CN107267008A - A kind of three-dimensional heat preservation and soundproof composite board material and preparation method - Google Patents
A kind of three-dimensional heat preservation and soundproof composite board material and preparation method Download PDFInfo
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- CN107267008A CN107267008A CN201710495169.2A CN201710495169A CN107267008A CN 107267008 A CN107267008 A CN 107267008A CN 201710495169 A CN201710495169 A CN 201710495169A CN 107267008 A CN107267008 A CN 107267008A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/108—Rockwool fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/10—Properties of the layers or laminate having particular acoustical properties
- B32B2307/102—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of three-dimensional heat preservation and soundproof composite board material and preparation method.In the present invention：Raw material including following weight parts：Silicone acrylic emulsion 55 60, water-base fluorocarbon emulsion 15 20, thermosetting phenolic resin 0.8 1.0, hollow ceramic particle 15 20；Polyester fiber 55 60, butyl rubber 15 20, aqua type adhesive 8 10；Mineral rock wool 65 70, animal collagen 35, synthetic resin 23, neoprene 57, modified nitrolacquer 12 15.The present invention is to adding water-base fluorocarbon emulsion, hollow ceramic particle in the insulation material of three-dimensional composite plate, the insulation that three composite plates are carried out with surface is operated, and water-base fluorocarbon emulsion is free of formaldehyde and any heavy metal, does not have any infringement to human body.To adding polyester fiber, butyl rubber in the acoustic material of three-dimensional composite board material, polyester fiber, butyl rubber effectively absorb echo and vibrations.Mineral rock wool is used to three-dimensional composite board material so that the supportive of whole three-dimensional composite plate is improved, and effectively enhances the resistance to compression effect of three-dimensional composite plate.
Description
Technical field
The invention belongs to three-dimensional composite material field, more particularly to a kind of three-dimensional heat preservation and soundproof composite board material and preparation
Method.
Background technology
Composite be by inorganic material, organic material, ceramic material or high polymer material etc. two or more
The heterogeneous material that material is prepared by combination process, various materials make up for each other's deficiencies and learn from each other in performance, produce cooperative effect, make
The combination property of composite is better than former composition material and meets a variety of requirements.
With the lifting of Three-dimension process production technology, composite is towards structure multiplex, the side of function diversification
To development, in the use environment of many three-dimensional composite materials, many severe condition elements are there are, more noise, environment
The quick change of temperature, external pressure, the change of wind-force etc., are all the key factors that the three-dimensional composite plate of influence uses process；
In addition, three composite plates can also be used in the more environment of personnel, injury of the reduction composite to human body is also to need solution
Certainly the problem of, while also to improve the soundproof effect and pressure-resistant degree of three-dimensional composite plate.
The content of the invention
It is an object of the invention to provide a kind of three-dimensional heat preservation and soundproof composite board material and preparation method, pass through, so as to
Enough supportives for causing whole three-dimensional composite plate are improved, and effectively enhance the resistance to compression effect of three-dimensional composite plate.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions：
The present invention is a kind of three-dimensional heat preservation and soundproof composite board material, and it includes the raw material of following weight parts：Silicone acrylic emulsion 55-
60th, water-base fluorocarbon emulsion 15-20, thermosetting phenolic resin 0.8-1.0, hollow ceramic particle 15-20；Polyester fiber 55-60, fourth
Base rubber 15-20, aqua type adhesive 8-10；Mineral rock wool 65-70, animal collagen 3-5, synthetic resin 2-3, neoprene 5-
7th, modified nitrolacquer 12-15.
A kind of preparation method of three-dimensional heat preservation and soundproof composite board material：
Hollow ceramic particle is added in silicone acrylic emulsion, the mixed liquor of water-base fluorocarbon emulsion, is sufficiently stirred for 15-25 minutes,
Add thermosetting phenolic resin to be solidified, complete the preparation of heat-insulation layer；The extexine of polyester fiber is subjected to cleaning operation,
Add aqua type adhesive again, graininess butyl rubber be finally uniformly laid on to the outside of aqua type adhesive, complete every
The preparation of sound-absorbing layer；Animal collagen, synthetic resin, neoprene are well mixed, are added into mineral rock wool, and by modified nitrocellulose
Paint is sprayed on the top layer of mineral rock wool, completes the preparation of resistance to compression layer.
Wherein, the preparation method of silicone acrylic emulsion：It will be added in the polymer of organosilicon and acrylic compounds appropriate aqueous molten
Agent, then be polymerized by nucleocapsid cladding polymerization technique.
Wherein, the preparation method of water-base fluorocarbon emulsion：Esters of acrylic acid, fluororesin copolymer are mixed, added in right amount
Warm water, and the temperature of 40-45 degree is kept, by the stirring of 1.5-2.2 hours, backflow, you can obtain water-base fluorocarbon emulsion.
Wherein, the preparation method of thermosetting phenolic resin：After excessive formaldehyde is uniformly mixed with appropriate phenol, add
Appropriate NH4OH, NaOH or Na2CO3Base catalyst, keeps 20-25 degree temperature, that is, generates thermosetting phenolic resin.
Wherein, the preparation method of mineral rock wool：Basalt and other natural crystals are carried out after crushing operation, through too high
Warm stove high-temperature fusion is into fibre, and cured machine is interior to add appropriate binding agent, completes solidification processing, generation mineral rock wool.
Wherein, the preparation method of modified nitrolacquer：By appropriate alkyd resin, modified rosin resin, acrylic resin, amino
Resin is mixed with nitrocotton, then adds dibutyl phthalate, dioctyl ester, blown castor oil to carrying out plasticizing operation,
Recycle ketone, alcohol ethers solvent to carry out instant, the preparation of modified nitrolacquer is finally completed using diluents such as benzene classes.
The invention has the advantages that：
1st, the present invention is to adding water-base fluorocarbon emulsion, hollow ceramic particle in the insulation material of three-dimensional composite plate, to three
Position composite plate carries out the insulation operation on surface, and water-base fluorocarbon emulsion is free of formaldehyde and any heavy metal, does not have any damage to human body
Evil, and water-base fluorocarbon emulsion coating is wear-resistant, and the life-span is 2-3 times of common coating.
2nd, to adding polyester fiber, butyl rubber, polyester fiber, butyl rubber in the acoustic material of three-dimensional composite board material
Echo and vibrations effectively are absorbed, the soundproof effect of three composite plates is improved.
3rd, mineral rock wool is used to three-dimensional composite board material so that the supportive of whole three-dimensional composite plate is improved, and is had
The resistance to compression effect for enhancing three-dimensional composite plate of effect.
Certainly, any product for implementing the present invention it is not absolutely required to while reaching all the above advantage.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, used required for being described below to embodiment
Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for ability
For the those of ordinary skill of domain, on the premise of not paying creative work, it can also be obtained according to these accompanying drawings other attached
Figure.
Fig. 1 is integral material structural representation of the invention；
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is all other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Refer to shown in accompanying drawing, the present invention is a kind of three-dimensional heat preservation and soundproof composite board material and preparation method, under it includes
State the raw material of parts by weight：Silicone acrylic emulsion 55-60, water-base fluorocarbon emulsion 15-20, thermosetting phenolic resin 0.8-1.0, hollow ceramic
Particle 15-20；Polyester fiber 55-60, butyl rubber 15-20, aqua type adhesive 8-10；Mineral rock wool 65-70, animal collagen
3-5, synthetic resin 2-3, neoprene 5-7, modified nitrolacquer 12-15.
A kind of preparation method of three-dimensional heat preservation and soundproof composite board material：
Hollow ceramic particle is added in silicone acrylic emulsion, the mixed liquor of water-base fluorocarbon emulsion, is sufficiently stirred for 15-25 minutes,
Add thermosetting phenolic resin to be solidified, complete the preparation of heat-insulation layer；The extexine of polyester fiber is subjected to cleaning operation,
Add aqua type adhesive again, graininess butyl rubber be finally uniformly laid on to the outside of aqua type adhesive, complete every
The preparation of sound-absorbing layer；Animal collagen, synthetic resin, neoprene are well mixed, are added into mineral rock wool, and by modified nitrocellulose
Paint is sprayed on the top layer of mineral rock wool, completes the preparation of resistance to compression layer
Wherein, the preparation method of silicone acrylic emulsion：It will be added in the polymer of organosilicon and acrylic compounds appropriate aqueous molten
Agent, then be polymerized by nucleocapsid cladding polymerization technique.
Wherein, the preparation method of water-base fluorocarbon emulsion：Esters of acrylic acid, fluororesin copolymer are mixed, added in right amount
Warm water, and the temperature of 40-45 degree is kept, by the stirring of 1.5-2.2 hours, backflow, you can obtain water-base fluorocarbon emulsion.
Wherein, the preparation method of thermosetting phenolic resin：After excessive formaldehyde is uniformly mixed with appropriate phenol, add
Appropriate NH4OH, NaOH or Na2CO3Base catalyst, keeps 20-25 degree temperature, that is, generates thermosetting phenolic resin.
Wherein, the preparation method of mineral rock wool：Basalt and other natural crystals are carried out after crushing operation, through too high
Warm stove high-temperature fusion is into fibre, and cured machine is interior to add appropriate binding agent, completes solidification processing, generation mineral rock wool.
Wherein, the preparation method of modified nitrolacquer：By appropriate alkyd resin, modified rosin resin, acrylic resin, amino
Resin is mixed with nitrocotton, then adds dibutyl phthalate, dioctyl ester, blown castor oil to carrying out plasticizing operation,
Recycle ketone, alcohol ethers solvent to carry out instant, the preparation of modified nitrolacquer is finally completed using diluents such as benzene classes.
Further explain and explanation：
Silicone acrylic emulsion has water-fast, acidproof, alkaline-resisting, dirt-resistant, is made up of pure third silicon, film not yellowing, UV resistant, resists
Aging, silicone acrylic emulsion formation glued membrane it is fine and close, tough and tensile, hardness is high, water whitening resistance good.
Water-base fluorocarbon emulsion, as the main filmogen of aqueous fluorocarbon coating, with excellent weatherability, water resistance,
Stain resistance, chemical-resistant, it is similar with solvent-based fluorocarbon resin.It is eager to excel very than other conventional acrylic water-based emulsion performances
It is many, and without organic solvent, therefore it is safe from harm to human body, and environment is not polluted.
Thermosetting phenolic resin is in preparation process：Under the conditions of base catalyst, the PH of reaction medium is more than 7, phenol and
Formaldehyde occurs addition reaction and generates a hydroxymethylphenol first, in the case where keeping room temperature condition, and the phenolic alcohol in alkaline medium is stable
, the reaction speed of the hydrogen on methylol and phenol in a hydroxymethylphenol is than the hydrogen on the ortho position and contraposition of formaldehyde and phenol
Reaction speed it is slow, therefore a hydroxymethylphenol is not easy further polycondensation, can be only generated hydroxymethyl-phenol and trihydroxy methyl
Phenol.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
At least one implementation of the present invention is contained in reference to specific features, structure, material or the feature that the embodiment or example are described
In example or example.In this manual, identical embodiment or example are not necessarily referring to the schematic representation of above-mentioned term.
Moreover, specific features, structure, material or the feature of description can be closed in any one or more embodiments or example
Suitable mode is combined.
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed
All details of narration, it is only described embodiment that the invention is not limited yet.Obviously, according to the content of this specification,
It can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention
Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and its four corner and equivalent.
Claims (7)
1. a kind of three-dimensional heat preservation and soundproof composite board material, it is characterised in that it includes the raw material of following weight parts：
Silicone acrylic emulsion 55-60, water-base fluorocarbon emulsion 15-20, thermosetting phenolic resin 0.8-1.0, hollow ceramic particle 15-20；
Polyester fiber 55-60, butyl rubber 15-20, aqua type adhesive 8-10；
Mineral rock wool 65-70, animal collagen 3-5, synthetic resin 2-3, neoprene 5-7, modified nitrolacquer 12-15.
2. a kind of preparation method of three-dimensional heat preservation and soundproof composite board material, it is characterised in that：
Hollow ceramic particle is added in silicone acrylic emulsion, the mixed liquor of water-base fluorocarbon emulsion, is sufficiently stirred for 15-25 minutes, then is added
Enter thermosetting phenolic resin to be solidified, complete the preparation of heat-insulation layer；
The extexine of polyester fiber is subjected to cleaning operation, then adds aqua type adhesive, it is finally that graininess butyl rubber is equal
The even outside for being laid on aqua type adhesive, completes the preparation of puigging；
Animal collagen, synthetic resin, neoprene are well mixed, are added into mineral rock wool, and modified nitrolacquer is sprayed
On the top layer of mineral rock wool, the preparation of resistance to compression layer is completed.
3. the preparation method of a kind of three-dimensional heat preservation and soundproof composite board material according to claim 2, it is characterised in that described
The preparation method of silicone acrylic emulsion：Appropriate aqueous solvent will be added in the polymer of organosilicon and acrylic compounds, then pass through nucleocapsid
Cladding polymerization technique is polymerized.
4. the preparation method of a kind of three-dimensional heat preservation and soundproof composite board material according to claim 2, it is characterised in that described
The preparation method of water-base fluorocarbon emulsion：Esters of acrylic acid, fluororesin copolymer are mixed, appropriate warm water is added, and keep 40-
45 degree of temperature, by the stirring of 1.5-2.2 hours, backflow, you can obtain water-base fluorocarbon emulsion.
5. the preparation method of a kind of three-dimensional heat preservation and soundproof composite board material according to claim 2, it is characterised in that described
The preparation method of thermosetting phenolic resin：After excessive formaldehyde is uniformly mixed with appropriate phenol, appropriate NH is added4OH、
NaOH or Na2CO3Base catalyst, keeps 20-25 degree temperature, that is, generates thermosetting phenolic resin.
6. the preparation method of a kind of three-dimensional heat preservation and soundproof composite board material according to claim 2, it is characterised in that described
The preparation method of mineral rock wool：Basalt and other natural crystals are carried out after crushing operation, by high temperature furnace high-temperature fusion
Into fibre, appropriate binding agent is added in cured machine, solidification processing is completed, generates mineral rock wool.
7. the preparation method of a kind of three-dimensional heat preservation and soundproof composite board material according to claim 2, it is characterised in that described
The preparation method of modified nitrolacquer：By appropriate alkyd resin, modified rosin resin, acrylic resin, amino resins and nitrocotton
Mixed, then add dibutyl phthalate, dioctyl ester, blown castor oil to carrying out plasticizing operation, recycle ketone, alcohol
Ether solvent progress is instant, and the preparation of modified nitrolacquer is finally completed using diluents such as benzene classes.
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| CN201710495169.2A CN107267008B (en) | 2017-06-26 | 2017-06-26 | A kind of three-dimensional heat preservation and soundproof composite board material and preparation method |
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| CN201710495169.2A CN107267008B (en) | 2017-06-26 | 2017-06-26 | A kind of three-dimensional heat preservation and soundproof composite board material and preparation method |
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| CN107267008B CN107267008B (en) | 2019-10-15 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815071A (en) * | 2017-11-22 | 2018-03-20 | 马鞍山松鹤信息科技有限公司 | One kind insulation special environment protection material and preparation method thereof |
| CN108485449A (en) * | 2018-02-08 | 2018-09-04 | 广州美的华凌冰箱有限公司 | Heat-insulation material and refrigeration equipment |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106746992A (en) * | 2016-12-16 | 2017-05-31 | 南京倍立达新材料系统工程股份有限公司 | A kind of cement heat preserving wallboard |
-
2017
- 2017-06-26 CN CN201710495169.2A patent/CN107267008B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106746992A (en) * | 2016-12-16 | 2017-05-31 | 南京倍立达新材料系统工程股份有限公司 | A kind of cement heat preserving wallboard |
Non-Patent Citations (1)
| Title |
|---|
| 邹振戊: "《实用新编五金手册》", 31 January 2015, 辽宁科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815071A (en) * | 2017-11-22 | 2018-03-20 | 马鞍山松鹤信息科技有限公司 | One kind insulation special environment protection material and preparation method thereof |
| CN108485449A (en) * | 2018-02-08 | 2018-09-04 | 广州美的华凌冰箱有限公司 | Heat-insulation material and refrigeration equipment |
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| Publication number | Publication date |
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| CN107267008B (en) | 2019-10-15 |
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