CN107271477A - A kind of apparatus and method for measuring hydrogeneous hot mixture state equation - Google Patents
A kind of apparatus and method for measuring hydrogeneous hot mixture state equation Download PDFInfo
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- CN107271477A CN107271477A CN201710387662.2A CN201710387662A CN107271477A CN 107271477 A CN107271477 A CN 107271477A CN 201710387662 A CN201710387662 A CN 201710387662A CN 107271477 A CN107271477 A CN 107271477A
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Abstract
The invention discloses a kind of apparatus and method for measuring the hydrogeneous mixture state equation of high temperature, shuttle is filled with after tested mixture is pressurizeed, it is heated to measurement temperature, the pressure of sample is measured using pressure sensor, using the temperature of platinum resistance thermometer or thermocouple measurement sample, shuttle is cooled afterwards, a part of sample mixture is introduced into another container known to volume, measurement obtains density of the sample in low temperature, thus obtains complete state equation.The present invention, which has, avoids hydrogen leakage under high temperature, measurement accuracy height, simple operation and other advantages, and the measurement for the hydrogeneous mixture state equation of high temperature provides feasible program.
Description
Technical field
The invention belongs to hot mixture state equation field of measuring technique, more particularly to a kind of measurement hydrogeneous mixing of high temperature
The apparatus and method of thing state equation.
Background technology
Hydrogen is a kind of clean energy resource.2005, Yan Qiuhui etc. had found to add biomass and coal slurry in supercritical water, can
Protium in coal slurry is continuously changed into hydrogen simple substance to separate out, the mixed working fluid containing hydrogen is generated.Experimental system is 650
DEG C, carried out under 25MPa, the working medium of generation contains 12% hydrogen, 8% carbon dioxide, 80% vapor.This mixed working fluid can quilt
For driving turbine, engine power generation is driven.And the design of the turbine, engine using this mixed working fluid is carried out, obtain
The problem of its state equation just turns into most direct and more crucial.
For the state equation measurement of hydrogen, mainly there are two methods at present:Burnett methods and constant volume area method.
2010, Sakoda etc. developed the device that hydrogen state equation is measured using Burnett methods.Its principle is foundation
State equation:PV=ZmRT, using the cavity of two fixed volumes, one is called sample cavity, and one is called expansion chamber.Sample cavity
There are two outlets, one is the pipeline for injecting sample, there is Valve controlling;Another is the pipeline for leading to expansion chamber, there is valve control
The flowing of system wherein mixture.There are three outlets on expansion chamber, one is the pipeline being connected with sample cavity, and another is bleeder pipe
Road, for discharging mixture in experiment, the 3rd is pipe outlet for vacuumizing.When testing beginning, into sample cavity
Injection is a certain amount of to contain hydrogen mixture, and the pressure of mixture is measured by pressure gauge, and the volume of mixture passes through calibration sample chamber
Volume measure, the temperature of mixture is measured by thermocouple.Unique unknown number is exactly the pressure of mixture initial temperature pressure
Contracting factor Z.This initial compression factor is obtained by following method fitting:Mixture is added, pressure initial in container is determined
After power, temperature, the valve between sample cavity and expansion chamber is opened, a certain amount of mixture is released into expansion chamber from sample cavity
Go, make sample cavity equal with the mixture pressure in expansion chamber.Turn off the valve between sample cavity and expansion chamber, it is ensured that sample
Mixture quality in chamber is constant, determines the pressure of mixture, temperature in now sample cavity.Afterwards, by the bleeder pipe of expansion chamber
Road is opened, and mixture therein is emptied, then expansion chamber is vacuumized, the shape for just adding sample into sample cavity is returned to
State.Then, it is again turned on connecting the valve of sample cavity and expansion chamber, by a part of mixture from sample cavity is discarded to expansion chamber
Go, make sample cavity equal with the mixture pressure in expansion chamber, close valve, it is ensured that the mixture quality in sample cavity is constant,
Determine pressure now in sample cavity, temperature.Afterwards, then by the atmospheric pipe of expansion chamber open, mixture therein emptied,
Then expansion chamber is vacuumized.So, circulated for several times, it is extremely thin until the gas pressure in sample cavity is minimum.Due to
Release a certain amount of mixture every time, the gas of releasing before accounting for the ratio of total gas be to be determined by expansion chamber with sample cavity volume ratio
, it is a constant.Mixture is believed that trend perfect gas when pressure is minimum, and its compressibility factor is intended to 1.So by institute
There is the data aggregate measured together, finding limit, you can obtain the compressibility factor Z of mixture original state.So, mixture exists
State equation in test scope just can be measured all.
Burnett methods can only determine state equation of the hydrogen at 200 DEG C, just occur more afterwards more than 200 DEG C
Serious hydrogen leakage problem, hydrogen is escaped from sample cavity and expansion chamber, makes measurement result inaccurate, and is had larger
Security risk.Therefore Burnett methods are not used to the measurement of 650 DEG C of hydrogeneous mixture state equation.
2012, Sakoda etc. developed the experimental provision that hydrogen state equation is measured using constant volume area method.Its principle is:
On the basis of Burnett methods, it is considered to sample cavity volume variation with temperature, the volume of sample cavity is much smaller than expansion chamber, is
About 1/10th of expansion chamber, first demarcate at different temperatures to sample cavity volume, then using with Burnett method classes
As method determine pressure and temp data.Finally, the state equation containing hydrogen mixture is calculated.Measuring, works as temperature
When reaching 800K, the volume of sample cavity about rises to 1.01 times of sample cavity volume under 400K.Measured using constant volume area method, hydrogen
The deviation of existing state equation is not more than 1% in 200 DEG C, 0-100MPa density and document.
Constant volume area method measuring state equation needs to obtain the state equation of low temperature under material in advance, or use perfect gas
State equation is carried out approximately, or the method directly weighed using balance weighs the quality of the larger the working fluid of molecular weight.But
For composition it is unknown contain hydrogen mixture, the state equation under its low temperature can not be obtained by simply measuring in advance, if used
Burnett methods are first measured, it is impossible to ensure the mixture in Burnett sample cavities and the mixture in constant volume area method container
Composition is identical;If calculated by equation for ideal gases, due to not fully meeting ideal at low temperature containing hydrogen mixture
Gas equation, can also make measurement result relatively large deviation occur;The molecular weight of each component containing hydrogen mixture is relatively low, adopts and weighs in the balance
The method of weight can also make experimental result relatively large deviation occur.
In summary, existing experimental method can only obtain state equation of the hydrogen below 500 DEG C and containing hydrogen mixture
State equation below 200 DEG C.Not yet there is researcher to propose the reality of 650 DEG C of measurement and its hydrogeneous mixture state equation of the above
Proved recipe method.
The content of the invention
In order to overcome the shortcoming of above-mentioned prior art, contain hydrogen mixture it is an object of the invention to provide one kind measurement high temperature
DEG C state equation containing hydrogen mixture of the apparatus and method of state equation, especially 1000.The each measurement process of the device passes through
Two pacings, which are measured, determines to contain under density hydrogen mixture from temperature value T20To the maximum temperature T for needing to measure10Between state equation
P=p (T), afterwards by changing the quality containing hydrogen mixture being initially filled with, is obtained under different densities containing hydrogen mixture same
In the range of state equation, finally give temperature value T20To the maximum temperature T for needing to measure10Scope is containing the complete of hydrogen mixture
State equation p=p (ρ, T).This device has the advantages that to avoid high-temperature hydrogen seepage, measurement accuracy high, easy to operate, compensate for
The blank of the hydrogeneous mixture state equation fields of measurement of high temperature.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of device for measuring the hydrogeneous mixture state equation of high temperature, including:
For holding the shuttle 1 containing hydrogen mixture;
The shuttle 22 connected with shuttle 1;
Electric heater 1 for heating the shuttle 1;
Electric heater 24 for heating the shuttle 22;
Pressure sensor 1 for measuring the internal pressure of shuttle 1;
Thermometer 1 for measuring the internal temperature of shuttle 1;
Pressure sensor 29 for measuring the internal pressure of shuttle 22;
Thermometer 2 10 for measuring the internal temperature of shuttle 22;
It is arranged on the control valve 1 on the hydrogeneous gaseous mixture entrance pipe of the shuttle 1;
It is arranged on the shuttle 1 and the control valve 2 12 on the connecting pipeline of shuttle 22;
And,
It is arranged on the control valve 3 13 on the hydrogeneous mixed gas outlet pipeline of the shuttle 22.
Apparatus of the present invention also include:
The closed container 5 of hydrogen leakage is prevented for being incubated the shuttle 1 and being filled with slumpability gas;
The closed container 6 of hydrogen leakage is prevented for being incubated the shuttle 22 and being filled with slumpability gas.
The method of the present invention measurement hydrogeneous mixture state equation of high temperature, comprises the following steps:
First, it will be filled with after the pressurization to be measured containing hydrogen mixture in shuttle 1, vessel inlet be then shut off, in sample
Container 1 is internally formed closing space, and the maximum temperature T that shuttle 1 makes its temperature reach needs measurement is heated afterwards10;
Then, at different temperatures, determine and record the pressure p in shuttle 1 and corresponding temperature T, it
Afterwards by the temperature control of shuttle 1 and shuttle 22 in identical value T20, will be a part of hydrogeneous in shuttle 1
Mixture is introduced into shuttle 22, and pressure is reached after balance, pressure p and temperature T in shuttle 1 is measured again, so
Closing control valve 2 12, opens control valve 3 13, shuttle 22 is vacuumized afterwards;Control valve 3 13 is turned off, control is opened
Valve 2 12, remaining a part of mixture among shuttle 1 is introduced among shuttle 22, pressure is reached after balance,
The pressure p and temperature T in measurement shuttle 1, repeat the process 6-8 times, thereby determine that containing in shuttle 1 again
Hydrogen mixture is in temperature value T20Under density value so that obtain containing hydrogen mixture under the density from temperature value T20To need survey
The maximum temperature T of amount10P=p (T) condition curve;
Finally, by changing initial be filled with the quality containing hydrogen mixture in shuttle 1, change shuttle 1
The density of mixture, obtains containing under different densities hydrogen mixture from temperature value T20To the maximum temperature T for needing to measure10P=p
(T) condition curve, it is thus final to determine containing hydrogen mixture in temperature value T20To the maximum temperature T for needing to measure10Scope it is complete
State equation p=p (ρ, T).
The hydrogeneous mixture temperature scope is at 150 DEG C-1000 DEG C, and pressure limit is in 0-100MPa.
It is described to vacuumize rear vacuum 5 × 10-4Below Pa, is vacuumized using mechanical pump and molecular pump two-stage, to prevent
Influence of the residual gas to measurement in container, molecular pump selects Leybold, TW70H, and the temperature is by electric heater and thermometer
Control.
The temperature T be shuttle 1, shuttle 22 with it is tested reach thermal balance containing hydrogen mixture when it is common
Temperature.
In two steps, the first step will only be tested and is filled with shuttle 1 containing hydrogen mixture each measurement process, heat sample
The maximum temperature T that product container 1 is measured to needs10, the pressure p that shuttle 1 includes hydrogen mixture is measured, is gradually subtracted afterwards
Small heating power, makes the reduction of the temperature and pressure containing hydrogen mixture in shuttle 1, then measure 6-8 times containing hydrogen mixture
Temperature T and pressure p, until the temperature of shuttle 1 is reduced to T20;Second step is by shuttle 1, shuttle 22
It is maintained at temperature value T simultaneously20, a part is exported from shuttle 1 containing hydrogen mixture into shuttle 22, two containers
After pressure balance, the pressure p in determination sample container 1, closing control valve 2 12, is taken out using mechanical pump molecular pump two-stage afterwards
Shuttle 22 is evacuated to 5 × 10 by gas-4Pa, forms vacuum environment;Export a part from shuttle 1 again afterwards
Mixture is into shuttle 22, so repeatedly 6-8 times;Change the quality for being filled with gaseous mixture afterwards, repeat above-mentioned measured
Journey, it is final to can obtain temperature value T20To the maximum temperature T for needing to measure10The good working condition equation p=p (ρ, T) of scope.
Compared with prior art, the present invention is dexterously by by the tested pressure containing hydrogen mixture, temperature survey and density
Measurement is separated, and the pressure containing hydrogen mixture, temperature and the density data of same sample ingredient are respectively obtained by two pacing amounts, is realized high
The measurement of hydrogeneous mixture state equation under temperature.The present invention, which has, prevents high-temperature hydrogen seepage, measurement accuracy high, simple to operate etc.
Advantage, has filled up the blank of the hydrogeneous mixture state equation fields of measurement of high temperature.
Brief description of the drawings
Temperature, pressure change schematic diagram when Fig. 1 is measurement high temperature hydrogeneous mixture state equation.
Fig. 2 is apparatus structure and concrete composition of the invention.
Embodiment
Describe embodiments of the present invention in detail with reference to the accompanying drawings and examples.
Each measurement process is divided into the progress of two steps, as shown in Figure 1.
First step measurement contains hydrogen mixture under certain density from temperature value T20To the maximum temperature T for needing to measure10Shape
State equation p=p (T).It is filled with shuttle 1 a certain amount of containing hydrogen mixture, afterwards closing control valve 1 and control
Valve 2 12, makes to form confined space in shuttle 1, accommodates a certain amount of containing hydrogen mixture.Electric heater 1 is used afterwards
Shuttle 1 is heated, temperature in use meter 1 is controlled, the maximum temperature for making the temperature stabilization of shuttle 1 be measured in needs
T10.The pressure p in shuttle is measured using pressure sensor 11, temperature in use meter 1 measurement shuttle 1 in temperature
Spend T1.Afterwards, reduce the heating power of electric heater 1, be gradually reduced temperature and pressure in shuttle 1, and
Stabilization is so repeated M times, wherein the temperature stabilization made in shuttle for the M times is in T in a temperature20.In ith temperature
When stable, the pressure p in shuttle is measured using pressure sensor 11i, temperature in use meter 1 measurement shuttle 1 in
Temperature T1i(i=1,2 ..., M).This step can obtain M group pressure and temp data (p1i, T1i)。
Second step measurement is containing hydrogen mixture in temperature value T20Density.Shuttle 1 is heated using electric heater 1,
Electric heater 24 heats the temperature in shuttle 22, the measurement shuttle 1 of temperature in use meter 1, and thermometer 2 10 is surveyed
The temperature in shuttle 22 is measured, the temperature in shuttle 1 and shuttle 22 is always held at T20.Close afterwards
Control valve 1 and control valve 3 13, open control valve 2 12, a part is entered sample from shuttle 1 containing hydrogen mixture
In container 22.Using the pressure in pressure sensor 1, the measurement of pressure sensor 29 shuttle 1, shuttle 22,
After after pressure balance, the pressure p in shuttle 1 is measured using pressure sensor 12j;Closing control valve 2 12, beats afterwards
Control valve 3 13 is opened, shuttle 22 is vacuumized, closing control valve 3 13.Repeating opening control valve 2 12 makes a part
Containing hydrogen mixture from shuttle 1 enter shuttle 22 after after pressure balance measure pressure, turn off control valve 2 12 dozens
The step of shuttle 22 is vacuumized simultaneously closing control valve 3 13 by control valve 3 13 is opened, n times is carried out, obtains N number of pressure data
p2j(j=1,2 ..., N).
In second step measurement, the pressure and temp (p of most original20, T20) it is equal to the most end pressure and temp that the first step is measured
(p1M, T1M).Afterwards, the process of each duplicate measurements, it is believed that be satisfied by state equation containing hydrogen mixture:
p2,j-1V1=Zj-1mj-1RT20 (1)
p2j(V1+V2)=Zjmj-1RT20 (2)
Wherein V1, V2It is shuttle 1, the volume of shuttle 22, Z respectivelyjFor the compression in jth time repetitive process
The factor, R is ideal gas constant.
Two formulas are divided by above, that is, are obtained:
Wherein N=(V1+V2)/V1For container volume specific ray constant.
By M times obtained M (3) formulas are repeated to be multiplied, M than it is larger when, hydrogeneous gaseous mixture is very thin, it is believed that close
Perfect gas property, compressibility factor is just 1, be can obtain
Finally give
So far, containing hydrogen mixture in temperature value T20Under density p20Also obtained.Under this density, from temperature value T20
To the maximum temperature T for needing to measure10Scope, (ρ, p, T) data containing hydrogen mixture are to be ultimately determined to:(ρ20, p1i, T1i)(i
=0,1,2 ..., M).
Afterwards, the initial quality containing hydrogen mixture for being filled with shuttle 1 is changed, you can change temperature value T20Under it is hydrogeneous
The density p of mixture20.Repeat two above-mentioned pacing amounts, you can obtain the numbers of (ρ, p, the T) containing hydrogen mixture under different densities
According to (ρ20, p1i, T1i) (i=0,1,2 ..., M).So, it is final to can obtain hydrogeneous mixture in temperature value T20- need what is measured
Maximum temperature T10The good working condition equation p=p (ρ, T) of scope.
In specific experiment, measuring process is as follows:
Step one:Be filled with shuttle 1 it is a certain amount of contain hydrogen mixture, closing control valve one 11 and 12 afterwards,
Make to form confined space in shuttle 1, accommodate a certain amount of containing hydrogen mixture.Afterwards sample is heated using electric heater 1
Product container 1, temperature in use meter 1 is controlled, the maximum temperature T for making the temperature stabilization of shuttle 1 be measured in needs10.Make
The pressure p in shuttle is measured with pressure sensor 11, temperature in use meter 1 measurement shuttle 1 in temperature T1。
Step 2:Reduce the heating power of electric heater 1, under making temperature and pressure in shuttle 1 gradually
Drop, and stably in a temperature.During temperature stabilization, the pressure p in shuttle is measured using pressure sensor 11i, use
Temperature T in the measurement shuttle 1 of thermometer 11i。
Step 3:Repeat step two M times, obtains M group pressure and temp data (p1i, T1i) (i=1,2,3 ..., M).Wherein
The temperature of M secondary controls shuttle 1 is T1M=T20。
Step 4:Electric heater 1 heats shuttle 1, the heating shuttle 22 of electric heater 24, temperature in use
The temperature in the temperature in one 9 measurement shuttles 1, the measurement shuttle 22 of thermometer 2 10 is counted, makes shuttle 1
T is always held at the temperature in shuttle 2220。
Step 5:Closing control valve 1, control valve 3 13, open control valve 2 12, make a part containing hydrogen mixture from
Shuttle 1 enters in shuttle 22.Using in the measurement of pressure sensor one 7,9 shuttle 1, shuttle 22
Pressure, after after pressure balance, use the pressure p in the measurement shuttle 1 of pressure sensor 12j;Closing control valve afterwards
2 12, control valve 3 13 is opened, shuttle 22 is vacuumized, closing control valve 3 13.
Step 6:The n times of repeat step five, obtain N number of pressure data p2j(j=1,2 ..., N)
Step 7:Closing control valve 1, opens control valve 2 12, control valve 3 13, and shuttle 1, sample are held
Device 22 is vacuumized, and changes the initial quality containing hydrogen mixture for being filled with shuttle 1, repeat step one to step 6 afterwards
Process, until obtaining sufficient amount of data.Last closing control valve 1, opens control valve 2 12, control valve 3 13, will
Shuttle 1, shuttle 22 are vacuumized, and instrument restPoses, and whole measurement process terminate.
The test philosophy that the present invention is not only limited in above-mentioned embodiment, the present invention can be widely applied to this area
And associated other field, the present invention can be implemented using other a variety of embodiments.Therefore, it is every to use this hair
Bright design philosophy, does some simple designs for changing or changing, both falls within the scope of protection of the invention.
Claims (7)
1. a kind of device for measuring the hydrogeneous mixture state equation of high temperature, it is characterised in that including:
For holding the shuttle one (1) containing hydrogen mixture;
The shuttle two (2) connected with shuttle one (1);
Electric heater one (3) for heating the shuttle one (1);
Electric heater two (4) for heating the shuttle two (2);
Pressure sensor one (7) for measuring described (1) internal pressure of shuttle one;
Thermometer one (8) for measuring described (1) internal temperature of shuttle one;
Pressure sensor two (9) for measuring described (2) internal pressure of shuttle two;
Thermometer two (10) for measuring described (2) internal temperature of shuttle two;
It is arranged on the control valve one (11) on the hydrogeneous gaseous mixture entrance pipe of the shuttle one (1);
It is arranged on the shuttle one (1) and the control valve two (12) on shuttle two (2) connecting pipeline;And,
It is arranged on the control valve three (13) on the hydrogeneous mixed gas outlet pipeline of the shuttle two (2).
2. the device of the hydrogeneous mixture state equation of high temperature is measured according to claim 1, it is characterised in that also included:
The closed container (5) of hydrogen leakage is prevented for being incubated the shuttle one (1) and being filled with slumpability gas;
The closed container (6) of hydrogen leakage is prevented for being incubated the shuttle two (2) and being filled with slumpability gas.
3. a kind of method for measuring the hydrogeneous mixture state equation of high temperature, it is characterised in that comprise the following steps:
First, it will be filled with after the pressurization to be measured containing hydrogen mixture in shuttle one (1), be then shut off vessel inlet, hold in sample
Device one (1) is internally formed closing space, and the maximum temperature that shuttle one (1) makes its temperature reach needs measurement is heated afterwards
T10;
Then, at different temperatures, determine and record the p temperature T corresponding to pressure p and pressure in shuttle one (1),
Afterwards by the temperature control of shuttle one (1) and shuttle two (2) in identical value T20, by one in shuttle one (1)
Part is introduced into shuttle two (2) containing hydrogen mixture, and pressure is reached after balance, and the pressure in shuttle one (1) is measured again
Power p and temperature T, is then shut off control valve two (12), opens control valve three (13), shuttle two (2) is vacuumized;Turn off
Control valve three (13), opens control valve two (12), and remaining a part of mixture among shuttle one (1) is introduced into sample holds
Among device two (2), pressure is reached after balance, and pressure p and temperature T in shuttle one (1) are measured again, repeat the process 6-
8 times, thereby determine that in shuttle one (1) and contain hydrogen mixture in temperature value T20Under density value, so as to obtain hydrogeneous mixing
Thing is under the density from temperature value T20To the maximum temperature T for needing to measure10P=p (T) condition curve;
Finally, by changing initial be filled with the quality containing hydrogen mixture in shuttle one (1), change shuttle one (1)
The density of mixture, obtains containing under different densities hydrogen mixture from temperature value T20To the maximum temperature T for needing to measure10P=p
(T) condition curve, it is thus final to determine containing hydrogen mixture in temperature value T20To the maximum temperature T for needing to measure10Scope it is complete
State equation p=p (ρ, T).
4. the method for the hydrogeneous mixture state equation of high temperature is measured according to claim 1, it is characterised in that described hydrogeneous mixed
Compound temperature range is at 150 DEG C-1000 DEG C, and pressure limit is in 0-100MPa.
5. the method for the hydrogeneous mixture state equation of high temperature is measured according to claim 1, it is characterised in that described to vacuumize
Vacuum is 5 × 10 afterwards-4Below Pa, is vacuumized using mechanical pump and molecular pump two-stage.
6. the method for the hydrogeneous mixture state equation of high temperature is measured according to claim 1, it is characterised in that the temperature T
For shuttle one (1), shuttle two (2) with it is tested reach thermal balance containing hydrogen mixture when common temperature.
7. the method for the hydrogeneous mixture state equation of high temperature is measured according to claim 1, it is characterised in that each survey
In two steps, the first step will be only tested and be filled with shuttle one (1) containing hydrogen mixture amount process, and heating shuttle one (1), which is arrived, to be needed
The maximum temperature T to be measured10, the pressure p that shuttle one (1) includes hydrogen mixture is measured, heating power is gradually reduced afterwards,
Make in shuttle one (1) containing hydrogen mixture temperature and pressure reduction, then measure the 6-8 temperature T containing hydrogen mixture with
Pressure p, until the temperature of shuttle one (1) is reduced to T20;Second step by shuttle one (1), shuttle two (2) simultaneously
It is maintained at temperature value T20, an export part contains hydrogen mixture into shuttle two (2) from shuttle one (1), two containers
After pressure balance, the pressure p in determination sample container one (1), closing control valve two (12), uses mechanical pump molecular pump two afterwards
Shuttle two (2) is evacuated to 5 × 10 by level pumping-4Pa, forms vacuum environment;Led again from shuttle one (1) afterwards
Go out a part of mixture into shuttle two (2), so repeatedly 6-8 times;Change afterwards in the quality for being filled with gaseous mixture, repetition
Measurement process is stated, it is final to can obtain temperature value T20To the maximum temperature T for needing to measure10The good working condition equation p=p of scope
(ρ,T)。
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CN108828137A (en) * | 2018-04-19 | 2018-11-16 | 辽宁石油化工大学 | A kind of controllable lift is used to measure the method and apparatus of Gas Compression Factor |
CN109374827A (en) * | 2018-10-08 | 2019-02-22 | 清华大学 | A kind of apparatus and method measuring high temperature and high pressure gas PVT property |
CN117268991A (en) * | 2023-08-07 | 2023-12-22 | 北京航天试验技术研究所 | Hydrogen density measuring device and method |
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CN105842273A (en) * | 2016-03-16 | 2016-08-10 | 华北电力大学(保定) | Acquiring method and system for compression factor |
CN206074384U (en) * | 2016-07-21 | 2017-04-05 | 浙江工业大学 | A kind of experimental provision for determining vapor liquid equilibrium data |
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CN2428769Y (en) * | 2000-05-19 | 2001-05-02 | 江汉石油学院 | High-temp. high-pressure PVT test instrument |
CN203490145U (en) * | 2013-10-11 | 2014-03-19 | 南京大学昆山创新研究院 | Gas solubility measuring device |
CN105842273A (en) * | 2016-03-16 | 2016-08-10 | 华北电力大学(保定) | Acquiring method and system for compression factor |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108828137A (en) * | 2018-04-19 | 2018-11-16 | 辽宁石油化工大学 | A kind of controllable lift is used to measure the method and apparatus of Gas Compression Factor |
CN109374827A (en) * | 2018-10-08 | 2019-02-22 | 清华大学 | A kind of apparatus and method measuring high temperature and high pressure gas PVT property |
CN109374827B (en) * | 2018-10-08 | 2020-06-30 | 清华大学 | Device and method for measuring PVT (pressure-volume-temperature) property of high-temperature high-pressure gas |
CN117268991A (en) * | 2023-08-07 | 2023-12-22 | 北京航天试验技术研究所 | Hydrogen density measuring device and method |
CN117268991B (en) * | 2023-08-07 | 2024-04-16 | 北京航天试验技术研究所 | Hydrogen density measuring device and method |
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