CN103709669A - Light stable and weatherable master batch applied to polyester fiber - Google Patents
Light stable and weatherable master batch applied to polyester fiber Download PDFInfo
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- CN103709669A CN103709669A CN201210373193.6A CN201210373193A CN103709669A CN 103709669 A CN103709669 A CN 103709669A CN 201210373193 A CN201210373193 A CN 201210373193A CN 103709669 A CN103709669 A CN 103709669A
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Abstract
The invention discloses light stable and weatherable master batch applied to polyester fiber, which is prepared from the following components by weight: 20-40% of resin carrier, 20-40% of light stabilizer, 10-30% of filler, 3-8% of compatilizer, 0.5-3% of coupling agent, 0.5-2% of nucleating agent, 3-5% of dispersant, and 0.1-1% of anti-oxidant. The beneficial effects reside in that: when the light stable and weatherable master batch prepared by the invention is applied to polyester fiber, the light stable and weatherable master batch has excellent light stability, weatherability and compatibility, can be used under harsh weather conditions, and makes the polyester fiber prepared from the master batch have strongest light absorption when wavelength is 380mm, thus can prolong service life of the product, simultaneously can improve toughness of the polyester fiber, makes the polyester fiber have good shock resistance, wear resistance and processing performance, has no harmful effect to human body in the polyester fiber processing, manufacturing and using processes, and has advantages of environmental protection, simple usage and low cost.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of light that is applied to trevira is stablized weather-proof master batch.
Background technology
Trevira refers to polyethylene terephthalate (PET) fiber, its excellent performance, raw material is easy to get, of many uses, be a kind of synthon with fastest developing speed in various synthon, output is the highest, application surface is the widest, be described as the king of the fiber that is 21 century.Along with the development of trevira, increasing trevira is applied to the outside surface of product, such as automobile decoration material, canopy and variable sign etc., and these Application Areass need fiber not degrade under the irradiation of UV-light.Photostabilizer is according to its chemical composition classification, and some can absorb UV-light, and some can hinder UV-light or the photodegradation of oxygen to synthon, thus the color of protecting materials and mechanical property.
Summary of the invention
The object of the present invention is to provide a kind of Heat stability is good, strong, the with low cost and easy to use light that is applied to trevira of weathering resistance to stablize weather-proof master batch.
The technical solution adopted for the present invention to solve the technical problems is: a kind of light that is applied to trevira is stablized weather-proof master batch, and its component by mass percent proportioning is: resin carrier 20%～40%, photostabilizer 20%～40%, weighting agent 10%～30%, compatilizer 3%～8%, coupling agent 0.5%～3%, nucleator 0.5%～2%, dispersion agent 3%～5%, oxidation inhibitor 0.1%～1%.
Described resin carrier is terephthalic acid binary alcohol esters-m-phthalic acid binary alcohol esters-terephthaldehyde acid polyol ester terpolymer resin.
Described photostabilizer is ESCALOL 567 or hindered amine as light stabilizer.
Described weighting agent is a kind of in glass microballon, kaolin, barium sulfate, silicon-dioxide, wollastonite.
Described compatilizer is a kind of in acetate ethylene copolymer (EVA), vinylformic acid and ethylene copolymer (EAA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA).
Described coupling agent is aluminium titanium composite coupler.
The nucleating agent is ethylene methacrylic acid polymer salt, polyethylene glycol two glycidyl ether, poly ethylene oxide, ethylene maleic acid copolymer sodium salt, Yu glycidyl methacrylate ethylene crisp vinegar, sodium acetate and poly adipic acid butyl Vinyl - two, a metal salt acrylic copolymer, metal salts of sulfonated polystyrene in the.
Described dispersion agent is a kind of in polyoxyethylene glycol, trimethylolethane, calcium stearate, polyvinylpyrrolidone.
Described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
The preparation method that above-mentioned a kind of light that is applied to trevira is stablized weather-proof master batch is: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, 140 ℃～180 ℃ of mixing temperatures, mix 15～30 minutes, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 270 ℃～290 ℃, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain a kind of light that is applied to trevira of the present invention and stablize weather-proof master batch.
The invention has the beneficial effects as follows, when the light making by the present invention is stablized weather-proof master batch and is applied to trevira, it has good light stability, weathering resistance and consistency, and can comparatively under exacting terms, use at weather, use trevira that this master batch manufactures the strongest to the absorptivity of light during for 380mm at wavelength, thereby can extend product work-ing life, can also improve the toughness of trevira simultaneously, make it have good shock resistance, wear resisting property and processing characteristics, and in its processing and manufacturing and use procedure to human body without deleterious effect, its environmental health is good, easy to use, with low cost.
Embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention.
Embodiment 1:
A kind of light that is applied to trevira is stablized weather-proof master batch, its component by mass percent proportioning is: the compound 0.5% of the sodium salt 1.5% of resin carrier 30%, ESCALOL 567 30%, glass microballon 25%, acetate ethylene copolymer (EVA) 6%, aluminium titanium composite coupler 3%, ethylene-methyl methacrylate polymkeric substance, polyoxyethylene glycol 4%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168, wherein, described resin carrier is terephthalic acid binary alcohol esters-m-phthalic acid binary alcohol esters-terephthaldehyde acid polyol ester terpolymer resin.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, 140 ℃～180 ℃ of mixing temperatures, mix 15～30 minutes, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 270 ℃～290 ℃, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain a kind of light that is applied to trevira of the present invention and stablize weather-proof master batch.
Embodiment 2:
A kind of light that is applied to trevira is stablized weather-proof master batch, its component by mass percent proportioning is: resin carrier 20%, ESCALOL 567 40%, kaolin 22%, maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA) 8%, aluminium titanium composite coupler 3%, polyethyleneglycol diglycidylether 1%, calcium stearate 5%, the compound 1% of hindered phenol antioxygen 1076 and phosphite ester kind antioxidant 168, wherein, described resin carrier is terephthalic acid binary alcohol esters-m-phthalic acid binary alcohol esters-terephthaldehyde acid polyol ester terpolymer resin.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, 140 ℃～180 ℃ of mixing temperatures, mix 15～30 minutes, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 270 ℃～290 ℃, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain a kind of light that is applied to trevira of the present invention and stablize weather-proof master batch.
Embodiment 3:
A kind of light that is applied to trevira is stablized weather-proof master batch, its component by mass percent proportioning is: resin carrier 40%, hindered amine as light stabilizer 20%, wollastonite 30%, ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA) 3%, aluminium titanium composite coupler 2%, the crisp sodium-acetate of second and poly-hexanodioic acid two fourth vinegar 1%, polyvinylpyrrolidone 3.5%, the compound 0.5% of hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168, wherein, described resin carrier is terephthalic acid binary alcohol esters-m-phthalic acid binary alcohol esters-terephthaldehyde acid polyol ester terpolymer resin.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, 140 ℃～180 ℃ of mixing temperatures, mix 15～30 minutes, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 270 ℃～290 ℃, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain a kind of light that is applied to trevira of the present invention and stablize weather-proof master batch.
Claims (10)
1. a light that is applied to trevira is stablized weather-proof master batch, it is characterized in that, its component by mass percent proportioning is: resin carrier 20%～40%, photostabilizer 20%～40%, weighting agent 10%～30%, compatilizer 3%～8%, coupling agent 0.5%～3%, nucleator 0.5%～2%, dispersion agent 3%～5%, oxidation inhibitor 0.1%～1%.
2. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described resin carrier is terephthalic acid binary alcohol esters-m-phthalic acid binary alcohol esters-terephthaldehyde acid polyol ester terpolymer resin.
3. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described photostabilizer is ESCALOL 567 or hindered amine as light stabilizer.
4. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described weighting agent is a kind of in glass microballon, kaolin, barium sulfate, silicon-dioxide, wollastonite.
5. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described compatilizer is a kind of in acetate ethylene copolymer (EVA), vinylformic acid and ethylene copolymer (EAA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA).
6. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described coupling agent is aluminium titanium composite coupler.
7.The light stability of weathering masterbatch 7 according to claim 1 wherein a used in polyester fiber, characterized in that, the nucleating agent is ethylene methacrylic acid polymer salt, polyethylene glycol two glycidyl ether, poly ethylene oxide, ethylene maleic acid copolymer sodium salt Yu, glycidyl methacrylate, ethyl acetate crisp sodium acetate and poly adipic acid butyl vinyl - two, a metal salt acrylic copolymer metal salts of sulfonated polystyrene, in.
8. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described dispersion agent is a kind of in polyoxyethylene glycol, trimethylolethane, calcium stearate, polyvinylpyrrolidone.
9. a kind of light that is applied to trevira according to claim 1 is stablized weather-proof master batch, it is characterized in that, described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
10. a kind of light that is applied to trevira according to claim 1 is stablized the preparation method of weather-proof master batch, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, 140 ℃～180 ℃ of mixing temperatures, mix 15～30 minutes, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 270 ℃～290 ℃, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain a kind of light that is applied to trevira and stablize weather-proof master batch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210373193.6A CN103709669A (en) | 2012-09-29 | 2012-09-29 | Light stable and weatherable master batch applied to polyester fiber |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210373193.6A CN103709669A (en) | 2012-09-29 | 2012-09-29 | Light stable and weatherable master batch applied to polyester fiber |
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| CN103709669A true CN103709669A (en) | 2014-04-09 |
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| CN201210373193.6A Pending CN103709669A (en) | 2012-09-29 | 2012-09-29 | Light stable and weatherable master batch applied to polyester fiber |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106087255A (en) * | 2016-06-07 | 2016-11-09 | 广东斯乐普环保技术股份有限公司 | The preparation method of polyester ageing resistance by ultraviolet light spunbonded needle-punched geotextile |
| WO2017062067A1 (en) * | 2015-10-05 | 2017-04-13 | Albany International Corp. | Compositions and methods for improved abrasion resistance of polymeric components |
| CN111675885A (en) * | 2020-06-22 | 2020-09-18 | 宿迁联宏新材料有限公司 | PET (polyethylene terephthalate) light aging resistant and weather resistant master batch and preparation method thereof |
| CN113308050A (en) * | 2021-06-09 | 2021-08-27 | 绍兴市上虞鸿越塑业有限公司 | Wall-hanging-prevention plastic master batch and preparation method and application thereof |
| JP2023007326A (en) * | 2021-06-30 | 2023-01-18 | 南亞塑膠工業股▲分▼有限公司 | Polyester material of antibacterial/anti-fungal |
-
2012
- 2012-09-29 CN CN201210373193.6A patent/CN103709669A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017062067A1 (en) * | 2015-10-05 | 2017-04-13 | Albany International Corp. | Compositions and methods for improved abrasion resistance of polymeric components |
| RU2687428C1 (en) * | 2015-10-05 | 2019-05-13 | Олбани Интернешнл Корп. | Composition and method for increasing wear resistance of polymer components |
| US10759923B2 (en) | 2015-10-05 | 2020-09-01 | Albany International Corp. | Compositions and methods for improved abrasion resistance of polymeric components |
| US11485836B2 (en) | 2015-10-05 | 2022-11-01 | Albany International Corp. | Compositions and methods for improved abrasion resistance of polymeric components |
| CN106087255A (en) * | 2016-06-07 | 2016-11-09 | 广东斯乐普环保技术股份有限公司 | The preparation method of polyester ageing resistance by ultraviolet light spunbonded needle-punched geotextile |
| CN111675885A (en) * | 2020-06-22 | 2020-09-18 | 宿迁联宏新材料有限公司 | PET (polyethylene terephthalate) light aging resistant and weather resistant master batch and preparation method thereof |
| CN113308050A (en) * | 2021-06-09 | 2021-08-27 | 绍兴市上虞鸿越塑业有限公司 | Wall-hanging-prevention plastic master batch and preparation method and application thereof |
| JP2023007326A (en) * | 2021-06-30 | 2023-01-18 | 南亞塑膠工業股▲分▼有限公司 | Polyester material of antibacterial/anti-fungal |
| JP7414788B2 (en) | 2021-06-30 | 2024-01-16 | 南亞塑膠工業股▲分▼有限公司 | Antibacterial and anti-mildew polyester material |
| US11968980B2 (en) | 2021-06-30 | 2024-04-30 | Nan Ya Plastics Corporation | Antibacterial and antifungal polyester material |
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Application publication date: 20140409 |