CN107267048A - A kind of multifunctional building coating and preparation method thereof - Google Patents

A kind of multifunctional building coating and preparation method thereof Download PDF

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Publication number
CN107267048A
CN107267048A CN201710609899.0A CN201710609899A CN107267048A CN 107267048 A CN107267048 A CN 107267048A CN 201710609899 A CN201710609899 A CN 201710609899A CN 107267048 A CN107267048 A CN 107267048A
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CN
China
Prior art keywords
building coating
mixed
minutes
multifunctional building
preparation
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Pending
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CN201710609899.0A
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Chinese (zh)
Inventor
潘丽君
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Changzhou Yuan Zhi Hui Electronics Co Ltd
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Changzhou Yuan Zhi Hui Electronics Co Ltd
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Priority to CN201710609899.0A priority Critical patent/CN107267048A/en
Publication of CN107267048A publication Critical patent/CN107267048A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1681Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives

Abstract

The present invention relates to a kind of multifunctional building coating, thermal emissivity is formulated by a certain percentage with environment temperature in height transition material, fluorocarbon resin, polyurethane resin, water, heat preserving and insulating material, auxiliary agent and filler under normal temperature.There is coating of the present invention thermal emissivity under normal temperature to be in height transition material and heat preserving and insulating material with environment temperature, winter temperature 5 DEG C 15 DEG C of the rise on year-on-year basis in the case where not consuming the energy, used using the intersection proportioning of resin, with good elasticity and ductility, wall 0.8mm 1.2mm large fracture can be resisted, so as to keep the attractive in appearance and service life of building, while making coating that there is good resistance to soiling and self-cleaning property using the high compatible degree between auxiliary agent.

Description

A kind of multifunctional building coating and preparation method thereof
Technical field
The present invention relates to building coating field, more particularly to a kind of integrate cool in summer and warm in winter, waterproof, cracking resistance, stain resistant Multifunctional coating and preparation method thereof.
Background technology
With the development of science and technology mankind's pursuit cool in summer and warm in winter to house has been no longer a dream.Nowadays building trade at a high speed Development, the utilization of new material and new technology largely improves the function of building, and the living environment of the mankind is also increasingly relaxed It is suitable.But the most common way of constructing architecture a home from home is artificial heating cooling, this mode largely consumes precious on the earth Expensive fossil energy, also exacerbates greenhouse effects, the energy and environmental protection situation are increasingly serious while pollution environment.
Solar energy, refers to the radiation energy of the sun, has the advantages that the huge permanent, clean environment firendly of energy, it has also become the mankind make With the important component of the energy.Each too busy to get away construction material of building, and the solar absorptance of construction material and transmitting Rate directly affects the thermal environment of building.Building surface temperature at summer is made using solar reflection coating and light-coloured coating Degree has larger reduction, but the temperature of building surface equally has larger reduction when in the winter time.Selected using solar spectrum Property absorbing material, building surface temperature can in the winter time raised, but can also be raised more to the temperature of building surface during summer It is many.Both coating have certain effect in the environment of each self application to the regulation of temperature, but in winter and summer all also not Energy fully treatment and use solar energy, so can't be applied to be in have on the building of seasonal variations.So wanting thoroughly solution The problem of certainly human residential environment is cold in winter and hot in summer, mitigates environmental pollution and greenhouse effects, just must pull against existing solar energy choosing Selecting property absorbing coating is only applicable to winter, the summer of not being suitable for, and solar reflection coating and is only applicable to summer, is not suitable for The shortcoming in winter.Therefore, building comfortable architectural environment needs one kind to reflect a large amount of solar radiant heats and itself energy in summer Itself a large amount of heat of diverging, winters are converted into largely absorbing solar radiant heat and seldom launch that itself is hot and inversion temperature is adjustable Construction material, could truly realize green energy conservation.
Exterior wall tile is used in traditional habit as the decoration of exterior wall of building, but exterior wall is laid bricks easily over time Come off, not only influence attractive in appearance also to bring danger to pedestrian.Therefore, exterior wall is replaced to lay bricks increasingly by each side with exterior coating Accreditation.The external wall structure of building is limited by, outer wall material has drying shrinkage stress, easily being colded and heat succeed each other by temperature influences and ftracture out 0.8mm-1.2mm crack, has a strong impact on the outward appearance and service life of building, thus develop a kind of good adhesive force, water resistance, It is resistant to the building coating in crack highly significant.
Chinese patent CN101691469A discloses a kind of heat-insulation and heat-preservation building paint, by water, antifreezing agent, dispersant, profit Hygroscopic water powder, defoamer etc. are made, and with heat-insulating property, but function is also relatively simple.
Building coating species in addition in the market is various, but function is also relatively simple, it is impossible to take into account many of building Aspect demand, therefore exploitation one kind can make building waterproof, cracking resistance, stain resistant and energy variation with temperature warm to adjust itself The multifunctional coating of degree is necessary.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides one kind can make building waterproof, cracking resistance, stain resistant again can be with temperature The multifunctional coating of the change of degree to adjust own temperature and preparation method thereof.
In order to realize foregoing invention purpose, the present invention provides a kind of multifunctional building coating, contains following raw material:
Currently preferred multifunctional building coating contains following raw material:
One preferred multifunctional building coating of spirit of the invention contains following raw material:
Thermal emissivity is in height transition material with environment temperature under normal temperature described in multifunctional building coating raw material of the present invention It is adjustable between 0.001-0.02 scopes for the barium oxide V1-xWxO2, the X of tungstenic.
Heat preserving and insulating material refers to be made up of inorganic porous material powder described in multifunctional building coating raw material of the present invention Trickle ball particle, particle diameter range is at 10 μm -100 μm.
The invention further relates to a kind of preparation method of multifunctional building coating, comprise the following steps:
(1) it is in height transition material with environment temperature to prepare thermal emissivity under normal temperature:Commercially available ammonium bicarbonate soln and Plus the oxygen vanadium sulphate solution of pertungstic acid sodium is sufficiently mixed, sediment is obtained, then sediment is calcined in nitrogen atmosphere, it is cold with stove But to room temperature, obtaining x, thermal emissivity is changed with environment temperature in height under V1-xWxO2 normal temperature between 0.001-0.02 scopes Material;
(2) heat preserving and insulating material is prepared:Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, passed through 10 μm of -100 μm of particles of diameter are made in granule formation technology;
(3) weigh raw material by weight, fluorocarbon resin and polyurethane resin mixed, add V1-xWxO, auxiliary agent and Filler, continues to stir, is subsequently transferred to sand mill, and finally the slurry of gained is mixed with heat preserving and insulating material, obtains many Functional Architectural Coatings in China.
Sediment 700-900 DEG C of sintering temperature in nitrogen atmosphere in the step (1), roasting time 2-4 hours.
Fluorocarbon resin and polyurethane resin are mixed 5-15 minutes in the step (3), V1-xWxO, auxiliary agent is added And filler, continue to stir 40-80 minutes, sand mill is subsequently transferred to 20-60 minutes, finally the slurry and insulation of gained Material is mixed 40-80 minutes, obtains multi-functional building coating.
Sediment 800 DEG C of sintering temperature in nitrogen atmosphere, roasting time 3 hours described in the step (1).
Fluorocarbon resin and polyurethane resin are mixed 10 minutes in the step (3), add V1-xWxO, auxiliary agent with Filler, continues to stir 60 minutes, is subsequently transferred to sand mill, finally the slurry gained and heat preserving and insulating material mixing 60 Minute, obtain multi-functional building coating.
The invention has the advantages that:
1. because there is the coating of the present invention thermal emissivity under normal temperature to be in height transition material and thermal insulation separation with environment temperature Hot material, so regional Indoor environment cold in winter and hot in summer can use coating of the present invention, the winter in the case where not consuming the energy Ji Wendu 5 DEG C -15 DEG C of rises on year-on-year basis, and fluctuations in indoor temperature scope is substantially much smaller with other coating on year-on-year basis.
2. because coating of the present invention is used using the intersection proportioning of resin, the present invention has elasticity and ductility well, Wall 0.8mm-1.2mm large fracture can be resisted while good water-proof effect, so as to keep the attractive in appearance of building and use the longevity Life.
3. there is the high compatible degree between the auxiliary agent used due to coating of the present invention, coating of the present invention obvious lotus leaf to imitate Should, and with good resistance to soiling and self-cleaning property.
4. the preparation technology of coating of the present invention ensures waterproof, cracking resistance, stain resistant, the function cool in summer and warm in winter of coating.
Embodiment
Those skilled in the art can use for reference present disclosure, be suitably modified technological parameter realization.In particular, All similar replacements and change are apparent to those skilled in the art, and they are considered as being included in this hair It is bright.The method of the present invention and application are described by preferred embodiment, and related personnel can substantially not depart from this hair Method described herein and application are modified in bright content, spirit and scope or suitably change is with combining, to realize and answer Use the technology of the present invention.
The raw material that the present invention is used is all common commercially available product, can all be bought in market.
The present invention will be described in detail below, the description of this part be only it is exemplary and explanatory, should not be to the present invention Protection domain have any restriction effect.
Embodiment 1:
Thermal emissivity is in the preparation of height transition material with environment temperature under normal temperature
Commercially available ammonium bicarbonate soln and plus the oxygen vanadium sulphate solution of pertungstic acid sodium be sufficiently mixed, obtain sediment, then Sediment in nitrogen atmosphere in 800 DEG C be calcined 3 hours, cool to room temperature with the furnace, can obtain X 0.001-0.02 scopes it Between under V1-xWxO2 normal temperature thermal emissivity be in height transition material with environment temperature.
The preparation of heat preserving and insulating material
Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, diameter is made by granule formation technology 10 μm of -100 μm of particles.
The preparation of coating
After fluorocarbon resin and polyurethane resin are mixed 10 minutes, V1-xWxO and auxiliary agent are added, continues to stir 60 points Clock, is subsequently transferred to sand mill 40 minutes, and finally the slurry of gained is mixed 60 minutes with heat preserving and insulating material, obtains many Functional Architectural Coatings in China.
The multi-functional building coating parts by weight of the present embodiment are as follows:
Embodiment 2:
Thermal emissivity is in the preparation of height transition material with environment temperature under normal temperature
Commercially available ammonium bicarbonate soln and plus the oxygen vanadium sulphate solution of pertungstic acid sodium be sufficiently mixed, obtain sediment, then Sediment in nitrogen atmosphere in 700 DEG C be calcined 4 hours, cool to room temperature with the furnace, can obtain X 0.001-0.02 scopes it Between under V1-xWxO2 normal temperature thermal emissivity be in height transition material with environment temperature.
The preparation of heat preserving and insulating material
Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, diameter is made by granule formation technology 10 μm of -100 μm of particles.
The preparation of coating
After fluorocarbon resin and polyurethane resin are mixed 5 minutes, V1-xWxO and auxiliary agent are added, continues to stir 80 points Clock, is subsequently transferred to sand mill 20 minutes, and finally the slurry of gained is mixed 80 minutes with heat preserving and insulating material, obtains many Functional Architectural Coatings in China.
The multi-functional building coating parts by weight of the present embodiment are as follows:
Embodiment 3:
Thermal emissivity is in the preparation of height transition material with environment temperature under normal temperature
Commercially available ammonium bicarbonate soln and plus the oxygen vanadium sulphate solution of pertungstic acid sodium be sufficiently mixed, obtain sediment, then Sediment in nitrogen atmosphere in 900 DEG C be calcined 2 hours, cool to room temperature with the furnace, can obtain X 0.001-0.02 scopes it Between under V1-xWxO2 normal temperature thermal emissivity be in height transition material with environment temperature.
The preparation of heat preserving and insulating material
Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, diameter is made by granule formation technology 10 μm of -100 μm of particles.
The preparation of coating
After fluorocarbon resin and polyurethane resin are mixed 15 minutes, V1-xWxO and auxiliary agent are added, continues to stir 40 points Clock, is subsequently transferred to sand mill 60 minutes, and finally the slurry of gained is mixed 40 minutes with heat preserving and insulating material, obtained Multi-functional building coating.
The multi-functional building coating parts by weight of the present embodiment are as follows:
Thermal emissivity is in 30 parts of height transition material with environment temperature under normal temperature
15 parts of fluorocarbon resin
10 parts of polyurethane resin
20 parts of water
10 parts of heat preserving and insulating material
30 parts of filler
2 parts of auxiliary agent
Embodiment 4:
Thermal emissivity is in the preparation of height transition material with environment temperature under normal temperature
Commercially available ammonium bicarbonate soln and plus the oxygen vanadium sulphate solution of pertungstic acid sodium be sufficiently mixed, obtain sediment, then Sediment in nitrogen atmosphere in 800 DEG C be calcined 2 hours, cool to room temperature with the furnace, can obtain X 0.001-0.02 scopes it Between under V1-xWxO2 normal temperature thermal emissivity be in height transition material with environment temperature.
The preparation of heat preserving and insulating material
Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, diameter is made by granule formation technology 10 μm of -100 μm of particles.
The preparation of coating
After fluorocarbon resin and polyurethane resin are mixed 10 minutes, V1-xWxO and auxiliary agent are added, continues to stir 50 points Clock, is subsequently transferred to sand mill 50 minutes, and finally the slurry of gained is mixed 60 minutes with heat preserving and insulating material, obtained Multi-functional building coating.
The multi-functional building coating parts by weight of the present embodiment are as follows:
Thermal emissivity is in 15 parts of height transition material with environment temperature under normal temperature
5 parts of fluorocarbon resin
10 parts of polyurethane resin
15 parts of water
5 parts of heat preserving and insulating material
20 parts of filler
1 part of auxiliary agent
Embodiment 5:
Thermal emissivity is in the preparation of height transition material with environment temperature under normal temperature
Commercially available ammonium bicarbonate soln and plus the oxygen vanadium sulphate solution of pertungstic acid sodium be sufficiently mixed, obtain sediment, then Sediment in nitrogen atmosphere in 700 DEG C be calcined 3 hours, cool to room temperature with the furnace, can obtain X 0.001-0.02 scopes it Between under V1-xWxO2 normal temperature thermal emissivity be in height transition material with environment temperature.
The preparation of heat preserving and insulating material
Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, diameter is made by granule formation technology 10 μm of -100 μm of particles.
The preparation of coating
After fluorocarbon resin and polyurethane resin are mixed 15 minutes, V1-xWxO and auxiliary agent are added, continues to stir 60 points Clock, is subsequently transferred to sand mill 40 minutes, and finally the slurry of gained is mixed 50 minutes with heat preserving and insulating material, obtains many Functional Architectural Coatings in China.
The multi-functional building coating parts by weight of the present embodiment are as follows:
Thermal emissivity is in 30 parts of height transition material with environment temperature under normal temperature
15 parts of fluorocarbon resin
20 parts of polyurethane resin
40 parts of water
15 parts of heat preserving and insulating material
45 parts of filler
5 parts of auxiliary agent
Coating obtained by above example of the present invention, compared with commercial coating have more preferable waterproof, cracking resistance, stain resistant, Function cool in summer and warm in winter.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (10)

1. a kind of multifunctional building coating, it is characterised in that contain following raw material:
2. multifunctional building coating according to claim 1, it is characterised in that contain following raw material:
3. multifunctional building coating according to claim 1, it is characterised in that contain following raw material:
4. according to any described multifunctional building coating of claims 1 to 3, it is characterised in that:Thermal emissivity under the normal temperature Can between 0.001-0.02 scopes for the barium oxide V1-xWxO2, the X of tungstenic in height transition material with environment temperature Adjust.
5. according to any described multifunctional building coating of claims 1 to 3, it is characterised in that:The heat preserving and insulating material is Refer to the trickle ball particle being made up of inorganic porous material powder, particle diameter range is at 10 μm -100 μm.
6. a kind of preparation method of multifunctional building coating, it is characterised in that comprise the following steps:
(1) it is in height transition material with environment temperature to prepare thermal emissivity under normal temperature:Commercially available ammonium bicarbonate soln and adding The oxygen vanadium sulphate solution of sodium tungstate is sufficiently mixed, and obtains sediment, then sediment is calcined in nitrogen atmosphere, is cooled to the furnace Room temperature, obtaining x, thermal emissivity is in height transition material with environment temperature under V1-xWxO2 normal temperature between 0.001-0.02 scopes;
(2) heat preserving and insulating material is prepared:Commercially available inorganic porous material powder and aqueous polyurethane glue are mixed, pass through particle 10 μm of -100 μm of particles of diameter are made in moulding process;
(3) raw material is weighed by weight, fluorocarbon resin and polyurethane resin are mixed, V1-xWxO is added, and auxiliary agent and is filled out Material, continues to stir, is subsequently transferred to sand mill, and finally the slurry of gained is mixed with heat preserving and insulating material, many work(are obtained Can property building coating.
7. the preparation method of multifunctional building coating according to claim 6, it is characterised in that sediment in the step (1) 700-900 DEG C of sintering temperature in nitrogen atmosphere, roasting time 2-4 hours.
8. the preparation method of multifunctional building coating according to claim 6, it is characterised in that fluorine carbon in the step (3) Resin and polyurethane resin are mixed 5-15 minutes, add V1-xWxO, auxiliary agent and filler, continue to stir 40-80 minutes, with After be transferred to sand mill 20-60 minutes, finally the slurry of gained is mixed 40-80 minutes with heat preserving and insulating material, obtained Multi-functional building coating.
9. the preparation method of multifunctional building coating according to claim 7, it is characterised in that sunk described in the step (1) Starch 800 DEG C of sintering temperature in nitrogen atmosphere, roasting time 3 hours.
10. the preparation method of multifunctional building coating according to claim 9, it is characterised in that fluorine in the step (3) Carbon resin and polyurethane resin are mixed 10 minutes, add V1-xWxO, auxiliary agent and filler, are continued to stir 60 minutes, are then turned Sand mill is moved to, finally the slurry of gained is mixed 60 minutes with heat preserving and insulating material, multi-functional building coating is obtained.
CN201710609899.0A 2017-07-25 2017-07-25 A kind of multifunctional building coating and preparation method thereof Pending CN107267048A (en)

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Application Number Priority Date Filing Date Title
CN201710609899.0A CN107267048A (en) 2017-07-25 2017-07-25 A kind of multifunctional building coating and preparation method thereof

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Publication Number Publication Date
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1389523A (en) * 2001-06-05 2003-01-08 同济大学 'Air conditioning' building paint
CN1837061A (en) * 2006-03-06 2006-09-27 复旦大学 Phase-transition intelligent materials with adjustable phase-transition temperature and process for preparing same
CN101768382A (en) * 2009-12-29 2010-07-07 同济大学 High-performance air-conditioning type building coating
CN103147278A (en) * 2013-03-11 2013-06-12 东华大学 Temperature-regulating intelligent tent fabric and preparation method thereof
CN106118307A (en) * 2016-07-05 2016-11-16 马承银 A kind of building coating with heat-insulation and heat-preservation function and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1389523A (en) * 2001-06-05 2003-01-08 同济大学 'Air conditioning' building paint
CN1837061A (en) * 2006-03-06 2006-09-27 复旦大学 Phase-transition intelligent materials with adjustable phase-transition temperature and process for preparing same
CN101768382A (en) * 2009-12-29 2010-07-07 同济大学 High-performance air-conditioning type building coating
CN103147278A (en) * 2013-03-11 2013-06-12 东华大学 Temperature-regulating intelligent tent fabric and preparation method thereof
CN106118307A (en) * 2016-07-05 2016-11-16 马承银 A kind of building coating with heat-insulation and heat-preservation function and preparation method thereof

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