CN107227622A - The preparation method of the super soft finishing agent of organic block silk - Google Patents
The preparation method of the super soft finishing agent of organic block silk Download PDFInfo
- Publication number
- CN107227622A CN107227622A CN201710451824.4A CN201710451824A CN107227622A CN 107227622 A CN107227622 A CN 107227622A CN 201710451824 A CN201710451824 A CN 201710451824A CN 107227622 A CN107227622 A CN 107227622A
- Authority
- CN
- China
- Prior art keywords
- finishing agent
- super soft
- degrees celsius
- soft finishing
- organic block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to textile cleaning agent technical field, preparation method of the organic block silk with super soft finishing agent is specifically disclosed, step 1, material prepare:Raw material are allyl polyethenoxy ether FB 2, and molecular weight is 1000, amido silicon oil molecular weight 2500.Step 2, heating, mixed melting is carried out using smelting furnace to allyl polyethenoxy ether FB 2, amido silicon oil, wherein, melting temperature is 60 degrees Celsius 70 degrees Celsius, and the melting time is 3.2 hours 2.5 hours.Step 3, arranged using infusion process machine, flow is examined to impregnate super soft finishing agent 1% 2% → de- liquid → drying is → whole to scald →.The organic block silk of the present invention is with super soft finishing agent beneficial effect:Polyether-based revolutionizes the fixation code name of organosilicon " hydrophobicity ", the problem of solving emulsion floating oil, simplifies emulsifying process, and the fabric after ternary polymerization silicone finish also has good soil resistant and antistatic behaviour;Polyether segment is embedded in molecule, can assign finish fabric good hydrophily.
Description
Technical field
The invention belongs to textile cleanser applied technical field, and in particular to organic block silk is with super soft finishing agent
Preparation method.
Background technology
Currently, foreign countries lead over the country in terms of the research of the multicomponent copolymerized and modified silicone softening agent of linearity block.4th
Be applied to for silicone softening agent on yarn fabric, often there is unique and excellent finishing effect, along with fibre process with
And the difference of fiber species, properties of product are even more ever-changing.Such excellent performance, also urgently China's researchers are complete
Face understands its molecular structure and characteristic, lifts its application performance, improves competition of China's silicone softening agent in international market
Position.
The content of the invention
Goal of the invention:It is an object of the invention to provide preparation method of the organic block silk with super soft finishing agent, polyethers
Base revolutionizes the fixation code name of organosilicon " hydrophobicity ", and the problem of solving emulsion floating oil simplifies emulsifying process, and warp
Fabric after ternary polymerization silicone finish also has good soil resistant and antistatic behaviour.
Technical scheme:The present invention provides the preparation method of the super soft finishing agent of organic block silk, and step 1, material are accurate
It is standby:Raw material are allyl polyethenoxy ether FB-2, and molecular weight is 1000, amido silicon oil molecular weight 2500.Step 2, heating, profit
Mixed melting is carried out to allyl polyethenoxy ether FB-2, amido silicon oil with smelting furnace, wherein, melting temperature is 60 degree Celsius -70
Degree Celsius, the melting time is -3.2 hours 2.5 hours.Step 3, arranged using infusion process machine, flow is super soft whole to impregnate
→ whole to scald → inspection of agent 1%-2% → de- liquid → drying is managed, wherein, 85 degrees Celsius -90 degrees Celsius of drying temperature, time are 15min-
20min。
The technical program, composition principle provides polyether segment for end epoxidized polyether, amido silicon oil there is provided it is hydrophobic into
Point,
N=14, m=6
Due to there is-NH in organic block molecule2, can be had an effect with fabric face group, so as to form firm orientation
And adsorption layer so that product flexibility, elasticity, fastness are greatly improved, and in the polyether segment in molecule containing EO and
PO bases, EO bases can strengthen the hydrophily of product, and the amount ratio of EO and PO bases and its position can flexible modulations.
The technical program, melting temperature is 65 degrees Celsius in the step 2, and the melting time is 3 hours, obtains product light
Yellow liquid, product has automatic emulsifying performance, without separately adding emulsifying agent, prevents the floating oil phenomenon during arranging from occurring.
The technical program, in the step 3,88 degrees Celsius of drying temperature, time are 18min.
Compared with prior art, the beneficial effect of the production method of a kind of pro-skin aloe Chinese angelica root health silk external member of the invention
Fruit is:1st, polyether-based revolutionizes the fixation code name of organosilicon " hydrophobicity ", and the problem of solving emulsion floating oil simplifies
Emulsifying process, and fabric after ternary polymerization silicone finish also has good soil resistant and antistatic behaviour;2nd, in molecule
Polyether segment is embedded in, can assign finish fabric good hydrophily.Compared with traditional organosilicon, because of polyether block amino-type
Modified organic silicon arrange to having in silk fabric " under the fabric high temperature after its arrangement without obvious xanthochromia, softness very well,
Washability is good ".
Embodiment
With reference to specific embodiment, the present invention is furture elucidated.
Embodiment
The preparation method of the super soft finishing agent of organic block silk of the present invention, step 1, material prepare:Raw material are
Allyl polyethenoxy ether FB-2, molecular weight is 1000, amido silicon oil molecular weight 2500.Step 2, heating, using smelting furnace to alkene
Propyl group APEO FB-2, amido silicon oil carry out mixed melting, wherein, melting temperature is 60 degrees Celsius -70 degrees Celsius, melting
Time is -3.2 hours 2.5 hours.Step 3, arranged using infusion process machine, flow for impregnate super soft finishing agent 1%-2% →
De- liquid → drying is → whole to scald → to be examined, wherein, 85 degrees Celsius -90 degrees Celsius of drying temperature, time are 15min-20min.
The composition principle of the present invention provides polyether segment for end epoxidized polyether, and amido silicon oil provides hydrophobic ingredient,
N=14, m=6
Due to there is-NH in organic block molecule2, can be had an effect with fabric face group, so as to form firm orientation
And adsorption layer so that product flexibility, elasticity, fastness are greatly improved, and in the polyether segment in molecule containing EO and
PO bases, EO bases can strengthen the hydrophily of product, and the amount ratio of EO and PO bases and its position can flexible modulation, these all make
The superiority for obtaining ternary polymerization organosilicon becomes apparent from:Such as polyether-based revolutionizes the fixation code name of organosilicon " hydrophobicity ",
The problem of solving emulsion floating oil, simplifies emulsifying process, and the fabric after ternary polymerization silicone finish also have it is good
Soil resistant and antistatic behaviour.Melting temperature is 65 degrees Celsius in the step 2, and the melting time is 3 hours, obtains product yellowish
Color liquid, product has automatic emulsifying performance, without separately adding emulsifying agent, prevents the floating oil phenomenon during arranging from occurring.
Polyoxyethylene EO and polyoxypropylene PO segments in the ratios of EO and PO segments in polyether segment, polyetheramine segment
The factors such as ratio, the size of Si-O chain segment molecular weights, all with the performance of super soft finishing agent can cause shadow to organic block silk
Ring, the present invention is using allyl polyethenoxy ether FB-2(Molecular weight is 1000), amido silicon oil molecular weight 2500, reaction temperature 65
DEG C, time 3h obtains product weak yellow liquid, and product has automatic emulsifying performance, without separately plus emulsifying agent, during preventing arrangement
Floating oil phenomenon occur.
Finishing technique:Infusion process:Dipping(Super soft finishing agent 1%-2%)→ take off liquid → 85-90 DEG C of drying, 15-20min → whole
Scald → examine.
Polyether block amino-type modified organic silicon softening agent is exactly a kind of linear structure of unprotected side chain, and main chain shows one kind
The spiral shape linear chain structure of easy flexing so that main chain is sufficiently flexible;Orientation be arranged in neat closely methyl layer because it is mutual it
Between have very big intermolecular distance so that-CH3The very low ,-CH around the activation energy needed for the rotation of Si-O keys3It is free to rotation
Turn, vibration, and then cause that the interaction force between polysiloxane chain and chain is smaller, surface tension is very low, works as polysiloxane chain
Cover after fiber surface, it is possible to significantly reduce the free energy of fiber surface, whole system is tended towards stability, film forming is strong.
In addition polyether segment is embedded in molecule, can assigns finish fabric good hydrophily.Compared with traditional organosilicon, because of polyethers
Block amino-type modified organic silicon is arranged to having in silk fabric " without obvious xanthochromia, soft under the fabric high temperature after its arrangement
It is soft can very well, washability it is good " etc. series of advantages.
Performance:4-5 grades of feel(Washing ten times), obtain sliding soft fluffy flexible feel.Contain amino, amino in molecule
Anchoring ability with fiber is very strong, improves washing fastness.
The environmental suitability of table 1 super soft finishing agent
Table 2 is organized the hydrophily of fabric
Domestic polyether modified silicon oil | External polyether modified silicon oil | Super soft finishing agent | |
Hydrophily, S | 2 | 1 | 1 |
The as shown by data of table 2, the hydrophilicity of super soft finishing agent can reach the hydrophilic level of external polyether modified silicon oil
Table 3 is organized the Huang of fabric(Color)Denaturation
△ Wg represent whiteness difference, and absolute value is bigger to represent that whiteness changes bigger, △ YIWhite fabrics xanthochromia value is represented, it is smaller to get over
It is good;△ L represent dyed fabric lightness changing value, and △ E represent dyed fabric standard deviation, the smaller the better.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as the present invention's
Protection domain.
Claims (4)
1. the organic block silk preparation method of super soft finishing agent, it is characterised in that:Comprise the following steps,
Step 1, material prepare:Raw material are allyl polyethenoxy ether FB-2, and molecular weight is 1000, amido silicon oil molecular weight
2500;
Step 2, heating, mixed melting is carried out using smelting furnace to allyl polyethenoxy ether FB-2, amido silicon oil, wherein, melting
Temperature is 60 degrees Celsius -70 degrees Celsius, and the melting time is -3.2 hours 2.5 hours;
Step 3, being arranged using infusion process machine, flow scalds to impregnate super soft finishing agent 1%-2% → de- liquid → drying → whole →
Examine, wherein, 85 degrees Celsius -90 degrees Celsius of drying temperature, time are 15min-20min.
2. the organic block silk according to claim 1 preparation method of super soft finishing agent, it is characterised in that:Synthesis
Principle provides polyether segment for end epoxidized polyether, and amido silicon oil provides hydrophobic ingredient,
N=14, m=6
Due to there is-NH in organic block molecule2, can and fabric face group have an effect so that formed firm orientation and
Adsorption layer so that product flexibility, elasticity, fastness are greatly improved, and contain EO and PO in the polyether segment in molecule
Base, EO bases can strengthen the hydrophily of product, and the amount ratio of EO and PO bases and its position can flexible modulations.
3. the organic block silk according to claim 1 preparation method of super soft finishing agent, it is characterised in that:It is described
Melting temperature is 65 degrees Celsius in step 2, and the melting time is 3 hours.
4. the organic block silk according to claim 1 preparation method of super soft finishing agent, it is characterised in that:It is described
In step 3,88 degrees Celsius of drying temperature, time are 18min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710451824.4A CN107227622A (en) | 2017-06-15 | 2017-06-15 | The preparation method of the super soft finishing agent of organic block silk |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710451824.4A CN107227622A (en) | 2017-06-15 | 2017-06-15 | The preparation method of the super soft finishing agent of organic block silk |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107227622A true CN107227622A (en) | 2017-10-03 |
Family
ID=59936418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710451824.4A Pending CN107227622A (en) | 2017-06-15 | 2017-06-15 | The preparation method of the super soft finishing agent of organic block silk |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107227622A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108085973A (en) * | 2018-01-13 | 2018-05-29 | 成光耀 | A kind of nti-freckle silk mask of high-moisture-retention |
CN111748098A (en) * | 2020-08-06 | 2020-10-09 | 广州市斯洛柯高分子聚合物有限公司 | Amino silicone oil and preparation method thereof |
EP3816229A4 (en) * | 2018-06-28 | 2022-04-06 | Shin-Etsu Chemical Co., Ltd. | Silicone composition and fiber treatment agent using same |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008081875A (en) * | 2006-09-27 | 2008-04-10 | Ohara Palladium Kagaku Kk | New emulsion for fiber processing and fiber product using the same |
CN102031698A (en) * | 2010-11-19 | 2011-04-27 | 浙江华晟化学制品有限公司 | Preparation method of non-ironing finishing agent of modified self-crosslinking organosilicon anti-wrinkle microemulsion |
CN102585229A (en) * | 2011-12-27 | 2012-07-18 | 华东理工大学 | Polyether/aminopolysiloxane block copolymer and use thereof |
CN102911367A (en) * | 2012-11-12 | 2013-02-06 | 浙江汉邦化工有限公司 | Preparation method of cross-linked block amino-modified silicone oil |
CN103215816A (en) * | 2012-01-20 | 2013-07-24 | 中国中化股份有限公司 | Organosilicone softening agent and preparation method |
CN104086779A (en) * | 2014-07-02 | 2014-10-08 | 佛山市传化富联精细化工有限公司 | Super-soft/smooth block silicon oil and preparation method thereof |
CN105237776A (en) * | 2014-07-10 | 2016-01-13 | 广州市延广化学工业有限公司 | Synthetic method for super-soft hydrophilic polyester silicone oil and epoxy active polyester intermediate thereof |
CN106146856A (en) * | 2016-08-03 | 2016-11-23 | 清远市宏图助剂有限公司 | A kind of terpolymer block hydrophilic amino silicone oil and its preparation method and application |
CN106397776A (en) * | 2016-08-30 | 2017-02-15 | 浙江科峰有机硅有限公司 | Double amino type block polyether amino silicone oil and preparation method thereof |
-
2017
- 2017-06-15 CN CN201710451824.4A patent/CN107227622A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008081875A (en) * | 2006-09-27 | 2008-04-10 | Ohara Palladium Kagaku Kk | New emulsion for fiber processing and fiber product using the same |
CN102031698A (en) * | 2010-11-19 | 2011-04-27 | 浙江华晟化学制品有限公司 | Preparation method of non-ironing finishing agent of modified self-crosslinking organosilicon anti-wrinkle microemulsion |
CN102585229A (en) * | 2011-12-27 | 2012-07-18 | 华东理工大学 | Polyether/aminopolysiloxane block copolymer and use thereof |
CN103215816A (en) * | 2012-01-20 | 2013-07-24 | 中国中化股份有限公司 | Organosilicone softening agent and preparation method |
CN102911367A (en) * | 2012-11-12 | 2013-02-06 | 浙江汉邦化工有限公司 | Preparation method of cross-linked block amino-modified silicone oil |
CN104086779A (en) * | 2014-07-02 | 2014-10-08 | 佛山市传化富联精细化工有限公司 | Super-soft/smooth block silicon oil and preparation method thereof |
CN105237776A (en) * | 2014-07-10 | 2016-01-13 | 广州市延广化学工业有限公司 | Synthetic method for super-soft hydrophilic polyester silicone oil and epoxy active polyester intermediate thereof |
CN106146856A (en) * | 2016-08-03 | 2016-11-23 | 清远市宏图助剂有限公司 | A kind of terpolymer block hydrophilic amino silicone oil and its preparation method and application |
CN106397776A (en) * | 2016-08-30 | 2017-02-15 | 浙江科峰有机硅有限公司 | Double amino type block polyether amino silicone oil and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108085973A (en) * | 2018-01-13 | 2018-05-29 | 成光耀 | A kind of nti-freckle silk mask of high-moisture-retention |
EP3816229A4 (en) * | 2018-06-28 | 2022-04-06 | Shin-Etsu Chemical Co., Ltd. | Silicone composition and fiber treatment agent using same |
CN111748098A (en) * | 2020-08-06 | 2020-10-09 | 广州市斯洛柯高分子聚合物有限公司 | Amino silicone oil and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104650364B (en) | A kind of preparation method of hyperbranched polyether amino block organosilicon | |
CN102643435B (en) | Supersoft hydrophilic block silicone oil compound and preparation method thereof | |
CN104086779B (en) | Sliding block silicone oil of a kind of ultra-soft and preparation method thereof | |
CN107227622A (en) | The preparation method of the super soft finishing agent of organic block silk | |
CN104072783B (en) | A kind of preparation method of superslide hydrophilic quaternary ammonium modified organic silicon copolymer | |
US4559056A (en) | Process for treating textile materials with silicone-containing composition | |
CN102505496B (en) | Aminosilicone durable hydrophilic potentiating agent, and preparation method and application thereof | |
CN102644200A (en) | Super-soft finishing agent of silicone oil | |
CN109535428B (en) | Polyammonium modified polyether silicone oil and preparation method and application thereof | |
CN107129578A (en) | The preparation method of network structure amino-modified silicone oil finishing agent | |
CN105220506B (en) | A kind of block polyether eiastomeric silicone softening agent and its preparation method and application | |
CN105694046A (en) | Preparation method of highly-branched block polyether-aminosiloxane finishing agent | |
CN107083683A (en) | A kind of preparation method of hydrophilic smooth organic silicone finishing agent | |
CN109403048A (en) | A kind of cotton hydrophilic block polyethers amido silicon oil and preparation method thereof | |
CN103025951A (en) | Method for producing antibacterial fibers, antibacterial fibers and antibacterial processing agent for fibers | |
CN105694062A (en) | Cross-linked structure dendritic amino silicone oil and preparation method thereof | |
CN102643436B (en) | Supersoft hydrophilic block silicone oil intermediate compound and preparation method thereof | |
CN102634036A (en) | Novel linear amino and polyester modified organosilicon compound for textiles | |
CN107761397A (en) | One kind suppression yellowing additive and preparation method thereof | |
CN107724086A (en) | A kind of silicone softening agent and preparation method thereof | |
CN114561811A (en) | Wear-resistant cloth and preparation method thereof | |
KR20110014144A (en) | Low viscosity, high molecular weight linear random-block silicone polyalkyleneoxide copolymers | |
CN112726211A (en) | Preparation method of polyurethane modified organic silicon softening agent | |
CN104233601A (en) | Super-soft knitted fabric and processing method thereof | |
CN109267355A (en) | A kind of preparation method of silicone oil softener |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171003 |
|
WD01 | Invention patent application deemed withdrawn after publication |