CN107268269A - A kind of multi-functional crease and shrink resistant finishing liquid and preparation method thereof - Google Patents
A kind of multi-functional crease and shrink resistant finishing liquid and preparation method thereof Download PDFInfo
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- CN107268269A CN107268269A CN201710623135.7A CN201710623135A CN107268269A CN 107268269 A CN107268269 A CN 107268269A CN 201710623135 A CN201710623135 A CN 201710623135A CN 107268269 A CN107268269 A CN 107268269A
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- Prior art keywords
- crease
- minutes
- shrink
- concentration
- slowly added
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- 239000007788 liquid Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 18
- 229960000583 acetic acid Drugs 0.000 claims abstract description 15
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 15
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 11
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims abstract description 7
- -1 silester Chemical compound 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 62
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 230000010355 oscillation Effects 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000002059 nanofabric Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of multi-functional crease and shrink resistant finishing liquid and preparation method thereof, dressing liquid is prepared from the following materials：Butyl titanate, silester, glacial acetic acid, silver nitrate, acetylacetone,2,4-pentanedione, polyethylene glycol 400, graphene oxide, crease and shrink resistance resin, deionized water.The dressing liquid of the present invention is while bafta crease and shrink resistance effect is ensured, moreover it is possible to provides good UV-preventing, antibiotic property, antistatic property, becomes a multi-functional crease and shrink resistant finishing agent.
Description
Technical field
It is more particularly to a kind of to be used for wollen fabrics the invention belongs to the crossing domain of inorganic nano material and textile material
The compounded technology of crease and shrink resistant finishing, a variety of function modified and aqueous sol and crease and shrink resistance resin.
Background technology
The demand and growing material for the social environment that functional textile market adapts to vary with people
Demand is arisen at the historic moment, and continues to develop growth.And with the development of science and technology and the improvement of people's living standards, feature
Textile presents more and more wide development space, and its performance has been not limited solely to simple function but tended to many
Function, high function, the direction of complex function are developed.
There is conventional textile feature can be realized by two kinds of approach：One is to take functional fibre, and two be to spinning
Fabric carries out functional treatment.Although functional fibre persistence is good, cost is high, is not suitable for mass consumption, so, typically all
It is that functional textile is produced using the method arranged.Functional finishing agent in the market is essentially all simple function,
Much the processing conditions of finishing agents is different, disturb each other each other, and this is that Multifunctional finishing brings very big difficulty.
With the rise of nanometer technology, sol-gel technique, which is increasingly becoming, improves a kind of novel universal skill of fabric property
Art, nano inorganic oxide is securely attached to fiber surface and is possibly realized, and is that multifunctional finish of textiles opens new road
Road.
When preparing colloidal sol, modification can be doped to colloidal sol, various additives, function organic matter or molecule, crystalline substance
Kind etc. is uniformly dispersed in colloidal sol, then is arranged on fabric, the gel of various ingredients can be formed in fabric face, so that knitting
Thing obtains a variety of different functions.
Current most domestic research is all still first disperseed nano particle, after then being compounded with resin, then
Fabric is arranged, this method shortcoming is a lot, such as energy consumption is big, cost is high, nano particle and fabric compatibility are poor, disperse not
Uniformly, easily reunite etc..It is combined using sol-gel technique with wrinkle proofing several to the report of bafta progress Multifunctional finishing
Do not have.
Disclosing one kind in application publication number number for CN101200851A Chinese patent allows pure cotton fabric while having
Have the compound finishing auxiliaries of creasing anti-bacterial function, its use no-ironing resin, nano titanium oxide, catalyst, bleeding agent etc. into
Part mixing composition, the dressing liquid uses nano-titanium dioxide powder, sol-gel technique is not used, also do not have doping, change
The research of property.
A kind of uvioresistant protection type of shirt is disclosed for CN106758200A Chinese patent in application publication number number
Include crease and shrink resistance resin and TiO 2 sol in noniron finish liquid and method for sorting, its dressing liquid prescription, but it is used
Be ethanol and hydrochloric acid to prepare TiO 2 sol, ethanol is volatile, easy firing blast, add the danger of industrialized production
Property；Hydrochloric acid is strong acid, and volatility is extremely strong, and hidden danger is brought to safety in production, and cellulose base fiber fabric, intolerant to strong acid, strength declines
Significantly.Emulsifying agent is added in the compounding of colloidal sol and resin in addition, compounding product should belong to emulsion, rather than colloidal sol, right
Finishing effect brings adverse effect.
The content of the invention
Goal of the invention：The present invention is for of the prior art not enough multi-functional shrinkproof anti-for wollen fabrics there is provided one kind
Wrinkle dressing liquid of arrangement and preparation method thereof.
Technical scheme：A kind of multi-functional crease and shrink resistant finishing liquid of the present invention, the dressing liquid is to include metatitanic acid fourth
Ester, silester, glacial acetic acid, silver nitrate, acetylacetone,2,4-pentanedione, polyethylene glycol 400, graphene oxide, crease and shrink resistance resin it is water-soluble
The concentration of glue, wherein butyl titanate is 3.4 ~ 68g/L；The concentration of glacial acetic acid is 4.8 ~ 96g/L；The concentration of silester be 0.2 ~
40g/L；The concentration of silver nitrate is 0.017 ~ 0.17g/L；The concentration of acetylacetone,2,4-pentanedione is 1 ~ 10g/L；The concentration of polyethylene glycol 400 is
10~80g/L；The concentration of graphene oxide is 0.5 ~ 50mg/L；The concentration of crease and shrink resistance resin is 50 ~ 150g/L；Remaining is to go
Ionized water.
Preferably, when the crease and shrink resistance resin contains formaldehyde, for low formaldehyde or the M2D resins of ultra-low formaldehyde；It is described
It is the Polycarboxylic acids such as BTCA, maleic acid, citric acid, the acid of propylene three when crease and shrink resistance resin is free of formaldehyde
In one or more.
The invention also discloses a kind of preparation method of multi-functional crease and shrink resistant finishing liquid, comprise the following steps：
（1）The glacial acetic acid of total consumption half is weighed, at room temperature, stirs while be slowly added to butyl titanate, continues after adding
Stir 5 ~ 10min；Then another side stirring is while be slowly added to silester, and continuation is stirred 5 ~ 10 minutes after adding；Then again
Stir while being slowly added to acetylacetone,2,4-pentanedione, continuation is stirred 5 ~ 10 minutes after adding；Finally another side stirring is slow on one side adds
Enter polyethylene glycol, continue to stir 5 ~ 10 minutes after adding, obtain yellow transparent solution A；
（2）Silver nitrate is first used to a small amount of deionized water dissolving, appropriate deionized water stirring is then added, is eventually adding remaining
Half glacial acetic acid, stirs 5~10 minutes, obtains clear solution B；
（3）Under conditions of 30 DEG C of water-baths, 800 ~ 1200r/min, solution B is added drop-wise in solution A dropwise, after completion of dropping,
Continuing vigorous is stirred 3 hours in a water bath, obtains the yellow transparent hydrosol, and handle 48 hours into changing；
（4）A certain amount of graphene oxide is weighed, a small amount of deionized water is added, after sonic oscillation dissolves 18 hours, adds suitable
Deionized water is measured, certain density graphene oxide solution is made into；
（5）At room temperature, stirred in the yellow hydrosol into change processing while being slowly added to going for total amount about 3/4ths
Ionized water, continues to stir 5 ~ 10 minutes after adding；Then the stirring of another side is while be slowly added to appropriate graphene oxide solution,
Continue to stir 5 ~ 10 minutes after adding；Then another side stirring is while be slowly added to a certain amount of crease and shrink resistance resin, after adding
Continue to stir 5 ~ 10 minutes；Last another side stirring is added follow-up while be slowly added to remaining deionized water to certain volume
Continuous stirring 30 minutes, obtains multi-functional crease and shrink resistant finishing liquid.
Beneficial effect：The multi-functional crease and shrink resistant finishing liquid of the present invention can also be arranged when ensureing crease and shrink resistance function to it
Fabric assign uvioresistant, antibacterial, self-cleaning function；Preparation method is simple simultaneously, low-temperature operation, without organic solvent, no
Using strong inorganic acid, compounded with resin after collosol stability it is good, be easy to industrial operation, no longer needed in addition when arranging processing
Add catalyst, particularly with the polybasic carboxylic acid class crease and shrink resistance tree such as BTCA, maleic acid, citric acid, the acid of propylene three
After fat compounding, make catalyst without using sodium hypophosphite, it is to avoid eutrophication pollution of the remaining dressing liquid to environment.
Embodiment
With reference to specific embodiment, the invention will be further described：
Embodiment 1
A kind of multi-functional crease and shrink resistant finishing liquid, the dressing liquid be include butyl titanate, silester, glacial acetic acid, silver nitrate,
Acetylacetone,2,4-pentanedione, polyethylene glycol 400, graphene oxide, ultra-low formaldehyde crease and shrink resistance resin KH-1.Its preparation method is as follows：
（1）4.8g glacial acetic acid is weighed as in beaker, at room temperature, stirs while be slowly added to 6.8g butyl titanates, adds
Continue to stir 5 ~ 10min afterwards；Then another side stirring is while be slowly added to 4.16g silester, and continuation stirs 5 ~ 10 after adding
Minute；Then another side stirring is while be slowly added to 2g acetylacetone,2,4-pentanediones, and continuation is stirred 5 ~ 10 minutes after adding；Finally again while stirring
Mix while being slowly added to 16g polyethylene glycol 400s, continuation is stirred 5 ~ 10 minutes after adding, and obtains yellow transparent solution A；
（2）A small amount of deionized water is first added in another beaker, 0.085g silver nitrates are added while stirring, to whole dissolvings, so
Afterwards plus deionized water to gross weight is 36g, finally add 4.8g glacial acetic acid, stir 5~10 minutes, obtain clear solution B；
（3）Under conditions of 30 DEG C of water-baths, 800 ~ 1200r/min, solution B is added drop-wise in solution A dropwise, after completion of dropping,
Continuing vigorous is stirred 3 hours in a water bath, obtains the yellow transparent hydrosol, and handle 48 hours into changing；
（4）A certain amount of graphene oxide is weighed, a small amount of deionized water is added, after sonic oscillation dissolves 18 hours, adds suitable
Deionized water is measured, 1g/L graphene oxide solution is made into；
（5）Into stirring in the yellow hydrosol of change while be slowly added to about 600mL deionized water, continue to stir after adding
Mix 5 ~ 10 minutes；Then the stirring of another side is slowly added to the graphene oxide solution that 1mL concentration is 1g/L on one side, continuation after adding
Stirring 5 ~ 10 minutes；Then the stirring of another side is added follow-up while be slowly added to 60g ultra-low formaldehyde crease and shrink resistance resin KH-1
Continuous stirring 5 ~ 10 minutes；Last another side stirring is while be slowly added to remaining deionized water to 1L, and continuation stirs 30 after adding
Minute, much Function, Super Low formaldehyde crease and shrink resistant finishing liquid.
Embodiment 2
A kind of multi-functional crease and shrink resistant finishing liquid, the dressing liquid be include butyl titanate, silester, glacial acetic acid, silver nitrate,
Acetylacetone,2,4-pentanedione, polyethylene glycol 400, graphene oxide, formaldehydeless crease and shrink resistance resin BTCA.Its preparation method is as follows：
（1）12g glacial acetic acid is weighed as in beaker, at room temperature, is stirred while 8.5g butyl titanates are slowly added to, after adding
Continue to stir 5 ~ 10min；Then another side stirring is while be slowly added to 10.4g silester, and continuation stirs 5 ~ 10 points after adding
Clock；Then another side stirring is while be slowly added to 4g acetylacetone,2,4-pentanediones, and continuation is stirred 5 ~ 10 minutes after adding；Last another side stirring
While being slowly added to 40g polyethylene glycol 400s, continue to stir 5 ~ 10 minutes after adding, obtain yellow transparent solution A；
（2）A small amount of deionized water is first added in another beaker, 0.102g silver nitrates are added while stirring, to whole dissolvings, so
Afterwards plus deionized water to gross weight is 90g, finally add 12g glacial acetic acid, stir 5~10 minutes, obtain clear solution B；
（3）Under conditions of 30 DEG C of water-baths, 800 ~ 1200r/min, solution B is added drop-wise in solution A dropwise, after completion of dropping,
Continuing vigorous is stirred 3 hours in a water bath, obtains the yellow transparent hydrosol, and handle 48 hours into changing；
（4）A certain amount of graphene oxide is weighed, a small amount of deionized water is added, after sonic oscillation dissolves 18 hours, adds suitable
Deionized water is measured, 1g/L graphene oxide solution is made into；
（5）Into stirring in the yellow hydrosol of change while be slowly added to about 600mL deionized water, continue to stir after adding
Mix 5 ~ 10 minutes；Then the stirring of another side is slowly added to graphene oxide solution of the 1.5mL concentration for 1g/L on one side, adds follow-up
Continuous stirring 5 ~ 10 minutes；Then the stirring of another side is while be slowly added to 90g formaldehydeless crease and shrink resistance resin BTCA, plus
Continue to stir 5 ~ 10 minutes after complete；Last another side stirring is slowly added to remaining deionized water to 1L on one side, continuation after adding
Stirring 30 minutes, obtains multi-functional formaldehydeless crease and shrink resistant finishing liquid.
The multi-functional crease and shrink resistant finishing liquid of the present invention is when ensureing crease and shrink resistance function, and the fabric that can be also arranged to it is assigned
Uvioresistant, antibacterial, self-cleaning function；Preparation method is simple simultaneously, low-temperature operation, without organic solvent, without using strong inorganic
Acid, compounded with resin after collosol stability it is good, be easy to industrial operation, addition catalysis in addition is no longer needed when arranging processing
Agent, particularly with the polybasic carboxylic acid class crease and shrink resistance such as BTCA, maleic acid, citric acid, the acid of propylene three resin compounding after,
Make catalyst without using sodium hypophosphite, it is to avoid eutrophication pollution of the remaining dressing liquid to environment.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people
Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification
For the equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention
Any simple modification, equivalent variations and the modification made to above example, in the range of still falling within technical solution of the present invention.
Claims (3)
1. a kind of multi-functional crease and shrink resistant finishing liquid, it is characterised in that：The dressing liquid be include butyl titanate, silester,
Glacial acetic acid, silver nitrate, acetylacetone,2,4-pentanedione, polyethylene glycol 400, graphene oxide, the hydrosol of crease and shrink resistance resin, wherein metatitanic acid fourth
The concentration of ester is 3.4 ~ 68g/L；The concentration of glacial acetic acid is 4.8 ~ 96g/L；The concentration of silester is 0.2 ~ 40g/L；Silver nitrate
Concentration be 0.017 ~ 0.17g/L；The concentration of acetylacetone,2,4-pentanedione is 1 ~ 10g/L；The concentration of polyethylene glycol 400 is 10 ~ 80g/L；Oxygen
The concentration of graphite alkene is 0.5 ~ 50mg/L；The concentration of crease and shrink resistance resin is 50 ~ 150g/L；Remaining is deionized water.
2. multi-functional crease and shrink resistant finishing liquid according to claim 1, it is characterised in that：The crease and shrink resistance resin contains
During formaldehyde, for low formaldehyde or the M2D resins of ultra-low formaldehyde；It is BTCA, horse when the crease and shrink resistance resin is free of formaldehyde
The one or more come in the Polycarboxylic acids such as sour, citric acid, the acid of propylene three.
3. a kind of preparation method of multi-functional crease and shrink resistant finishing liquid, it is characterised in that：Comprise the following steps：
（1）The glacial acetic acid of total consumption half is weighed, at room temperature, stirs while be slowly added to butyl titanate, continues after adding
Stir 5 ~ 10min；Then another side stirring is while be slowly added to silester, and continuation is stirred 5 ~ 10 minutes after adding；Then again
Stir while being slowly added to acetylacetone,2,4-pentanedione, continuation is stirred 5 ~ 10 minutes after adding；Finally another side stirring is slow on one side adds
Enter polyethylene glycol, continue to stir 5 ~ 10 minutes after adding, obtain yellow transparent solution A；
（2）Silver nitrate is first used to a small amount of deionized water dissolving, appropriate deionized water stirring is then added, is eventually adding remaining
Half glacial acetic acid, stirs 5~10 minutes, obtains clear solution B；
（3）Under conditions of 30 DEG C of water-baths, 800 ~ 1200r/min, solution B is added drop-wise in solution A dropwise, after completion of dropping,
Continuing vigorous is stirred 3 hours in a water bath, obtains the yellow transparent hydrosol, and handle 48 hours into changing；
（4）A certain amount of graphene oxide is weighed, a small amount of deionized water is added, after sonic oscillation dissolves 18 hours, adds suitable
Deionized water is measured, certain density graphene oxide solution is made into；
（5）At room temperature, stirred in the yellow hydrosol into change processing while being slowly added to going for total amount about 3/4ths
Ionized water, continues to stir 5 ~ 10 minutes after adding；Then the stirring of another side is while be slowly added to appropriate graphene oxide solution,
Continue to stir 5 ~ 10 minutes after adding；Then another side stirring is while be slowly added to a certain amount of crease and shrink resistance resin, after adding
Continue to stir 5 ~ 10 minutes；Last another side stirring is added follow-up while be slowly added to remaining deionized water to certain volume
Continuous stirring 30 minutes, obtains multi-functional crease and shrink resistant finishing liquid.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108468213A (en) * | 2018-04-02 | 2018-08-31 | 东莞市佳乾新材料科技有限公司 | A kind of preparation method for the dressing liquid improving fabric antistatic property |
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| CN1936168A (en) * | 2006-08-08 | 2007-03-28 | 中原工学院 | Fabric product finishing agent and its preparing process and method thereof |
| CN102002854A (en) * | 2010-12-06 | 2011-04-06 | 中原工学院 | Multifunctional textile finishing agent, preparation method thereof and cotton textile finishing method |
| CN102154829A (en) * | 2010-12-20 | 2011-08-17 | 北京服装学院 | Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application |
| CN103806266A (en) * | 2013-11-25 | 2014-05-21 | 江南大学 | Method for manufacturing graphene oxide conductive cellulose fabric by ultraviolet light |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1936168A (en) * | 2006-08-08 | 2007-03-28 | 中原工学院 | Fabric product finishing agent and its preparing process and method thereof |
| CN102002854A (en) * | 2010-12-06 | 2011-04-06 | 中原工学院 | Multifunctional textile finishing agent, preparation method thereof and cotton textile finishing method |
| CN102154829A (en) * | 2010-12-20 | 2011-08-17 | 北京服装学院 | Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application |
| CN103806266A (en) * | 2013-11-25 | 2014-05-21 | 江南大学 | Method for manufacturing graphene oxide conductive cellulose fabric by ultraviolet light |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108468213A (en) * | 2018-04-02 | 2018-08-31 | 东莞市佳乾新材料科技有限公司 | A kind of preparation method for the dressing liquid improving fabric antistatic property |
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Application publication date: 20171020 |