CN107236395A - Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof - Google Patents

Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof Download PDF

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Publication number
CN107236395A
CN107236395A CN201710457089.8A CN201710457089A CN107236395A CN 107236395 A CN107236395 A CN 107236395A CN 201710457089 A CN201710457089 A CN 201710457089A CN 107236395 A CN107236395 A CN 107236395A
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China
Prior art keywords
alcohol
parts
organic silicon
silicon sol
soluble organic
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Pending
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CN201710457089.8A
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Chinese (zh)
Inventor
张英强
闫雅贤
李婧怡
李烨
谢志伟
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Shanghai Institute of Technology
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Shanghai Institute of Technology
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Priority to CN201710457089.8A priority Critical patent/CN107236395A/en
Publication of CN107236395A publication Critical patent/CN107236395A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0881Titanium

Abstract

The invention discloses a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, calculate, be made up of 60 70 parts of multiple cross-linked resins of alcohol-soluble, 60 70 parts of alcohol-soluble organic silicon sols, 0.05 0.1 parts of levelling agent, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 38 parts of composite iron-titanium powders and 10 20 parts of functional stuffings by weight.Present invention also offers the preparation method of above-mentioned coating, partially wetted dose, part defoamer and alcoholic solvent are added in high speed dispersor, functional stuffing is added after scattered, the multiple cross-linked resin of alcohol-soluble, alcohol-soluble organic silicon sol and remaining defoamer, remaining wetting agent, levelling agent are added after redisperse and is stirred, continue scattered, through being filtered to remove filter residue after well mixed, that is, obtain the quick-drying Stripable paint containing alcohol-soluble organic silicon sol.The quick-drying Stripable paint of the present invention has fast rate of drying, preferable rust-preventing characteristic and preferable rippability.

Description

Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, it is related to a kind of coating, specifically one kind has containing alcohol-soluble Quick-drying Stripable paint of machine Ludox and preparation method thereof.
Background technology
Strippable coatings is a kind of temporary protection material using macromolecule as main film forming substance, and object is sprayed on when using On surface, protective effect in short-term is played to coated article after film forming;In coated article in use, by film layer from coated article surface with hand gently Peel off, do not result in injury not only to coated article surface, can also the original device appearance of energy it is sparkling clean.Strippable coatings due to Application is convenient, it is easy to peel off, thus is extensively welcome by industries such as instrument, instrument, household electrical appliances, machinery, automobile, electronic apparatus, develops Rapidly.
At present, it is mainly solvent-borne type rippability coating and the aqueous class of rippability coating two on domestic market.Wherein, contain Although the solvent-borne type rippability coating better performances of aromatic hydrocarbons, it gradually fades out market due to being unsatisfactory for environmental requirement, and mesh Although preceding aqueous Stripable paint meets environmental protection, there is drying time long(2 ~ 3 hours), used in metal object surface when gold The problems such as metal surface easily gets rusty, it is difficult to meet the need of the quick production of high-speed production streamline and social development to high-performance coating Will, it greatly limit its popularization and application.
Based on background above, it is necessary to develop a kind of environmental protection, the Stripable paint that drying time is short, peeling effect is good and its system Preparation Method.
The content of the invention
For above-mentioned technical problem of the prior art, contain the fast of alcohol-soluble organic silicon sol the invention provides a kind of Dry Stripable paint and preparation method thereof, the described this quick-drying Stripable paint containing alcohol-soluble organic silicon sol and its system Preparation Method will solve aqueous Stripable paint drying time length of the prior art, the technical problem easily got rusty.
The invention provides a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, calculate by weight, Its raw material is constituted and content is as follows:
Multiple cross-linked resin 60-70 parts of alcohol-soluble;
60-70 parts of alcohol-soluble organic silicon sol;
0.05-0.1 parts of levelling agent;
1-10 parts of wetting agent;
0.2-1 parts of defoamer;
3-8 parts of composite iron-titanium powder;
10-20 parts of functional stuffing;
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described levelling agent is Germany BYK Bi Ke BYK-3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK- 347th, in BYK-348 any one or two or more mixtures;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described functional stuffing is mica.
Further, a kind of above-mentioned quick-drying Stripable paint containing alcohol-soluble organic silicon sol, is counted by weight Calculate, its raw material composition and content are as follows:
60 parts of the multiple cross-linked resin of alcohol-soluble;
60 parts of alcohol-soluble organic silicon sol;
0.05 part of levelling agent;
1 part of wetting agent;
0.2 part of defoamer;
3 parts of composite iron-titanium powder;
10 parts of functional stuffing;
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described levelling agent is the BYK 346 of BYK companies;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described functional stuffing is mica.
Further, above-mentioned a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, it is characterised in that press Parts by weight are calculated, and its raw material composition and content are as follows:
70 parts of the multiple cross-linked resin of alcohol-soluble;
70 parts of alcohol-soluble organic silicon sol;
0.1 part of levelling agent;
10 parts of wetting agent;
1 part of defoamer;
8 parts of composite iron-titanium powder;
20 parts of functional stuffing;
The multiple cross-linked resin of wherein described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described levelling agent is Germany BYK Bi Ke BYK-3510;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described functional stuffing is mica.
Present invention also offers a kind of preparation side of above-mentioned quick-drying Stripable paint containing alcohol-soluble organic silicon sol Method, comprises the following steps:According to formula, 70 ~ 90% wetting agent, 10 ~ 30% defoamer, compound is added in high speed dispersor Ferrotitanium powder and alcoholic solvent, through disperseing 15-20min under 600-800r/min rotating speeds, add functional stuffing, through 1600-2800r/ Disperse under min rotating speeds after 30-50min, rotating speed is down to 300r/min, add the multiple cross-linked resin of alcohol-soluble, alcohol-soluble organic Ludox and remaining defoamer, remaining wetting agent, levelling agent simultaneously stir, and continue scattered 5-10min, after being well mixed Filter residue is removed by filtration, that is, obtains the quick-drying Stripable paint containing alcohol-soluble organic silicon sol.
A kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol of the present invention, in environment-friendly type solvent alcoholic solvent Under effect, the rate of drying for making coating overall is greatly speeded up, and drying time shortens dramatically, through being scratched in treated tinplate sheet Twice, drying time is 30-60min, far faster than the drying time of 2~3 hours of current aqueous Stripable paint.The present invention's A kind of functional stuffing in quick-drying Stripable paint containing alcohol-soluble organic silicon sol, the raw material of addition is to fill to tie with lamella The filler of structure, with stronger barrier, is delayed corrosion of the external environment to ground, while assigning film excellent stripping From performance.When determining the drying of film by drying time GB/T 1728-1979 " paint film, putty membrane drying time determination method " Between be 30-60min;Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/ using Shenzhen T2790-1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/ min;Peel strength is measured for 0.25 ~ 0.93kN/m;
The present invention is compared with prior art, and its technological progress is significant.Have the invention provides one kind environmentally friendly, preferably anti- Rust property, drying time is short, peeling effect well can Stripable paint, and its preparation method due to technique it is simple, it is easy to control, technology into It is ripe, make it possible to use in the industry technology such as instrument, instrument, household electrical appliances, machinery, automobile, electronic apparatus field.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available, Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows:
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai;
Newly think carefully that company produces in CMT5104 electronic tension testers, Shenzhen;
GS450 small-size vibration screens, the production of Laizhou City Jingtai chemical.
Embodiment 1
A kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, is calculated by weight, its raw material composition and content It is as follows:
60 parts of the multiple cross-linked resin of alcohol-soluble
60 parts of alcohol-soluble organic silicon sol
0.05 part of levelling agent
1 part of wetting agent
0.2 part of defoamer
3 parts of composite iron-titanium powder
10 parts of functional stuffing
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described levelling agent is the BYK 346 of BYK companies;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described functional stuffing is mica;
A kind of preparation method of above-mentioned quick-drying Stripable paint containing alcohol-soluble organic silicon sol, specifically includes following step Suddenly:
According to formula, add 0.7 part of wetting agent, 0.02 part of defoamer, 3 parts of composite iron-titanium powders and 20ml alcoholic solvents and be added to GFJ- 0.4 type high speed dispersor(The new promise experimental instruments and equipment limited in Shanghai)In, through disperseing 15min under 600r/min rotating speeds, add 10 parts of functional stuffings, after disperseing 30min under 1600r/min rotating speeds, 300r/min is down to by rotating speed, 60 parts of alcohol-solubles are added many Weight crosslinked resin, 60 parts of alcohol-soluble organic silicon sols and 0.18 part of defoamer, 0.3 part of wetting agent, 0.05 part of levelling agent are simultaneously stirred Uniformly, scattered 5min is continued, through GS450 small-size vibration screens after being well mixed(Laizhou City Jingtai chemical)Filtering, is produced To the quick-drying Stripable paint containing alcohol-soluble organic silicon sol.
By the quick-drying Stripable paint obtained above containing alcohol-soluble organic silicon sol using knife coating in by acetone, Twice are scratched in the treated tinplate sheet of alcoholic solvent, ventilation drying at room temperature is placed on.According to GB/T 1728-1979 " paint film, The drying time that putty membrane drying time determination method " determines film is 30min;
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min;Measure stripping Intensity is 0.25kN/m;
Have in summary after the quick-drying Stripable paint film containing alcohol-soluble organic silicon sol obtained by the present invention faster Drying time and preferable rust-preventing characteristic, relatively low peel strength.
Embodiment 2
A kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, is calculated by weight, its raw material composition and content It is as follows:
70 parts of the multiple cross-linked resin of alcohol-soluble
70 parts of alcohol-soluble organic silicon sol
0.1 part of levelling agent
10 parts of wetting agent
1 part of defoamer
8 parts of composite iron-titanium powder
20 parts of functional stuffing
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described levelling agent is Germany BYK Bi Ke BYK-3510;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described functional stuffing is mica;
A kind of preparation method of above-mentioned quick-drying Stripable paint containing alcohol-soluble organic silicon sol, specifically includes following step Suddenly:
According to formula, add 9 parts of wetting agents, 0.3 part of defoamer, 8 parts of composite iron-titanium powders and 40ml alcoholic solvents and be added to GFJ-0.4 Type high speed dispersor(The new promise experimental instruments and equipment limited in Shanghai)In, through disperseing 20min under 800r/min rotating speeds, add 20 parts Functional stuffing, after disperseing 50min under 2800r/min rotating speeds, 300r/min is down to by rotating speed, adds the multiple friendship of 70 parts of alcohol-solubles Join resin, 70 parts of alcohol-soluble organic silicon sols and remaining 0.7 part of defoamer, 1 part of wetting agent, 0.1 part of levelling agent and stir equal It is even, continue scattered 10min, through GS450 small-size vibration screens after being well mixed(Laizhou City Jingtai chemical)Filtering, that is, obtain Quick-drying Stripable paint containing alcohol-soluble organic silicon sol.
By the quick-drying Stripable paint obtained above containing alcohol-soluble organic silicon sol using knife coating in by acetone, Twice are scratched in the treated tinplate sheet of alcoholic solvent, ventilation drying at room temperature is placed on.According to GB/T 1728-1979 " paint film, The drying time that putty membrane drying time determination method " determines film is 60min;
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min;Measure stripping Intensity is 0.93kN/m;
There is faster drying time after the quick-drying Stripable paint film containing alcohol-soluble organic silicon sol obtained by the present invention With preferable rust-preventing characteristic, relatively low peel strength.
The multiple cross-linked resin of alcohol-soluble and alcohol-soluble organic silicon sol in the raw material obtained by the present invention exist in summary Crosslinked formation tridimensional network in the volatilization process of alcoholic solvent, the volatilization auxiliary of alcoholic solvent makes coating have quick-drying, applies There is shorter drying time after film(30-60min);The complexing power of the bind metal ion of addition makes it have preferably anti- Protect effect.Functional stuffing in raw material is the filler with lamella assembling structure, with stronger barrier, is effectively reduced into The tack of membrane interface, with preferable rippability, peel strength is 0.25 ~ 0.93kN/m.
The content is only the basic explanation under present inventive concept, and according to technical scheme made it is any etc. Effect conversion, all should belong to protection scope of the present invention.

Claims (4)

1. a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol, it is characterised in that calculate by weight, it is former Material composition and content are as follows:
Multiple cross-linked resin 60-70 parts of alcohol-soluble;
60-70 parts of alcohol-soluble organic silicon sol;
0.05-0.1 parts of levelling agent;
1-10 parts of wetting agent;
0.2-1 parts of defoamer;
3-8 parts of composite iron-titanium powder;
10-20 parts of functional stuffing;
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described levelling agent is Germany BYK Bi Ke BYK-3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK- 347th, in BYK-348 any one or two or more mixtures;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described functional stuffing is mica.
2. a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol as claimed in claim 1, it is characterised in that press Parts by weight are calculated, and its raw material composition and content are as follows:
60 parts of the multiple cross-linked resin of alcohol-soluble;
60 parts of alcohol-soluble organic silicon sol;
0.05 part of levelling agent;
1 part of wetting agent;
0.2 part of defoamer;
3 parts of composite iron-titanium powder;
10 parts of functional stuffing;
Wherein, the multiple cross-linked resin of described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described levelling agent is the BYK 346 of BYK companies;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described functional stuffing is mica.
3. a kind of quick-drying Stripable paint containing alcohol-soluble organic silicon sol as claimed in claim 1, it is characterised in that press Parts by weight are calculated, and its raw material composition and content are as follows:
70 parts of the multiple cross-linked resin of alcohol-soluble;
70 parts of alcohol-soluble organic silicon sol;
0.1 part of levelling agent;
10 parts of wetting agent;
1 part of defoamer;
8 parts of composite iron-titanium powder;
20 parts of functional stuffing;
The multiple cross-linked resin of wherein described alcohol-soluble is the multiple cross-linked acrylate of alcohol-soluble;
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol;
Described composite iron-titanium powder is the WD-H-803 of Jinan Ward Chemical Co., Ltd.;
Described levelling agent is Germany BYK Bi Ke BYK-3510;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described functional stuffing is mica.
4. a kind of preparation method of quick-drying Stripable paint containing alcohol-soluble organic silicon sol described in claim 1,2 or 3, It is characterized in that comprising the following steps:According to formula, the wetting agent of addition 70 ~ 90%, 10 ~ 30% froth breaking in high speed dispersor Agent, composite iron-titanium powder and alcoholic solvent, through disperseing 15-20min under 600-800r/min rotating speeds, add functional stuffing, through 1600- Disperse under 2800r/min rotating speeds after 30-50min, rotating speed is down to 300r/min, add the multiple cross-linked resin of alcohol-soluble, alcohol molten Property organic silicon sol and remaining defoamer, remaining wetting agent, levelling agent and stir, continue scattered 5-10min, mixing Through being filtered to remove filter residue after uniform, that is, obtain the quick-drying Stripable paint containing alcohol-soluble organic silicon sol.
CN201710457089.8A 2017-06-16 2017-06-16 Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof Pending CN107236395A (en)

Priority Applications (1)

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CN201710457089.8A CN107236395A (en) 2017-06-16 2017-06-16 Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710457089.8A CN107236395A (en) 2017-06-16 2017-06-16 Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof

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CN107236395A true CN107236395A (en) 2017-10-10

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613434A (en) * 2009-07-15 2009-12-30 华南理工大学 A kind of alcohol soluble polyacrylate resin and preparation method thereof and application
CN104449390A (en) * 2014-11-24 2015-03-25 天长市开林化工有限公司 Quick-drying, alcohol-soluble and antirust paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613434A (en) * 2009-07-15 2009-12-30 华南理工大学 A kind of alcohol soluble polyacrylate resin and preparation method thereof and application
CN104449390A (en) * 2014-11-24 2015-03-25 天长市开林化工有限公司 Quick-drying, alcohol-soluble and antirust paint and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
田龙飞: "交联型醇溶性丙烯酸树脂的制备及应用研究", 《中国优秀硕士学位论文全文数据库工程科技I辑》 *
钟燕妮: "水性可剥离涂料的制备", 《中国优秀硕士学位论文全文数据库工程科技I辑》 *

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