CN107418197B - Heat-conducting nylon engineering plastic and preparation method thereof - Google Patents
Heat-conducting nylon engineering plastic and preparation method thereof Download PDFInfo
- Publication number
- CN107418197B CN107418197B CN201710255936.2A CN201710255936A CN107418197B CN 107418197 B CN107418197 B CN 107418197B CN 201710255936 A CN201710255936 A CN 201710255936A CN 107418197 B CN107418197 B CN 107418197B
- Authority
- CN
- China
- Prior art keywords
- parts
- heat
- plasticizer
- nylon
- engineering plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004677 Nylon Substances 0.000 title claims abstract description 34
- 229920001778 nylon Polymers 0.000 title claims abstract description 34
- 229920006351 engineering plastic Polymers 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000004014 plasticizer Substances 0.000 claims abstract description 26
- 239000012745 toughening agent Substances 0.000 claims abstract description 22
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 20
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 13
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 229920002292 Nylon 6 Polymers 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- DHRXPBUFQGUINE-UHFFFAOYSA-N n-(2-hydroxypropyl)benzenesulfonamide Chemical group CC(O)CNS(=O)(=O)C1=CC=CC=C1 DHRXPBUFQGUINE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 3
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 3
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 claims description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical class C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 7
- 239000003063 flame retardant Substances 0.000 abstract description 7
- 238000001746 injection moulding Methods 0.000 abstract description 3
- 230000017525 heat dissipation Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000011049 filling Methods 0.000 description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 229920006152 PA1010 Polymers 0.000 description 1
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- UXYRZJKIQKRJCF-TZPFWLJSSA-N mesterolone Chemical compound C1C[C@@H]2[C@@]3(C)[C@@H](C)CC(=O)C[C@@H]3CC[C@H]2[C@@H]2CC[C@H](O)[C@]21C UXYRZJKIQKRJCF-TZPFWLJSSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a heat-conducting nylon engineering plastic and a preparation method thereof. The engineering plastic comprises the following components in parts by weight: 100 parts of nylon matrix resin; 150-300 parts of magnesium hydroxide; 2-10 parts of a toughening agent; 1-20 parts of a plasticizer; 0-5 parts of a processing aid. The preparation method comprises the steps of mixing the toughening agent, the plasticizer, the processing aid and the nylon matrix resin, granulating by a double-screw extruder, and adding the magnesium hydroxide from the middle section of the side surface of the extruder through forced feeding. The heat-conducting engineering plastic prepared by the invention has excellent toughness and flame retardant property, good ductility and low cost, and can be applied to injection molding for preparing LED lamp radiators and other electronic and electric parts needing heat dissipation.
Description
Technical Field
The invention relates to the field of polymer composite materials, in particular to a heat-conducting nylon engineering plastic with excellent toughness and a preparation method thereof.
Background
The heat-conducting polymer composite material has the advantages of simple processing and forming, low density, corrosion resistance, good insulating property and the like, and becomes a preferable material for solving the problem of heat dissipation of the LED lamp. With the rapid development of scientific technology, the demand for polymer materials with excellent thermal conductivity is increasing. However, the development of the existing heat-conducting polymer materials still faces many problems, for example, when the filling amount of the existing filling type heat-conducting materials which are researched more intensively is large, the physical and mechanical properties of the materials are obviously reduced, and the materials become seriously brittle, so that the application of the materials is greatly limited.
Magnesium hydroxide [ Mg (OH)2Abbreviated as MH]Belongs to an additive inorganic flame retardant, and compared with the similar inorganic flame retardants, the flame retardant has excellent flame retardant effect on high polymer materialsBesides, the magnesium hydroxide can also inhibit the generation of toxic gases such as smoke, hydrogen halide and the like, namely, the magnesium hydroxide has triple functions of flame retardance, smoke abatement and filling, and has the characteristics of no toxicity, no corrosion and the like. MH has higher decomposition temperature (300-320 ℃), is not easy to decompose at the melting processing temperature of nylon, and is an ideal flame retardant for flame-retardant nylon. The amount added is often very high (typically 60% to 200% of the resin) to achieve a certain flame retardant rating. Because magnesium hydroxide has large polarity and poor compatibility with a base material, the processing performance of the polymer and the mechanical property of the polymer are influenced by high addition amount.
Disclosure of Invention
In order to solve the above problems, the present invention aims to provide a heat conductive nylon engineering plastic with excellent processability and toughness and a preparation method thereof. The heat-conducting nylon engineering plastic with excellent processability and toughness is obtained by matching and using the toughening agent and the plasticizer.
In a first aspect, the invention provides a heat-conducting nylon engineering plastic with excellent toughness, which comprises the following components in parts by weight:
the plasticizer is N- (2-hydroxypropyl) benzene sulfonamide.
Preferably, the paint comprises the following components in parts by weight:
the plasticizer is N- (2-hydroxypropyl) benzene sulfonamide.
Preferably, the matrix resin is one or more of nylon 6(PA6), nylon 66(PA66), nylon 610(PA610), nylon 612(PA612), nylon 1010(PA1010) and nylon 1212(PA 1212).
Preferably, the magnesium hydroxide is prepared by a chemical method or a mineral method, the particle size is 0.5-5 microns, and the surface of the magnesium hydroxide is treated by a silane coupling agent.
Preferably, the toughening agent is a vinyl graft or copolymer.
More preferably, the toughening agent is one or two of polyethylene grafted maleic anhydride (PE-MAH), polyethylene octene copolymer grafted maleic anhydride (POE-MAH), hydrogenated styrene-butadiene-styrene triblock copolymer grafted maleic anhydride (SEBS-MAH), ethylene-acrylate-glycidyl methacrylate copolymer (E-BA-GMA) and ethylene-glycidyl methacrylate copolymer (E-GMA).
Preferably, the processing aid is selected from one or more of an antioxidant, a heat stabilizer, a lubricant and a toner.
More preferably, the antioxidant is 1010 and 168, the heat stabilizer is SEED, and the lubricant is pentaerythritol tetrastearate.
In a second aspect, the invention provides a preparation method of a heat-conducting nylon engineering plastic with excellent toughness, which comprises the following steps:
step 1: the following components are taken according to parts by weight: 100 parts of nylon matrix resin; 150-250 parts of magnesium hydroxide; 2-10 parts of a toughening agent; 1-20 parts of a plasticizer; 0-5 parts of a processing aid. (ii) a
Step 2: adding nylon matrix resin and a toughening agent into a mixer, and continuously stirring for 1-3 minutes;
and step 3: adding a plasticizer into the mixer, and continuously stirring for 1-3 minutes;
and 4, step 4: adding a processing aid into the mixer, and continuously stirring for 1-2 minutes;
and 5: and respectively adding the mixture and the insulating heat-conducting filler into a main feeding hopper and a side feeding hopper of the extruder, and extruding and granulating to obtain the heat-conducting nylon engineering plastic with excellent toughness.
The heat-conducting nylon engineering plastic with excellent toughness provided by the invention has the following beneficial effects:
(1) the toughening agent and the plasticizer are matched for use, so that the toughness of the heat-conducting nylon composite material is well improved, and compared with the toughening of a simple toughening agent, the influence of the addition of the plasticizer on the heat-conducting property and the flame retardant property is small.
(2) The N- (2-hydroxypropyl) benzene sulfonamide plasticizer does not belong to an environmentally-friendly limited o-benzene plasticizer, and the addition of the plasticizer improves the coating capability of the resin on the powder, and is safe and environmentally-friendly. The hydrogen bonding effect between nylon molecular chains is influenced, and the nylon becomes softer.
(3) The heat-conducting nylon engineering plastic provided by the invention has the advantages that the processing current is reduced by about 20% compared with the normal current due to the addition of the liquid plasticizer, the productivity is improved, the energy is saved, and the cost performance of the product is higher.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The invention provides a heat-conducting nylon engineering plastic which has excellent toughness. The composition comprises the following components: 100 parts of nylon matrix resin; 150-250 parts of magnesium hydroxide; 2-10 parts of a toughening agent; 1-20 parts of a plasticizer; 0-5 parts of a processing aid.
In the formulations of the examples and comparative examples, PA6 is available under the trademark PA6M200, manufactured by Nippon Mada; the magnesium hydroxide is HO 12FM, produced by Jiangsu Ettke company; the toughening agent SEBS-g-MAH is of the mark
FG1901, manufactured by kraton, usa; plasticizer grade 2102, produced by Proviron corporation, belgium; the processing aid is an antioxidant 1098: antioxidant 168: the lubricant is a mixture of 1:1:2, wherein the antioxidant 1098 and the antioxidant 168 are produced by BASF company in Germany, and the lubricant is pentaerythritol stearate with the mark number of
P (ETS), manufactured by Lonza, USA.
Example 1
A heat-conducting nylon engineering plastic with excellent toughness is prepared by the following steps: adding the PA6 resin and the toughening agent into a mixer, and stirring for 2 min; then adding a plasticizer into the mixer, and continuously stirring for 2 min; adding antioxidant and lubricant into the mixer, and stirring for 2 min; adding the mixture into a main feeding hopper of a double-screw extruder, and adding magnesium hydroxide into a side feeding hopper of the double-screw extruder; extruding and granulating, setting the temperature to be 220-260 ℃, preparing high-toughness heat-conducting nylon 6 engineering plastic particles, and testing the performance by injection molding.
Examples 2 to 4
The preparation method is the same as that of example 1, except that the components and the dosage are different, and the specific reference is made to table 1.
Comparative example 1
An insulating engineering plastic is prepared by the following steps: adding the PA6 resin and the toughening agent into a mixer, and stirring for 2 min; adding antioxidant and lubricant into the mixer, and stirring for 2 min; adding the mixture into a main feeding hopper of a double-screw extruder, and adding magnesium hydroxide into a side feeding hopper of the double-screw extruder; extruding and granulating, setting the temperature to be 220-260 ℃, preparing high-toughness heat-conducting nylon 6 engineering plastic particles, and testing the performance by injection molding.
Comparative example 2
The preparation method is the same as that of comparative example 1, only the differences of the components and the dosage are shown in Table 1.
TABLE 1 Components and parts by weight (unit: parts) of examples 1 to 4 and comparative examples 1 to 2
| Matrix resin | Magnesium hydroxide | Toughening agent | Plasticizer | Processing aid | |
| Example 1 | 100 | 150 | 2 | 1 | 0 |
| Example 2 | 100 | 250 | 2 | 1 | 0 |
| Example 3 | 100 | 200 | 10 | 10 | 2 |
| Example 4 | 100 | 250 | 10 | 20 | 5 |
| Comparative example 1 | 100 | 200 | 10 | 0 | 2 |
| Comparative example 2 | 100 | 200 | 0 | 10 | 2 |
Effects of the embodiment
The products obtained in examples 1-4 and comparative examples 1-2 were injection molded to prepare standard test sample strips, and the test results are shown in Table 2.
TABLE 2 Performance test results of examples 1 to 4 and comparative examples 1 to 2
In comparative example 1, a toughening agent is added, no plasticizer is added, and the material has strong rigidity and weak deformability.
In the comparative example 2, the plasticizer is used for replacing the toughening agent, the rigidity of the material is reduced, the elongation at break and the deflection are improved, the heat conductivity coefficient is also higher, and the extrusion current is reduced by 20%.
From examples 1-4, it can be seen that the addition of the toughening agent and the plasticizer greatly reduces the flexural modulus of the material, and the impact strength, the elongation at break and the deflection are all significantly increased, indicating that the ductility of the material becomes better and the deformation resistance is enhanced. The tensile strength of the composite material is always kept above 40MPa, which is higher than that of general plastics (such as polypropylene PP), and the requirement of products such as LED radiators and the like on the strength can be met. In example 3, the addition of the plasticizer reduced the extrusion current by about 10% compared to comparative example 1, but had substantially no effect on the thermal conductivity. The reduction in current means that the material is more fluid, that lower processing temperatures can be used or that a greater capacity is obtained, and is therefore very significant in terms of energy consumption and production efficiency.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (3)
1. The heat-conducting nylon engineering plastic is characterized by comprising the following components in parts by weight:
100 parts of nylon matrix resin;
150-250 parts of magnesium hydroxide;
2-10 parts of a toughening agent;
1-20 parts of a plasticizer;
0-5 parts of a processing aid;
the plasticizer is N- (2-hydroxypropyl) benzene sulfonamide;
the nylon matrix resin is one or a mixture of more than one of PA6, PA66, PA612 and PA 610;
the magnesium hydroxide is prepared by a chemical method or a mineral method, the particle size is 0.5-5 microns, and the surface of the magnesium hydroxide is treated by a silane coupling agent;
the toughening agent is one or two of polyethylene grafted maleic anhydride (PE-MAH), polyethylene octene copolymer grafted maleic anhydride (POE-MAH), hydrogenated styrene-butadiene-styrene triblock copolymer grafted maleic anhydride (SEBS-MAH), ethylene-acrylate-glycidyl methacrylate copolymer (E-BA-GMA) and ethylene-glycidyl methacrylate copolymer (E-GMA);
the processing aid is selected from one or more of an antioxidant, a heat stabilizer, a lubricant and a toner;
the lubricant is pentaerythritol tetrastearate;
the heat stabilizer is SEED.
2. The heat-conducting nylon engineering plastic as claimed in claim 1, which is characterized by comprising the following components in parts by weight:
100 parts of nylon matrix resin;
200 parts of magnesium hydroxide;
10 parts of a toughening agent;
10 parts of a plasticizer;
and 2 parts of a processing aid.
3. The preparation method of the heat-conducting nylon engineering plastic as claimed in any one of claims 1-2, characterized by comprising the following steps:
step 1: taking the following components in parts by weight: nylon matrix resin; magnesium hydroxide; a toughening agent; a plasticizer; a processing aid;
step 2: adding nylon matrix resin and a toughening agent into a mixer, and continuously stirring for 1-3 minutes;
and step 3: adding a plasticizer into the mixer, and continuously stirring for 1-3 minutes;
and 4, step 4: adding a processing aid into the mixer, and continuously stirring for 1-2 minutes;
and 5: and respectively adding the mixture and the magnesium hydroxide into a main feeding hopper and a side feeding hopper of the extruder, and extruding and granulating to obtain the heat-conducting nylon engineering plastic with excellent toughness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710255936.2A CN107418197B (en) | 2017-04-18 | 2017-04-18 | Heat-conducting nylon engineering plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710255936.2A CN107418197B (en) | 2017-04-18 | 2017-04-18 | Heat-conducting nylon engineering plastic and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107418197A CN107418197A (en) | 2017-12-01 |
| CN107418197B true CN107418197B (en) | 2020-09-01 |
Family
ID=60424223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710255936.2A Active CN107418197B (en) | 2017-04-18 | 2017-04-18 | Heat-conducting nylon engineering plastic and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107418197B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178922A (en) * | 2017-12-28 | 2018-06-19 | 南京鸿瑞塑料制品有限公司 | One kind is for super flexible PA6 composite materials of car floor boring cover and preparation method thereof |
| CN111171563A (en) * | 2020-03-06 | 2020-05-19 | 广州华新科智造技术有限公司 | Polyamide material and preparation method thereof |
| CN112430391A (en) * | 2020-11-23 | 2021-03-02 | 山东星达新材料有限公司 | Super-tough super-low temperature-resistant super-wear-resistant flexible nylon alloy material and preparation method thereof |
| CN112724662B (en) * | 2020-12-08 | 2022-12-06 | 金发科技股份有限公司 | Toughened wear-resistant polyamide composition and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005113679A1 (en) * | 2004-05-20 | 2005-12-01 | E. I. Du Pont De Nemours And Company | Polymeric fuel system components |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060093772A1 (en) * | 2004-10-27 | 2006-05-04 | Fish Robert B Jr | Multilayered pipes comprising hydrolysis resistant polyamides |
| US20070083033A1 (en) * | 2005-10-06 | 2007-04-12 | Fish Robert B Jr | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
| CN101423666B (en) * | 2008-10-31 | 2011-04-27 | 广东新会美达锦纶股份有限公司 | Halogen-free flame retardant polyamide 6 composition |
| FR2981357B1 (en) * | 2011-10-13 | 2013-10-25 | Arkema France | SEMI-AROMATIC POLYAMIDE-BASED SOFT COMPOSITION, PROCESS FOR PREPARING SAME AND USES THEREOF |
| CN102702738B (en) * | 2012-07-06 | 2015-01-14 | 上海日之升新技术发展有限公司 | High-glowing-filament high-toughness flame-retardant PA66 composite material and preparation method thereof |
| CN103013100A (en) * | 2012-12-06 | 2013-04-03 | 黄武林 | Nylon plastic material for LED (light-emitting diode) lamp and preparation method thereof |
| CN105111727A (en) * | 2015-09-07 | 2015-12-02 | 东莞市宝临塑胶有限公司 | Heat conducting nylon composite material and preparation method thereof |
| CN105838061A (en) * | 2015-11-05 | 2016-08-10 | 东莞市伟的工程塑料有限公司 | Heat conduction plastic alloy and preparation method thereof |
-
2017
- 2017-04-18 CN CN201710255936.2A patent/CN107418197B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005113679A1 (en) * | 2004-05-20 | 2005-12-01 | E. I. Du Pont De Nemours And Company | Polymeric fuel system components |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107418197A (en) | 2017-12-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101831110B (en) | Polypropylene composite material capable of being welded at high frequency and preparation method thereof | |
| CN107418197B (en) | Heat-conducting nylon engineering plastic and preparation method thereof | |
| CN104629187B (en) | A kind of multi-functional PP composite material and preparation method thereof | |
| CN102234419B (en) | Halogen-free flameproof polyphenylene ether resin composition and preparation method thereof | |
| CN111073242A (en) | High-melt-strength halogen-free flame-retardant blow-molded PC/ABS alloy and preparation method thereof | |
| CN103862589B (en) | A kind of melt blending prepares the method for polyamide-based heat-conductive composite material | |
| CN107955368B (en) | Heat-conducting nylon with improved heat resistance and preparation method thereof | |
| CN113248901B (en) | Halogen-free flame-retardant ABS alloy material and preparation method thereof | |
| WO2022110673A1 (en) | Shock-absorbing, damping, halogen-containing, flame-retardant, reinforced pbt material, and preparation method therefor | |
| CN107541049B (en) | Graphene-continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO/HIPS alloy material and preparation method thereof | |
| CN105504798A (en) | Glass fiber reinforced nylon composite material | |
| CN112321947A (en) | 5 VA-grade halogen-free flame-retardant polypropylene material and preparation method thereof | |
| CN104277323A (en) | Heat-conduction impact resistant polypropylene/polyester composite material and its preparation method | |
| CN104387747A (en) | Polyphenylether/polyamide/polystyrene plastic alloy, and preparation method and application thereof | |
| CN109957238B (en) | Thermoplastic flame-retardant bio-based PA56 and PA66 composite material and preparation method thereof | |
| CN111592742B (en) | High-temperature-resistant PPO/PBT material and preparation method thereof | |
| CN104448806A (en) | Low-warping-rate halogen-free flame retardant carbon fiber-reinforced nylon alloy material and preparation method | |
| CN103059536A (en) | Polycarbonate/polyethylene alloy heat conduction composite material and preparation method thereof | |
| CN108329647A (en) | Low internal stress, high-impact ABS compositions and its preparation method and application | |
| CN108219351B (en) | Low-internal-stress high-impact-resistance flame-retardant ABS (acrylonitrile-butadiene-styrene) composition as well as preparation method and application thereof | |
| CN111040307A (en) | Polypropylene corrugated pipe composite material and preparation method of composite polypropylene corrugated pipe | |
| CN106366617B (en) | A kind of polyphenyl ether resin composition and preparation method thereof for processing electrolytic negative plate contained side item | |
| CN104277448A (en) | Polyphenylene ether resin alloy material for housings of air-condition compressors | |
| CN111019287B (en) | Graphene synergistic flame-retardant ABS/SBS composite material and preparation method thereof | |
| CN110760177B (en) | Conductive polyphenyl ether/high impact polystyrene composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231129 Address after: 512529 No. 3 Zhongtai Road, Shashui Industrial Park, Shixing County, Shaoguan City, Guangdong Province Patentee after: Guangdong Huaju Technology Co.,Ltd. Address before: 516127 Jiaoyuan Industrial Zone, Jiaoxian Village, Shiwan, Boluo County, Huizhou City, Guangdong Province Patentee before: HUAJU PLASTICS TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right |