CN106042561A - Antibacterial biomass plastic product - Google Patents

Antibacterial biomass plastic product Download PDF

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Publication number
CN106042561A
CN106042561A CN201610457896.5A CN201610457896A CN106042561A CN 106042561 A CN106042561 A CN 106042561A CN 201610457896 A CN201610457896 A CN 201610457896A CN 106042561 A CN106042561 A CN 106042561A
Authority
CN
China
Prior art keywords
antibacterial
plastic
layer
antibacterial biological
matter plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610457896.5A
Other languages
Chinese (zh)
Inventor
闻伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Xingyi Coating Co Ltd
Original Assignee
Taicang Xingyi Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Xingyi Coating Co Ltd filed Critical Taicang Xingyi Coating Co Ltd
Priority to CN201610457896.5A priority Critical patent/CN106042561A/en
Publication of CN106042561A publication Critical patent/CN106042561A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552Fatigue strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi

Abstract

The invention discloses an antibacterial biomass plastic product which comprises an antibacterial material layer at the outermost layer, a PP composite material layer at an intermediate layer and a substrate layer at an innermost layer, wherein the PP composite material layer comprises inorganic nanoparticles and polypropylene; the substrate layer is prepared from thermoplastic plastic and melamine resin ether. The antibacterial biomass plastic product provided by the invention has the advantages of being non-toxic, free of peculiar smell and harmless to environment.

Description

Antibacterial biological matter plastic
Technical field
The present invention relates to a kind of antibacterial biological matter plastic.
Background technology
In the world, always amorphous bulk conjunction is explored in the synthesis carrying out having the metal glass of excellent glass forming ability One of main contents of gold research.For many years, we are including that the synthesis of Cu-Zr binary bulk amorphous alloy is interior multiple Nearly 2 years of important results & is achieved on the study on the synthesis of rare earth base lump non-crystalline alloy in the bulk amorphous alloy research of system Also impressive progress is achieved.
Plastic is the most common in our daily life, and application is very extensive, especially in domestic, has foot bath The daily household goods such as basin, the washing tub of washing machine, plastic tub.Due to the shortcoming that high-intensity plastic product own is the most aging, Plastic crushing often occurs during use.The finished product of prior art has higher elongation percentage, bending strength and tensile strength, But impact strength is the highest, therefore some are required that product that bending strength height, good impact resistance, good rigidly, hardness are higher is just The requirement of its serviceability can not be met.
Summary of the invention
It is an object of the invention to provide a kind of antibacterial biological matter plastic, there is nontoxic, free from extraneous odour, environmental sound Advantage.
The technical scheme is that a kind of antibacterial biological matter plastic, described antibacterial biological matter plastic includes Outermost anti-biotic material layer, the PP composite layer in intermediate layer and the base layer of innermost layer, described PP composite layer includes Inorganic nano-particle and polypropylene, described base layer is made up of thermoplastic and melmac ether, and described is anti- Bacterium material layer accounts for the 7%-13% of the antibacterial biological overall component of matter plastic, and described PP composite layer accounts for antibacterial biological matter and moulds The 40%-44% of the overall component of material products, described base layer accounts for the 44%-47% of the antibacterial biological overall component of matter plastic.
In a preferred embodiment of the present invention, described anti-biotic material layer is superfine polypropylene fibre-grade antibacterial plastic concentrate.
In a preferred embodiment of the present invention, described anti-biotic material layer accounts for the antibacterial biological overall component of matter plastic 13%, described PP composite layer accounts for the 42% of the antibacterial biological overall component of matter plastic, and described base layer accounts for antibacterial The 45% of the overall component of biomass plastic.
A kind of antibacterial biological matter plastic of the present invention, has nontoxic, the advantage of free from extraneous odour, environmental sound.
Detailed description of the invention
It is described in detail below in conjunction with to presently preferred embodiments of the present invention, so that advantages and features of the invention can be more easy to In being readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Wherein, described antibacterial biological matter plastic includes the PP composite in outermost anti-biotic material layer, intermediate layer Layer and the base layer of innermost layer, described PP composite layer include inorganic nano-particle and polypropylene, described base layer be by Thermoplastic and melmac ether are made, and described anti-biotic material layer accounts for the antibacterial biological overall component of matter plastic 7%-13%, described PP composite layer accounts for the 40%-44% of the antibacterial biological overall component of matter plastic, and described base layer accounts for The 44%-47% of the overall component of antibacterial biological matter plastic.
Further illustrating, described anti-biotic material layer is superfine polypropylene fibre-grade antibacterial plastic concentrate, and described anti-biotic material layer accounts for The 13% of the overall component of antibacterial biological matter plastic, described PP composite layer accounts for antibacterial biological matter plastic and totally divides The 42% of amount, described base layer accounts for the 45% of the antibacterial biological overall component of matter plastic.
Further illustrating, the inorganic nano-particle in PP composite refers to size solid between 1nm~100nm Granule.Owing to its size is little, light transmittance is good, therefore the density of plastics can be increased, improve resistance to ag(e)ing and the thermostability etc. of plastics. Compared with traditional PP blend, nano composite material has more preferable rigidity, maintains good low-temperature impact toughness.Fill The nano material of 5 % is suitable with the performance of the Pulvis Talci gained composite filling 25 %.Conventional inorganic nano rigid particles Mainly there are CaCO3, SiO2, TiO2, Y2O3 etc..Homemade dispersant carries out surface process to nanosized SiO_2, then with pulverizing Pelletized polypropylene, ethylene propylene diene rubber premixing on high-speed mixer together, then by premix material at double screw extruder Upper melt blending extruding pelletization, be prepared for PP/ nanosized SiO_2 PEPDM nano composite material.Find after tested, work as nanometer When SiO2 content is 2 %~3 %, the impact strength of composite reaches maximum.In addition, nanosized SiO_2 also can improve poly-third The crystallization temperature of alkene and crystalline rate, and make spherocrystal refine.Nano TiO 2 particle is because of its distinctive semiconductor structure, on the one hand It can absorb and reflected sunlight, therefore can improve the light fastness aging of body as high polymer photomask agent;On the other hand Absorb after sunlight, occur photocatalysis chemical reaction to produce the group of strong oxidizing property, can be thus permissible with oxide mineral impurity Make antibacterial, be a kind of free of contamination new material.The present invention provides a kind of antibacterial biological matter plastic, have nontoxic, be as good as Taste, the advantage of environmental sound.
The detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any is familiar with this area Technical staff in the technical scope that disclosed herein, the change can expected without creative work or replacement, all should contain Cover within protection scope of the present invention.Therefore, the protection model that protection scope of the present invention should be limited with claims Enclose and be as the criterion.

Claims (3)

1. an antibacterial biological matter plastic, it is characterised in that: described antibacterial biological matter plastic includes outermost anti- Bacterium material layer, the PP composite layer in intermediate layer and the base layer of innermost layer, described PP composite layer includes inorganic nano-particle Son and polypropylene, described base layer is made up of thermoplastic and melmac ether, and described anti-biotic material layer accounts for The 7%-13% of the overall component of antibacterial biological matter plastic, it is overall that described PP composite layer accounts for antibacterial biological matter plastic The 40%-44% of component, described base layer accounts for the 44%-47% of the antibacterial biological overall component of matter plastic.
Antibacterial biological matter plastic the most according to claim 1, it is characterised in that: described anti-biotic material layer is ultra-fine third Synthetic fibre fibre-grade antibacterial plastic concentrate.
Antibacterial biological matter plastic the most according to claim 1, it is characterised in that: described anti-biotic material layer accounts for antibacterial The 13% of the overall component of biomass plastic, described PP composite layer accounts for the antibacterial biological overall component of matter plastic 42%, described base layer accounts for the 45% of the antibacterial biological overall component of matter plastic.
CN201610457896.5A 2016-06-22 2016-06-22 Antibacterial biomass plastic product Pending CN106042561A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610457896.5A CN106042561A (en) 2016-06-22 2016-06-22 Antibacterial biomass plastic product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610457896.5A CN106042561A (en) 2016-06-22 2016-06-22 Antibacterial biomass plastic product

Publications (1)

Publication Number Publication Date
CN106042561A true CN106042561A (en) 2016-10-26

Family

ID=57169276

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610457896.5A Pending CN106042561A (en) 2016-06-22 2016-06-22 Antibacterial biomass plastic product

Country Status (1)

Country Link
CN (1) CN106042561A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106476385A (en) * 2016-12-09 2017-03-08 闽南师范大学 A kind of Novel antibacterial CPP thin film and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1282756A (en) * 1999-07-29 2001-02-07 上海杰事杰新材料股份有限公司 Composite pipe material for building
CN1823134A (en) * 2003-07-22 2006-08-23 Ami阿格罗林茨三聚氰胺国际有限公司 Plastic products with high strength and flexibility
CN101628645A (en) * 2009-07-30 2010-01-20 浙江大东南包装股份有限公司 Antibacterial BOPP/PP food composite package film and preparation method
CN102850678A (en) * 2012-09-20 2013-01-02 吴江市天源塑胶有限公司 High-strength conductive plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1282756A (en) * 1999-07-29 2001-02-07 上海杰事杰新材料股份有限公司 Composite pipe material for building
CN1823134A (en) * 2003-07-22 2006-08-23 Ami阿格罗林茨三聚氰胺国际有限公司 Plastic products with high strength and flexibility
CN101628645A (en) * 2009-07-30 2010-01-20 浙江大东南包装股份有限公司 Antibacterial BOPP/PP food composite package film and preparation method
CN102850678A (en) * 2012-09-20 2013-01-02 吴江市天源塑胶有限公司 High-strength conductive plastic

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106476385A (en) * 2016-12-09 2017-03-08 闽南师范大学 A kind of Novel antibacterial CPP thin film and preparation method thereof

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Application publication date: 20161026