and the capacitor using the electrolyte |
| CN112687472A (en) * | 2020-12-03 | 2021-04-20 | 盐城星晨科技有限公司 | High-frequency electrolyte and preparation method thereof |
| CN114420455A (en) * | 2022-02-28 | 2022-04-29 | 珠海格力新元电子有限公司 | Sparking voltage improver, preparation method thereof and electrolyte |
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| CN107275093B (en) | 2019-04-02 |
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