CN107236301A - PPS PC short glass fiber high molecule alloy materials and preparation method thereof - Google Patents
PPS PC short glass fiber high molecule alloy materials and preparation method thereof Download PDFInfo
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- CN107236301A CN107236301A CN201710496107.3A CN201710496107A CN107236301A CN 107236301 A CN107236301 A CN 107236301A CN 201710496107 A CN201710496107 A CN 201710496107A CN 107236301 A CN107236301 A CN 107236301A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/02—Polythioethers; Polythioether-ethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of PPS PC short glass fiber high molecule alloy materials, and the present invention also provides the preparation method of the PPS PC short glass fiber high molecule alloy materials.PPS PC short glass fibers high molecule alloy material density of the present invention is small, intensity is high and with higher toughness, mechanics harmony is good, resistant to chemical etching, it is easy to processing and forming.
Description
Technical field
The present invention relates to PPS-PC- short glass fiber high molecule alloy materials and preparation method thereof.
Background technology
The fields such as household electrical appliance, electronic apparatus, automobile, aviation will accomplish more and more thinner, less and less, weight increasingly
Gently, it is necessary to develop the fixed component that a kind of high polymer material substitutes traditional integrated circuit board, with not only thin but also hard special
High molecular weight plastic substitutes the supporting members such as traditional metallic support, fixed plate.
Polyphenylene sulfide（PPS）It is a kind of novel high-performance thermoplastic resin, with high mechanical strength, high temperature resistant, chemically-resistant
Medicine, fire retardant, heat endurance are good, excellent electrical properties the advantages of.But it is due to PPS highly crystalline feature, strand is more stiff
Firmly, cause material that fragility is presented, make it not only hard but also crisp, impact strength is low, melt fluidity is poor, received in application
Limitation, PPS is enough hard, hard such as steel, but relatively more crisp.
For this, it is necessary to which PPS materials are modified, the need for meeting domestic and international enterprise product engineering material.
The content of the invention
It is an object of the invention to provide a kind of PPS-PC- short glass fibers high molecule alloy material and preparation method thereof,
The PPS-PC- short glass fiber high molecule alloy material density is small, intensity is high and with higher toughness, mechanics harmony is good,
It is resistant to chemical etching, it is easy to processing and forming.
To achieve the above object, the present invention provides a kind of PPS-PC- short glass fibers high molecule alloy material, by weight
Meter is composed of the following components：
65 parts of PPS resins,
22 parts of PC resins,
17 parts of short glass fibers,
2.8 parts of butanedioic acid alkyl ester sulfonate sodium,
1.7 parts of two acetals of polyalcohol-aluminium hydroxide grafts,
1.9 parts of Cyanuric Chlorides,
5.5 parts of ethylene-alpha-octylene copolymers,
3.1 parts of Trimethyllaurylammonium chlorides,
2.7 parts of triisopropanolamines,
1.4 parts of disodium hydrogen phosphates,
2.8 parts of γ-(methacryloxypropyl) propyl trimethoxy silicanes,
1.6 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
9.3 parts of nanometric magnesium hydroxides,
1.5 parts of betulic acids.
The present invention also provides the preparation method of above-mentioned PPS-PC- short glass fibers high molecule alloy material, including following step
Suddenly：
1）By 65 parts by weight PPS resins, 22 parts by weight PC resins, 17 parts by weight short glass fibers, 2.8 parts by weight amber dialkylaminobenzoic acids
Ester sodium sulfonate, 1.7 two acetals of weight polyol-aluminium hydroxide graft, 1.9 parts by weight Cyanuric Chlorides, 5.5 parts by weight second
Alkene-α-octene copolymer, 3.1 parts by weight Trimethyllaurylammonium chlorides, 2.7 parts by weight triisopropanolamines, 1.4 parts by weight of phosphoric acid
Disodium hydrogen, 2.8 parts by weight γ-(methacryloxypropyl) propyl trimethoxy silicane, the nonyl certain herbaceous plants with big flowers base barium sulfonate of 1.6 parts by weight two, 9.3
Parts by weight nanometric magnesium hydroxide, 1.5 parts by weight betulic acids carry out ultrahigh speed dispersion mixing, obtain mixing finely dispersed mixed
Close material；
2）High-temperature molten is carried out to compound by double screw extruder and melts mixing extrusion；
3）Cooling and dicing is carried out to extruded stock, PPS-PC- short glass fiber high molecule alloy materials are obtained.
The advantages of the present invention are：There is provided a kind of PPS-PC- short glass fibers high molecule alloy material and
Its preparation method, the PPS-PC- short glass fiber high molecule alloy material density is small, intensity is high and has higher toughness, power
Learn harmonious good, resistant to chemical etching, it is easy to processing and forming.
Embodiment
With reference to embodiment, the embodiment to the present invention is further described.Following examples are only used for more
Plus technical scheme is clearly demonstrated, and can not be limited the scope of the invention with this.
The present invention provides a kind of PPS-PC- short glass fibers high molecule alloy material, by weight by following components group
Into：
65 parts of PPS resins,
22 parts of PC resins,
17 parts of short glass fibers,
2.8 parts of butanedioic acid alkyl ester sulfonate sodium,
1.7 parts of two acetals of polyalcohol-aluminium hydroxide grafts,
1.9 parts of Cyanuric Chlorides,
5.5 parts of ethylene-alpha-octylene copolymers,
3.1 parts of Trimethyllaurylammonium chlorides,
2.7 parts of triisopropanolamines,
1.4 parts of disodium hydrogen phosphates,
2.8 parts of γ-(methacryloxypropyl) propyl trimethoxy silicanes,
1.6 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
9.3 parts of nanometric magnesium hydroxides,
1.5 parts of betulic acids.
The present invention also provides the preparation method of above-mentioned PPS-PC- short glass fibers high molecule alloy material, including following step
Suddenly：
1）By 65 parts by weight PPS resins, 22 parts by weight PC resins, 17 parts by weight short glass fibers, 2.8 parts by weight amber dialkylaminobenzoic acids
Ester sodium sulfonate, 1.7 two acetals of weight polyol-aluminium hydroxide graft, 1.9 parts by weight Cyanuric Chlorides, 5.5 parts by weight second
Alkene-α-octene copolymer, 3.1 parts by weight Trimethyllaurylammonium chlorides, 2.7 parts by weight triisopropanolamines, 1.4 parts by weight of phosphoric acid
Disodium hydrogen, 2.8 parts by weight γ-(methacryloxypropyl) propyl trimethoxy silicane, the nonyl certain herbaceous plants with big flowers base barium sulfonate of 1.6 parts by weight two, 9.3
Parts by weight nanometric magnesium hydroxide, 1.5 parts by weight betulic acids carry out ultrahigh speed dispersion mixing, obtain mixing finely dispersed mixed
Close material；
2）High-temperature molten is carried out to compound by double screw extruder and melts mixing extrusion；
3）Cooling and dicing is carried out to extruded stock, PPS-PC- short glass fiber high molecule alloy materials are obtained.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (2)
1.PPS-PC- short glass fiber high molecule alloy materials, it is characterised in that composed of the following components by weight：
65 parts of PPS resins,
22 parts of PC resins,
17 parts of short glass fibers,
2.8 parts of butanedioic acid alkyl ester sulfonate sodium,
1.7 parts of two acetals of polyalcohol-aluminium hydroxide grafts,
1.9 part Cyanuric Chloride,
5.5 parts of ethylene-alpha-octylene copolymers,
3.1 parts of Trimethyllaurylammonium chlorides,
2.7 parts of triisopropanolamines,
1.4 parts of disodium hydrogen phosphates,
2.8 parts of γ-(methacryloxypropyl) propyl trimethoxy silicanes,
1.6 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
9.3 parts of nanometric magnesium hydroxides,
1.5 parts of betulic acids.
2. the preparation method of PPS-PC- short glass fibers high molecule alloy material according to claim 1, it is characterised in that
Comprise the following steps：
1）By 65 parts by weight PPS resins, 22 parts by weight PC resins, 17 parts by weight short glass fibers, 2.8 parts by weight amber dialkylaminobenzoic acids
Ester sodium sulfonate, 1.7 two acetals of weight polyol-aluminium hydroxide graft, 1.9 parts by weight Cyanuric Chlorides, 5.5 parts by weight second
Alkene-α-octene copolymer, 3.1 parts by weight Trimethyllaurylammonium chlorides, 2.7 parts by weight triisopropanolamines, 1.4 parts by weight of phosphoric acid
Disodium hydrogen, 2.8 parts by weight γ-(methacryloxypropyl) propyl trimethoxy silicane, the nonyl certain herbaceous plants with big flowers base barium sulfonate of 1.6 parts by weight two, 9.3
Parts by weight nanometric magnesium hydroxide, 1.5 parts by weight betulic acids carry out ultrahigh speed dispersion mixing, obtain mixing finely dispersed mixed
Close material；
2）High-temperature molten is carried out to compound by double screw extruder and melts mixing extrusion；
3）Cooling and dicing is carried out to extruded stock, PPS-PC- short glass fiber high molecule alloy materials are obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710496107.3A CN107236301A (en) | 2017-06-26 | 2017-06-26 | PPS PC short glass fiber high molecule alloy materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710496107.3A CN107236301A (en) | 2017-06-26 | 2017-06-26 | PPS PC short glass fiber high molecule alloy materials and preparation method thereof |
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| CN107236301A true CN107236301A (en) | 2017-10-10 |
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| CN201710496107.3A Pending CN107236301A (en) | 2017-06-26 | 2017-06-26 | PPS PC short glass fiber high molecule alloy materials and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194895A (en) * | 2020-09-30 | 2021-01-08 | 特塑（大连）高分子材料有限公司 | Glass fiber reinforced PPS alloy modified material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104211985A (en) * | 2013-10-31 | 2014-12-17 | 中国石油化工股份有限公司 | Aluminum hydroxide-containing nucleating agent and preparation method thereof |
| CN106147230A (en) * | 2015-04-09 | 2016-11-23 | 东丽先端材料研究开发（中国）有限公司 | The polyphenyl thioether resin composition of high fluidity high rigidity and products formed thereof |
-
2017
- 2017-06-26 CN CN201710496107.3A patent/CN107236301A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104211985A (en) * | 2013-10-31 | 2014-12-17 | 中国石油化工股份有限公司 | Aluminum hydroxide-containing nucleating agent and preparation method thereof |
| CN106147230A (en) * | 2015-04-09 | 2016-11-23 | 东丽先端材料研究开发（中国）有限公司 | The polyphenyl thioether resin composition of high fluidity high rigidity and products formed thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194895A (en) * | 2020-09-30 | 2021-01-08 | 特塑（大连）高分子材料有限公司 | Glass fiber reinforced PPS alloy modified material and preparation method thereof |
| CN112194895B (en) * | 2020-09-30 | 2023-04-11 | 特塑（大连）高分子材料有限公司 | Glass fiber reinforced PPS alloy modified material and preparation method thereof |
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Address after: 215103 No. 2001, Swan Road, Wuzhong Economic Development Zone, Suzhou, Jiangsu Applicant after: Suzhou Huitong Hui Chuang Technology Co., Ltd. Address before: 215103 No. 2001, Swan Road, Wang Shan Industrial Park, Wuzhong Economic Development Zone, Suzhou, Jiangsu Applicant before: Suzhou Huitong Plastic Co., Ltd. |
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Application publication date: 20171010 |