CN1282756A - Composite pipe material for building - Google Patents
Composite pipe material for building Download PDFInfo
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- CN1282756A CN1282756A CN 99113931 CN99113931A CN1282756A CN 1282756 A CN1282756 A CN 1282756A CN 99113931 CN99113931 CN 99113931 CN 99113931 A CN99113931 A CN 99113931A CN 1282756 A CN1282756 A CN 1282756A
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- composite pipe
- pipe material
- building according
- polypropylene
- oxidation inhibitor
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Abstract
A composite pipe material for building is composed for high-weatherability flame-retarding polypropene layer as external layer, glass fibre reinforced polypropene layer as middle layer and sanitary-class high-glossy polypropene layer as internal layer. Its advantages are high antiageing nature, high photogradation and fire-resistance, high strength and rigidity, low flow resistance and low noise.
Description
Current era, novel material emerges in an endless stream, and is embodying particularly evidently aspect the chemical building material of building trade.With the pipeline material of chemical building material, it is mainly used in the transmission of various liquid or gas, and its material develops into plastic material of today, matrix material by initial cast iron materials.No matter, still on performance, all being greatly improved from the material application facet, common having be hard-polyvinyl chloride (U-PVC) pipe, crosslinked polyethylene (XPLE) pipe, aluminum-plastic laminated tube.
The U-PVC pipeline material occurs as the substitute of cast iron pipe.This strength of materials height, corrosion-resistant, flame retardant properties good, low price, but it has several fatal weakness: temperature resistant grade is low, and the life-time service temperature is no more than 65 ℃; The frost resistance aspect, the U-PVC pipe can not be at the sub-zero temperature life-time service; The shock resistance aspect, UPVC manages because employing glue is bonding, poor-performing; And polyvinyl chloride is polymerized by vinylchlorid (VCM), and inevitably VCM has residual existence, and VCM is the carcinogenic substance that has been identified, therefore limited the application that PVC becomes the water service pipe material; The U-PVC pipe adds the additive of heavy metal aborning in addition, from environmental angle, causes medium pollution easily.From present domestic situation, the U-PVC pipe generally only limits to the conveying of undrinkable water under the normal temperature.
Aluminum-plastic laminated tube is that employing polyethylene (PE) or crosslinked polyethylene (XPLE) are ectonexine, and intermediate core layer folder one welding aluminum pipe is bonding at aluminum pipe surfaces externally and internally coating glue paste and plastic layer, by the pipeline material of composite co-extruding technological forming.This composite pipe material material mechanical property is good, but it also has weak point, mainly shows: heatproof aspect, life-time service temperature are 85 ℃, if temperature is too high, the difference of the SMIS aluminium lamination and the inside and outside PE layer coefficient of expansion easily causes the interlayer breakaway; Poor fire; From environmental angle, because the centre is the non-degradable aluminium lamination, its rubbish causes environmental pollution easily; From in price, material price costliness, and production unit, the many dependence on import of technology at present, production cost height.
Crosslinked polyethylene (XPLE) adopts cross-linking method, make PE form the space reticulated structure, thereby had good comprehensive physical and mechanical properties, thermal characteristics and wholesomeness, but the XPLE material does not have flame retardant resistance, and environment for use is had certain requirement; And price is more than a times of general polypropylene material.
Purpose of the present invention is exactly to provide a kind of composite pipe material for building in order to overcome the defective that above-mentioned prior art exists, and it has excellent flame-retardant performance, anti-aging, anti-photodegradation, and has the characteristic of high just high-strength, inwall high glossiness.
Purpose of the present invention can realize in the following manner:
A kind of composite pipe material for building is characterized in that: it is composited by trilaminate material, the prescription of every layer material following (weight part, down together):
A. outer
Polypropylene 445～580
Inorganic filler 100～200
Oxidation inhibitor 3～7
Thermo-stabilizer 3～6
Photostabilizer 2～10
Auxiliary agent 1～2
B. middle layer
Polypropylene 500～700
Glass fibre 200～400
Compatilizer 30～120
Coupling agent 10～15
Oxidation inhibitor 1～5
Auxiliary agent 1～10
C. internal layer
Polypropylene 30～70
Inorganic filler 20～50
Oxidation inhibitor 0.3～0.7
Antiseptic-germicide 0.2～0.5
Auxiliary agent 0.1～0.4
Described skin also comprises fire retardant 315～360, and described fire retardant comprises bromide fire retardant 130～150, chlorine-based flame retardant 110～125, Sb system fire retardant 75～85.
Described outer field inorganic filler is a superfine talcum powder.
The oxidation inhibitor of described skin and internal layer comprises main anti-Hinered phenols, auxilliary anti-sulfur compound or phosphorous acid esters.
Described thermo-stabilizer comprises barium stearate, cadmium stearate.
Described compatilizer is the oligopolymer of the graft polymerization of polypropylene and unsaturated acid anhydride.
Described coupling agent is silicane or titante coupling agent.
The oxidation inhibitor in described middle layer is Hinered phenols antioxidant.
The weighting material of described internal layer comprises 325～600 purpose talcum powder, mica powder, inorganicss such as the lime carbonate more than 1250 orders, barium sulfate.
Described auxiliary agent is a calcium stearate.
Compared with prior art, the present invention proposes a kind of novel composite building material, this material has taken into full account the environment for use requirement as material of construction, has satisfied simultaneously and has built required mechanical strength requirement, composite inner has adopted the high glossiness anti-biotic material, has satisfied hygienic requirements.This novel composite material is to be that the base-material modification gets low price with the polypropylene.Because polypropylene material density is a kind of of minimum in the plastics, and is therefore in light weight, and can be to the stressed difficulty that causes of upholder.Polyacrylic Applicable temperature can fully satisfy the requirement of hot-water line in the material of construction up to 120 ℃.
The 3-layer composite material that the present invention proposes, skin is the weather-resistance flame-retardant polypropylene layer, and the centre is the glass-reinforced polypropylene layer, and internal layer is a high gloss health grade polypropylene layer.This compound structure is to consider to have the characteristic that integrates numerous advantages from usability and suitability as material of construction.Its cladding material directly contacts with external environment, and material has well anti-aging, anti-photodegradation.Consider the outside atmosphere that material of construction uses, so cladding material also has flame retardant resistance, to reach the fp requirement.The intermediary glass-reinforced polypropylene, the mechanical property of having given the high-strength Gao Gang in middle layer.As the pipeline material material, it is low that the high gloss antibacterial polypropylene of internal layer can show surface tension, prevents fouling, and resistance is little, and flow is big, and noise is little, and the while is breed bacteria not, meets the GB9687-88 hygienic requirements.This matrix material outer, in, interior three layers can adopt composite co-extruding technology because three layers be polypropylene modified material all, consistency is fine, does not need to adopt technologies such as bonding, has simplified the requirement to technology.
Below in conjunction with specific embodiment, the present invention is described in further detail:
Embodiment 1
A. outer flame-proof weather-resisting polypropylene material material formula (weight unit: kilogram, down together):
| Component | Weight |
| Polypropylene decabromodiphynly oxide chlorinatedpolyethylene (CPE) Sb 2O 3Superfine talcum powder antioxidant 1010 oxidation inhibitor DSTP barium stearate cadmium stearate photostabilizer auxiliary agent | ????570 ????135 ????110 ?????85 ????100 ?????1 ?????2 ?????2 ?????1 ?????5 ?????2 |
After mixing according to the above ratio, the feeding length-to-diameter ratio is not less than blend granulation in 28: 1 the parallel dual-screw extruding machine, and extrusion temperature is not less than 200 ℃.
The material of utilization present embodiment blend has good flame retardant resistance, reaches the V-0 level, can be suitable for Flammable atmosphere, and weathering resistance reaches resist oxygen aging more than 800 hours after tested simultaneously, meets the outdoor environment service requirements fully.This material simply supported beam notched Izod impact strength is 8.2KJ/m
2, have shock resistance preferably, tensile strength 27.5MPa, (230 ℃, 2.16Kg) 1.3-1.4g/10min can satisfy the requirement of squeezing pipe to melting index.
B. the firm high-strength polypropylene material material formula of floor height in the middle of:
| Component | Weight |
| Polypropylene glass polypropylene-g-MAH antioxidant 1010 KH-550 | ????500 ????400 ????100 ?????1 ?????10 |
This mixture is matrix resin with the homo-polypropylene, at first adds a kind of homemade compatilizer PP-g-MAH, has increased the interface binding power between glass and the polypropylene, makes between glass and the polypropylene to combine with stronger chemical bond, has improved the performance of material.Silane resin acceptor kh-550 not only makes glass and polyacrylic interface binding power strengthen, and glass is cross-linked with each other in polypropylene, makes material become netted system, has effectively reduced molten finger, and has improved the performance of material.The simply supported beam notched Izod impact strength of this material reaches 17.77KJ/m
2, tensile strength reaches 97.21MPa, and it has played good enhancement to whole matrix material.
C. internal layer high gloss antibacterial polypropylene material is filled a prescription
| Component | Weight |
| Polypropylene talcum powder (325 orders, 1%KH-550 handles) treated carbonates (nano level) antiseptic-germicide antioxidant 1010 oxidation inhibitor DSTP calcium stearate | ????600 ????250 ????150 ?????3 ?????1 ????2．5 ?????1 |
After above raw material mixed by described proportioning, the feeding length-to-diameter ratio was not less than blend granulation in 28: 1 the parallel dual-screw extruding machine.Extrusion temperature is not less than 210 ℃.
Resulting tensile strength of material 27.4MPa, simply supported beam notched Izod impact strength 6.5KJ/m
2, the heat oxygen aging resistance time is more than 800 hours.As seen, adopt the method that matrix is composite, filler is composite and antioxidant system is composite, we have obtained the reasonable material of rigidity, toughness, and the ability of this material heat oxygen aging resistance is also very strong.Has certain germ-killing efficiency simultaneously.Because used the different inorganics of order number mutually composite in the filler, and the dissemination of dispersion agent, when obtaining better mechanical property, inorganics that the order number is higher and dispersion agent all make bill of material reveal glossiness and slickness preferably.
Adopt the matrix material of above three-layer polypropylene coextrusion, overcome existing single defective of planting material, have excellent comprehensive performances.
Embodiment 2,3
A. outer flame-proof weather-resisting polypropylene material material formula (weight unit: kilogram, down together):
After mixing according to the above ratio, the feeding length-to-diameter ratio is not less than blend granulation in 28: 1 the parallel dual-screw extruding machine, and extrusion temperature is not less than 200 ℃.
The material of utilization present embodiment blend has good flame retardant resistance, reaches the V-0 level, can be suitable for Flammable atmosphere, and weathering resistance reaches resist oxygen aging more than 800 hours after tested simultaneously, meets the outdoor environment service requirements fully.This material simply supported beam simply supported beam notched Izod impact strength is 10～10.5KJ/m
2, have shock resistance preferably, tensile strength 28.5～31MPa, (230 ℃, 2.16Kg) 1.0-1.2g/10min can satisfy the requirement of squeezing pipe to melting index.
B. the firm high-strength polypropylene material material formula of floor height in the middle of:
This mixture is matrix resin with the homo-polypropylene, at first adds a kind of homemade compatilizer PP-g-MAH, has increased the interface binding power between glass and the polypropylene, makes between glass and the polypropylene to combine with stronger chemical bond, has improved the performance of material.Silane resin acceptor kh-550 not only makes glass and polyacrylic interface binding power strengthen, and glass is cross-linked with each other in polypropylene, makes material become netted system, has effectively reduced molten finger, and has improved the performance of material.The simply supported beam notched Izod impact strength of this material reaches 17.77KJ/m
2, tensile strength reaches 97.21MPa, and it has played good enhancement to whole matrix material.
C. internal layer high gloss antibacterial polypropylene material is filled a prescription
After above raw material mixed by described proportioning, the feeding length-to-diameter ratio was not less than blend granulation in 28: 1 the parallel dual-screw extruding machine.Extrusion temperature is not less than 210 ℃.
Resulting tensile strength of material 29.22～34.56MPa, simply supported beam notched Izod impact strength 7.38～7.64KJ/m
2, the heat oxygen aging resistance time is more than 800 hours.As seen, adopt the method that matrix is composite, filler is composite and antioxidant system is composite, we have obtained the reasonable material of rigidity, toughness, and the ability of this material heat oxygen aging resistance is also very strong.Has certain germ-killing efficiency simultaneously.Because used the different inorganics of order number mutually composite in the filler, and the dissemination of dispersion agent, when obtaining better mechanical property, inorganics that the order number is higher and dispersion agent all make bill of material reveal glossiness and slickness preferably.
Adopt the matrix material of above three-layer polypropylene coextrusion, overcome existing single defective of planting material, have excellent comprehensive performances.
Claims (10)
1. composite pipe material for building, it is characterized in that: it is composited by trilaminate material, the prescription of layers of material following (weight part, down with):
A. outer
Polypropylene 445～580
Inorganic filler 100～200
Oxidation inhibitor 3～7
Thermo-stabilizer 3～6
Photostabilizer 2～10
Auxiliary agent 1～2
B. middle layer
Polypropylene 500～700
Glass fibre 200～400
Compatilizer 30～120
Coupling agent 10～15
Oxidation inhibitor 1～5
Auxiliary agent 1～10
C. internal layer
Polypropylene 30～70
Inorganic filler 20～50
Oxidation inhibitor 0.3～0.7
Antiseptic-germicide 0.2～0.5
Auxiliary agent 0.1～0.4
2. a kind of composite pipe material for building according to claim 1, it is characterized in that: described skin also comprises fire retardant 315～360, described fire retardant comprises bromide fire retardant 130～150, chlorine-based flame retardant 110～125, Sb system fire retardant 75～85.
3. a kind of composite pipe material for building according to claim 1 is characterized in that: described outer field inorganic filler is a superfine talcum powder.
4. a kind of composite pipe material for building according to claim 1 is characterized in that: the oxidation inhibitor of described skin and internal layer comprises main anti-Hinered phenols, auxilliary anti-sulfur compound or phosphorous acid esters.
5. a kind of composite pipe material for building according to claim 1 is characterized in that: described thermo-stabilizer comprises barium stearate, cadmium stearate.
6. a kind of composite pipe material for building according to claim 1 is characterized in that: described compatilizer is the oligopolymer of the graft polymerization of polypropylene and unsaturated acid anhydride.
7. a kind of composite pipe material for building according to claim 1 is characterized in that: described coupling agent is silicane or titante coupling agent.
8. a kind of composite pipe material for building according to claim 1 is characterized in that: the oxidation inhibitor in described middle layer is Hinered phenols antioxidant.
9. a kind of composite pipe material for building according to claim 1 is characterized in that: the weighting material of described internal layer comprises 325～600 purpose talcum powder, mica powder, inorganicss such as the lime carbonate more than 1250 orders, barium sulfate.
10. a kind of composite pipe material for building according to claim 1 is characterized in that: described auxiliary agent is a calcium stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113931 CN1210342C (en) | 1999-07-29 | 1999-07-29 | Composite pipe material for building |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113931 CN1210342C (en) | 1999-07-29 | 1999-07-29 | Composite pipe material for building |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1282756A true CN1282756A (en) | 2001-02-07 |
| CN1210342C CN1210342C (en) | 2005-07-13 |
Family
ID=5277069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99113931 Expired - Lifetime CN1210342C (en) | 1999-07-29 | 1999-07-29 | Composite pipe material for building |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1210342C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1295274C (en) * | 2004-12-29 | 2007-01-17 | 刘明春 | Recovery and shaping process of polypropylene composite waste material |
| CN100419018C (en) * | 2006-02-08 | 2008-09-17 | 华东理工大学 | Swell type combustion-proof glass fiber reinforced polypropylene composite material and its preparation method |
| CN101270211B (en) * | 2007-03-21 | 2011-04-20 | 上海海隆赛能新材料有限公司 | Corrosion-protecting steel pipeline polypropylene jacket material with three-layer sandwich and preparing method |
| CN103009760A (en) * | 2011-09-26 | 2013-04-03 | 合肥杰事杰新材料股份有限公司 | Composite polyolefin material, preparation method and use of composite polyolefin material |
| CN103554666A (en) * | 2013-10-29 | 2014-02-05 | 上海骏齐新材料科技有限公司 | Mica-reinforced polypropylene composite material and preparation method thereof |
| CN106042561A (en) * | 2016-06-22 | 2016-10-26 | 太仓市兴益披覆有限公司 | Antibacterial biomass plastic product |
| CN110014696A (en) * | 2019-03-01 | 2019-07-16 | 日丰企业集团有限公司 | PA tube of high-strength anti-flaming and preparation method thereof |
| CN110529667A (en) * | 2019-08-16 | 2019-12-03 | 禹州市建通塑胶管业有限公司 | A kind of super-silent pp drainage pipe |
| CN111336324A (en) * | 2019-12-31 | 2020-06-26 | 日丰企业集团有限公司 | High-performance PP composite heat-insulation pipe |
| CN111572103A (en) * | 2020-04-13 | 2020-08-25 | 日丰企业集团有限公司 | Polypropylene composite thermal insulation pipe |
| CN114456492A (en) * | 2022-02-24 | 2022-05-10 | 禹州市建通塑胶管业有限公司 | FRPP ultra-silent drain pipe |
-
1999
- 1999-07-29 CN CN 99113931 patent/CN1210342C/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1295274C (en) * | 2004-12-29 | 2007-01-17 | 刘明春 | Recovery and shaping process of polypropylene composite waste material |
| CN100419018C (en) * | 2006-02-08 | 2008-09-17 | 华东理工大学 | Swell type combustion-proof glass fiber reinforced polypropylene composite material and its preparation method |
| CN101270211B (en) * | 2007-03-21 | 2011-04-20 | 上海海隆赛能新材料有限公司 | Corrosion-protecting steel pipeline polypropylene jacket material with three-layer sandwich and preparing method |
| CN103009760A (en) * | 2011-09-26 | 2013-04-03 | 合肥杰事杰新材料股份有限公司 | Composite polyolefin material, preparation method and use of composite polyolefin material |
| CN103009760B (en) * | 2011-09-26 | 2016-02-03 | 合肥杰事杰新材料股份有限公司 | A kind of compound polyolefin material and its production and use |
| CN103554666A (en) * | 2013-10-29 | 2014-02-05 | 上海骏齐新材料科技有限公司 | Mica-reinforced polypropylene composite material and preparation method thereof |
| CN106042561A (en) * | 2016-06-22 | 2016-10-26 | 太仓市兴益披覆有限公司 | Antibacterial biomass plastic product |
| CN110014696A (en) * | 2019-03-01 | 2019-07-16 | 日丰企业集团有限公司 | PA tube of high-strength anti-flaming and preparation method thereof |
| CN110529667A (en) * | 2019-08-16 | 2019-12-03 | 禹州市建通塑胶管业有限公司 | A kind of super-silent pp drainage pipe |
| CN111336324A (en) * | 2019-12-31 | 2020-06-26 | 日丰企业集团有限公司 | High-performance PP composite heat-insulation pipe |
| CN111572103A (en) * | 2020-04-13 | 2020-08-25 | 日丰企业集团有限公司 | Polypropylene composite thermal insulation pipe |
| CN114456492A (en) * | 2022-02-24 | 2022-05-10 | 禹州市建通塑胶管业有限公司 | FRPP ultra-silent drain pipe |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1210342C (en) | 2005-07-13 |
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Owner name: HEFEI JIESHIJIE NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: JIESHIJIE NOVEL MATERIALS CO., LTD, SHANGHAI Effective date: 20060915 |
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Address after: 230601 Hefei economic and Technological Development Zone, Anhui Lianhua Road, No. 2388 Patentee after: Hefei Genius New Materials Co., Ltd. Address before: 201109 Minhang District North Road, Shanghai, No. 800 Patentee before: Hefei Genius New Materials Co., Ltd. |
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Denomination of invention: Composite pipe material for building Effective date of registration: 20150205 Granted publication date: 20050713 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000004 |
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Denomination of invention: Composite pipe material for building Effective date of registration: 20160415 Granted publication date: 20050713 Pledgee: Hefei Heng Hai investment holding group company Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000015 |
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