CN107216755A - A kind of quick-drying Stripable paint and preparation method thereof - Google Patents
A kind of quick-drying Stripable paint and preparation method thereof Download PDFInfo
- Publication number
- CN107216755A CN107216755A CN201710456735.9A CN201710456735A CN107216755A CN 107216755 A CN107216755 A CN 107216755A CN 201710456735 A CN201710456735 A CN 201710456735A CN 107216755 A CN107216755 A CN 107216755A
- Authority
- CN
- China
- Prior art keywords
- alcohol
- parts
- byk
- drying
- organic silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
Abstract
The invention provides a kind of quick-drying Stripable paint, calculate, be made up of 50 100 parts of alcohol-soluble self-crosslinking resins, 50 100 parts of alcohol-soluble organic silicon sols, 0.05 0.1 parts of levelling agent, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 38 parts of rust resisting pigments and 10 20 parts of functional stuffings by weight.Present invention also offers the preparation method of above-mentioned coating, according to formula, added in high speed dispersor partially wetted dose, defoamer, rust resisting pigment and alcoholic solvent, added after scattered after functional stuffing, redisperse, rotating speed is down to 300r/min, add alcohol-soluble self-crosslinking resin, alcohol-soluble organic silicon sol and remaining defoamer, wetting agent, levelling agent and stir, continue scattered, through being filtered to remove filter residue after being well mixed, that is, obtain quick-drying Stripable paint.The quick-drying Stripable paint of the present invention has fast rate of drying, preferable rust-preventing characteristic and preferable rippability.
Description
Technical field
The invention belongs to technical field of polymer materials, it is related to a kind of coating, specifically a kind of quick-drying is peelable applies
Material and preparation method thereof.
Background technology
Strippable coatings is a kind of temporary protection material using macromolecule as main film forming substance, and object is sprayed on when using
On surface, protective effect in short-term is played to coated article after film forming；In coated article in use, by film layer from coated article surface with hand gently
Peel off, do not result in injury not only to coated article surface, can also the original device appearance of energy it is sparkling clean.Strippable coatings due to
Application is convenient, it is easy to peel off, thus is extensively welcome by industries such as instrument, instrument, household electrical appliances, machinery, automobile, electronic apparatus, develops
Rapidly.
At present, it is mainly solvent-borne type rippability coating and the aqueous class of rippability coating two on domestic market.Wherein, contain
Although the solvent-borne type rippability coating better performances of aromatic hydrocarbons, it gradually fades out market due to being unsatisfactory for environmental requirement, and mesh
Although preceding aqueous Stripable paint meets environmental protection, there is drying time long（2 ~ 3 hours）, used in metal object surface when gold
The problems such as metal surface easily gets rusty, it is difficult to meet the need of the quick production of high-speed production streamline and social development to high-performance coating
Will, it greatly limit its popularization and application.
Based on background above, it is necessary to develop a kind of environmental protection, the Stripable paint that drying time is short, peeling effect is good and its system
Preparation Method.
The content of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of quick-drying Stripable paint and its preparation side
Method, described this quick-drying Stripable paint and preparation method thereof will solve aqueous Stripable paint of the prior art when drying
Between it is long, used in metal object surface when the metal surface technical problem easily got rusty.
The invention provides a kind of quick-drying Stripable paint, calculate by weight, its raw material composition and content are as follows：
50-100 parts of alcohol-soluble self-crosslinking resin；
50-100 parts of alcohol-soluble organic silicon sol；
0.05-0.1 parts of levelling agent；
1-10 parts of wetting agent；
0.2-1 parts of defoamer；
3-8 parts of rust resisting pigment；
10-20 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described levelling agent is Germany BYK Bi Ke BYK-3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-
347th, in BYK-348 any one or two or more mixtures；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described rust resisting pigment is any one in composite iron-titanium powder, trbasic zinc phosphate or aluminium triphosphate or two kinds of mixing；
Described functional stuffing is mica.
Further, a kind of described quick-drying Stripable paint, is calculated by weight, and its raw material composition and content are such as
Under：
50 parts of alcohol-soluble self-crosslinking resin；
50 parts of alcohol-soluble organic silicon sol；
0.05 part of levelling agent；
1 part of wetting agent；
0.2 part of defoamer；
3 parts of rust resisting pigment；
10 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described levelling agent is the BYK 346 of BYK companies；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described functional stuffing is mica.
Further, a kind of described quick-drying Stripable paint, is calculated by weight, and its raw material composition and content are such as
Under：
100 parts of alcohol-soluble self-crosslinking resin；
100 parts of alcohol-soluble organic silicon sol；
0.1 part of levelling agent；
10 parts of wetting agent；
1 part of defoamer；
8 parts of rust resisting pigment；
20 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described levelling agent is Germany BYK Bi Ke BYK-3510；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described functional stuffing is mica.
Present invention also offers a kind of preparation method of above-mentioned quick-drying Stripable paint, comprise the following steps：According to
Side, wetting agent, 10 ~ 30% defoamer, rust resisting pigment and the alcoholic solvent of addition 70 ~ 90% in high speed dispersor, through 600-
Disperse 15-20min under 800r/min rotating speeds, add functional stuffing, through disperseing 30-50min under 2000-2500r/min rotating speeds
Afterwards, rotating speed is down to 300r/min, adds alcohol-soluble self-crosslinking resin, alcohol-soluble organic silicon sol and remaining defoamer, remains
Remaining wetting agent, levelling agent simultaneously stir, and continue scattered 5-10min, through being filtered to remove filter residue after being well mixed, that is, obtain fast
Dry Stripable paint.
A kind of quick-drying Stripable paint of the present invention, in the presence of environment-friendly type solvent alcoholic solvent, makes coating is overall to do
Dry speed is greatly speeded up, and drying time shortens dramatically, and through scratching twice in treated tinplate sheet, drying time is 30-
60min, far faster than the drying time of 2~3 hours of current aqueous Stripable paint.A kind of quick-drying of the present invention is peelable to be applied
Functional stuffing in material, the raw material of addition is the filler with lamella assembling structure, with stronger barrier, makes external environment pair
The corrosion of ground is delayed, while assigning film excellent stripping performance.By drying time GB/T 1728-1979 " paints
The drying time that film, putty membrane drying time determination method " determines film is 30-60min；Peel strength newly thinks carefully public affairs using Shenzhen
The CMT5104 electronic tension testers of department press GB/T2790-1995 standards " 180 ° of peeling strength test sides of adhesive at room temperature
Method " carries out 180 ° of peel test, draw speed 50mm/min；Peel strength is measured for 0.25 ~ 0.91kN/m.
The present invention is compared with prior art, and its technological progress is significant.The quick-drying Stripable paint of the present invention has dry
Dry speed is fast, preferable rust-preventing characteristic and preferable rippability, and its preparation method due to technique it is simple, it is easy to control, technology into
It is ripe.It can use in the industry technology such as instrument, instrument, household electrical appliances, machinery, automobile, electronic apparatus field.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai；
Newly think carefully that company produces in CMT5104 electronic tension testers, Shenzhen；
GS450 small-size vibration screens, the production of Laizhou City Jingtai chemical.
Embodiment 1
A kind of quick-drying Stripable paint, is calculated by weight, and its raw material composition and content are as follows：
50 parts of alcohol-soluble self-crosslinking resin；
50 parts of alcohol-soluble organic silicon sol；
0.05 part of levelling agent；
1 part of wetting agent；
0.2 part of defoamer；
3 parts of rust resisting pigment；
10 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described levelling agent is the BYK 346 of BYK companies；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described functional stuffing is mica.
A kind of preparation method of above-mentioned quick-drying Stripable paint, specifically includes following steps：
According to formula, add 0.7 part of wetting agent, 0.02 part of defoamer, 3 parts of rust resisting pigments and 20 parts of alcoholic solvents and be added to GFJ-
0.4 type high speed dispersor（The new promise experimental instruments and equipment limited in Shanghai）In, through disperseing 15min under 600r/min rotating speeds, add
10 parts of functional stuffings, after disperseing 30min under 2000r/min rotating speeds, 300r/min is down to by rotating speed, adds 50 parts of alcohol-solubles certainly
Crosslinked resin, 50 parts of alcohol-soluble organic silicon sols and 0.18 part of defoamer, 0.3 part of wetting agent, 0.05 part of levelling agent simultaneously stir equal
It is even, continue scattered 5min, through GS450 small-size vibration screens after being well mixed（Laizhou City Jingtai chemical）Filtering, that is, obtain
Quick-drying Stripable paint.
By quick-drying Stripable paint obtained above using knife coating in by the treated tinplate sheet of acetone, alcoholic solvent
Upper blade coating twice, are placed on ventilation drying at room temperature.Surveyed according to GB/T 1728-1979 " paint film, putty membrane drying time determination method "
The drying time for determining film is 30min；
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
Have in summary after the quick-drying Stripable paint film obtained by the present invention faster drying time and preferable rust-preventing characteristic,
Relatively low peel strength.
Embodiment 2
A kind of quick-drying Stripable paint, is calculated by weight, and its raw material composition and content are as follows：
100 parts of alcohol-soluble self-crosslinking resin；
100 parts of alcohol-soluble organic silicon sol；
0.1 part of levelling agent；
10 parts of wetting agent；
1 part of defoamer；
8 parts of rust resisting pigment；
20 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is acid alcohol-soluble organic silicon sol；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described levelling agent is Germany BYK Bi Ke BYK-3510；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described functional stuffing is mica.
A kind of preparation method of above-mentioned quick-drying Stripable paint, specifically includes following steps：
According to formula, add 9 parts of wetting agents, 0.3 part of defoamer, 8 parts of rust resisting pigments and 40 parts of alcoholic solvents and be added to GFJ-0.4 types
High speed dispersor（The new promise experimental instruments and equipment limited in Shanghai）In, through disperseing 20min under 800r/min rotating speeds, add 20 parts of work(
Energy filler, after disperseing 50min under 2500r/min rotating speeds, 300r/min is down to by rotating speed, 100 parts of alcohol-soluble self-crosslinkings are added
Resin, 100 parts of alcohol-soluble organic silicon sols and remaining 0.7 part of defoamer, 1 part of wetting agent, 0.1 part of levelling agent simultaneously stir equal
It is even, continue scattered 10min, through GS450 small-size vibration screens after being well mixed（Laizhou City Jingtai chemical）Filtering, that is, obtain
Quick-drying Stripable paint.
By quick-drying Stripable paint obtained above using knife coating in by the treated tinplate sheet of acetone, alcoholic solvent
Upper blade coating twice, are placed on ventilation drying at room temperature.Surveyed according to GB/T 1728-1979 " paint film, putty membrane drying time determination method "
The drying time for determining film is 60min；
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.91kN/m；
There is faster drying time and preferable rust-preventing characteristic, relatively low stripping after quick-drying Stripable paint film obtained by the present invention
From intensity.
The alcohol-soluble self-crosslinking resin and alcohol-soluble organic silicon sol in the raw material obtained by the present invention are in alcohol in summary
Crosslinked formation tridimensional network in the volatilization process of solvent, the volatilization auxiliary of alcoholic solvent makes coating have quick-drying, film
There is shorter drying time afterwards（30-60min）；The complexing power of the rust resisting pigment bind metal ion of addition make it have compared with
Good protection effect.Functional stuffing in raw material is the filler with lamella assembling structure, with stronger barrier, is effectively subtracted
The low tack into membrane interface, with preferable rippability, peel strength is 0.25 ~ 0.91kN/m.
The content is only the basic explanation under present inventive concept, and according to technical scheme made it is any etc.
Effect conversion, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of quick-drying Stripable paint, it is characterised in that calculate by weight, its raw material composition and content are as follows：
50-100 parts of alcohol-soluble self-crosslinking resin；
50-100 parts of alcohol-soluble organic silicon sol；
0.05-0.1 parts of levelling agent；
1-10 parts of wetting agent；
0.2-1 parts of defoamer；
3-8 parts of rust resisting pigment；
10-20 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described levelling agent is Germany BYK Bi Ke BYK-3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-
347th, in BYK-348 any one or two or more mixtures；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described rust resisting pigment is any one in composite iron-titanium powder, trbasic zinc phosphate or aluminium triphosphate or two kinds of mixing；
Described functional stuffing is mica.
2. a kind of quick-drying Stripable paint as claimed in claim 1, it is characterised in that calculate by weight, its raw material composition
And content is as follows：
50 parts of alcohol-soluble self-crosslinking resin；
50 parts of alcohol-soluble organic silicon sol；
0.05 part of levelling agent；
1 part of wetting agent；
0.2 part of defoamer；
3 parts of rust resisting pigment；
10 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described levelling agent is the BYK 346 of BYK companies；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described functional stuffing is mica.
3. a kind of quick-drying Stripable paint as claimed in claim 1, it is characterised in that calculate by weight, its raw material composition
And content is as follows：
100 parts of alcohol-soluble self-crosslinking resin；
100 parts of alcohol-soluble organic silicon sol；
0.1 part of levelling agent；
10 parts of wetting agent；
1 part of defoamer；
8 parts of rust resisting pigment；
20 parts of functional stuffing；
Wherein, described alcohol-soluble self-crosslinking resin is alcohol-soluble self-crosslinking acrylic ester resin；
Described alcohol-soluble organic silicon sol is alkaline alcohol-soluble organic silicon sol；
Described rust resisting pigment is the H-803 rust resisting pigments of Jinan Ward Chemical Co., Ltd.；
Described levelling agent is Germany BYK Bi Ke BYK-3510；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described functional stuffing is mica.
4. the preparation method of a kind of quick-drying Stripable paint described in claim 1,2 or 3, it is characterised in that including following step
Suddenly：According to formula, wetting agent, 10 ~ 30% defoamer, rust resisting pigment and the alcoholic solvent of addition 70 ~ 90% in high speed dispersor,
Through disperseing 15-20min under 600-800r/min rotating speeds, functional stuffing is added, through disperseing 30- under 2000-2500r/min rotating speeds
After 50min, rotating speed is down to 300r/min, alcohol-soluble self-crosslinking resin, alcohol-soluble organic silicon sol and remaining froth breaking is added
Agent, remaining wetting agent, levelling agent simultaneously stir, and continue scattered 5-10min, through being filtered to remove filter residue after being well mixed, i.e.,
Obtain quick-drying Stripable paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710456735.9A CN107216755A (en) | 2017-06-16 | 2017-06-16 | A kind of quick-drying Stripable paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710456735.9A CN107216755A (en) | 2017-06-16 | 2017-06-16 | A kind of quick-drying Stripable paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107216755A true CN107216755A (en) | 2017-09-29 |
Family
ID=59949565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710456735.9A Pending CN107216755A (en) | 2017-06-16 | 2017-06-16 | A kind of quick-drying Stripable paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107216755A (en) |
-
2017
- 2017-06-16 CN CN201710456735.9A patent/CN107216755A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 田龙飞: "交联型醇溶性丙烯酸树脂的制备及应用研究", 《中国优秀硕士学位论文全文数据库工程科技I辑》 * |
| 钟燕妮: "水性可剥离涂料的制备", 《中国优秀硕士学位论文全文数据库工程科技I辑》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103173095B (en) | A kind of Zinc-rich epoxy anticorrosion paint and preparation method thereof | |
| CN103450611B (en) | Damping material and preparation method thereof | |
| CN107141863B (en) | A kind of high-intensity corrosion coating and the preparation method and application thereof | |
| CN105440830B (en) | Scrubbable interior wall coating of a kind of low viscosity height covering height and preparation method thereof | |
| CN105038401B (en) | A kind of washable touch screen protects ink and preparation method and application temporarily | |
| CN110343455A (en) | Aqueous heavy anti-corrosion paint, preparation method and the purposes of the coupling agent modified graphene of silane-containing | |
| CN105462466B (en) | A kind of aqueous-based coating composition of the high pin hole limit | |
| CN105331209A (en) | Extractor hood oil pollution prevention peelable protective film and preparation method | |
| CN105111868A (en) | Self-adhesive paint for silicon steel sheets of high-voltage motor iron core, and preparation method of self-adhesive paint | |
| CN102516847B (en) | Aqueous expansion-preventing transparent primer of medium-density fiber board as well as preparation method and application thereof | |
| JP2020531639A (en) | Low VOC aqueous UV curable single layer coating composition, method for applying the composition, and substrate coated with the composition. | |
| CN106675363A (en) | Graphene functional metal surface long-effect treatment material and preparation method thereof | |
| CN106634449A (en) | Recombined organosilicone modified epoxide resin water-based coat used for corrosion resistant electric power fitting and preparation method thereof | |
| CN106634467A (en) | Rheological metal basecoat and preparation method thereof | |
| CN105131750B (en) | A kind of electrical sheet environment-friendly type self-adhesive coating and preparation method thereof | |
| CN107216756A (en) | Quick-drying Stripable paint containing alkaline alcohol-soluble Ludox and preparation method thereof | |
| CN104387922B (en) | Water-based static conductive paint and preparation method thereof | |
| CN106243875B (en) | BOPP citicall limited aluminiums film transfer water-based back-coating and preparation method thereof | |
| CN107043565A (en) | A kind of inorganic powder inner wall putty of antistatic and its application | |
| CN107216755A (en) | A kind of quick-drying Stripable paint and preparation method thereof | |
| CN105385303A (en) | Hybrid curing peelable coating material and preparation method thereof | |
| CN108659656A (en) | A kind of antifouling paint for building and preparation method thereof | |
| CN105907306A (en) | Anti-static insulating paint | |
| CN107337973B (en) | A kind of quick-drying Stripable paint and preparation method thereof | |
| CN107236395A (en) | Quick-drying Stripable paint containing alcohol-soluble organic silicon sol and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170929 |