CN107236151A - A kind of starch polyarylate plastic alloy goblet - Google Patents
A kind of starch polyarylate plastic alloy goblet Download PDFInfo
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- CN107236151A CN107236151A CN201710474792.XA CN201710474792A CN107236151A CN 107236151 A CN107236151 A CN 107236151A CN 201710474792 A CN201710474792 A CN 201710474792A CN 107236151 A CN107236151 A CN 107236151A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The present invention discloses a kind of starch polyarylate plastic alloy goblet, including following weight parts component：50 60 parts of polyarylate, 8 15 parts of calcium carbonate, 14 parts of carbon fiber, 10 20 parts of benzoin ethyl ether, 79 parts of nano imvite, 1.2 1.4 parts of butyl titanate, 12 14 parts of isocyanic acid ammonium, 60 65 parts of cornstarch, 23 parts of gelatin, 12 parts of magnesium stearate, 13 15 parts of polysorbate, 1 1.5 parts of pentaerythrite, 46 parts of potassium titanate crystal whisker, 12 parts of sulfated lauryl alcohol, 46 parts of plant saponin.Product of the present invention is safety formula production, can be for manufacture plastic beverage cup for covering, free from extraneous odour, safety and environmental protection when product is used, it is advantageously implemented large-scale industrial production simultaneously, it is easy to grasp, is easy to promote, the meeting automatic classifying in the presence of oxygen-enriched and microorganism of the product after discarding, ultimately generate carbon dioxide and water, ecological, environmental protective.
Description
Technical field
The present invention relates to plastics arts, specifically a kind of starch-polyarylate plastic alloy goblet.
Background technology
In recent years, due to waste plastic be difficult to degrade " white pollution " that brings be on the rise, cause global wide
Limitation has been put into effect successively or the relevant laws and regulations of non-degradable plastics are prohibitted the use of in general concern, countries in the world.On the other hand, due to manufacture
The raw material oil of conventional plastic is non-renewable resources, will be exhausted with a large amount of use of the mankind, thus is developed with renewable
Resource is raw material, degradable environment-friendly plastic is extremely urgent.
The content of the invention
It is an object of the invention to provide a kind of starch-polyarylate plastic alloy goblet.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of starch-polyarylate plastic alloy goblet, is prepared from by the component of following portions by weight：Polyarylate 50-
60 parts, 8-15 parts of calcium carbonate, 1-4 parts of carbon fiber, 10-20 parts of benzoin ethyl ether, 7-9 parts of nano imvite, butyl titanate
1.2-1.4 parts, 12-14 parts of isocyanic acid ammonium, 60-65 parts of cornstarch, 2-3 parts of gelatin, 1-2 parts of magnesium stearate, polysorbate
13-15 parts, 1-1.5 parts of pentaerythrite, 4-6 parts of potassium titanate crystal whisker, 1-2 parts of sulfated lauryl alcohol, 4-6 parts of plant saponin.
Preferably, described starch-polyarylester plastic plastic alloy goblet, is prepared by the component of following portions by weight
Form：55 parts of polyarylester plastic, 10 parts of calcium carbonate, 3 parts of carbon fiber, 15 parts of benzoin ethyl ether, 8 parts of nano imvite, metatitanic acid four
1.3 parts of butyl ester, 13 parts of isocyanic acid ammonium, 63 parts of cornstarch, 2 parts of gelatin, 2 parts of magnesium stearate, 13 parts of polysorbate, Ji Wusi
1 part of alcohol, 5 parts of potassium titanate crystal whisker, 1 part of sulfated lauryl alcohol, 5 parts of plant saponin.
The starch-polyarylate plastic alloy goblet, is made up of step in detail below：
(1) after cornstarch is well mixed with nano imvite, taken out after being dried 120 minutes under conditions of 130 DEG C,
It is cooled to after room temperature and mixed-powder is utilized into sonic oscillation 30-40 minutes, it is 30 DEG C to control bath temperature, ultrasonic power is
Mixed-powder, is then transferred in stirred tank by 100W, adds butyl titanate, and it is 75 DEG C to control temperature, with 1500 revs/min
After speed is stirred 15 minutes, the mixed-powder for producing surface hydrophobicity processing for 60 minutes is dried under conditions of 120 DEG C；
(2) 80-100 mesh powders are made by corase grind, fine grinding after isocyanic acid ammonium is dried, nanoscale powder is then comminuted into
End, is mixed with gelatin, and well mixed rear and magnesium stearate is together put into kneader, and 120 DEG C of temperature control is mediated 15 minutes, is released
Cooling, produces isocyanic acid ammonium enhancing material；
(3) mixed-powder of the surface hydrophobicity processing obtained step (1) is mixed with pentaerythrite, passes through colloidal mill point
Dissipate 60-90 minutes, then add the isocyanic acid ammonium enhancing material that step (2) is obtained, melted under conditions of 170-180 DEG C of temperature of control
Melt extruding pelletization, obtain a diameter of 6mm starch masterbatch；
(4) starch masterbatch, polyarylester plastic, polysorbate and remaining residual components obtained step (3) are normal
After being well mixed under temperature, control temperature carries out hot-melt extruded blow molding under 170-180 DEG C of processing temperature.
Beneficial effects of the present invention：Product of the present invention is safety formula production, can be for manufacture plastic beverage cup for covering, product
Free from extraneous odour, safety and environmental protection when using, while being advantageously implemented large-scale industrial production, it is easy to grasp, are easy to promote, after discarding
Product in the presence of oxygen-enriched and microorganism can automatic classifying, ultimately generate carbon dioxide and water, ecological, environmental protective.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
A kind of starch-polyarylate plastic alloy goblet, weighs following weight component：The ㎏ of polyarylester plastic 50, calcium carbonate 8
㎏, the ㎏ of carbon fiber 1, the ㎏ of benzoin ethyl ether 10, the ㎏ of nano imvite 7, the ㎏ of butyl titanate 1.2, the ㎏ of isocyanic acid ammonium 12, corn form sediment
The ㎏ of powder 60, the ㎏ of gelatin 2, the ㎏ of magnesium stearate 1, the ㎏ of polysorbate 13, the ㎏ of pentaerythrite 1, the ㎏ of potassium titanate crystal whisker 4, laruyl alcohol sulphur
The ㎏ of hydrochlorate 1, the ㎏ of plant saponin 4.
It is made up of step in detail below：
(1) after cornstarch is well mixed with nano imvite, taken out after being dried 120 minutes under conditions of 130 DEG C,
It is cooled to after room temperature and mixed-powder is utilized into sonic oscillation 30-40 minutes, it is 30 DEG C to control bath temperature, ultrasonic power is
Mixed-powder, is then transferred in stirred tank by 100W, adds butyl titanate, and it is 75 DEG C to control temperature, with 1500 revs/min
After speed is stirred 15 minutes, the mixed-powder for producing surface hydrophobicity processing for 60 minutes is dried under conditions of 120 DEG C；
(2) 80-100 mesh powders are made by corase grind, fine grinding after isocyanic acid ammonium is dried, nanoscale powder is then comminuted into
End, is mixed with gelatin, and well mixed rear and magnesium stearate is together put into kneader, and 120 DEG C of temperature control is mediated 15 minutes, is released
Cooling, produces isocyanic acid ammonium enhancing material；
(3) mixed-powder of the surface hydrophobicity processing obtained step (1) is mixed with pentaerythrite, passes through colloidal mill point
Dissipate 60-90 minutes, then add the isocyanic acid ammonium enhancing material that step (2) is obtained, melted under conditions of 170-180 DEG C of temperature of control
Melt extruding pelletization, obtain a diameter of 6mm starch masterbatch；
(4) starch masterbatch, polyarylester plastic, polysorbate and remaining residual components obtained step (3) are normal
After being well mixed under temperature, control temperature carries out hot-melt extruded blow molding under 170-180 DEG C of processing temperature.
Embodiment 2
A kind of starch-polyarylate plastic alloy goblet, weighs the component of following weight：The ㎏ of polyarylester plastic 60, carbonic acid
The ㎏ of calcium 15, the ㎏ of carbon fiber 4, the ㎏ of benzoin ethyl ether 20, the ㎏ of nano imvite 9, the ㎏ of butyl titanate 1.4, the ㎏ of isocyanic acid ammonium 14, jade
The ㎏ of rice starch 65, the ㎏ of gelatin 3, the ㎏ of magnesium stearate 2, the ㎏ of polysorbate 15, the ㎏ of pentaerythrite 1.5, the ㎏ of potassium titanate crystal whisker 6, the moon
The ㎏ of cinnamic alcohol sulfate 2, the ㎏ of plant saponin 6.
It is made up of step in detail below：
(1) after cornstarch is well mixed with nano imvite, taken out after being dried 120 minutes under conditions of 130 DEG C,
It is cooled to after room temperature and mixed-powder is utilized into sonic oscillation 30-40 minutes, it is 30 DEG C to control bath temperature, ultrasonic power is
Mixed-powder, is then transferred in stirred tank by 100W, adds butyl titanate, and it is 75 DEG C to control temperature, with 1500 revs/min
After speed is stirred 15 minutes, the mixed-powder for producing surface hydrophobicity processing for 60 minutes is dried under conditions of 120 DEG C；
(2) 80-100 mesh powders are made by corase grind, fine grinding after isocyanic acid ammonium is dried, nanoscale powder is then comminuted into
End, is mixed with gelatin, and well mixed rear and magnesium stearate is together put into kneader, and 120 DEG C of temperature control is mediated 15 minutes, is released
Cooling, produces isocyanic acid ammonium enhancing material；
(3) mixed-powder of the surface hydrophobicity processing obtained step (1) is mixed with pentaerythrite, passes through colloidal mill point
Dissipate 60-90 minutes, then add the isocyanic acid ammonium enhancing material that step (2) is obtained, melted under conditions of 170-180 DEG C of temperature of control
Melt extruding pelletization, obtain a diameter of 6mm starch masterbatch；
(4) starch masterbatch, polyarylester plastic, polysorbate and remaining residual components obtained step (3) are normal
After being well mixed under temperature, control temperature carries out hot-melt extruded blow molding under 170-180 DEG C of processing temperature.
Embodiment 3
A kind of starch-polyarylate plastic alloy goblet, weighs the component of following weight：The ㎏ of polyarylester plastic 55, carbonic acid
The ㎏ of calcium 10, the ㎏ of carbon fiber 3, the ㎏ of benzoin ethyl ether 15, the ㎏ of nano imvite 8, the ㎏ of butyl titanate 1.3, the ㎏ of isocyanic acid ammonium 13, jade
The ㎏ of rice starch 63, the ㎏ of gelatin 2, the ㎏ of magnesium stearate 2, the ㎏ of polysorbate 13, the ㎏ of pentaerythrite 1, the ㎏ of potassium titanate crystal whisker 5, bay
The ㎏ of alcohol sulfate 1, the ㎏ of plant saponin 5.
It is made up of step in detail below：
(1) after cornstarch is well mixed with nano imvite, taken out after being dried 120 minutes under conditions of 130 DEG C,
It is cooled to after room temperature and mixed-powder is utilized into sonic oscillation 30-40 minutes, it is 30 DEG C to control bath temperature, ultrasonic power is
Mixed-powder, is then transferred in stirred tank by 100W, adds butyl titanate, and it is 75 DEG C to control temperature, with 1500 revs/min
After speed is stirred 15 minutes, the mixed-powder for producing surface hydrophobicity processing for 60 minutes is dried under conditions of 120 DEG C；
(2) 80-100 mesh powders are made by corase grind, fine grinding after isocyanic acid ammonium is dried, nanoscale powder is then comminuted into
End, is mixed with gelatin, and well mixed rear and magnesium stearate is together put into kneader, and 120 DEG C of temperature control is mediated 15 minutes, is released
Cooling, produces isocyanic acid ammonium enhancing material；
(3) mixed-powder of the surface hydrophobicity processing obtained step (1) is mixed with pentaerythrite, passes through colloidal mill point
Dissipate 60-90 minutes, then add the isocyanic acid ammonium enhancing material that step (2) is obtained, melted under conditions of 170-180 DEG C of temperature of control
Melt extruding pelletization, obtain a diameter of 6mm starch masterbatch；
(4) starch masterbatch, polyarylester plastic, polysorbate and remaining residual components obtained step (3) are normal
After being well mixed under temperature, control temperature carries out hot-melt extruded blow molding under 170-180 DEG C of processing temperature.
Claims (3)
1. a kind of starch-polyarylate plastic alloy goblet, it is characterised in that be prepared from by the component of following portions by weight：
50-60 parts of polyarylate, 8-15 parts of calcium carbonate, 1-4 parts of carbon fiber, 10-20 parts of benzoin ethyl ether, 7-9 parts of nano imvite, metatitanic acid
Four 1.2-1.4 parts of butyl esters, 12-14 parts of isocyanic acid ammonium, 60-65 parts of cornstarch, 2-3 parts of gelatin, 1-2 parts of magnesium stearate, poly- mountain
13-15 parts of pears acid esters, 1-1.5 parts of pentaerythrite, 4-6 parts of potassium titanate crystal whisker, 1-2 parts of sulfated lauryl alcohol, plant saponin 4-6
Part.
2. a kind of starch-polyarylate plastic alloy goblet as claimed in claim 1, it is characterised in that by following weight parts
Several components are prepared from：55 parts of polyarylate, 10 parts of calcium carbonate, 3 parts of carbon fiber, 15 parts of benzoin ethyl ether, nano imvite 8
Part, 1.3 parts of butyl titanate, 13 parts of isocyanic acid ammonium, 63 parts of cornstarch, 2 parts of gelatin, 2 parts of magnesium stearate, polysorbate 13
Part, 1 part of pentaerythrite, 5 parts of potassium titanate crystal whisker, 1 part of sulfated lauryl alcohol, 5 parts of plant saponin.
3. a kind of starch-polyarylate plastic alloy goblet according to claim 1, it is characterised in that by walking in detail below
Suddenly it is made：
(1) after cornstarch is well mixed with nano imvite, taken out after being dried 120 minutes under conditions of 130 DEG C, cooling
Mixed-powder is utilized into sonic oscillation 30-40 minutes after to room temperature, it is 30 DEG C to control bath temperature, and ultrasonic power is 100W, so
Mixed-powder is transferred in stirred tank afterwards, butyl titanate is added, it is 75 DEG C to control temperature, is stirred with 1500 revs/min of speed
Mix after 15 minutes, the mixed-powder for producing surface hydrophobicity processing for 60 minutes is dried under conditions of 120 DEG C；
(2) 80-100 mesh powders are made by corase grind, fine grinding after isocyanic acid ammonium is dried, nanometer grade powder is then comminuted into,
Mixed with gelatin, well mixed rear and magnesium stearate is together put into kneader, 120 DEG C of temperature control is mediated 15 minutes, is released cold
But, isocyanic acid ammonium enhancing material is produced；
(3) mixed-powder of the surface hydrophobicity processing obtained step (1) is mixed with pentaerythrite, scattered by colloidal mill
60-90 minutes, the isocyanic acid ammonium enhancing material that step (2) is obtained then is added, melted under conditions of 170-180 DEG C of temperature of control
Extruding pelletization, obtains a diameter of 6mm starch masterbatch；
(4) starch masterbatch, polyarylester plastic, polysorbate and remaining residual components obtained step (3) are at normal temperatures
After well mixed, control temperature carries out hot-melt extruded blow molding under 170-180 DEG C of processing temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710474792.XA CN107236151A (en) | 2017-06-21 | 2017-06-21 | A kind of starch polyarylate plastic alloy goblet |
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| CN201710474792.XA CN107236151A (en) | 2017-06-21 | 2017-06-21 | A kind of starch polyarylate plastic alloy goblet |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327468A (en) * | 2014-10-22 | 2015-02-04 | 青岛东泰诚恩新材料科技发展有限公司 | Formula of polyarylester plastic |
| CN104479317A (en) * | 2014-12-01 | 2015-04-01 | 金发科技股份有限公司 | Biodegradable aliphatic-aromatic copolyester composition and application thereof |
| CN106243636A (en) * | 2016-08-02 | 2016-12-21 | 安徽美翔塑业有限公司 | A kind of starch novolac epoxy resin is blended degradable sealing bag and preparation method thereof |
| CN106279780A (en) * | 2016-08-02 | 2017-01-04 | 安徽美翔塑业有限公司 | A kind of starch polyvinyl chloride resin is blended degradable patch bone bag and preparation method thereof |
-
2017
- 2017-06-21 CN CN201710474792.XA patent/CN107236151A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327468A (en) * | 2014-10-22 | 2015-02-04 | 青岛东泰诚恩新材料科技发展有限公司 | Formula of polyarylester plastic |
| CN104479317A (en) * | 2014-12-01 | 2015-04-01 | 金发科技股份有限公司 | Biodegradable aliphatic-aromatic copolyester composition and application thereof |
| CN106243636A (en) * | 2016-08-02 | 2016-12-21 | 安徽美翔塑业有限公司 | A kind of starch novolac epoxy resin is blended degradable sealing bag and preparation method thereof |
| CN106279780A (en) * | 2016-08-02 | 2017-01-04 | 安徽美翔塑业有限公司 | A kind of starch polyvinyl chloride resin is blended degradable patch bone bag and preparation method thereof |
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