A kind of waste paper recycles the preparation method of paper sludge
Technical field
The invention belongs to Material Field, and in particular to a kind of preparation method of paper sludge.
Background technology
Traditional paper sludge, be by paper bubble after, and glue holds group, after certain make, makes " paper sludge ".Made of " paper sludge "
Into after animal and other articles, being placed on after being dried under the sun can become very hard, afterwards again by processes such as description, colourings,
Just lifelike artistic creation image one by one can be presented.
But in actual life, such as take unworn paper product to make paper sludge, then can bring the significant wastage of resource, therefore
Reclaimed with waste paper and carry out resource reutilization to make paper sludge, the problem of nature raw material are nervous can be alleviated significantly, while also having
There is environmental protection, pollute the low advantage of small, energy resource consumption.
But the higher waste paper of some paper product quality, its fiber quality is excellent, but because mode of printing is special, printing-ink
Composition is special, there is the problem of ink particle is larger to be difficult to separate from fiber, can only be abandoned because deinking efficiency is undesirable again sharp
With or degradation reuse, constrain significantly waste paper recycle prepare paper sludge application and development.
The content of the invention
Goal of the invention:The problem of existing for prior art, the technical problems to be solved by the invention are to provide a kind of useless
Paper recycles the preparation method of paper sludge.
Technical scheme:In order to solve the above technical problems, the invention provides the preparation method that a kind of waste paper recycles paper sludge,
The preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
It is preferred that, the blending agents is made according to parts by weight including following components:25~30 parts of latex;Starch paste 15
~30 parts;3~8 parts of Flos Chrysanthemi extract;7~12 parts of lignocellulosic.
It is preferred that, the step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 2~3 hours, the antioxidant and auxiliary agent of corresponding parts by weight are added, in the same of black light light irradiation
When, stirring prepares target product.
Be used as preferred, the step 3) in by after micro- fermentation process shredded paper tablet immersion, flotation removal ink processing
Step includes:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
5-8 hours;
32) flotation at normal temperatures, removes the ink in material.
As preferred, wherein the step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 0.8~1.2% the first additive is added into shredded paper tablet,
It is mixed with water, carries out preposition micro- fermentation 1~2 day;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.1~0.15% Second addition is added, mixing is equal
It is even, carry out rearmounted micro- fermentation 5~6 days.
It is preferred that, first additive is made according to parts by weight including following component:3~8 parts of saccharomycete;Live on surface
3~6 parts of agent of property;5-10 parts of glycerine.
It is preferred that, the Second addition is made according to parts by weight including following component:1~2 part of phragmites communis extract;Sea
2~5 parts of mosanom.
Beneficial effect:The waste paper that the present invention is provided recycles the preparation method of paper sludge, and on the one hand gained paper sludge is by useless
Paper is recycled and is prepared from, and realizes the cycling and reutilization of precious resources, green, economic, environmental protection;On the other hand by by shredded paper
The method that tablet carries out micro- fermentation process so that can subsequently carry out flotation removal ink at normal temperatures, effectively improves gained paper
The use quality of mud.
Meanwhile, what is more important using the excellent waste paper cycling and reutilization of fiber quality when making paper sludge, by preceding
Put, micro- fermentation process of rearmounted different modes twice and follow-up workshop section are complementary to one another Synergistic so that follow-up removal ink work
Section can obtain higher deinking rate;And each processing step coordinates the Synergistic between first, second additive each component, is not required to
Extra increase dispersant, the just effective ink removal amount of lifting flotation removal ink, takes into account excellent removal ink effect and hole is equal
Even the characteristics of, free from extraneous odour.
Embodiment
Embodiment 1:
The environmentally friendly paper sludge that the present embodiment is provided, its raw material is made according to parts by weight including following components:Waste paper fragment 200
Part;5 parts of deinking agent;10 parts of bentonite;3 parts of saccharomycete;5 parts of glycerine;3 parts of surfactant;1 part of phragmites communis extract;Blending agents
50 parts;1 part of antioxidant;2 parts of sodium alginate;1 part of auxiliary agent.
Wherein surfactant is water soluble surfactant active.
Wherein blending agents is made according to parts by weight including following components:25 parts of latex;15 parts of starch paste;FLOS CHRYSANTHEMI ALBA from Haizhou of China is carried
Take 3 parts of thing;7 parts of lignocellulosic.
Wherein auxiliary agent is made according to parts by weight including following components:0.5 part of defoamer;0.2 part of thickener;Toughener
0.1 part;0.2 part of preservative.
Preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
Wherein step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 2 hours, the antioxidant and auxiliary agent of corresponding parts by weight is added, while black light light irradiation, is stirred
Mix and prepare target product.
Wherein step 3) in the shredded paper tablet immersion after micro- fermentation process, the process step of flotation removal ink are included:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
5 hours;
32) flotation at normal temperatures, removes the ink in material.
Wherein step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 0.8% the first additive is added into shredded paper tablet, is added water
It is well mixed, carry out preposition micro- fermentation 1 day;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.1% Second addition is added, is well mixed, carries out
Rearmounted micro- fermentation 5 days.
Wherein the first additive is made according to parts by weight including following component:3 parts of saccharomycete;3 parts of surfactant;It is sweet
5 parts of oil.
Wherein Second addition is made according to parts by weight including following component:1 part of phragmites communis extract;2 parts of sodium alginate.
Embodiment 2:
The environmentally friendly paper sludge that the present embodiment is provided, its raw material is made according to parts by weight including following components:Waste paper fragment 300
Part;8 parts of deinking agent;20 parts of bentonite;8 parts of saccharomycete;10 parts of glycerine;6 parts of surfactant;2 parts of phragmites communis extract;Blending agents
80 parts;3 parts of antioxidant;5 parts of sodium alginate;2 parts of auxiliary agent.
Wherein surfactant is lauric acid amide of ethanol.
Wherein blending agents is made according to parts by weight including following components:30 parts of latex;30 parts of starch paste;FLOS CHRYSANTHEMI ALBA from Haizhou of China is carried
Take 8 parts of thing;12 parts of lignocellulosic.
Wherein auxiliary agent is made according to parts by weight including following components:0.8 part of defoamer;0.5 part of thickener;Toughener
0.2 part;0.5 part of preservative.
Preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
Wherein step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 3 hours, the antioxidant and auxiliary agent of corresponding parts by weight is added, while black light light irradiation, is stirred
Mix and prepare target product.
Wherein step 3) in the shredded paper tablet immersion after micro- fermentation process, the process step of flotation removal ink are included:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
5-8 hours;
32) flotation at normal temperatures, removes the ink in material.
Wherein step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 1.2% the first additive is added into shredded paper tablet, is added water
It is well mixed, carry out preposition micro- fermentation 2 days;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.15% Second addition is added, is well mixed, enters
The rearmounted micro- fermentation of row 6 days.
Wherein the first additive is made according to parts by weight including following component:8 parts of saccharomycete;6 parts of surfactant;It is sweet
10 parts of oil.
Wherein Second addition is made according to parts by weight including following component:2 parts of phragmites communis extract;5 parts of sodium alginate.
Embodiment 3:
The environmentally friendly paper sludge that the present embodiment is provided, its raw material is made according to parts by weight including following components:Waste paper fragment 250
Part;6 parts of deinking agent;15 parts of bentonite;6 parts of saccharomycete;8 parts of glycerine;4 parts of surfactant;2 parts of phragmites communis extract;Blending agents
62 parts;2 parts of antioxidant;3 parts of sodium alginate;1.5 parts of auxiliary agent.
Wherein surfactant is lactic acid bacteria.
Wherein blending agents is made according to parts by weight including following components:30 parts of latex;18 parts of starch paste;FLOS CHRYSANTHEMI ALBA from Haizhou of China is carried
Take 3 parts of thing;8 parts of lignocellulosic;3 parts of pigment.
Wherein auxiliary agent is made according to parts by weight including following components:0.6 part of defoamer;0.3 part of thickener;Toughener
0.2 part;0.4 part of preservative.
Preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
Wherein step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 3 hours, the antioxidant and auxiliary agent of corresponding parts by weight is added, while black light light irradiation, is stirred
Mix and prepare target product.
Wherein step 3) in the shredded paper tablet immersion after micro- fermentation process, the process step of flotation removal ink are included:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
6 hours;
32) flotation at normal temperatures, removes the ink in material.
Wherein step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 1% the first additive is added into shredded paper tablet, is added water mixed
Close uniform, carry out preposition micro- fermentation 2 days;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.12% Second addition is added, is well mixed, enters
The rearmounted micro- fermentation of row 6 days.
Wherein the first additive is made according to parts by weight including following component:6 parts of saccharomycete;4 parts of surfactant;It is sweet
8 parts of oil.
Wherein Second addition is made according to parts by weight including following component:2 parts of phragmites communis extract;3 parts of sodium alginate.
Embodiment 4:
The environmentally friendly paper sludge that the present embodiment is provided, its raw material is made according to parts by weight including following components:Waste paper fragment 220
Part;6 parts of deinking agent;12 parts of bentonite;5 parts of saccharomycete;7 parts of glycerine;4 parts of surfactant;1 part of phragmites communis extract;Blending agents
55 parts;2 parts of antioxidant;3 parts of sodium alginate;1 part of auxiliary agent.
Wherein surfactant is lauric acid amide of ethanol.
Wherein blending agents is made according to parts by weight including following components:26 parts of latex;20 parts of starch paste;FLOS CHRYSANTHEMI ALBA from Haizhou of China is carried
Take 4 parts of thing;8 parts of lignocellulosic.
Wherein auxiliary agent is made according to parts by weight including following components:0.5 part of defoamer;0.2 part of thickener;Toughener
0.1 part;0.2 part of preservative.
Preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
Wherein step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 2 hours, the antioxidant and auxiliary agent of corresponding parts by weight is added, while black light light irradiation, is stirred
Mix and prepare target product.
Wherein step 3) in the shredded paper tablet immersion after micro- fermentation process, the process step of flotation removal ink are included:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
6 hours;
32) flotation at normal temperatures, removes the ink in material.
Wherein step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 0.9% the first additive is added into shredded paper tablet, is added water
It is well mixed, carry out preposition micro- fermentation 1 day;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.11% Second addition is added, is well mixed, enters
The rearmounted micro- fermentation of row 5 days.
Wherein the first additive is made according to parts by weight including following component:5 parts of saccharomycete;4 parts of surfactant;It is sweet
7 parts of oil.
Wherein Second addition is made according to parts by weight including following component:1 part of phragmites communis extract;3 parts of sodium alginate.
Embodiment 5:
The environmentally friendly paper sludge that the present embodiment is provided, its raw material is made according to parts by weight including following components:Waste paper fragment 280
Part;7 parts of deinking agent;18 parts of bentonite;7 parts of saccharomycete;8 parts of glycerine;5 parts of surfactant;2 parts of phragmites communis extract;Blending agents
72 parts;2 parts of antioxidant;4 parts of sodium alginate;2 parts of auxiliary agent.
Wherein surfactant is lactic acid bacteria.
Wherein blending agents is made according to parts by weight including following components:28 parts of latex;26 parts of starch paste;FLOS CHRYSANTHEMI ALBA from Haizhou of China is carried
Take 7 parts of thing;11 parts of lignocellulosic.
Wherein auxiliary agent is made according to parts by weight including following components:0.7 part of defoamer;0.4 part of thickener;Toughener
0.2 part;0.4 part of preservative.
Preparation method comprises the following steps:
1) waste paper of collection is smashed and obtains shredded paper tablet;
2) shredded paper tablet is subjected to micro- fermentation process;
3) by the shredded paper tablet immersion after micro- fermentation process, flotation removal ink;
4) material after flotation removal ink is washed into sediment decontamination, autoclaving, sterilizing and softening;
5) gas is steamed to the material mashing after softening and paper pulp is made;
6) in step 5) made from paper pulp, add blending agents, stirring is prepared into paper sludge.
Wherein step 6) comprise the following steps:
61) by step 7) made from paper pulp, the bentonite and blending agents of corresponding parts by weight are added, in black light light irradiation
While, stir;
62) after standing 3 hours, the antioxidant and auxiliary agent of corresponding parts by weight is added, while black light light irradiation, is stirred
Mix and prepare target product.
Wherein step 3) in the shredded paper tablet immersion after micro- fermentation process, the process step of flotation removal ink are included:
31) material after rearmounted micro- fermentation process is added to the deinking agent of corresponding parts by weight, stirred, immersion is stood
5-8 hours;
32) flotation at normal temperatures, removes the ink in material.
Wherein step 2) in the process step of micro- fermentation include:
21) according to the percentage by weight for accounting for over dry raw material, 1.1% the first additive is added into shredded paper tablet, is added water
It is well mixed, carry out preposition micro- fermentation 2 days;
22) according to the percentage by weight for accounting for over dry raw material, and then 0.14% Second addition is added, is well mixed, enters
The rearmounted micro- fermentation of row 6 days.
Wherein the first additive is made according to parts by weight including following component:7 parts of saccharomycete;5 parts of surfactant;It is sweet
8 parts of oil.
Wherein Second addition is made according to parts by weight including following component:2 parts of phragmites communis extract;4 parts of sodium alginate.
The waste paper that is there is provided in above-described embodiment recycles the preparation method of paper sludge, on the one hand gained paper sludge be by waste paper again
Using being prepared from, the cycling and reutilization of precious resources, green, economic, environmental protection are realized;On the other hand by by shredded paper tablet
The method for carrying out micro- fermentation process so that can subsequently carry out flotation removal ink at normal temperatures, effectively improves gained paper sludge
Use quality.
Meanwhile, what is more important using the excellent waste paper cycling and reutilization of fiber quality when making paper sludge, by preceding
Put, micro- fermentation process of rearmounted different modes twice and follow-up workshop section are complementary to one another Synergistic so that follow-up removal ink work
Section can obtain higher deinking rate;And each processing step coordinates the Synergistic between first, second additive each component, is not required to
Extra increase dispersant, the just effective ink removal amount of lifting flotation removal ink, takes into account excellent removal ink effect and hole is equal
Even the characteristics of, free from extraneous odour.
It is 22~27 DEG C that normal temperature is referred in text.
Embodiment 6
Testing inspection is carried out to embodiment 1-5, as a result shown:
Embodiment |
ERIC values after flotation |
Deinking rate |
Embodiment 1 |
32.6×10-6 |
89.1% |
Embodiment 2 |
31.3×10-6 |
85.5% |
Embodiment 3 |
26.0×10-6 |
92.3% |
Embodiment 4 |
29.1×10-6 |
89.9% |
Embodiment 5 |
27.6×10-6 |
90.1% |
Note:Deinking rate is obtained according to the ERIC value calculating of the forward and backward lodicule of flotation.
Implement row above and restriction is not constituted to the present invention, relevant staff is in the scope without departing from the technology of the present invention thought
It is interior, carried out it is various change and modifications, all fall within protection scope of the present invention.