CN107244738A - Sewage denitrification dephosphorization system and the method that biochemical unit switches are carried out according to season - Google Patents

Sewage denitrification dephosphorization system and the method that biochemical unit switches are carried out according to season Download PDF

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Publication number
CN107244738A
CN107244738A CN201710601999.9A CN201710601999A CN107244738A CN 107244738 A CN107244738 A CN 107244738A CN 201710601999 A CN201710601999 A CN 201710601999A CN 107244738 A CN107244738 A CN 107244738A
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biochemistry pool
pond
valve
sewage
anoxic
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CN201710601999.9A
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CN107244738B (en
Inventor
刘鲁建
董俊
张岚欣
庞承刚
熊蔚
王黎伟
张双峰
许存根
方潇
刘卫勇
陶威
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Junji Environmental Technology Co ltd
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Hubei Junji Water Treatment Co Ltd
Wuhan Technology and Business University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

Sewage denitrification dephosphorization system and the method that biochemical unit switches are carried out according to season the invention discloses a kind of, system includes preprocessing subsystem, pre- anoxic pond, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry pool, the 4th biochemistry pool, Aerobic Pond, second pond;The present invention carries out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, and winter uses inversion A2/ O techniques, spring uses modified form A2/ O techniques, summer uses pre- anoxic+inversion A2/ O techniques, autumn is using hypoxemia/alternate pre- anoxic+inversion A of normal oxygen2/ O techniques;The present invention realize set up a set of biochemical system it is changeable be four kinds of biochemical unit modes technique, by adjusting dissolved oxygen (DO) concentration, changing the means such as water inlet flow direction and sludge flow direction, to strengthen nitration denitrification effect, release phosphorus and the effect of poly- phosphorus, total nitrogen and total phosphorus can effectively be removed, system stable effluent quality, technological operation is simple, automaticity is high, operation energy consumption is relatively low, can stably reach one-level A effluent standards.

Description

Sewage denitrification dephosphorization system and the method that biochemical unit switches are carried out according to season
Technical field
The invention belongs to technical field of sewage, and in particular to biochemical unit mode switching is utilized in a kind of Various Seasonal Carry out the system and method for sewage denitrification and dephosphorization.
Background technology
During " 13 ", major part sewage treatment plant of China faces the problem of proposing mark upgrading.Some areas of southern china The organic pollution concentration of municipal sewage is relatively low, and nitrogen, phosphorus concentration are of a relatively high, and nitrogen phosphorus can excessively cause body eutrophication. The raising of nutrient removal efficiency is limited due to carbon source deficiency, it is relatively low for municipal sewage plant's entering organic matter of water ratio The problem of, it is rational to be just particularly important using water-inlet carbon source.
During bio-denitrifying sewage dephosphorization, temperature and carbon source are two highly important factors.Low temperature limits nitre Change bacterium, denitrifying bacterium, the activity of polyP bacteria, so as to have impact on degradation effect of the biochemical system to pollutant;Organic carbon source is anti- Nitrify and release phosphorus process and provide the required energy, carbon source deficiency will directly affect the effect of denitrogenation dephosphorizing.Sewage treatment plant exists , can be by adjusting technological parameter or improvement existing process, to improve the biochemistry under low temperature and the not enough operating mode of carbon source in actual motion Treatment effect.
Shown according to experimental result:To reach optimal Nitrogen/Phosphorus Removal, winter preferably uses inversion A2/ O techniques, spring is suitable From modified form A2/ O techniques, summer preferably selects pre- anoxic+inversion A2/ O techniques, autumn preferably uses hypoxemia/normal oxygen alternate pre- scarce Oxygen+inversion A2/ O techniques, can effectively remove pollutant, denitrogenation dephosphorizing in the different corresponding technique of Season select, reach Discharge standard.In order to realize optimization process effect, if a sewage treatment plant sets up many set biochemical systems, one-time investment is huge Greatly, operation maintenance is difficult, high energy consumption;If only setting up a set of single biochemical system, it cannot be guaranteed that most when replacing in the four seasons Good treatment effect, it is impossible to make the nitrogen and phosphorus indexes of system water outlet meet discharge into water standard.
The content of the invention
In view of the deficienciess of the prior art, the invention provides biochemical unit mode switching is utilized in a kind of Various Seasonal Carry out the system and method for sewage denitrification and dephosphorization.
The technical scheme that is used of system of the present invention is:It is a kind of that the sewage water denitrification that biochemical unit switches is carried out according to season Dephosphorization system, it is characterised in that:Including preprocessing subsystem, pre- anoxic pond, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry Pond, the 4th biochemistry pool, Aerobic Pond, second pond;
The preprocessing subsystem is connected with the pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool respectively by conduit, Valve A and valve B, preprocessing subsystem and are provided with the conduit wherein connected between preprocessing subsystem and pre- anoxic pond Valve A, valve D and valve F are provided with the conduit connected between one biochemistry pool, between preprocessing subsystem and the 3rd biochemistry pool Valve A, valve E and valve J are provided with the conduit of connection;
The pre- anoxic pond is connected by conduit with first biochemistry pool, and valve C and valve are provided with connecting pipe F;
First biochemistry pool is connected with second biochemistry pool, the 3rd biochemistry pool respectively by conduit;First biochemistry pool Valve I, the conduit connected between the first biochemistry pool and the 3rd biochemistry pool are provided with the conduit being connected between the second biochemistry pool On be provided with valve G and valve J;
Second biochemistry pool is connected by conduit with the 3rd biochemistry pool, and valve H and valve are provided with connecting pipe Door J;
3rd biochemistry pool is connected with the 4th biochemistry pool, Aerobic Pond respectively by conduit;3rd biochemistry pool and It is provided with valve M, the conduit connected between the 3rd biochemistry pool and Aerobic Pond and is provided with the conduit connected between four biochemistry pools Valve K;
The Aerobic Pond is connected by conduit with the second pond;
The second pond is connected by reflux line with the pre- anoxic pond, the first biochemistry pool respectively, is divided on connecting pipe Valve P, valve O are not provided with;The Aerobic Pond is connected by reflux line with the 3rd biochemistry pool, is set on connecting pipe There is valve N.
The method that is used of method of the present invention is:It is a kind of that the sewage denitrification and dephosphorization that biochemical unit switches is carried out according to season Method, it is characterised in that:Winter uses inversion A2/ O techniques, spring uses modified form A2/ O techniques, summer using pre- anoxic+fall Put A2/ O techniques, autumn is using hypoxemia/alternate pre- anoxic+inversion A of normal oxygen2/ O techniques;
The inversion A2/ O techniques, implement and comprise the following steps:
Step A1:Open valve A, valve D, valve F, valve E, valve I, valve J, close remaining valve;Now first Biochemistry pool has been connected with the second biochemistry pool, and is combined as anoxic pond, the 3rd biochemistry pool separately as anaerobic pond;Preprocessed son The pretreated water of system is respectively fed to the first biochemistry pool, the 3rd biochemistry pool;Water inlet is sent out in the first biochemistry pool, the second biochemistry pool Raw denitrification, nitrifies the nitrite produced and nitrate is reduced into nitrogen in the presence of denitrifying bacteria, so that Realize denitrogenation;
Step A2:Sewage enters in the 3rd biochemistry pool in Open valve H, the second biochemistry pool, now the 3rd biochemistry pool conduct Anaerobic pond, polyP bacteria releases phosphorus in anaerobic pond;
Step A3:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, and polyP bacteria is after anaerobic pond releases phosphorus, directly Into Aerobic Pond, poly- phosphorus reaction and nitrification occur in Aerobic Pond, mud mixture gravity flow enters after pollutant is degraded Second pond;
Step A4:In Open valve O, second pond in nitrification liquid and sludge reflux to the first biochemistry pool;
The modified form A2/ O techniques, implement and comprise the following steps:
Step B1:Open valve A, valve B, valve D, valve F, valve E, valve J, close remaining valve, preprocessed The pretreated water of subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, and now the first biochemistry pool is individually made For anaerobic pond;Denitrification occurs in pre- anoxic pond for sewage, removes total nitrogen;
Step B2:Sewage in Open valve C, pre- anoxic pond sends into the first biochemistry pool, by the effect of polyP bacteria, utilizes Itself carbon source of water inlet, realizes the release of phosphorus;
Step B3:Sewage sends into the 3rd biochemistry pool in Open valve G, the first biochemistry pool;Open valve M, connects the three lives Change pond, the 4th biochemistry pool;Now the 3rd biochemistry pool, the combination of the 4th biochemistry pool are as anoxic pond, and sewage is in the 3rd biochemistry pool, the 4th Continue occur denitrification in biochemistry pool, nitrify the nitrite produced and nitrate is gone back in the presence of denitrifying bacteria Original is into nitrogen, it is achieved thereby that denitrogenation;
Step B4:Sewage enters Aerobic Pond in Open valve L, the 4th biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step B5:In Open valve P, valve N, second pond in sludge reflux to pre- anoxic pond, nitrification liquid is returned in Aerobic Pond It flow in the 3rd biochemistry pool;
Pre- anoxic+the inversion A2/ O techniques, implement and comprise the following steps:
Step C1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve, warp The pretreated water of preprocessing subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, now the first biochemistry pool Connect, and combined as anoxic pond, the 3rd biochemistry pool separately as anaerobic pond with the second biochemistry pool;Sewage is in pre- anoxic pond Generation denitrification, removes total nitrogen;
Step C2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, and sewage is first Continue occur denitrification in biochemistry pool, the second biochemistry pool, nitrify the nitrite produced and nitrate in denitrifying bacteria In the presence of be reduced into nitrogen, it is achieved thereby that denitrogenation;
Step C3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is individually made For anaerobic pond, sewage, using itself carbon source of intaking, realizes the release of phosphorus by the effect of polyP bacteria;
Step C4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step C5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond;
The hypoxemia/alternate pre- anoxic+the inversion A of normal oxygen2/ O techniques, implement and comprise the following steps:
Step D1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve, warp The pretreated water of preprocessing subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, now the first biochemistry pool Connect, and combined as anoxic pond, the 3rd biochemistry pool separately as anaerobic pond with the second biochemistry pool;
Sewage enters pre- anoxic pond, now controls to adjust DO concentration in pre- anoxic pond using hypoxemia/normal alternate mode of oxygen;
Step D2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, biochemical first Continue occur denitrification in pond, the second biochemistry pool, nitrify the work of the nitrite produced and nitrate in denitrifying bacteria Nitrogen is reduced under, it is achieved thereby that denitrogenation;
Step D3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is as detesting Oxygen pond, sewage, using itself carbon source of intaking, realizes the release of phosphorus by the effect of polyP bacteria;
Step D4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step D5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond.
The characteristics of the inventive method has following and beneficial effect:
The present invention, which is realized, sets up a set of biochemical system, and four kinds of different biochemical units are freely switched to according to seasonal variations The technique of pattern, carries out the switching of pipeline, so as to realize the conversion of different pond bodies by the keying of valve;By adjusting dissolving The means such as oxygen (DO) concentration, change water inlet flow direction and sludge flow direction, to strengthen nitration denitrification effect, release phosphorus and the effect of poly- phosphorus, It can effectively remove total nitrogen and total phosphorus, system stable effluent quality, technological operation is simple, automaticity is high, operation energy consumption is relatively low, It can stably reach《Urban wastewater treatment firm pollutant emission standard》One-level A effluent standards.
Brief description of the drawings
Fig. 1:The system construction drawing of the embodiment of the present invention.
Embodiment
Understand for the ease of those of ordinary skill in the art and implement the present invention, the present invention is made into one below in conjunction with the accompanying drawings The detailed description of step, it will be appreciated that implementation example described herein is merely to illustrate and explain the present invention, is not used to limit The present invention.
See Fig. 1, a kind of sewage denitrification dephosphorization system that biochemical unit switching is carried out according to season that the present invention is provided, bag Include preprocessing subsystem, pre- anoxic pond, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry pool, the 4th biochemistry pool, Aerobic Pond, two Heavy pond;
Preprocessing subsystem is connected with pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool respectively by conduit, wherein pre- place Valve A and valve B, preprocessing subsystem and the first biochemistry pool are provided with the conduit connected between reason subsystem and pre- anoxic pond Between be provided with valve A, valve D and valve F on the conduit that connects, what is connected between preprocessing subsystem and the 3rd biochemistry pool leads Valve A, valve E and valve J are provided with pipe;Pre- anoxic pond is connected by conduit with the first biochemistry pool, is set on connecting pipe There are valve C and valve F;First biochemistry pool is connected with the second biochemistry pool, the 3rd biochemistry pool respectively by conduit;First biochemistry pool with It is provided with the conduit connected between second biochemistry pool on valve I, the conduit connected between the first biochemistry pool and the 3rd biochemistry pool It is provided with valve G and valve J;Second biochemistry pool is connected by conduit with the 3rd biochemistry pool, be provided with connecting pipe valve H and Valve J;3rd biochemistry pool is connected with the 4th biochemistry pool, Aerobic Pond respectively by conduit;3rd biochemistry pool and the 4th biochemistry pool it Between be provided with valve M, the conduit connected between the 3rd biochemistry pool and Aerobic Pond on the conduit that connects and be provided with valve K;It is aerobic Pond is connected by conduit with second pond;Second pond is connected by reflux line with pre- anoxic pond, the first biochemistry pool respectively, connecting tube Valve P, valve O are respectively arranged with road;Aerobic Pond is connected by reflux line with the 3rd biochemistry pool, is provided with connecting pipe Valve N.
Aerator is provided with the pre- anoxic pond of the present embodiment, installing aeration plate by bottom of pond using roots blower is carried out Oxygen supply is aerated, to realize the alternating of hypoxemia in pre- anoxic pond/normal oxygen operating mode;Aerator is provided with Aerobic Pond, using Roots Blower fan installs aeration plate by bottom of pond and carries out aeration oxygen supply.
The pre- anoxic pond of the present embodiment, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry pool, it is all provided with the 4th biochemistry pool It is equipped with submersible agitator;Submersible agitator uses low-speed propulsion device, and wheel speed is set to during operation:36r/min~56r/ min。
A kind of sewage denitrification and dephosphorization method that biochemical unit switching is carried out according to season that the present invention is provided, winter uses Put A2/ O techniques, spring uses modified form A2/ O techniques, summer uses pre- anoxic+inversion A2/ O techniques, autumn using hypoxemia/often The alternate pre- anoxic+inversion A of oxygen2/ O techniques;
Inversion A2/ O techniques (winter is optimal), implement and comprise the following steps:
Step A1:Open valve A, valve D, valve F, valve E, valve I, valve J, close remaining valve, preprocessed The pretreated water of subsystem is respectively fed to the first biochemistry pool, the 3rd biochemistry pool;Water inlet ratio is 4:6, with distribute denitrification and The carbon source required for phosphorus effect is released, now the first biochemistry pool has been connected with the second biochemistry pool, and combination is used as anoxic pond, the three lives Change pond separately as anaerobic pond, the submersible agitator in the first biochemistry pool, the second biochemistry pool is opened, and rotating speed is disposed as 50r/ Min, the first biochemistry pool, the combination pond body hydraulic detention time of the second biochemistry pool are 4h;Water inlet is in the first biochemistry pool, the second biochemistry Denitrification occurs in pond, nitrifies the nitrite produced and nitrate is reduced into nitrogen in the presence of denitrifying bacteria Gas, it is achieved thereby that denitrogenation;
Step A2:Sewage enters in the 3rd biochemistry pool in Open valve H, the second biochemistry pool, now the 3rd biochemistry pool conduct Anaerobic pond, the 3rd biochemical pool inner water power residence time was that submersible agitator is closed in 1.5h, pond, and polyP bacteria releases phosphorus in anaerobic pond;
Step A3:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, and polyP bacteria is after anaerobic pond releases phosphorus, directly Into Aerobic Pond, poly- phosphorus reaction and nitrification occur in Aerobic Pond, mud mixture gravity flow enters after pollutant is degraded Second pond;
Step A4:In Open valve O, second pond in nitrification liquid and sludge reflux to the first biochemistry pool, reflux ratio is 150%;All sludge whole experience for participating in backflow are complete to be released phosphorus, inhales phosphorus process, has " population effect " in terms of dephosphorization Advantage.
Modified form A2/ O techniques (spring is optimal), implement and comprise the following steps:
Step B1:Open valve A, valve B, valve D, valve F, valve E, valve J, close remaining valve, preprocessed The pretreated water of subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, and water inlet ratio is 4:3:3, to divide With the carbon source that denitrification is required with phosphorus effect is released;Now the first biochemistry pool is separately as anaerobic pond;Diving in pre- anoxic pond Agitator is opened, and rotating speed is set to 45r/min, and denitrification occurs in pre- anoxic pond for sewage, removes total nitrogen;
Step B2:Sewage in Open valve C, pre- anoxic pond sends into the first biochemistry pool, and hydraulic detention time is 1.5h, pond Interior submersible agitator is closed;By the effect of polyP bacteria, using itself carbon source of intaking, the release of phosphorus is realized;
Step B3:Sewage sends into the 3rd biochemistry pool in Open valve G, the first biochemistry pool;Open valve M, connects the three lives Change pond, the 4th biochemistry pool;Now the 3rd biochemistry pool, the combination of the 4th biochemistry pool are used as anoxic pond, the 3rd biochemistry pool, the 4th biochemistry pool Submersible agitator open, rotating speed is set to 45r/min, the 3rd biochemistry pool, the combination pond body hydraulic retention of the 4th biochemistry pool Time is 4h, and sewage continues occur denitrification in the 3rd biochemistry pool, the 4th biochemistry pool, nitrify the nitrite that produces and Nitrate is reduced into nitrogen in the presence of denitrifying bacteria, it is achieved thereby that denitrogenation;
Step B4:Sewage enters Aerobic Pond in Open valve L, the 4th biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step B5:In Open valve P, valve N, second pond in sludge reflux to pre- anoxic pond, reflux ratio is 75%;It is aerobic Nitrification liquid is back in the 3rd biochemistry pool in pond, and reflux ratio is 200%.
Pre- anoxic+inversion A2/ O techniques (summer is optimal), implement and comprise the following steps:
Step C1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve, warp The pretreated water of preprocessing subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, and water inlet ratio is 4:3: 3, to distribute denitrification and release the carbon source required for phosphorus effect;Now the first biochemistry pool has been connected with the second biochemistry pool, and is combined As anoxic pond, the 3rd biochemistry pool separately as anaerobic pond;Submersible agitator in pre- anoxic pond is opened, and rotating speed is set to 40r/ Denitrification occurs in pre- anoxic pond for min, sewage, removes total nitrogen;
Step C2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, and first is biochemical Pond, the submersible agitator of the second biochemistry pool are opened, and rotating speed is set to 40r/min, the first biochemistry pool, the combination of the second biochemistry pool Pond body hydraulic detention time is 4h, and sewage continues occur denitrification in the first biochemistry pool, the second biochemistry pool, and nitrification is produced Nitrite and nitrate nitrogen is reduced into the presence of denitrifying bacteria, it is achieved thereby that denitrogenation;
Step C3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is individually made For anaerobic pond, hydraulic detention time is that submersible agitator is closed in 1.5h, pond, and sewage utilizes water inlet by the effect of polyP bacteria Itself carbon source, realizes the release of phosphorus;
Step C4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step C5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond;Reflux ratio value 150%;All sludge whole experience for participating in backflow are complete to be released phosphorus, inhales phosphorus process, has " population effect " in terms of dephosphorization Advantage.
Hypoxemia/alternate pre- anoxic+the inversion A of normal oxygen2/ O techniques (autumn is optimal), implement and comprise the following steps:
Step D1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve, warp The pretreated water of preprocessing subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, and water inlet ratio is 4:3: 3, to distribute denitrification and release the carbon source required for phosphorus effect;Now the first biochemistry pool has been connected with the second biochemistry pool, and is combined As anoxic pond, the 3rd biochemistry pool separately as anaerobic pond;
Sewage enters pre- anoxic pond, now controls to adjust DO concentration in pre- anoxic pond using hypoxemia/normal alternate mode of oxygen; When using normal oxygen operating mode, the submersible agitator set in pre- anoxic pond is closed, aeration plate in pre- anoxic pond is opened, adjustment DO is arrived 1.5~2.5mg/L;When using hypoxemia operating mode, aeration plate in pre- anoxic pond is closed, the diving set in pre- anoxic pond is opened and stirs Device is mixed, rotating speed is set to 40r/min, adjusts DO to 0.3~0.6mg/L;Realized by this hypoxemia/normal alternate mode of oxygen The short-cut nitrification and denitrification of sewage, hypoxemia and normal oxygen alternate cycle be 1~2 week, by such a method of operation for water compared with Higher nitric efficiency is can reach under few carbon source operating mode;
Step D2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, and first is biochemical Pond, the submersible agitator of the second biochemistry pool are opened, and rotating speed is disposed as 40r/min, the first biochemistry pool, the group of the second biochemistry pool It is 4h to close pond body hydraulic detention time, continues occur denitrification in the first biochemistry pool, the second biochemistry pool, what nitrification was produced Nitrite and nitrate are reduced into nitrogen in the presence of denitrifying bacteria, it is achieved thereby that denitrogenation;
Step D3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is as detesting Oxygen pond, hydraulic detention time is that submersible agitator is closed in 1.5h, pond, and sewage is by the effect of polyP bacteria, using intaking itself Carbon source, realizes the release of phosphorus;
Step D4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, occur in Aerobic Pond poly- phosphorus reaction and Nitrification, mud mixture gravity flow enters second pond after pollutant is degraded;
Step D5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond, reflux ratio value 150%;All sludge whole experience for participating in backflow are complete to be released phosphorus, inhales phosphorus process, has " population effect " in terms of dephosphorization Advantage.
In the present embodiment, when the first biochemistry pool, the 3rd biochemistry pool are run in anaerobic pond form, the control of DO concentration exists Below 0.2mg/L;When the first biochemistry pool and the combination of the second biochemistry pool, the 3rd biochemistry pool and the combination of the 4th biochemistry pool are with anoxic pond shape When formula is run, DO concentration is controlled in 0.3~0.6mg/L;In Aerobic Pond, DO concentration is controlled in 1.5~2.5mg/L.
All valves of the present embodiment can be realized and automatically controlled.
Present invention employs the sewage disposal technology of " strengthened denitrification+reinforced phosphor-removing ", and according to Four seasons change, pass through pipe Valve realizes the operation switching of four kinds of different biochemical modes with the conversion of pond body, to reach the effect of optimal denitrogenation dephosphorizing.
Sewage flows into biochemical system after pretreatment, by anaerobic pond, the release of phosphorus is carried out under polyP bacteria effect, then Into after aerobic zone, polyP bacteria can be by the aerobic decomposition of the PHB of repertory, and the big energy discharged is available for polyP bacteria growth numerous Grow.In the presence of having dissolving phosphorus in environment, part energy is available for polyP bacteria active absorption phosphate, and is accumulated in the form of poly- phosphorus Storage is in vivo.Now exceed the phosphorus amount needed for microorganism normal growth to the summation of phosphorus, it is seen that microorganism is in aerobic condition The phosphorus of lower absorption greatly exceed the phosphorus discharged under anaerobic.It is excessive by bacterium because system often discharges excess sludge The phosphorus of intake also will discharge system, thus can obtain preferable phosphor-removing effect therewith.
At the same time, sewage obtains the dissolved oxygen of abundance in Aerobic Pond, occurs nitration reaction, and ammonia nitrogen is in nitrous acid in water Nitrite is oxidized in the presence of bacterium, nitrate is then further oxidized in the presence of Nitromonas.Nitre in Aerobic Pond Change liquid and be back to anoxic pond, under conditions of dissolved oxygen is 0.5mg/L or so, using the carbon source of itself of intaking, occur denitrification Reaction, makes nitrite and nitrate that nitrification is produced be reduced into nitrogen in the presence of denitrifying bacteria, so as to realize total The removal of nitrogen.
In actual motion, the effect of above-mentioned denitrogenation dephosphorizing process is by two factor controllings of temperature and carbon source.In order in difference Season and different inlet COD concentration operating mode under, optimal Nitrogen/Phosphorus Removal can be obtained, the present invention, which is realized, only to be set up A set of biochemical system, the operation for realizing four kinds of different biochemical modes by pipe valve and the conversion of pond body switches, and realizes each Corresponding biochemical mode can be run in season with optimal treatment effect.Meanwhile, each system uses multipoint water feeding, leads to The reasonable distribution to water-inlet carbon source is crossed, solves to be difficult to total nitrogen and total phosphorus in conventional treatment the problem of removal up to standard.
It should be appreciated that the part that this specification is not elaborated belongs to prior art.
It should be appreciated that the above-mentioned description for preferred embodiment is more detailed, therefore it can not be considered to this The limitation of invention patent protection scope, one of ordinary skill in the art is not departing from power of the present invention under the enlightenment of the present invention Profit is required under protected ambit, can also be made replacement or be deformed, each fall within protection scope of the present invention, this hair It is bright scope is claimed to be determined by the appended claims.

Claims (10)

1. a kind of carry out the sewage denitrification dephosphorization system that biochemical unit switches according to season, it is characterised in that:Including pretreatment System, pre- anoxic pond, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry pool, the 4th biochemistry pool, Aerobic Pond, second pond;
The preprocessing subsystem is connected with the pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool respectively by conduit, wherein Valve A and valve B, preprocessing subsystem and the first life are provided with the conduit connected between preprocessing subsystem and pre- anoxic pond Change and be provided with valve A, valve D and valve F on the conduit connected between pond, connected between preprocessing subsystem and the 3rd biochemistry pool Conduit on be provided with valve A, valve E and valve J;
The pre- anoxic pond is connected by conduit with first biochemistry pool, and valve C and valve F are provided with connecting pipe;
First biochemistry pool is connected with second biochemistry pool, the 3rd biochemistry pool respectively by conduit;First biochemistry pool and It is provided with valve I, the conduit connected between the first biochemistry pool and the 3rd biochemistry pool and sets on the conduit connected between two biochemistry pools It is equipped with valve G and valve J;
Second biochemistry pool is connected by conduit with the 3rd biochemistry pool, and valve H and valve J are provided with connecting pipe;
3rd biochemistry pool is connected with the 4th biochemistry pool, Aerobic Pond respectively by conduit;3rd biochemistry pool and the 4th life Change to be provided with valve M, the conduit connected between the 3rd biochemistry pool and Aerobic Pond on the conduit connected between pond and be provided with valve K;
The Aerobic Pond is connected by conduit with the second pond;
The second pond is connected by reflux line with the pre- anoxic pond, the first biochemistry pool respectively, is set respectively on connecting pipe It is equipped with valve P, valve O;The Aerobic Pond is connected by reflux line with the 3rd biochemistry pool, and valve is provided with connecting pipe Door N.
2. according to claim 1 carry out the sewage denitrification dephosphorization system that biochemical unit switches according to season, its feature exists In:Aerator is provided with the pre- anoxic pond, installing aeration plate by bottom of pond using roots blower carries out aeration oxygen supply, with Realize the alternating of hypoxemia in pre- anoxic pond/normal oxygen operating mode;Aerator is provided with the Aerobic Pond, is passed through using roots blower Bottom of pond installs aeration plate and carries out aeration oxygen supply.
3. according to claim 1 carry out the sewage denitrification dephosphorization system that biochemical unit switches according to season, its feature exists In:The pre- anoxic pond, the first biochemistry pool, the second biochemistry pool, the 3rd biochemistry pool, it is provided with submersible agitating in the 4th biochemistry pool Device.
4. according to claim 3 carry out the sewage denitrification dephosphorization system that biochemical unit switches according to season, its feature exists In:The submersible agitator uses low-speed propulsion device, and wheel speed is set to during operation:36r/min~56r/min.
5. a kind of carry out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, it is characterised in that:Winter is using inversion A2/ O techniques, spring uses modified form A2/ O techniques, summer uses pre- anoxic+inversion A2/ O techniques, autumn is using hypoxemia/normal oxygen Alternate pre- anoxic+inversion A2/ O techniques;
The inversion A2/ O techniques, implement and comprise the following steps:
Step A1:Open valve A, valve D, valve F, valve E, valve I, valve J, close remaining valve, and now first is biochemical Pond is connected with the second biochemistry pool, is combined as anoxic pond, the 3rd biochemistry pool is separately as anaerobic pond;Preprocessed subsystem is located in advance Water after reason is respectively fed to the first biochemistry pool, the 3rd biochemistry pool;In the first biochemistry pool, the second biochemistry pool denitrification occurs for water inlet Effect, nitrifies the nitrite produced and nitrate is reduced into nitrogen in the presence of denitrifying bacteria, it is achieved thereby that de- Nitrogen;
Step A2:Sewage enters in the 3rd biochemistry pool in Open valve H, the second biochemistry pool, and polyP bacteria releases phosphorus in anaerobic pond;
Step A3:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, and polyP bacteria is directly entered after anaerobic pond releases phosphorus Aerobic Pond, occurs poly- phosphorus reaction and nitrification in Aerobic Pond, and mud mixture gravity flow enters two and sunk after pollutant is degraded Pond;
Step A4:In Open valve O, second pond in nitrification liquid and sludge reflux to the first biochemistry pool;
The modified form A2/ O techniques, implement and comprise the following steps:
Step B1:Open valve A, valve B, valve D, valve F, valve E, valve J, close remaining valve, preprocessed subsystem Pretreated water of uniting is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, and now the first biochemistry pool is separately as detesting Oxygen pond;Denitrification occurs in pre- anoxic pond for sewage, removes total nitrogen;
Step B2:Sewage in Open valve C, pre- anoxic pond sends into the first biochemistry pool, by the effect of polyP bacteria, utilizes water inlet Itself carbon source, realizes the release of phosphorus;
Step B3:Sewage sends into the 3rd biochemistry pool in Open valve G, the first biochemistry pool;Open valve M, the 3rd biochemistry pool of connection, 4th biochemistry pool;Now the 3rd biochemistry pool, the combination of the 4th biochemistry pool are as anoxic pond, and sewage is in the 3rd biochemistry pool, the 4th biochemistry Continue occur denitrification in pond, nitrify the nitrite produced and nitrate is reduced into the presence of denitrifying bacteria Nitrogen, it is achieved thereby that denitrogenation;
Step B4:Sewage enters Aerobic Pond in Open valve L, the 4th biochemistry pool, and poly- phosphorus reaction and nitrification occur in Aerobic Pond Effect, mud mixture gravity flow enters second pond after pollutant is degraded;
Step B5:In Open valve P, valve N, second pond in sludge reflux to pre- anoxic pond, nitrification liquid is back in Aerobic Pond In 3rd biochemistry pool;
Pre- anoxic+the inversion A2/ O techniques, implement and comprise the following steps:
Step C1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve, and now One biochemistry pool is connected with the second biochemistry pool, is combined as anoxic pond, the 3rd biochemistry pool is separately as anaerobic pond;Preprocessed subsystem Pretreated water of uniting is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool;Anti- nitre occurs in pre- anoxic pond for sewage Change is acted on, and removes total nitrogen;
Step C2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, and sewage is biochemical first Continue occur denitrification in pond, the second biochemistry pool, nitrify the work of the nitrite produced and nitrate in denitrifying bacteria Nitrogen is reduced under, it is achieved thereby that denitrogenation;
Step C3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is separately as detesting Oxygen pond, sewage, using itself carbon source of intaking, realizes the release of phosphorus by the effect of polyP bacteria;
Step C4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, and poly- phosphorus reaction and nitrification occur in Aerobic Pond Effect, mud mixture gravity flow enters second pond after pollutant is degraded;
Step C5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond;
The hypoxemia/alternate pre- anoxic+the inversion A of normal oxygen2/ O techniques, implement and comprise the following steps:
Step D1:Open valve A, valve B, valve D, valve F, valve E, valve I, valve J, close remaining valve;Now One biochemistry pool is connected with the second biochemistry pool, is combined as anoxic pond, the 3rd biochemistry pool is separately as anaerobic pond;Preprocessed subsystem Pretreated water of uniting is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool;
Sewage enters pre- anoxic pond, now controls to adjust DO concentration in pre- anoxic pond using hypoxemia/normal alternate mode of oxygen;
Step D2:Sewage sends into the first biochemistry pool, in the second biochemistry pool in Open valve C, pre- anoxic pond, the first biochemistry pool, Continue occur denitrification in second biochemistry pool, nitrify the nitrite produced and nitrate in the presence of denitrifying bacteria Nitrogen is reduced into, it is achieved thereby that denitrogenation;
Step D3:Sewage sends into the 3rd biochemistry pool in Open valve H, the second biochemistry pool;Now the 3rd biochemistry pool is as anaerobic pond, Sewage, using itself carbon source of intaking, realizes the release of phosphorus by the effect of polyP bacteria;
Step D4:Sewage enters Aerobic Pond in Open valve K, the 3rd biochemistry pool, and poly- phosphorus reaction and nitrification occur in Aerobic Pond Effect, mud mixture gravity flow enters second pond after pollutant is degraded;
Step D5:In Open valve P, second pond in nitrification liquid and sludge reflux to pre- anoxic pond.
6. according to claim 5 carry out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, its feature exists In:In step A1, the preprocessed pretreated water of subsystem is respectively fed to the first biochemistry pool, the 3rd biochemistry pool, ratio of intaking For 4:6, to distribute denitrification and release the carbon source required for phosphorus effect;It is latent in the first biochemistry pool, the second biochemistry pool in step A1 Water agitator is opened, and rotating speed is disposed as 50r/min, when the first biochemistry pool, the combination pond body hydraulic retention of the second biochemistry pool Between be 4h;In step A2, the 3rd biochemical pool inner water power residence time was 1.5h, and submersible agitator is closed;In step A4, reflux ratio For 150%.
7. according to claim 5 carry out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, its feature exists In:In step B1, the preprocessed pretreated water of subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, Water inlet ratio is 4:3:3, to distribute denitrification and release the carbon source required for phosphorus effect;Submersible agitator in pre- anoxic pond is opened Open, rotating speed is set to 45r/min;In step B2, hydraulic detention time is 1.5h in the first biochemistry pool;In step B3, the three lives Change pond, the submersible agitator of the 4th biochemistry pool to open, rotating speed is set to 45r/min, and hydraulic detention time is 4h;Step B5 In, in second pond in nitrification liquid and sludge reflux to pre- anoxic pond, reflux ratio is 75%;Nitrification liquid and sludge reflux in Aerobic Pond To the 3rd biochemistry pool, reflux ratio is 200%.
8. according to claim 5 carry out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, its feature exists In:In step C1, the preprocessed pretreated water of subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, Water inlet ratio is 4:3:3, to distribute denitrification and release the carbon source required for phosphorus effect;Submersible agitator in pre- anoxic pond is opened Open, rotating speed is set to 40r/min;In step C2, the first biochemistry pool, the submersible agitator of the second biochemistry pool are opened, and rotating speed is set 40r/min is set to, hydraulic detention time is 4h;In step C3, the 3rd biochemical pool inner water power residence time was 1.5h;Step C5 In, reflux ratio is 150%.
9. according to claim 5 carry out the sewage denitrification and dephosphorization method that biochemical unit switches according to season, its feature exists In:In step D1, the preprocessed pretreated water of subsystem is respectively fed to pre- anoxic pond, the first biochemistry pool, the 3rd biochemistry pool, Water inlet ratio is 4:3:3, to distribute denitrification and release the carbon source required for phosphorus effect;The hypoxemia/alternate the mode of normal oxygen, when During using normal oxygen operating mode, the submersible agitator set in pre- anoxic pond is closed, aeration plate in pre- anoxic pond is opened, adjustment DO is arrived 1.5~2.5mg/L;When using hypoxemia operating mode, aeration plate in pre- anoxic pond is closed, the diving set in pre- anoxic pond is opened and stirs Device is mixed, rotating speed is set to 40r/min, adjusts DO to 0.3~0.6mg/L;Hypoxemia and normal oxygen alternate cycle are 1~2 week;Step In D2, the first biochemistry pool, the submersible agitator of the second biochemistry pool are opened, and rotating speed is disposed as 40r/min, hydraulic detention time For 4h;In step D3, the 3rd biochemical pool inner water power residence time was 1.5h;In step D5, reflux ratio is 150%.
10. the sewage denitrification and dephosphorization side that biochemical unit switches is carried out according to season according to claim 5-9 any one Method, it is characterised in that:When the first biochemistry pool, the 3rd biochemistry pool are run in anaerobic pond form, DO concentration control 0.2mg/L with Under;When the first biochemistry pool and the combination of the second biochemistry pool, the 3rd biochemistry pool and the combination of the 4th biochemistry pool are run in anoxic pond form, DO concentration is controlled in 0.3~0.6mg/L;In the Aerobic Pond, DO concentration is controlled in 1.5~2.5mg/L.
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