CN107266815A - A kind of heat-resistant fireproof cable material - Google Patents
A kind of heat-resistant fireproof cable material Download PDFInfo
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- CN107266815A CN107266815A CN201710520670.XA CN201710520670A CN107266815A CN 107266815 A CN107266815 A CN 107266815A CN 201710520670 A CN201710520670 A CN 201710520670A CN 107266815 A CN107266815 A CN 107266815A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of heat-resistant fireproof cable material, it is made up of the component of following parts by weight：20~30 parts of Corvic, 20~30 parts of ethylene propylene diene rubber, 20~30 parts of silicon rubber, 10~20 parts of hydrogenated nitrile-butadiene rubber, 14~18 parts of modified nano concave good soil, 2~4 parts of carbon black, 4~6 parts of calcium carbonate, 15~20 parts of APP, 5~10 parts of melamine, 2~4 parts of pentaerythrite, 0.5~2 part of expanded vermiculite, 2~5 parts of zinc oxide, 1~3 part of stearic acid, 1~3 part of cumyl peroxide, 1~3 part of dimethicone, 1~2 part of stabilizer, 3~5 parts of antioxidant 1010.The present invention is using Corvic, ethylene propylene diene rubber, silicon rubber, hydrogenated nitrile-butadiene rubber as base material, and rationally, good processability, stability is excellent, while using Compound intumescent flame retardant, fire resistant flame retardant effect is extremely excellent, and Halogen, asepsis environment-protecting for compatibility.
Description
Technical field
The invention belongs to cable material technical field, and in particular to a kind of heat-resistant fireproof cable material.
Background technology
Cable is by this section of system in power system from step-down distribution substation exit to user terminal.In transmission line of electricity
The big multi rack of cable is answered between two electric poles, and mostly exposed to outdoor therefore high to the performance requirement of cable material
This possesses preferable mechanical performance and flame-resistant insulation performance.
As economic develops rapidly, electric wire is widely used in industry-by-industry, field, with electric
The frequent generation of fire incident, the fire-retardant problem of electric wire gradually causes the attention of countries in the world, is discharged during cable fire
A large amount of smog and poisonous, corrosive gas are hazards in fire, hamper in a fire people safe escape and
Fire-fighting work, makes lives and properties by heavy losses, while with the development of communication career, auto industry and computer industry,
Many occasions such as wire particularly peculiar to vessel, line for cars, high temperature instrument cable, oil drilling platform cable, fire resistant screen
It is also essential to cover CABLE MATERIALS.
The content of the invention
It is an object of the invention to provide a kind of heat-resistant fireproof cable material, material heat-resistant fireproof is functional, burning
Discharged afterwards without noxious material.
To achieve these goals, the present invention is adopted the following technical scheme that：A kind of heat-resistant fireproof cable material, by following
The component composition of parts by weight：20~30 parts of Corvic, 20~30 parts of ethylene propylene diene rubber, 20~30 parts of silicon rubber, hydrogen
Change 10~20 parts of nitrile rubber, 14~18 parts of modified nano concave good soil, 2~4 parts of carbon black, 4~6 parts of calcium carbonate, APP
15~20 parts, 5~10 parts of melamine, 2~4 parts of pentaerythrite, 0.5~2 part of expanded vermiculite, 2~5 parts of zinc oxide, stearic acid 1
~3 parts, 1~3 part of cumyl peroxide, 1~3 part of dimethicone, 1~2 part of stabilizer, 3~5 parts of antioxidant 1010.
It is preferred that, described heat-resistant fireproof cable material is made up of the component of following parts by weight：Corvic 25
Part, 26 parts of ethylene propylene diene rubber, 23 parts of silicon rubber, 15 parts of hydrogenated nitrile-butadiene rubber, 16 parts of modified nano concave good soil, 3 parts of carbon black,
5 parts of calcium carbonate, 16 parts of APP, 8 parts of melamine, 3 parts of pentaerythrite, 1 part of expanded vermiculite, 3 parts of zinc oxide, stearic acid 2
Part, 2 parts of cumyl peroxide, 2 parts of dimethicone, 1.5 parts of stabilizer, 4 parts of antioxidant 1010.
It is preferred that, the modified nano concave good soil is silane coupler modified nano-attapulgite.
It is preferred that, the silane coupler in the silane coupler modified nano-attapulgite is the ethoxy of γ-aminopropyl three
One kind in base silane, γ-aminopropyltrimethoxysilane.
It is preferred that, the APP is high polymerization degree APP after Overheating Treatment, the APP it is poly-
Right is 1500.
The preparation method of above-mentioned cable material comprises the following steps：
(1) processing is modified to nano-attapulgite first, silane coupler is dissolved in absolute ethyl alcohol and is made necessarily
The solution of concentration, adds nano-attapulgite and stirs and heat, and is fully cooled to room temperature, high speed centrifugation, washing, baking after reaction
It is dry, modified nano concave good soil is produced after crushing；
(2) banbury temperature is adjusted to 80-85 DEG C, preheating time is 15-20min, by the polyvinyl chloride of corresponding parts by weight
Resin, ethylene propylene diene rubber, silicon rubber, hydrogenated nitrile-butadiene rubber are added in the banbury that preheating is completed, and open agitating device,
It is stirred in the way of stirring is intersected clockwise and anticlockwise, while raising temperature to 100-120 DEG C, stirs above-mentioned material
10-20min is mixed, major ingredient is obtained：
(3) banbury temperature is kept at 100-120 DEG C, and adds into the banbury containing above-mentioned major ingredient corresponding parts by weight
Modified nano concave good soil, carbon black, calcium carbonate, APP, melamine part, pentaerythrite, expanded vermiculite, zinc oxide,
Stearic acid, continues to stir 15-20min；
(4) after the temperature in banbury is warming up to 145-160 DEG C, the peroxidating diisopropyl of corresponding parts by weight is added
Benzene, dimethicone, stabilizer, antioxidant 1010, and continue to stir 20-25min, obtain homogeneous mixture；
(5) said mixture is put into the charging aperture of single screw extrusion machine, and squeezed at a temperature of 70-80 DEG C from discharging opening
Go out, produce heat-resistant fireproof cable material.
The present invention uses the high polymerization degree APP after Overheating Treatment (degree of polymerization is 1500), its heat endurance
Good, persistently, nontoxic suppression cigarette belongs to phosphorus flame retardant to fire resistance.Melamine is a kind of conventional nitrogenated flame retardant, nitrogenous resistance
The non-flammable compressive gases such as the heated releasing carbon dioxide of agent, nitrogen, ammonia are fired, this based flame retardant also acts as other fire retardants such as phosphorus system and hindered
The synergist of agent is fired, foaming agent is used as in phosphorus-nitrogen collaboration system.The addition of pentaerythrite, can shape with phosphorus system, nitrogenated flame retardant
Into expansion type flame retardant.Vermiculite is a kind of natural, inorganic, nontoxic mineral matter, can be expanded under high temperature action.Add intumescent
Can form one layer of uniform carbonaceous froth bed during the polymer combustion of fire retardant on the surface, this layer of charcoal condensed phase can play every
Heat, oxygen barrier, the effect for pressing down cigarette and anti-molten drop.
The present invention is using Corvic, ethylene propylene diene rubber, silicon rubber, hydrogenated nitrile-butadiene rubber as base material, and compatibility is reasonable,
Good processability, stability is excellent, while using Compound intumescent flame retardant, fire resistant flame retardant effect is extremely excellent, and Halogen,
Asepsis environment-protecting；Cable material low raw-material cost of the present invention, it is thermally-stabilised good, and cable has high temperature resistant and good fire resistant flame retardant
Performance.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
A kind of heat-resistant fireproof cable material, is made up of the component of following parts by weight：25 parts of Corvic, ternary second
Third 26 parts of rubber, 23 parts of silicon rubber, 15 parts of hydrogenated nitrile-butadiene rubber, 16 parts of silane coupler modified nano-attapulgite, carbon black 3
Part, 5 parts of calcium carbonate, 16 parts of APP, 8 parts of melamine, 3 parts of pentaerythrite, 1 part of expanded vermiculite, 3 parts of zinc oxide, tristearin
2 parts of acid, 2 parts of cumyl peroxide, 2 parts of dimethicone, 1.5 parts of stabilizer, 4 parts of antioxidant 1010.
The preparation method of above-mentioned cable material comprises the following steps：
(1) processing is modified to nano-attapulgite first, γ-aminopropyltrimethoxysilane is dissolved in absolute ethyl alcohol
In be made certain density solution, add nano-attapulgite and stir and heat, room temperature is cooled to after fully reacting, at a high speed from
Silane coupler modified nano-attapulgite is produced after the heart, washing, drying, crushing；
(2) banbury temperature is adjusted to 80-85 DEG C, preheating time is 15-20min, by the polyvinyl chloride of corresponding parts by weight
Resin, ethylene propylene diene rubber, silicon rubber, hydrogenated nitrile-butadiene rubber are added in the banbury that preheating is completed, and open agitating device,
It is stirred in the way of stirring is intersected clockwise and anticlockwise, while raising temperature to 100-120 DEG C, stirs above-mentioned material
10-20min is mixed, major ingredient is obtained：
(3) banbury temperature is kept at 100-120 DEG C, and adds into the banbury containing above-mentioned major ingredient corresponding parts by weight
Modified nano concave good soil, carbon black, calcium carbonate, APP, melamine part, pentaerythrite, expanded vermiculite, zinc oxide,
Stearic acid, continues to stir 15-20min；
(4) after the temperature in banbury is warming up to 145-160 DEG C, the peroxidating diisopropyl of corresponding parts by weight is added
Benzene, dimethicone, stabilizer, antioxidant 1010, and continue to stir 20-25min, obtain homogeneous mixture；
(5) said mixture is put into the charging aperture of single screw extrusion machine, and squeezed at a temperature of 70-80 DEG C from discharging opening
Go out, produce heat-resistant fireproof cable material.
Embodiment 2
A kind of heat-resistant fireproof cable material, is made up of the component of following parts by weight：20 parts of Corvic, ternary second
Third 20 parts of rubber, 20 parts of silicon rubber, 10 parts of hydrogenated nitrile-butadiene rubber, 14 parts of silane coupler modified nano-attapulgite, carbon black 2
It is part, 4 parts of calcium carbonate, 15 parts of APP, 5 parts of melamine, 2 parts of pentaerythrite, 0.5 part of expanded vermiculite, 2 parts of zinc oxide, hard
1 part of resin acid, 1 part of cumyl peroxide, 1 part of dimethicone, 1 part of stabilizer, 3 parts of antioxidant 1010.
The preparation method of above-mentioned cable material comprises the following steps：
(1) processing is modified to nano-attapulgite first, gamma-aminopropyl-triethoxy-silane is dissolved in absolute ethyl alcohol
In be made certain density solution, add nano-attapulgite and stir and heat, room temperature is cooled to after fully reacting, at a high speed from
Silane coupler modified nano-attapulgite is produced after the heart, washing, drying, crushing；
(2) banbury temperature is adjusted to 80-85 DEG C, preheating time is 15-20min, by the polyvinyl chloride of corresponding parts by weight
Resin, ethylene propylene diene rubber, silicon rubber, hydrogenated nitrile-butadiene rubber are added in the banbury that preheating is completed, and open agitating device,
It is stirred in the way of stirring is intersected clockwise and anticlockwise, while raising temperature to 100-120 DEG C, stirs above-mentioned material
10-20min is mixed, major ingredient is obtained：
(3) banbury temperature is kept at 100-120 DEG C, and adds into the banbury containing above-mentioned major ingredient corresponding parts by weight
Modified nano concave good soil, carbon black, calcium carbonate, APP, melamine part, pentaerythrite, expanded vermiculite, zinc oxide,
Stearic acid, continues to stir 15-20min；
(4) after the temperature in banbury is warming up to 145-160 DEG C, the peroxidating diisopropyl of corresponding parts by weight is added
Benzene, dimethicone, stabilizer, antioxidant 1010, and continue to stir 20-25min, obtain homogeneous mixture；
(5) said mixture is put into the charging aperture of single screw extrusion machine, and squeezed at a temperature of 70-80 DEG C from discharging opening
Go out, produce heat-resistant fireproof cable material.
Embodiment 3
A kind of heat-resistant fireproof cable material, 30 parts of Corvic, 30 parts of ethylene propylene diene rubber, 30 parts of silicon rubber,
20 parts of hydrogenated nitrile-butadiene rubber, 18 parts of silane coupler modified nano-attapulgite, 4 parts of carbon black, 6 parts of calcium carbonate, APP 20
Part, 10 parts of melamine, 4 parts of pentaerythrite, 2 parts of expanded vermiculite, 5 parts of zinc oxide, 3 parts of stearic acid, cumyl peroxide 3
Part, 3 parts of dimethicone, 2 parts of stabilizer, 5 parts of antioxidant 1010.
Its preparation method be the same as Example 1.
Claims (5)
1. a kind of heat-resistant fireproof cable material, it is characterised in that be made up of the component of following parts by weight：Corvic 20
~30 parts, 20~30 parts of ethylene propylene diene rubber, 20~30 parts of silicon rubber, 10~20 parts of hydrogenated nitrile-butadiene rubber, modified Nano it is concavo-convex
14~18 parts of rod soil, 2~4 parts of carbon black, 4~6 parts of calcium carbonate, 15~20 parts of APP, 5~10 parts of melamine, Ji Wusi
2~4 parts of alcohol, 0.5~2 part of expanded vermiculite, 2~5 parts of zinc oxide, 1~3 part of stearic acid, 1~3 part of cumyl peroxide, diformazan
1~3 part of base silicone oil, 1~2 part of stabilizer, 3~5 parts of antioxidant 1010.
2. a kind of heat-resistant fireproof cable material according to claim 1, it is characterised in that by the component of following parts by weight
Composition：25 parts of Corvic, 26 parts of ethylene propylene diene rubber, 23 parts of silicon rubber, 15 parts of hydrogenated nitrile-butadiene rubber, modified Nano are recessed
Convex 16 parts of rod soil, 3 parts of carbon black, 5 parts of calcium carbonate, 16 parts of APP, 8 parts of melamine, 3 parts of pentaerythrite, expanded vermiculite 1
Part, 3 parts of zinc oxide, 2 parts of stearic acid, 2 parts of cumyl peroxide, 2 parts of dimethicone, 1.5 parts of stabilizer, antioxidant
10104 parts.
3. a kind of heat-resistant fireproof cable material according to claim 1 or 2, it is characterised in that the modified Nano is recessed
Convex rod soil is silane coupler modified nano-attapulgite.
4. a kind of heat-resistant fireproof cable material according to claim 3, it is characterised in that described silane coupler modified
Silane coupler in nano-attapulgite is one in gamma-aminopropyl-triethoxy-silane, γ-aminopropyltrimethoxysilane
Kind.
5. a kind of heat-resistant fireproof cable material according to claim 1 or 2, it is characterised in that the APP is
High polymerization degree APP after Overheating Treatment, the degree of polymerization of the APP is 1500.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710520670.XA CN107266815A (en) | 2017-06-30 | 2017-06-30 | A kind of heat-resistant fireproof cable material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710520670.XA CN107266815A (en) | 2017-06-30 | 2017-06-30 | A kind of heat-resistant fireproof cable material |
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| CN107266815A true CN107266815A (en) | 2017-10-20 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556667A (en) * | 2017-10-23 | 2018-01-09 | 徐州市新大电缆有限公司 | A kind of heat-resistant fireproof reliability power cable material |
| CN108546025A (en) * | 2018-06-28 | 2018-09-18 | 江苏百瑞吉新材料有限公司 | A kind of gunite concrete and its production method of high tenacity |
| CN108690293A (en) * | 2018-06-15 | 2018-10-23 | 浙江威思康塑胶有限公司 | A kind of high-low temperature resistant high strength PVC cable material |
| CN108752795A (en) * | 2018-06-15 | 2018-11-06 | 浙江威思康塑胶有限公司 | A kind of preparation process of high-low temperature resistant high strength PVC cable material |
| CN110105690A (en) * | 2019-05-17 | 2019-08-09 | 天长市富达电子有限公司 | A kind of high tenacity cold-resistant electric wire protective materials and preparation method thereof |
| CN111670225A (en) * | 2018-03-22 | 2020-09-15 | 株式会社藤仓 | Flame-retardant resin composition, and insulated wire, cable and optical fiber cable using same |
| CN112143452A (en) * | 2020-10-21 | 2020-12-29 | 南京信息工程大学 | Organic high-temperature-resistant packaging adhesive and preparation method thereof |
| CN114149645A (en) * | 2021-11-25 | 2022-03-08 | 浙江亚厦装饰股份有限公司 | Fireproof PVC plate for partition wall and manufacturing method thereof |
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| CN105086037A (en) * | 2015-08-14 | 2015-11-25 | 重庆红旗杰勋车轮有限公司 | Antiskid wear-resistant tire composition and preparation method thereof |
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| CN105086037A (en) * | 2015-08-14 | 2015-11-25 | 重庆红旗杰勋车轮有限公司 | Antiskid wear-resistant tire composition and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556667A (en) * | 2017-10-23 | 2018-01-09 | 徐州市新大电缆有限公司 | A kind of heat-resistant fireproof reliability power cable material |
| CN111670225A (en) * | 2018-03-22 | 2020-09-15 | 株式会社藤仓 | Flame-retardant resin composition, and insulated wire, cable and optical fiber cable using same |
| CN108690293A (en) * | 2018-06-15 | 2018-10-23 | 浙江威思康塑胶有限公司 | A kind of high-low temperature resistant high strength PVC cable material |
| CN108752795A (en) * | 2018-06-15 | 2018-11-06 | 浙江威思康塑胶有限公司 | A kind of preparation process of high-low temperature resistant high strength PVC cable material |
| CN108546025A (en) * | 2018-06-28 | 2018-09-18 | 江苏百瑞吉新材料有限公司 | A kind of gunite concrete and its production method of high tenacity |
| CN110105690A (en) * | 2019-05-17 | 2019-08-09 | 天长市富达电子有限公司 | A kind of high tenacity cold-resistant electric wire protective materials and preparation method thereof |
| CN112143452A (en) * | 2020-10-21 | 2020-12-29 | 南京信息工程大学 | Organic high-temperature-resistant packaging adhesive and preparation method thereof |
| CN112143452B (en) * | 2020-10-21 | 2022-05-17 | 南京信息工程大学 | Organic high-temperature-resistant packaging adhesive and preparation method thereof |
| CN114149645A (en) * | 2021-11-25 | 2022-03-08 | 浙江亚厦装饰股份有限公司 | Fireproof PVC plate for partition wall and manufacturing method thereof |
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