CN102154829A - Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application - Google Patents
Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application Download PDFInfo
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- CN102154829A CN102154829A CN 201010595876 CN201010595876A CN102154829A CN 102154829 A CN102154829 A CN 102154829A CN 201010595876 CN201010595876 CN 201010595876 CN 201010595876 A CN201010595876 A CN 201010595876A CN 102154829 A CN102154829 A CN 102154829A
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- titanium alkoxide
- alkoxide
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- -1 titanium alkoxide Chemical class 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 239000010936 titanium Substances 0.000 claims abstract description 29
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 28
- 239000000243 solution Substances 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 18
- 239000010703 silicon Substances 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 239000004744 fabric Substances 0.000 claims description 26
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 15
- 229920000742 Cotton Polymers 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- HZBAVWLZSLOCFR-UHFFFAOYSA-N oxosilane Chemical compound [SiH2]=O HZBAVWLZSLOCFR-UHFFFAOYSA-N 0.000 claims description 10
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 239000013110 organic ligand Substances 0.000 claims description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000004224 protection Effects 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 238000007730 finishing process Methods 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 21
- 230000008569 process Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 230000006750 UV protection Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229960000583 acetic acid Drugs 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 239000012362 glacial acetic acid Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 description 2
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 229960001173 oxybenzone Drugs 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000009988 textile finishing Methods 0.000 description 2
- 229910018557 Si O Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910003077 Ti−O Inorganic materials 0.000 description 1
- 229910003088 Ti−O−Ti Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000004546 feltproofing Methods 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application. The finishing agent is prepared by the method comprising the following steps: (1) dissolving titanium alkoxide in an organic solvent, adding the obtained solution into acid aqueous solution and stirring uniformly to obtain a mixture; and (2) adding silicon alkoxide into the mixture obtained in the step (1), and stirring uniformly to obtain transparent solution; or (1) sequentially dissolving acid and silicon alkoxide in water, and stirring uniformly to obtain a mixture; and (2) dissolving titanium alkoxide in an organic solvent, adding the obtained solution into the mixture obtained in the step (1), and stirring uniformly to obtain transparent solution. The finishing agent disclosed by the invention is simple in preparation and short in the finishing process, and meets the requirements of water and energy conservation, low carbon and environmental protection.
Description
Technical field
The invention belongs to the finishing functions of textile fabrics field, relate to a kind of finishing agent, particularly a kind of anti-pilling, anti-ultraviolet finishing agent, and preparation method thereof with application.
Background technology
Finishing functions is the important means that promotes the textiles wearability, increases the textiles added value, mainly comprise anti-ultraviolet, anti-pilling, wrinkle resistant, antibiotic, refuse water, refuse oil, felt proofing, fire-retardant, softness etc.Because the mechanism of every kind of finishing functions has nothing in common with each other, therefore often need to adopt different finishing auxiliarieses.Along with developing rapidly of consumption demand, requirement improves constantly to functions of textile fabrics, and especially textiles being had polyfunctional requirement simultaneously increases gradually.
Anti-pilling and the arrangement of anti-ultraviolet are textile two kinds of arrangements often adopting with polyester cotton.Anti-ultraviolet arrangement is main by ultraviolet absorption and reflection are realized, mainly adopts Oxybenzone, hydroxy-phenyl benzotriazole, hydroxyphenyl-triazine etc.; In addition, nano titanium oxide also has certain ultraviolet shielded effect.Pill resistant finish is an approach to reduce interfibrous slippage or to increase surface of cotton fabric fineness, and biology enzyme, polyacrylate, polyurethane, organo-silicon compound etc. are main auxiliary agent.
When Oxybenzone, hydroxy-phenyl benzotriazole, hydroxyphenyl-triazine and biology enzyme carried out with the bath processing to textiles, biological enzyme activity can be affected, and weakens finishing effect; And during auxiliary agent couplings such as the anti-ultraviolet finishing agent of tradition and polyacrylate, polyurethane, organo-silicon compound, colloidal sol, will reduce the diffusivity of preventing the ultraviolet finishing agent again.Therefore at present textiles realizes that if desired anti-pilling is functional with two kinds of anti-ultraviolets, must carry out a kind of arrangement earlier and realize once putting in order after a kind of function again and realize another kind of function, processing technology complexity, water consumption power consumption, increase cost.
Therefore study the anti-pilling of textiles, anti-ultraviolet mechanism, the development of new finishing agent is realized single bath process, reduces the pollution of chemical assistant to environment, cuts down the consumption of energy, and this is one of main developing direction in current finishing functions field.
Summary of the invention
At the deficiency of existing processing technology, the invention provides a kind of anti-pilling that can make by single bath process, the finishing functions of textile fabrics agent of anti-ultraviolet.
One of purpose of the present invention is to provide the anti-pilling of this kind, anti-ultraviolet finishing agent.Described finishing agent is got by the method preparation that may further comprise the steps:
(1) the titanium alkoxide is dissolved in the organic solvent, the solution with gained adds in the acidic aqueous solution again, stirs, and obtains mixture;
(2) silicon alkoxide is joined in the mixture that obtains in the step (1), stir, obtain clear solution, promptly described finishing agent;
Perhaps get by the method preparation that may further comprise the steps:
(1) acid, silicon alkoxide is soluble in water successively, stir, obtain mixture;
(2) the titanium alkoxide is dissolved in the organic solvent, the solution of gained joins in the mixture that obtains in the step (1), stirs, and obtains clear solution, promptly described finishing agent;
In two kinds of above-mentioned preparation processes, preferred first kind.
More specifically,
Described silicon alkoxide is selected from least a in C4～C20 alkoxy silane; Preferred at least a in C4～C9 alkoxy silane.More specifically examples of compounds comprises: methyl silicate, ethyl orthosilicate, γ-glycidyl ether oxygen propyl trimethyl oxosilane, vinyl trimethyl oxosilane, vinyl triethyl group oxosilane, γ-(methacryloxy) oxypropyl trimethyl oxosilane; Wherein, preferred γ-glycidyl ether oxygen propyl trimethyl oxosilane, vinyl trimethyl oxosilane.
Described titanium alkoxide is selected from least a in C8～C20 alkoxytitanium acid esters; Preferred at least a in C8～C16 alkoxytitanium acid esters.More specifically examples of compounds comprises: butyl titanate, metatitanic acid four n-propyls, tetraisopropyl titanate, metatitanic acid four isobutyl esters, tetraethyl titanate; Wherein, preferred butyl titanate.
Described acid is selected from least a in inorganic acid or the water miscible organic acid; Preferred at least a in hydrochloric acid, nitric acid, formic acid.
Described organic solvent is to form chelate structure and water-soluble organic solvent with the titanium alkoxide, is selected from least a in the hydroxyl organic ligand compound; Preferred at least a in acetic acid, acetylacetone,2,4-pentanedione.Wherein, the consumption of each component is as follows:
The mol ratio of described titanium alkoxide and water is 1: (1～200); Preferred 1: (30～100);
The mol ratio of described titanium alkoxide and organic solvent is 1: (0.5～100); Preferred 1: (4～10);
Described titanium alkoxide is 1 with the mol ratio of acid: (0.001～10); Preferred 1: (0.01～0.1);
The mol ratio of described titanium alkoxide and silicon alkoxide is 1: (0.01～100); Preferred 1: (1～10).
The effect of finishing agent of the present invention is the mating reaction of each reagent, and its consumption can be regulated in the scope of broad, and effect is not had much affect.
It is raw material that the present invention adopts titanium alkoxide and silicon alkoxide, utilize them that hydrolysis and polycondensation reaction take place in water, generation is uniformly distributed in the water, the nano particle that contains Si-O-Si, Ti-O-Ti, Si-O-Ti key, because the Ti-O key has excellent uvioresistant performance, and Si-O has two dimension and three-dimensional valence bond structure simultaneously, the two in conjunction with after also can improve the anti-pilling of fabric.In addition, because nanostructured has than bigger serface, can be spontaneous absorption fast takes place, assemble at fabric face so do not need to add any adhesive in the finishing agent, and safer environmental protection has also reduced cost simultaneously.
Two of purpose of the present invention is to provide the preparation method of this kind finishing agent, and this preparation method is the single bath process process, may further comprise the steps:
(1) the titanium alkoxide is dissolved in the organic solvent, the solution with gained adds in the acidic aqueous solution again, stirs, and obtains mixture;
(2) silicon alkoxide is joined in the mixture that step (1) obtains, stir, obtain clear solution, promptly described finishing agent;
Perhaps described method may further comprise the steps:
(1) acid, silicon alkoxide is soluble in water successively, stir, obtain mixture;
(2) the titanium alkoxide is dissolved in the organic solvent, the solution of gained joins in the mixture that obtains in the step (1), stirs, and obtains clear solution, promptly described finishing agent.
In the described operation, the interpolation of its material and alr mode are common processing method.
Three of purpose of the present invention is to provide the purposes of this kind finishing agent, and described finishing agent is used to put in order pure cotton fabric, or chemical fibre and cotton blended fabric.
Wherein, described chemical fibre is selected from least a in polyester fiber, polyamide fiber, the polypropylene fibre.Textiles in the described step (2) is cotton or chemical fibre and cotton blended fabric, and wherein chemical fibre comprises polyester fiber, polyamide fiber, polypropylene fibre etc.
When using finishing agent of the present invention to put textiles in order, can finishing agent of the present invention be handled on the textiles by padding or flood single bath process, liquid carrying rate is 40～100%, and oven dry baked in 100～130 ℃ 0.5～3 minute then, promptly finished the arrangement process.
The present invention has the following advantages:
(1) uses titanium alkoxide and silicon alkoxide to prepare textile finish, adopt and pad or flood the single bath process arrangement, improve the anti-pilling of textiles, uv resistance energy simultaneously.
(2) effect of finishing agent of the present invention is the mating reaction of each reagent, and its consumption can be regulated in the scope of broad, and effect is not had much affect, and makes working condition simplify, and technical process is not harsh.
(3) use this finishing agent and can realize that textiles prevents pilling, the arrangement of anti-ultraviolet, simplified processing technology, reduced consumption, reduced processing cost, improved production efficiency water, the energy by single bath process.
The specific embodiment
The present invention will be further described below in conjunction with specific embodiment.But the present invention is not limited in following embodiment.
Embodiment 1
(1) finishing agent preparation
A. the 1mol butyl titanate is dissolved in the 6mol glacial acetic acid, is made into the glacial acetic acid solution of butyl titanate; 0.03mol hydrochloric acid is dissolved in the 37.5mol pure water, and the glacial acetic acid solution that adds described butyl titanate again stirs, and obtains mixture;
B. 8mol γ-glycidyl ether oxygen propyl trimethoxy silicane is joined in the mixture that obtains among the step a, stir, obtain clear solution;
(2) textile finishing
With pure cotton fabric (2/1 twill, 40 * 40/128 * 60,140g/m
2) in above-mentioned finishing agent, two soak two and roll, liquid carrying rate 80%～90% after 80 ℃ of oven dry, baked 3 minutes at 130 ℃ again.
According to same quadrat method, do not use finishing agent, fabric directly pads water, and preparation is in the same old way.
(3) performance test
According to " the mensuration second portion of GBT 4802.2-2008 textile fabric pilling performance: Martindale's method ", use the anti-pilling performance of M235Martindale ABRASION RESISTANCE and pilling tendency tester (Lars, tin Lay Asia-Pacific (Shenzhen) Co., Ltd) test textiles;
According to " evaluation of GB/T 18830-2009 ultraviolet resistance of fabric ", use Lambda 750UV/VIS Spectrometer (platinum Ai Ermo instrument (Shanghai) Co., Ltd.) test ultraviolet resistance of fabric.
After above-mentioned arrangement, COTTON FABRIC pilling performance and ultraviolet through performance are as shown in table 1, arrangement back sample pilling performance is brought up to 3～4 grades by 1 grade, the UPF value brings up to 146 by 25, through the fabric of finishing agent arrangement gained of the present invention, anti-fluffing and anti-pilling performance and uvioresistant through performance all are largely increased as can be seen.
Performance relatively before and after the arrangement of table 1 embodiment 1 pure cotton fabric
| - | Pilling performance (level) | Ultraviolet through performance (UPF value) |
| To in the same old way | 1 | ?25 |
| The arrangement sample | 3～4 | ?50+ |
Embodiment 2
(1) finishing agent preparation
A. successively with the 0.06mol formic acid, 1.2mol γ-glycidyl ether oxygen propyl trimethoxy silicane adds in the 68mol water, stirs, and obtains mixture;
B. the 1mol butyl titanate is dissolved in the solution that the 8mol acetylacetone,2,4-pentanedione is made into butyl titanate, the acetylacetone,2,4-pentanedione solution of this butyl titanate is joined in the mixture that obtains among the step a, stir, obtain clear solution;
(2) textile finishing
With 70/30 polyester cotton blending knitted fabric (single face weft plain weave, 18tex, vertical close 85 lines/5 centimetres, horizontal close 68 stringers/5 centimetres, grammes per square metre 175g/m
2) in above-mentioned finishing agent, two soak two and roll, liquid carrying rate 70%～80% after 80 ℃ of oven dry, baked 3 minutes at 130 ℃ again.
According to same quadrat method, do not use finishing agent, fabric directly pads water, and preparation is in the same old way.
(3) performance test
According to " mensuration the 3rd part of GB/T 4802.3-2008 textile fabric pilling performance: balling-up case method ", use the anti-pilling performance of the box balling-up case of YG511A (Ningbo of Zhejiang textile instrument factory) test textiles;
According to " evaluation of GB/T 18830-2009 ultraviolet resistance of fabric ", use Lambda 750UV/VIS Spectrometer (platinum Ai Ermo instrument (Shanghai) Co., Ltd.) test ultraviolet resistance of fabric.
After above-mentioned arrangement, polyester-cotton fabric pilling performance and ultraviolet through performance are as shown in table 2, arrangement back sample pilling performance is brought up to 4～5 grades by 2 grades, the UPF value brings up to 152 by 36, through the fabric of finishing agent arrangement gained of the present invention, anti-fluffing and anti-pilling performance and uvioresistant through performance all are largely increased as can be seen.
70/30 polyester cotton blending knit fabric finishing front and back performance relatively among table 2 embodiment 2
| - | Pilling performance (level) | Ultraviolet through performance (UPF value) |
| To in the same old way | 2 | ?36 |
| The arrangement sample | 4～5 | ?50+ |
Claims (10)
1. an anti-pilling is prevented the ultraviolet finishing agent, it is characterized in that described finishing agent is made by the method that may further comprise the steps:
(1) the titanium alkoxide is dissolved in the organic solvent, the solution with gained adds in the acidic aqueous solution again, stirs, and obtains mixture;
(2) silicon alkoxide is joined in the mixture that step (1) obtains, stir, obtain clear solution, promptly described finishing agent;
Perhaps make by the method that may further comprise the steps:
(1) acid, silicon alkoxide is soluble in water successively, stir, obtain mixture;
(2) the titanium alkoxide is dissolved in the organic solvent, the solution of gained joins in the mixture that obtains in the step (1), stirs, and obtains clear solution, promptly described finishing agent.
2. finishing agent as claimed in claim 1 is characterized in that:
Described silicon alkoxide is selected from least a in the alkoxy silane of C4～C20;
Described titanium alkoxide is selected from least a in C8～C20 alkoxytitanium acid esters;
Described acid is selected from least a in inorganic acid or the water miscible organic acid;
Described organic solvent is selected from least a in the hydroxyl organic ligand compound.
3. finishing agent as claimed in claim 1 is characterized in that:
Described silicon alkoxide is selected from least a in methyl silicate, ethyl orthosilicate, γ-glycidyl ether oxygen propyl trimethyl oxosilane, vinyl trimethyl oxosilane, vinyl triethyl group oxosilane, γ-(methacryloxy) oxypropyl trimethyl oxosilane.
4. finishing agent as claimed in claim 1 is characterized in that:
Described titanium alkoxide is selected from least a in butyl titanate, metatitanic acid four n-propyls, tetraisopropyl titanate, metatitanic acid four isobutyl esters, the tetraethyl titanate.
5. finishing agent as claimed in claim 1 is characterized in that:
Described acid is selected from least a in hydrochloric acid, nitric acid, the formic acid.
6. finishing agent as claimed in claim 1 is characterized in that:
Described organic solvent is selected from least a in acetic acid, the acetylacetone,2,4-pentanedione.
7. as the described finishing agent of one of claim 1～6, it is characterized in that:
The mol ratio of described titanium alkoxide and water is 1: (1～200);
The mol ratio of described titanium alkoxide and organic solvent is 1: (0.5～100);
Described titanium alkoxide is 1 with the mol ratio of acid: (0.001～10);
The mol ratio of described titanium alkoxide and silicon alkoxide is 1: (0.01～100).
8. finishing agent as claimed in claim 7 is characterized in that:
The mol ratio of described titanium alkoxide and water is 1: (30～100);
The mol ratio of described titanium alkoxide and organic solvent is 1: (4～10);
Described titanium alkoxide is 1 with the mol ratio of acid: (0.01～0.1);
The mol ratio of described titanium alkoxide and silicon alkoxide is 1: (1～10).
9. preparation is characterized in that as the preparation method of the anti-ultraviolet finishing agent of the described anti-pilling of one of claim 1～8 described method may further comprise the steps:
(1) the titanium alkoxide is dissolved in the organic solvent, the solution with gained adds in the acidic aqueous solution again, stirs, and obtains mixture;
(2) silicon alkoxide is joined in the mixture that step (1) obtains, stir, obtain clear solution, promptly described finishing agent;
Perhaps described method may further comprise the steps:
(1) acid, silicon alkoxide is soluble in water successively, stir, obtain mixture;
(2) the titanium alkoxide is dissolved in the organic solvent, the solution of gained joins in the mixture that obtains in the step (1), stirs, and obtains clear solution, promptly described finishing agent.
10. as the purposes of the anti-ultraviolet finishing agent of the described anti-pilling of one of claim 1～8, it is characterized in that:
Described finishing agent is used for pure cotton fabric, or the anti-pilling of the BLENDED FABRIC of chemical fibre and cotton and the arrangement of anti-ultraviolet;
Described chemical fibre is selected from least a in polyester fiber, polyamide fiber, the polypropylene fibre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010595876 CN102154829B (en) | 2010-12-20 | 2010-12-20 | Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010595876 CN102154829B (en) | 2010-12-20 | 2010-12-20 | Fuzzing, pilling and ultraviolet-prevention finishing agent and preparation method and application |
Publications (2)
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103396698A (en) * | 2013-07-19 | 2013-11-20 | 浙江理工大学 | Blue-ray curing formula and textile digital functional finishing method utilizing same |
| CN104499064A (en) * | 2014-12-22 | 2015-04-08 | 常熟市金羽纤维制品厂 | Anti-pilling shell fabric spinning method |
| CN106702718A (en) * | 2016-12-05 | 2017-05-24 | 苏州榕绿纳米科技有限公司 | Method for preparing fabric with super wearing resistance, special wettability and anti-ultraviolet function |
| CN107268269A (en) * | 2017-07-27 | 2017-10-20 | 江苏工程职业技术学院 | A kind of multi-functional crease and shrink resistant finishing liquid and preparation method thereof |
| CN107287893A (en) * | 2017-07-27 | 2017-10-24 | 江苏工程职业技术学院 | A kind of method for sorting of multi-functional cotton wash-and-wear fabrics |
| CN109235023A (en) * | 2018-08-31 | 2019-01-18 | 黄勇 | A kind of preparation method of high-affinity Anti-ultraviolet true silk textile finishing agent material |
| CN115652617A (en) * | 2022-11-15 | 2023-01-31 | 苏州联胜化学有限公司 | Anti-infrared anti-pilling agent and preparation method thereof |
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| CN1631996A (en) * | 2004-12-07 | 2005-06-29 | 中国科学院山西煤炭化学研究所 | Method for preparing silicon oxide/titanium dioxide composite oxide ultraviolet screening agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396698A (en) * | 2013-07-19 | 2013-11-20 | 浙江理工大学 | Blue-ray curing formula and textile digital functional finishing method utilizing same |
| CN104499064A (en) * | 2014-12-22 | 2015-04-08 | 常熟市金羽纤维制品厂 | Anti-pilling shell fabric spinning method |
| CN106702718A (en) * | 2016-12-05 | 2017-05-24 | 苏州榕绿纳米科技有限公司 | Method for preparing fabric with super wearing resistance, special wettability and anti-ultraviolet function |
| CN106702718B (en) * | 2016-12-05 | 2019-05-14 | 苏州榕绿纳米科技有限公司 | A kind of special wellability uvioresistant function fabric construction method of super abrasive |
| CN107268269A (en) * | 2017-07-27 | 2017-10-20 | 江苏工程职业技术学院 | A kind of multi-functional crease and shrink resistant finishing liquid and preparation method thereof |
| CN107287893A (en) * | 2017-07-27 | 2017-10-24 | 江苏工程职业技术学院 | A kind of method for sorting of multi-functional cotton wash-and-wear fabrics |
| CN107287893B (en) * | 2017-07-27 | 2019-11-26 | 江苏工程职业技术学院 | A kind of method for sorting of multi-functional cotton wash-and-wear fabrics |
| CN109235023A (en) * | 2018-08-31 | 2019-01-18 | 黄勇 | A kind of preparation method of high-affinity Anti-ultraviolet true silk textile finishing agent material |
| CN115652617A (en) * | 2022-11-15 | 2023-01-31 | 苏州联胜化学有限公司 | Anti-infrared anti-pilling agent and preparation method thereof |
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| CN102154829B (en) | 2012-11-07 |
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