CN107236218A - A kind of durable type PVC bionic fish baits - Google Patents
A kind of durable type PVC bionic fish baits Download PDFInfo
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- CN107236218A CN107236218A CN201710513499.XA CN201710513499A CN107236218A CN 107236218 A CN107236218 A CN 107236218A CN 201710513499 A CN201710513499 A CN 201710513499A CN 107236218 A CN107236218 A CN 107236218A
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- bionic fish
- fatty acid
- acid ester
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Feed For Specific Animals (AREA)
- Fodder In General (AREA)
Abstract
Processing technique field is researched and developed the present invention relates to fishing gear, a kind of durable type PVC bionic fish baits is disclosed, is made up of following component：Polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, citrate, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether, zinc stearate, calcium stearate, sierozem power, talcum powder, aluminate coupling agent, titanium dioxide, antiseptic, the use of PVC is main material, remaining is added as its performance of enhancing, with excellent resistance to low temperature, the brittle temperature of product can be made to be reduced to subzero 70 DEG C subzero 30 DEG C, and low-temperature pliability is preferable, heat resistance and weatherability are higher, the service life of bionic fish bait can be improved, and recovery utilization rate is high, the inorganic antiseptic used may be homogenously dispersed in bionic fish bait and play antibacterial action for a long time.
Description
Technical field
The invention belongs to fishing gear research and development processing technique field, and in particular to a kind of durable type PVC bionic fish baits.
Background technology
Bionic fish bait is that the law for utilizing " big fish swallowing little fish " is manufactured, and is floated in seawater, other ocean fishes have seen, with
To be small fish, once stinging up, just it is taken in.Fish hook on bionic fish bait is very professional, and lethality is very strong.Bionic fish bait exists
Flourishing city utilization rate is higher, and bionic fish bait is popular abroad, and external many people compare emphasis environmental protection, domestic traditional fish
Bait is all to have pollution to environment, in recent years, and people step up for the understanding of environmental protection, and the development of bionic fish bait will have extensively
Wealthy prospect, existing bionic fish bait service life mostly in half a year to 1 year, high temperature and winter often over summer
Low temperature, performance is substantially reduced, the problem of still there is short life, and the pollution produced is more serious.
The content of the invention
The purpose of the present invention is there is provided a kind of durable type PVC bionic fish baits, based on PVC the problem of being directed to existing
Material is wanted, remaining is added as its performance of enhancing, it is possible to increase the service life of bionic fish bait, and recovery utilization rate is high.
The present invention is achieved by the following technical solutions：
A kind of durable type PVC bionic fish baits, are made up of following component in parts by weight：70-80 parts of polyvinyl chloride, O-phthalic
Sour dihexyl 15-17 parts, 7.5-9.5 parts of SA dibutyl ester, 7.5-8.5 parts of epoxidized soybean oil, tricresyl phosphate benzene methyl 5.5-6.5
Part, 3.5-4.5 parts of citrate, 2.5-3.0 parts of binary alcohol fatty acid ester, 2.0-2.5 parts of pentaerythritol fatty acid ester, dihydric alcohol benzene first
1.5-2.0 parts of acid esters, 1.3-1.5 parts of zinc stearate, 1.1-1.3 parts of calcium stearate, 1.0-1.2 parts of sierozem power, talcum powder 2.0-
2.5 parts, 0.3-0.5 parts of aluminate coupling agent, 0.2-0.4 parts of titanium dioxide, 0.1-0.3 parts of antiseptic, its preparation method includes
Following steps：
（1）By polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, lemon
Acid esters, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether are added in high-speed mixer, are mixed 3-5 minutes,
Residual components are added to mix 4-6 minutes；
（2）The material after plasticating will be mixed and pass through extruder extruding pelletization or section at 130-150 DEG C, note is added to after drying
In molding machine, then by bionic fish bait model extrusion equipment extrusion bait model, extrusion temperature is 135-145 DEG C, obtains Biomimetic Fish
Bait model is cooled down, and color spray, eye droppings are produced after drying.
As further improvement of these options, the preparation method of the antiseptic is：Rubbed by 0.5-0.7 of concentration
You/liter sodium radio-phosphate,P-32 solution and silver nitrate solution that concentration is 0.3-0.5 mol/Ls be raw material, according to 1：2.3-2.5 ratio
Reacted, sodium radio-phosphate,P-32 solution is slowly added dropwise into silver nitrate solution, rate of addition is 70-80 drops/minute, and reaction temperature is
35-40 DEG C, phosphoric acid silver colloid is made, is washed, dried, obtains silver orthophosphate precipitation, 40-50 points is calcined at 280-300 DEG C
Clock, grinds to form 150-180 mesh sizes and produces the antiseptic.
It is used as further improvement of these options, step（1）The mixing speed is 7000-8000 revs/min,
Temperature is 120-140 DEG C.
It is used as further improvement of these options, step（2）Described injection machine preheating temperature is 120-130 DEG C, in advance
The hot time is 3-4 hours.
The present invention has advantages below compared with prior art：In order to solve existing bionic fish bait service life mostly half
Year, the low temperature of high temperature and winter often over summer, performance was substantially reduced, and still there is asking for short life to 1 year
Topic, and it is discarded after the pollution that produces it is more serious, the invention provides a kind of durable type PVC bionic fish baits, be using PVC
Main material, adds remaining as its performance is strengthened, changes PVC properties brittle, it is difficult to the problem of processing, the polyalcohol used
Ester not only has excellent heat-proof aging, resistance to extractable and excellent stain resistance, also with excellent resistance to low temperature, can make
The brittle temperature of product be reduced to subzero 70 DEG C-it is subzero 30 DEG C, and low-temperature pliability preferably, heat resistance and weatherability are higher, energy
The service life of bionic fish bait is enough improved, and recovery utilization rate is high, and the inorganic antiseptic used may be homogenously dispersed in Biomimetic Fish
Play in bait and for a long time antibacterial action.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of durable type PVC bionic fish baits, are made up of following component in parts by weight：70 parts of polyvinyl chloride, phthalic acid
15 parts of dihexyl, 7.5 parts of SA dibutyl ester, 7.5 parts of epoxidized soybean oil, 5.5 parts of tricresyl phosphate benzene methyl, 3.5 parts of citrate,
2.5 parts of binary alcohol fatty acid ester, 2.0 parts of pentaerythritol fatty acid ester, 1.5 parts of binary alcohol benzoic ether, 1.3 parts of zinc stearate, tristearin
Sour 1.1 parts of calcium, 1.0 parts of sierozem power, 2.0 parts of talcum powder, 0.3 part of aluminate coupling agent, 0.2 part of titanium dioxide, antiseptic 0.1
Part, its preparation method comprises the following steps：
（1）By polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, lemon
Acid esters, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether are added in high-speed mixer, are mixed 3 minutes, plus
Enter residual components to mix 4 minutes；
（2）The material after plasticating will be mixed and pass through extruder extruding pelletization or section at 130 DEG C, injection machine is added to after drying
In, then by bionic fish bait model extrusion equipment extrusion bait model, extrusion temperature is 135 DEG C, obtains bionic fish bait model and enters
Row is cooled, and color spray, eye droppings are produced after drying.
As further improvement of these options, the preparation method of the antiseptic is：Using concentration as 0.5 mol/L
Sodium radio-phosphate,P-32 solution and silver nitrate solution that concentration is 0.3 mol/L be raw material, according to 1：2.3 ratio is reacted, by phosphorus
Acid sodium solution is slowly added dropwise into silver nitrate solution, and rate of addition is 70 drops/minute, and reaction temperature is 35 DEG C, and silver orthophosphate is made
Colloid, is washed, is dried, and is obtained silver orthophosphate precipitation, is calcined 40 minutes at 280 DEG C, grind to form 150 mesh sizes produce it is described
Antiseptic.
It is used as further improvement of these options, step（1）The mixing speed is 7000 revs/min, temperature
For 120 DEG C.
It is used as further improvement of these options, step（2）Described injection machine preheating temperature is 120 DEG C, during preheating
Between be 3 hours.
Embodiment 2
A kind of durable type PVC bionic fish baits, are made up of following component in parts by weight：75 parts of polyvinyl chloride, phthalic acid
16 parts of dihexyl, 8.5 parts of SA dibutyl ester, 8.0 parts of epoxidized soybean oil, 6.0 parts of tricresyl phosphate benzene methyl, 4.0 parts of citrate,
2.7 parts of binary alcohol fatty acid ester, 2.3 parts of pentaerythritol fatty acid ester, 1.7 parts of binary alcohol benzoic ether, 1.4 parts of zinc stearate, tristearin
Sour 1.2 parts of calcium, 1.1 parts of sierozem power, 2.2 parts of talcum powder, 0.4 part of aluminate coupling agent, 0.3 part of titanium dioxide, antiseptic 0.2
Part, its preparation method comprises the following steps：
（1）By polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, lemon
Acid esters, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether are added in high-speed mixer, are mixed 4 minutes, plus
Enter residual components to mix 5 minutes；
（2）The material after plasticating will be mixed and pass through extruder extruding pelletization or section at 140 DEG C, injection machine is added to after drying
In, then by bionic fish bait model extrusion equipment extrusion bait model, extrusion temperature is 140 DEG C, obtains bionic fish bait model and enters
Row is cooled, and color spray, eye droppings are produced after drying.
As further improvement of these options, the preparation method of the antiseptic is：Using concentration as 0.6 mol/L
Sodium radio-phosphate,P-32 solution and silver nitrate solution that concentration is 0.4 mol/L be raw material, according to 1：2.4 ratio is reacted, by phosphorus
Acid sodium solution is slowly added dropwise into silver nitrate solution, and rate of addition is 75 drops/minute, and reaction temperature is 38 DEG C, and silver orthophosphate is made
Colloid, is washed, is dried, and is obtained silver orthophosphate precipitation, is calcined 45 minutes at 290 DEG C, grind to form 160 mesh sizes produce it is described
Antiseptic.
It is used as further improvement of these options, step（1）The mixing speed is 7500 revs/min, temperature
For 130 DEG C.
It is used as further improvement of these options, step（2）Described injection machine preheating temperature is 125 DEG C, during preheating
Between be 3.5 hours.
Embodiment 3
A kind of durable type PVC bionic fish baits, are made up of following component in parts by weight：80 parts of polyvinyl chloride, phthalic acid
17 parts of dihexyl, 9.5 parts of SA dibutyl ester, 8.5 parts of epoxidized soybean oil, 6.5 parts of tricresyl phosphate benzene methyl, 4.5 parts of citrate,
3.0 parts of binary alcohol fatty acid ester, 2.5 parts of pentaerythritol fatty acid ester, 2.0 parts of binary alcohol benzoic ether, 1.5 parts of zinc stearate, tristearin
Sour 1.3 parts of calcium, 1.2 parts of sierozem power, 2.5 parts of talcum powder, 0.5 part of aluminate coupling agent, 0.4 part of titanium dioxide, antiseptic 0.3
Part, its preparation method comprises the following steps：
（1）By polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, lemon
Acid esters, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether are added in high-speed mixer, are mixed 5 minutes, plus
Enter residual components to mix 6 minutes；
（2）The material after plasticating will be mixed and pass through extruder extruding pelletization or section at 150 DEG C, injection machine is added to after drying
In, then by bionic fish bait model extrusion equipment extrusion bait model, extrusion temperature is 145 DEG C, obtains bionic fish bait model and enters
Row is cooled, and color spray, eye droppings are produced after drying.
As further improvement of these options, the preparation method of the antiseptic is：Using concentration as 0.7 mol/L
Sodium radio-phosphate,P-32 solution and silver nitrate solution that concentration is 0.5 mol/L be raw material, according to 1：2.5 ratio is reacted, by phosphorus
Acid sodium solution is slowly added dropwise into silver nitrate solution, and rate of addition is 80 drops/minute, and reaction temperature is 40 DEG C, and silver orthophosphate is made
Colloid, is washed, is dried, and is obtained silver orthophosphate precipitation, is calcined 50 minutes at 300 DEG C, grind to form 180 mesh sizes produce it is described
Antiseptic.
It is used as further improvement of these options, step（1）The mixing speed is 8000 revs/min, temperature
For 140 DEG C.
It is used as further improvement of these options, step（2）Described injection machine preheating temperature is 130 DEG C, during preheating
Between be 4 hours.
Contrast test
Embodiment 1-3 method processing and fabricating bionic fish bait is used respectively, while using existing bionic fish bait as control, will be imitative
The performance of raw bait is measured, and result is recorded into as shown in the table：
By it was found that：The present invention is main material using PVC, adds remaining as its performance is strengthened, solves existing
Bionic fish bait service life is mostly in half a year to 1 year, and the low temperature of high temperature and winter often over summer, performance drops significantly
Low, the problem of still there is short life, the present invention can improve the service life of bionic fish bait, and recovery utilization rate is high.
Claims (4)
1. a kind of durable type PVC bionic fish baits, it is characterised in that be made up in parts by weight of following component：Polyvinyl chloride 70-
80 parts, 15-17 parts of DHP, 7.5-9.5 parts of SA dibutyl ester, 7.5-8.5 parts of epoxidized soybean oil, tricresyl phosphate
5.5-6.5 parts of benzene methyl, 3.5-4.5 parts of citrate, 2.5-3.0 parts of binary alcohol fatty acid ester, pentaerythritol fatty acid ester 2.0-2.5
Part, 1.5-2.0 parts of binary alcohol benzoic ether, 1.3-1.5 parts of zinc stearate, 1.1-1.3 parts of calcium stearate, sierozem power 1.0-1.2
Part, 2.0-2.5 parts of talcum powder, 0.3-0.5 parts of aluminate coupling agent, 0.2-0.4 parts of titanium dioxide, 0.1-0.3 parts of antiseptic, its
Preparation method comprises the following steps：
（1）By polyvinyl chloride, DHP, SA dibutyl ester, epoxidized soybean oil, tricresyl phosphate benzene methyl, lemon
Acid esters, binary alcohol fatty acid ester, pentaerythritol fatty acid ester, binary alcohol benzoic ether are added in high-speed mixer, are mixed 3-5 minutes,
Residual components are added to mix 4-6 minutes；
（2）The material after plasticating will be mixed and pass through extruder extruding pelletization or section at 130-150 DEG C, note is added to after drying
In molding machine, then by bionic fish bait model extrusion equipment extrusion bait model, extrusion temperature is 135-145 DEG C, obtains Biomimetic Fish
Bait model is cooled down, and color spray, eye droppings are produced after drying.
2. a kind of durable type PVC bionic fish baits as claimed in claim 1, it is characterised in that the preparation method of the antiseptic is：
Using silver nitrate solution that the sodium radio-phosphate,P-32 solution and concentration that concentration is 0.5-0.7 mol/Ls are 0.3-0.5 mol/Ls as raw material, press
According to 1：2.3-2.5 ratio is reacted, and sodium radio-phosphate,P-32 solution is slowly added dropwise into silver nitrate solution, and rate of addition is 70-80
Drop/minute, reaction temperature is 35-40 DEG C, and phosphoric acid silver colloid is made, and is washed, dried, and silver orthophosphate precipitation is obtained, in 280-
Calcined 40-50 minutes at 300 DEG C, grind to form 150-180 mesh sizes and produce the antiseptic.
3. a kind of durable type PVC bionic fish baits as claimed in claim 1, it is characterised in that step（1）The mixing speed
For 7000-8000 revs/min, temperature is 120-140 DEG C.
4. a kind of durable type PVC bionic fish baits as claimed in claim 1, it is characterised in that step（2）Described injection machine preheating
Temperature is 120-130 DEG C, and preheating time is 3-4 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710513499.XA CN107236218A (en) | 2017-06-29 | 2017-06-29 | A kind of durable type PVC bionic fish baits |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710513499.XA CN107236218A (en) | 2017-06-29 | 2017-06-29 | A kind of durable type PVC bionic fish baits |
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| Publication Number | Publication Date |
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| CN107236218A true CN107236218A (en) | 2017-10-10 |
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| CN201710513499.XA Pending CN107236218A (en) | 2017-06-29 | 2017-06-29 | A kind of durable type PVC bionic fish baits |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240770A (en) * | 2019-07-10 | 2019-09-17 | 安徽宏飞钓具有限公司 | A kind of high tenacity bionic fish bait resistant to high temperature and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294148A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Non-toxic polyvinyl chloride composition and its preparing process |
| CN102516682A (en) * | 2011-11-22 | 2012-06-27 | 界首市蒙特普休闲用品有限公司 | Bionic bait processed by waste plastic |
-
2017
- 2017-06-29 CN CN201710513499.XA patent/CN107236218A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294148A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Non-toxic polyvinyl chloride composition and its preparing process |
| CN102516682A (en) * | 2011-11-22 | 2012-06-27 | 界首市蒙特普休闲用品有限公司 | Bionic bait processed by waste plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240770A (en) * | 2019-07-10 | 2019-09-17 | 安徽宏飞钓具有限公司 | A kind of high tenacity bionic fish bait resistant to high temperature and preparation method thereof |
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Application publication date: 20171010 |